Using modified [Formula: see text] gravity and the diagonal tetrad, we propose a new kind of analytical solution to describe anisotropic charged stellar structures in this study. We obtain precise solutions by applying the linear form of [Formula: see text] as [Formula: see text] in the framework of Tolman–Kuchowicz physically sound metric potentials. The stellar structures of the compact star EXO 1785-248 are then investigated using the model by incorporating a linear equation of state relating the radial pressure [Formula: see text] and the matter density [Formula: see text]. We computed the closed-form expressions for the model parameters and illustrated their characteristics. The comprehensive graphical analysis demonstrates the scientific plausibility, causality, and dynamical stability of the model describing charged anisotropic stars. Finally, using the M-R curve, we estimate the numerical values of mass for different values of [Formula: see text]. The observational data of the neutron star candidates 4U 1820-30, PSR J1614-2230, and PSR J2215 + 5135 are covered by the maximum allowable masses for different values of [Formula: see text] additionally, when [Formula: see text], the charged compact star’s maximum permissible mass is calculated to be [Formula: see text], which could indicate the secondary component of the GW190814 event discovered by LIGO/VIRGO experiments.