Solar Cell Model Research Articles

Numerical modelling of an effective perovskite solar cell and PV-module for comparison analysis of organic and inorganic electron transport layers

The demand for energy has increased over the past few decades due to both the industrial sector's rapid development and the world's population growth. As we know, the main source of energy consists primarily of fossil fuels, which are expected to be exhausted very soon. Researchers were therefore urged to locate an alternative source of energy that may substitute for fossil fuels in order to meet the world's growing energy needs. Substitute energy sources, like renewable energy, can be used to reduce reliance on conventional energy. As its irradiance may produce electricity when struck by photovoltaic solar (PV) panels, one of the increasingly prevalent types of energy is solar energy. With the help of capacitance simulator software for solar cells (SCAPS-1D), a thorough study of comparison analysis for the design of more efficient, inexpensive, and non-toxic Ni/Cu2O/MASnI3/PCBM/FTO and Ni/Cu2O/MASnI3/WO3/FTO module configurations of solar cells was carried out, and the PVsyst photovoltaic software package investigated the dependence of solar panels on temperature and irradiation. In order to investigate how altering the electron transport layer (ETL) affects conversion efficiency, this work offers a perovskite solar cell simulation with both organic and inorganic ETLs. The absorber layer of perovskite and the HTL (hole transport layer) are maintained uniformly across all ETL configurations. This particular research takes into account the CH3NH3SnI3 absorber layer with Cu2O as HTL. In order to determine which cell combination has the maximum conversion efficiency, we examine the outcomes of both cell combinations. The SCAPS-1D software is used for all simulation work. The power conversion efficiency (PCE) for organic ETL was found to be 28.79%., in addition to a number of electrical parameters like short-circuit current density (Jsc) of 33.42 mA/cm2, open-circuit voltage (Voc) of 1.032 V, and fill factor (FF) of 83.43%. For inorganic ETL, PCE was 29.54%, Jsc was 34.28 mA/cm2, Voc was 1.033, and fill factor was 83.34%. The optimised layer thickness of HTL was 0.2 µm, for ETL it was 0.02 µm, and the CH3NH3SnI3 absorber layer was 0.8 µm. For a solar module with 72 cells with dimensions of 2.2×1.1 m, the results obtained from the simulation of electrical parameters derived from SCAPS-1D were configured in the PVsyst software package for panel performance.

Filtered spectrum modeling of high-performance perovskite tandem solar cells: Tailoring absorber properties and electron/hole transport layers for 31.55 % efficiency

In this study, the perovskite tandem solar cell (TPSC) has been accomplished using SCAPS-1D. The present study focuses on comprehensive exploration and detailed optimization using various strategies constructing a tandem device. To calculate high photovoltaic power conversion efficiency (PCE), the numerical analysis has been carried out for a wide-bandgap halide (WBH) FA0.75Cs0·25Pb(I0·8Br0.2)3 of bandgap 1.67eV and a Pb–Sn based narrow-bandgap halide (NBH) FA0.7MA0.3Pb0·5Sn0·5I3 of bandgap 1.22eV as absorber layer in top-cell (TCELL) and bottom-cell (BCELL) respectively. The WBH has huge potential as a front light absorber and the NBH based BCELL provides stability and high performance by accepting high and low energy photons respectively. This method mitigates thermalization and non-absorbed photon loss which results in the growth in PCE. The proposed work demonstrates the impact of active-layer thickness along with defect density on the solar-cell parameters. It has been observed that defect density is low for the optimal performance. An investigation for various electron transport medium (ETMs) and hole transport medium (HTMs) has been done to secure an optimum performing TCELL as well as BCELL. Using filtered-spectrum study along with current-matching method, every PV metric parameter has been analyzed after their deployment into tandem configuration. The numerical investigation has shown promising photovoltaic parameters with aa high open circuit voltage (VOC) of 2.33 V, a short circuit current density (JSC) of 17.07 mA/cm2, a fill factor (FF) of 79.34 % and PCE of 31.55 % in tandem configuration.

Design and optimization of Cs2SnI6 based inorganic perovskite solar cell model: numerical simulation

To overcome the drawbacks of high lead toxicity and poor corrosion resistance of lead-based perovskite solar cells (PSCs), and to compensate for the poor air stability of Sn2+ compound-based perovskite, Cs2SnI6 (Sn4+ compound) is selected as the absorber for the PSC in this study. Using FTO/ETL/Cs2SnI6/HTL/Au as the model, the high-performance non-toxic inorganic PSC structure is explored through theoretical simulation and calculation by SCAPS-1D. The conduction band offsets (CBO) and valence band offsets (VBO) of commonly used electron transport layer materials (ETMs), hole transport layer materials (HTMs), and Cs2SnI6 are calculated based on electron affinity potential (χ) and bandgap (E g ). Then, by analyzing the pn junction composed of ETL and HTL and the bandgap structure at the n-i, i-p interfaces, the most matching n-i-p planar heterojunction model, FTO/IGZO/Cs2SnI6/Cu2BaSnS4/Au, was selected. Finally, by analyzing and adjusting the material thickness, defect density of each layer, operation temperature, the optimal performance of PSC was determined to be 30.39% power conversion efficiency (PCE), 1.27 V open circuit voltage (V oc ), 28.46 mA cm−2 short circuit current (J sc ), and 84.02% fill factor (FF). A new and more efficient PSC is proposed in this study, providing some terrific clues for finding high-quality alternatives to lead-based PSCs.

Numerical modelling of CuBi2O4 thin film solar cells with SCAPS-1D: Bridging the gap ideal and non-ideal conditions

Several simulation studies have been conducted in copper bismuth oxide (CuBi2O4) based solar cells (SCs) using SCAPS-1D simulator, demonstrating a high photoconversion efficiency (PCE) of up to 33 % under ideal conditions. The introduction of non-ideal conditions such as resistive losses, optical, and recombination losses could provide the actual performance of the SCs. In this letter, we applied all nonideal conditions to the SCs structure consisting of Mo/CuBi2O4/TiO2/ITO/Al with varied thicknesses of absorber layer of CuBi2O4 from 50 nm to 2 µm and evaluated the photovoltaic (PV) parameters and PCE of SCs. Under ideal conditions, cells exhibited a PCE of 31.23 % and 3.55 % with an absorber layer thickness of 2000 nm and 50 nm, respectively. The introduction of nonideal conditions with an absorber layer thickness of 50 nm, exhibited a drastic reduction of PCE from 3.55 to 0.46 % and other PV parameters such as open circuit voltage (Voc) from 1.19 to 1.04 V, short circuit current density (Jsc) from 4.27 to 0.77 mA/cm2, and fill factor (FF) from 69.40 to 56.42 %. The increase in thickness of the absorber layer further to 2000 nm did not improve the PCE of SCs.

Parameter extraction of tandem solar cell model including radiative coupling from measured data of photovoltaic system

Parameter extraction of tandem solar cell model including radiative coupling from measured data of photovoltaic system

Unveiling the potential of lead-free Cs2AgBiBr6 (CABB) perovskite for solar cell application

The remarkable structural stability and optoelectronic properties of Cs2AgBiBr6 (CABB) material have positioned it as a highly appealing candidate for the solar cell application. The research focused on modeling and examination of perovskite solar cells utilizing Cs2AgBiBr6 as the active material, incorporating various electron transport layers (ETL) and hole transport layers (HTL). The device structure comprised of ITO/ZnO:Al/ZnO/Cs2AgBiBr6/Cu2O/Au. This optimized device, shows Voc = 1.67 V, Jsc = 15.52 mA/cm2, fill factor (FF) = 71.32 %, and conversion efficiency = 18.5 %. Active layer defects and trap charges at the interface of the CABB layer can trap photo generated electrons and holes, permitting higher carrier recombination. That reduces both open circuit voltage and short circuit current density. The conversion efficiency deteriorates from 18.5 % to 2.65 % when the defect density increases from 1 × 1010/cm3 from 1 × 1016/cm3. Also trap charges and multiple trap charges play a vital role in the performance of the CABB solar cell.

Numerical optimization of interface engineering parameters for a highly efficient HTL-free perovskite solar cell

Decarbonizing the world’s energy system has set the stage in favor of renewable energy alternatives such as the more reliable, abundant, inexhaustible, and sustainable solar energy. However, the photovoltaic technology faces significant stability, longevity, and scalability challenges. These difficulties can be overcome by judicious optimization of interfacial engineering of the solar cell architecture that will decrease the cost of fabrication and enhance the solar cell performance and durability. Herein, a comprehensive analysis of a novel high-performance hole transport layer-free (HTL-free) perovskite solar cell (PSC) of the configuration, ITO/PC61BM/CH3NH3SnI3/Pt, was investigated by device simulation while optimizing electron transport materials, metal back contacts, front contact materials, and buffer layers. The focus is on enhancing device performance by introducing various types of buffer layers, such as cadmium sulphide (CdS) in the proposed solar cell model. By fine-tuning the ETL layers and manipulating perovskite acceptor and donor densities, better device performance was achieved. Furthermore, the Mott-Schottky capacitance analysis yielded critical insights into the interface properties and dynamics of charge carriers within the solar cell structure. Optimizing back contacts also play a critical role in charge extraction and reduced recombination losses. Leveraging a sophisticated simulation platform, SCAPS-1D, the study assesses how design strategies impact photovoltaic electrical outcomes such as open-circuit voltage (Voc), power conversion efficiency (PCE), short-circuit current density (Jsc), and Fill factor (FF). The proposed HTL-free device posted remarkable results – PCE of 38.11 %, Jsc of 35.32 mAcm−2, FF of 88.67 %, and Voc of 1.2168 V. Accordingly, this work inspires the promising prospects of HTL-free PSCs in achieving robust solar harvesting capabilities while streamlining device affordability. Therefore, the proposed device architecture stimulates the journey towards affordable and high-performance scalable solar cell modules.

Device modeling and performance analysis of an all-inorganic lead-free Ag2BiI5 rudorffite-based solar cell with AgSCN as HTL via GPVDM simulation software

Device modeling and performance analysis of an all-inorganic lead-free Ag2BiI5 rudorffite-based solar cell with AgSCN as HTL via GPVDM simulation software

Modeling and performance investigation of novel inorganic Cs4CuSb2Cl12 nanocrystal perovskite solar cell using SCAPS-1D

For the next generation of photovoltaic devices, perovskite solar cells (PSCs) appear as a good choice because they are simple and convert energy to electricity very efficiently. Recent years have seen a great deal of interest in organic-inorganic lead halide perovskites due to their exceptional optoelectronic properties. Nonetheless, additional commercialization of the Pb element is still restricted by its inevitable toxicity. To address the instability and toxicity of the lead hybrid perovskite, it is imperative to produce entirely inorganic lead-free perovskite nanocrystals. Cs4CuSb2Cl12 offers promising qualities and strong stability against light, heat, and humidity to overcome these drawbacks. It possesses an efficient photo-generated carrier and good carrier mobility. In this study, a lead-free perovskite solar cell with the novel configuration of FTO/WS2/Cs4CuSb2Cl12/CuSbS2/Ni has been optimized using SCAPS-1D simulation software and investigates the potential of Cs4CuSb2Cl12 nanocrystal solar cell. The impact of different characteristics of charge transport materials on Cs4CuSb2Cl12 nanocrystal solar cells has been reported. Additionally, the study computationally optimizes the thickness of perovskite layer, doping concentration, defect density, and other input parameters to propose an effective PSC with power conversion efficiency of 23.10 %, Voc of 1.1675V, and FF of 83.33 %.

Efficient parameter extraction of photovoltaic models with a novel enhanced prairie dog optimization algorithm

The growing demand for solar energy conversion underscores the need for precise parameter extraction methods in photovoltaic (PV) plants. This study focuses on enhancing accuracy in PV system parameter extraction, essential for optimizing PV models under diverse environmental conditions. Utilizing primary PV models (single diode, double diode, and three diode) and PV module models, the research emphasizes the importance of accurate parameter identification. In response to the limitations of existing metaheuristic algorithms, the study introduces the enhanced prairie dog optimizer (En-PDO). This novel algorithm integrates the strengths of the prairie dog optimizer (PDO) with random learning and logarithmic spiral search mechanisms. Evaluation against the PDO, and a comprehensive comparison with eighteen recent algorithms, spanning diverse optimization techniques, highlight En-PDO’s exceptional performance across different solar cell models and CEC2020 functions. Application of En-PDO to single diode, double diode, three diode, and PV module models, using experimental datasets (R.T.C. France silicon and Photowatt-PWP201 solar cells) and CEC2020 test functions, demonstrates its consistent superiority. En-PDO achieves competitive or superior root mean square error values, showcasing its efficacy in accurately modeling the behavior of diverse solar cells and performing optimally on CEC2020 test functions. These findings position En-PDO as a robust and reliable approach for precise parameter estimation in solar cell models, emphasizing its potential and advancements compared to existing algorithms.

Modeling of Photovoltaic Characteristics of a TiO<sub>2</sub>/Porous-Si/Si-Based Heterojunction Solar Cell

This work is focused on the study of photosensitive structures based on porous Si and film TiO2, which are promising for solar energy. For numerical simulation of the transportation and accumulation of charge carriers in the considered heterostructure, the drift-diffusion approximation of the semiclassical approach was proposed. A device scheme of a solar cell model based on TiO2/porous-Si/Si heterostructures is proposed. Production of photoconverters of solar cells based on the TiO2/porous-Si/Si heterostructure can be carried out according to the standard method supplemented by additional technological operations. Ohmic contacts are formed in the upper and lower parts of the structure above the TiO2 and Si layers. The strip system of contacts is a contact grid, with hatching, the surface coefficient should not exceed 5%. The thickness of the applied layer of photoresist should be 1 μm. Using the PC1D program, the light characteristics of the fabricated structure were calculated (open circuit voltage VOC, short circuit current ISC, fill factor FF and efficiency η), and current-voltage characteristics were plotted. The influence of the thickness and doping level Nd and Na of porous Si and TiO2 layers on the productivity of a heterojunction solar cell TiO2/porous-Si/Si was studied in order to obtain a device with a good conversion efficiency. It was found that the energy conversion efficiency of a TiO2/porous-Si/Si solar cell can reach 22.5 %. Based on the optimized simulation conditions, it was found that the maximum solar cell efficiency is achieved at thicknesses of 100 and 200 nm and donor concentration of Nd=1∙1017 cm-3 and acceptor concentration of Na=1∙1018 cm-3 for TiO2 and porous Si buffer layer, accordingly.

Indoor photovoltaics: A numerical model of dye-sensitized solar cells based on indoor illumination for the Internet of Things applications

Since dye-sensitized solar cells (DSSC) have a suitable efficiency in the invisible region, they present a promising avenue for sustainable energy generation, particularly in the context of indoor environments where ambient lighting prevails. This paper proposes a novel numerical model tailored to assess the performance of DSSCs under indoor lighting conditions, with a specific focus on their potential application in powering Internet of Things (IoT) devices. By considering factors such as radiation intensity and spectral composition, particularly from common indoor light sources like Light Emitting Diodes (LEDs) and Fluorescent lights, the model offers insights into the efficiency and viability of DSSCs in indoor settings. Since empirical analyses are difficult and expensive, the existence of a numerical model that investigates cell behavior under indoor illumination can be beneficial for developing such cells. In conducting verifying analyses under varying lighting conditions, the study demonstrates notable efficiencies of DSSCs, with LED 3000 K illumination at 1000 lux intensity yielding the highest performance. While DSSCs may appear less economically viable in environments with readily available electricity, their potential significance lies in providing sustainable energy solutions for IoT devices, thus reducing dependency on conventional power sources and contributing to environmental sustainability. The scientific significance of this research lies in its contribution to understanding the behavior of DSSCs under indoor lighting, offering insights into their potential applications in powering IoT devices. By providing a numerical model for evaluating DSSC performance under realistic indoor conditions, this study opens avenues for further research in optimizing DSSC technology for indoor energy harvesting applications, thereby advancing the field of renewable energy and sustainable technology integration.

Maximizing Conversion Efficiency: A Numerical Analysis on P+ a-SiC/i Interface/n-Si Heterojunction Solar Cells with AMPS-1D

In this study, a heterojunction (P+ a-SiC/i intrinsic/n-Si) solar cell has been examined and characterized using the Analysis of Microelectronics and Photonic Structures (AMPS-1D) simulator. In this heterojunction solar cell, an intrinsic layer is imposed to enhance the efficiency and performance. The optimum efficiency of 36.52% (Voc=1.714 V, Jsc=27.006 mA/cm2, and FF=0.789) has been achieved with this intrinsic layer. It has also been observed the solar cell without intrinsic layer. In this case, the maximum efficiency of 2.378% has been observed which is very poor. The heterojunction solar cell also has been investigated with electron blocking layer (EBL) and defect layer. In this case, the simulation result shows the lower efficiency (34.357%) than the previous. This research paper introduces an optimized model of a heterojunction solar cell enhanced with an intrinsic layer to improve efficiency. The proposed design shows significant promise in its theoretical framework. Looking forward, the design could be realized in laboratory settings and has the potential to be scaled up for broader applications.

Porphyrins as key components for photoinduced charge separation, solar cells and optogenetics

This review presents typical examples of porphyrins, which serve as highly effective building blocks, primarily drawn from our past achievements. They function as both an electron donor and an energy donor/acceptor in various applications. These applications include photosynthetic and solar cell models, dye-sensitized solar cells, bulk heterojunction solar cells, and optogenetics based on photoinduced charge separation. Consequently, porphyrins are essential components for evaluating energy and electron transfer properties, as well as for energy and biological applications.

Two Completely Non‐Fused Ring Acceptors Working in an Alloy‐Like Model for Efficient and Stable Organic Solar Cells

AbstractSimple chemical structure and simplified synthesis process of active layer materials are critical for advancing the practical application of organic solar cells. Herin, two completely non‐fused ring electron acceptors BTZT‐2Cl and BTZT‐4Cl are developed. BTZT‐4Cl exhibits an enhanced absorption band, increases electrostatic potential differences with D18, and improves crystallinity and molecular packing properties. Consequently, the binary device based on BTZT‐4Cl displays a markedly improved efficiency of 14.12%, compared to the BTZT‐2Cl‐based device, which only achieves a moderate efficiency of 11.25%. More importantly, an alloy‐like structure can be formed by incorporating a small amount of high miscibility and compatibility BTZT‐2Cl. The ternary blend exhibits more compact molecular packing, efficient exciton dissociation, and an extended charge carrier lifetime due to the formation of an alloy‐like structure. The ternary device achieves a decent efficiency of 15.41% with superior thermal stability and a high T80 lifetime over 1600 h after being aged at 65 °C. These results establish it as the most efficient among devices based on completely non‐fused ring acceptors with both high efficiency and voltage. This study demonstrates a simple material design strategy and high‐performance device optimization techniques, which are critical for advancing practical applications in the OSC field.

Effective-diode-based analysis of industrial solar photovoltaic panel by utilizing novel three-diode solar cell model against conventional single and double solar cell.

Currently, the majority of the country has moved to renewable energy sources for electricity generation, and power companies are concentrating their efforts on renewable resources. Solar, wind, hydropower, and biomass are examples of renewable resources; of these, due to a lack of non-renewable resources, the solar industry is expanding. All year long, solar electricity is available, and it creates a calm, quiet atmosphere. The majority of large and small companies, as well as individual consumers, have shifted to PV solar cells for electricity generation. A trustworthy and precise simulation design of a photovoltaic system prior to installation is required to predict a photovoltaic system's performance. The current research aims to build models for solar PV systems with one, two, and three diodes and determine which model is most appropriate for each environmental circumstance to forecast performance accurately. By contrasting the experimental data of solar panel with simulated results of single-, double-, and triple-diode models, this study examines the accuracy of each model. These models' comparative performance study has been done using the MATLAB/Simulink, taking into account the influence of changing model parameters and the performance of the models under varying climatic circumstances. These models, despite their simplicity, are quite sensitive and react to even a little change in temperature and irradiance. Under conditions of low solar irradiance or shading conditions, three-diode photovoltaic models are shown to be more accurate. We can forecast the power output of solar photovoltaic systems under changeable input circumstances by understanding the I-V curves with the help of the performance assessment of the models used in this work.

Smart city compatible thin film solar cell based on extraordinary transmission and metallic patch nanoantenna

An effective performance enhancement model for the thin film solar cell conjointly based on extraordinary transmission and nanoantenna is proposed and investigated. The absorber layer of the extraordinary transmission based solar cell contains a metallic thin film with periodic holes. Maximum extraordinary transmission is accomplished as the metallic film has the same refractive index on both sides. Increased light transmission causes the absorber layer to absorb more light, which increases short circuit current density and subsequently the efficiency of the thin film solar cell. The presented analysis demonstrates that adding a square nano patch on the top surface of the absorber layer can further boost the extraordinary transmission. The extraordinary transmission is increased because of the formation of cavity nanoantenna. Cavity nanoantenna increases the coupling of light into the hole due to the excitation of surface plasmons polaritons. The proposed design of solar cell exhibits around 98% absorption and the short circuit current density is increased by a factor of 3.23. The study has been carried out using finite difference time domain (FDTD) method.

Numerical Simulation and Modeling of Nontoxic Perovskite Solar Cell Based on CH3NH3SnI3 with TiO2 as ETL and CuSbS2 as HTL

Numerical Simulation and Modeling of Nontoxic Perovskite Solar Cell Based on CH3NH3SnI3 with TiO2 as ETL and CuSbS2 as HTL

Parameter extraction of solar cell models using improved war strategy algorithm

A study proposed an improved war strategy algorithm called the chaos genetic manifestation war strategy algorithm (CGM-WSO) to extract parameters of solar cell model. The CGM-WSO algorithm incorporates three improvement measures. First, it introduces the logistic–tent chaos map to enable random perturbation during initialization. Second, it utilizes the crossover and mutation operators of the genetic algorithm to enhance the algorithm’s ability to escape local optima. Finally, the Lambert W function is employed to obtain explicit analytic expressions of single and double diode models. The performance of the CGM-WSO algorithm was validated using several cell’s models, and the results demonstrated significantly improved accuracy, reliability, and convergence speed compared to other algorithms.

Solar cell parameter extraction, with less than 10% percentage error, integrating the Co-Content function, using up to order 6 Simpson integration method, and 51 measured points per volt or less, in the case of a percentage noise of the maximum current

In this article, the solar cell parameters (within the one-diode solar cell model) are obtained with less than 10% error, integrating the Co-Content function using up to order 6 Simpson integration method, and as a function of the number of measured points per volt and a percentage noise of the maximum current. It is shown, that less than 10% error (in some cases around 1%) can be obtained, in case the percentage noise is as larger as 0.1%, using higher order Simpson integration than 1, the usually used trapezoidal integration method.