Behavior Of Modes Research Articles

C─H···π interaction induced H‐aggregates for wide range water content detection in organic solvents

AbstractJ‐aggregation and H‐aggregation are identified as two classical models of functionally oriented non‐covalent interactions, and significant attention has been drawn by researchers. However, due to the scarcity of single‐crystal examples of H‐aggregation, a comprehensive understanding of the relationship between its stacking mode and optical behaviour has been hindered. In recent studies, two polyaromatic Schiff base compounds, Cl‐Salmphen and H‐Salmphen, were successfully synthesized, and both were found to exhibit H‐aggregation. In the findings, H‐Salmphen was shown to display typical C─H···π interactions, characteristic of Aggregation‐Induced Emission (AIE) active molecules, whereas its halogenated counterpart was identified as behaving similar to Aggregation‐Caused Quenching (ACQ) active molecules. These types of results suggest that identical intermolecular interactions can produce differing optical behaviours. Light was shed, at least in part, on the formation mechanisms of H‐type aggregates and their luminescence properties from these observations. Additionally, the high optical signal‐to‐noise ratio inherent to H‐aggregates was utilized for the exploration of water content detection. As an outcome, a high‐performance fluorescent filter paper was developed, enabling easy real‐time detection using a smartphone.

Unit Selection with Nonbinary Treatment and Effect

The unit selection problem aims to identify a set of individuals who are most likely to exhibit a desired mode of behavior or to evaluate the percentage of such individuals in a given population, for example, selecting individuals who would respond one way if encouraged and a different way if not encouraged. Using a combination of experimental and observational data, Li and Pearl solved the binary unit selection problem (binary treatment and effect) by deriving tight bounds on the "benefit function," which is the payoff/cost associated with selecting an individual with given characteristics. This paper extends the benefit function to the general form such that the treatment and effect are not restricted to binary. We then propose an algorithm to test the identifiability of the nonbinary benefit function and an algorithm to compute the bounds of the nonbinary benefit function using experimental and observational data.

Learning Diverse Risk Preferences in Population-Based Self-Play

Among the remarkable successes of Reinforcement Learning (RL), self-play algorithms have played a crucial role in solving competitive games. However, current self-play RL methods commonly optimize the agent to maximize the expected win-rates against its current or historical copies, resulting in a limited strategy style and a tendency to get stuck in local optima. To address this limitation, it is important to improve the diversity of policies, allowing the agent to break stalemates and enhance its robustness when facing with different opponents. In this paper, we present a novel perspective to promote diversity by considering that agents could have diverse risk preferences in the face of uncertainty. To achieve this, we introduce a novel reinforcement learning algorithm called Risk-sensitive Proximal Policy Optimization (RPPO), which smoothly interpolates between worst-case and best-case policy learning, enabling policy learning with desired risk preferences. Furthermore, by seamlessly integrating RPPO with population-based self-play, agents in the population optimize dynamic risk-sensitive objectives using experiences gained from playing against diverse opponents. Our empirical results demonstrate that our method achieves comparable or superior performance in competitive games and, importantly, leads to the emergence of diverse behavioral modes. Code is available at https://github.com/Jackory/RPBT.

Design of a simplified cranial substitute with a modal behavior close to that of a human skull.

Individuals exposed to the propagation of shock waves generated by the detonation of explosive charges may suffer Traumatic Brain Injury. The mechanism of cranial deflection is one of many hypotheses that could explain the observed brain damage. To investigate this physical phenomenon in a reproducible manner, a new simplified cranial substitute was designed with a mechanical response close to that of a human skull when subjected to this type of loading. As a first step, a Finite Element Model was employed to dimension the new substitute. The objective was indeed to obtain a vibratory behavior close to that of a dry human skull over a wide range of frequencies up to 10kHz. As a second step, the Finite Element Model was used together with Experimental Modal Analyses to identify the vibration modes of the substitute. A shaker excited the structure via a metal rod, while a laser vibrometer recorded the induced vibrations at defined measurement points. The results showed that despite differences in material properties and geometry, the newly developed substitute has 10/13 natural frequencies in common with those of dry human skulls. When filled with a simulant of cerebral matter, it could therefore be used in future studies as an approximation to assess the mechanical response of a simplified skull substitute to a blast threat.

Сострадание и доброта как разные сценарии просоциального поведения личности

Introduction: the relevance problem of differentiating modes of prosocial behavior is substantiated and the main goal is determined: to identify differences in the recognition and experience of modes of prosocial behavior among psychology students and the role of subjective well-being of the person in them. Theoretical analysis of compassion and kindness made it possible to formulate a hypothesis: the empirical referents of distinguishing between the prosocial scenario of kindness, associated with concern for the future of the Other and the activation of his psychological resources, and the scenario of compassion, aimed at reducing the negative experiences of the Other by providing one’s own resources, are actualized emotions, and the facilitator is the current level of subjective well-being of the person. Empirical analysis. Participants: psychology students (N = 76; M = 24.4; SD = 9.5). Methods: Kindness and Compassion Script Scale (P. Gilbert et al.); Kindness modes technique (D. E. Youngs et al.); Methods of diagnostics of subjective well-being of the person (R. Shamionov, T. Beskova). Conclusions: differences were identified in the recognition of prosocial scenarios of kindness and compassion; emotional markers have been identified that allow them to be differentiated; differences were found in the indicators of subjective well-being of participants with different abilities to recognize kindness and compassion, and a significant connection was established between compassionate kindness and the components of subjective well-being. The results can be used in the educational process for developing the professional competencies of psychology students through training in the practices of mindfulness, compassion, and self-care.

An exploratory study of information re-finding behaviour modes of Chinese college students on social media: video diary analysis from Chinese platforms

ABSTRACT This study aims to explore college students’ information-re-finding behaviour in the context of social media by identifying different behaviour modes to enrich the research on the information behaviour of social media users. Thirty-two college students volunteered to record their re-finding process once it occurred within two weeks by the video diary method. One hundred and forty-six valid events were collected and analysed qualitatively and quantitatively. It was shown that the behaviour process of information re-finding on social media experienced six stages: scene triggering, information demand generating, social media selecting, re-finding, information confirmation and information processing. Forty-eight kinds of information re-finding modes were illustrated and summarised into seven categories according to where and how the information was finally found: following, chat record, keyword, favourites, history, personal dynamics and the like. From further analysis, it was proved that significant differences did exist between varied re-finding behaviour modes in information needs and re-finding time rather than information processing behaviour. The study could expand the traditional information search model into mixed timing by considering recalling and re-finding. Practically, it generates useful practical implications for the design of re-finding functions, information recommendation and memory services of social media.

BAGAIL: Multi-modal imitation learning from imbalanced demonstrations

Expert demonstrations in imitation learning often contain different behavioral modes, e.g., driving modes such as driving on the left, keeping the lane, and driving on the right in the driving tasks. Although most existing multi-modal imitation learning methods allow learning from demonstrations of multiple modes, they have strict constraints on the data of each mode, generally requiring a near data ratio of all modes. Otherwise, it tends to fall into a mode collapse or only learn the data distribution of the mode that has the largest data volume. To address the problem, an algorithm that balances real-fake loss and classification loss by modifying the output of the discriminator, referred to as BAlanced Generative Adversarial Imitation Learning (BAGAIL), is proposed. With this modification, the generator is only rewarded for generating real trajectories with correct modes. BAGAIL is therefore able to deal with imbalanced expert demonstrations and carry out efficient learning for each mode. The learning process of BAGAIL is divided into a pre-training stage and an imitation learning stage. During the pre-training stage, BAGAIL initializes the generator parameters by means of conditional Behavioral Cloning, laying the foundation for the direction of parameter optimization. During the imitation learning stage, BAGAIL optimizes the parameters by using the adversary between the generator and the modified discriminator so that the finally obtained policy can successfully learn the distribution of imbalanced expert data. The experiments showed that BAGAIL accurately distinguished different behavioral modes with imbalanced demonstrations. What is more, the learning result of each mode is close to the expert standard and more stable than other multi-modal imitation learning methods.

Vibrational Analysis and Concentration Dependent SERS Study of Cefoperazone

Cefoperazone is a broad-spectrum antibiotic that is extremely efficient in the treatment of respiratory, abdominal, or genital infections. Vibrational spectroscopic techniques, FT-IR, Raman, and SERS, along with DFT calculations, were involved in investigating the normal modes of vibration and adsorption behavior of this antibiotic. Using both the experimental and theoretical data, the bands in the Raman and IR spectra were assigned to the normal vibrational modes. The SERS spectra were successively obtained by using silver and gold colloidal nanoparticles as a substrate. Their analysis revealed that the molecule is chemisorbed on the nanostructured surface through the as-denoted nitrogen ring. Changes observed in the SERS spectra recorded at different cefoperazone concentrations, i.e., modifications in the relative intensity of specific bands suggest the reorientation of adsorbed molecules towards the metal surface.

The nonlinear instability of transverse vibration behavior of functionally graded materials sandwich rectangular plates of under a harmonic loading and subsonic flow

This work is devoted to studying the combined action of periodic in-plane load and tangential subsonic flow on the nonlinear mechanism of the out-plane deformation of the functionally graded composite plate. Three distribution functions are proposed to investigate the distribution of the transverse shear strains and stresses across the thickness of the plates. By using Hamilton’s variational principle, the equations governing the plate instability boundaries are formulated. A nonlinear differential equation describing the first mode of the plate dynamic instability behavior by employing Galerkin’s method. The method of multiple time scales is used to obtain a periodic one-mode solution, which directly leads to the solvability condition. The different resonance cases for the interaction between the frequency of out- plane deformation and the external forces are discussed to discover the extent of the sandwich functionally graded material (FGM) rectangular plate resistance in the presence of external influences. Various bifurcation diagrams for different cases of resonance are obtained versus the basic parameters. In view of this study, we could get a deeper look at the complexity of frequency components in resonance responses of the sandwich FGM rectangular plate. The results could provide some suggestions for the sandwich plate’s vibration reduction design or fault diagnosis field or design fault diagnosis.

On the behaviour of the upstream-travelling waves in merging twin-jet systems

There is currently considerable interest in the guided-jet mode, as a result of recent works demonstrating it being the upstream component of various resonant systems in high-speed flows. For given jet operating conditions, the mode is known to exist over only a finite-frequency range that, for a twin-jet system, has been observed to vary with both jet separation and solution symmetry. Vortex-sheet and finite-thickness linear stability models are here employed to consider the behaviour of the guided-jet mode as the two jets are brought together, for both a planar and round twin-jet system. It is demonstrated that in both cases as the twin-jet system merges it forms a higher-order mode of an equivalent single-jet geometry. This then imposes a constraint on the guided-jet mode as the finite-frequency range must change to meet that of the equivalent geometry the system merges to, explaining the previously observed dependence on jet separation.

Towards a Real-Life Understanding of the Altered Functional Behaviour of the Default Mode and Salience Network in Chronic Pain: Are People with Chronic Pain Overthinking the Meaning of Their Pain?

Chronic pain is a source of substantial physical and psychological suffering, yet a clear understanding of the pathogenesis of chronic pain is lacking. Repeated studies have reported an altered behaviour of the salience network (SN) and default mode network (DMN) in people with chronic pain, and a majority of these studies report an altered behaviour of the dorsal ventromedial prefrontal cortex (vmPFC) within the anterior DMN. In this topical review, we therefore focus specifically on the role of the dorsal vmPFC in chronic pain to provide an updated perspective on the cortical mechanisms of chronic pain. We suggest that increased activity in the dorsal vmPFC may reflect maladaptive overthinking about the meaning of pain for oneself and one's actions. We also suggest that such overthinking, if negative, may increase the personal "threat" of a given context, as possibly reflected by increased activity in, and functional connectivity to, the anterior insular cortex within the SN.

Morphological entropy encodes cellular migration strategies on multiple length scales

Cell migration is crucial for numerous physiological and pathological processes. A cell adapts its morphology, including the overall and nuclear morphology, in response to various cues in complex microenvironments, such as topotaxis and chemotaxis during migration. Thus, the dynamics of cellular morphology can encode migration strategies, from which diverse migration mechanisms can be inferred. However, deciphering the mechanisms behind cell migration encoded in morphology dynamics remains a challenging problem. Here, we present a powerful universal metric, the Cell Morphological Entropy (CME), developed by combining parametric morphological analysis with Shannon entropy. The utility of CME, which accurately quantifies the complex cellular morphology at multiple length scales through the deviation from a perfectly circular shape, is illustrated using a variety of normal and tumor cell lines in different in vitro microenvironments. Our results show how geometric constraints affect the MDA-MB-231 cell nucleus, the emerging interactions of MCF-10A cells migrating on collagen gel, and the critical transition from proliferation to invasion in tumor spheroids. The analysis demonstrates that the CME-based approach provides an effective and physically interpretable tool to measure morphology in real-time across multiple length scales. It provides deeper insight into cell migration and contributes to the understanding of different behavioral modes and collective cell motility in more complex microenvironments.

How adolescents lose control over social networks: A process-based approach to problematic social network use

Social networks (SNs) are immensely popular, especially among teenagers, yet our understanding of problematic SNs remains limited. Understanding motivations and patterns of use is crucial given the current prevalence of problematic SNs use. Perarles et al. (2020) distinguish two behavioral control modes: Model-Free Control, where actions are characterized by actions driven by immediate gratification without reflective consideration for long-term consequences, and Model-Based Control, enabling planned and goal-directed actions. Both control modes can lead to problematic social network use. This study aims to delve into problematic SNs use and the underlying motives behind adolescents' participation in SNs, drawing upon the theoretical proposal by Perales et al. (2020). We conducted four focus groups with adolescents aged 13–17 (50 % female; Mage = 14.5, SD = 1.75), comprising two public school and two Catholic private school groups. Thematic analysis using Atlas.ti software revealed three themes. The first uncovers characteristics of problematic SNs use, including withdrawal, increased usage time, impaired control, behavioral salience and attentional capture and cognitive hijacking. The second spotlights motives, emphasizing emotional regulation, finding out what is going on, and social interaction. The third theme explores consequences such as compromised academic performance and physical harm. In conclusion, addressing both motives and problematic behaviors present a more effective approach to confronting SNs use challenges and fostering healthier online experiences for adolescents.

Understanding layered compounds under high pressure

This Tutorial focuses on the physics of layered compounds under high pressure. We have chosen h-BN and III–VI layered materials as representative materials. h-BN layers are strictly two-dimensional. Layers in III–VI compounds are more complex, and subtle details in their structural behavior play an important role in the evolution of high pressure properties. They are also interesting because they contain a different number of layers in their primitive unit cell and/or have a different ionic character. We begin describing the structural evolution. We discuss the experimental challenges encountered as well as the main findings related to intra- and interlayer compressibility, polytype influence, and geometrical modifications induced by pressure inside the layers. We then describe lattice vibrations. The origin of the modes is reviewed, paying attention to the relationships between atom motions in different layers. We discuss the convenience of redefining the Grüneisen parameter and describe the behavior of rigid layer modes, soft modes, and Davidov pairs. The last section is devoted to the electronic properties. We show that the changes observed when passing from a single layer to a three-dimensional BN are qualitatively similar to those induced by high pressure. The pressure behavior of electronic transitions in III–VI layered compounds is very rich, revealing the subtle balance between intra- and inter-layer interactions. Finally, we take advantage of high pressure studies to explain the formation of the Mexican hat type of valence band at ambient conditions in single layers of InSe and GaSe, but not in three-dimensional compounds.

Hybrid event-triggered control for networked switched Takagi–Sugeno fuzzy systems with aperiodic DoS attacks

This article investigates the event-triggered control problem for networked switched Takagi–Sugeno fuzzy systems (NSTSFSs) with denial of service (DoS) attacks. First, an attack-instant-constrained hybrid event-triggered mechanism (ETM) is proposed, which uses the acknowledgment character (ACK) detection scheme. It can describe the triggering schemes under different attack intervals and modify the triggering frequency based on the performance of the system. Second, a new segmented Lyapunov function is designed that takes into account the asynchronous behavior of system and controller modes, as well as DoS frequency and duration constraints. Then, sufficient conditions are provided to ensure the exponential stability of the system and have an H∞ performance. Furthermore, a collaborative design scheme is proposed to obtain controller gains, the switching law, and event-triggered parameters. Finally, the accuracy and effectiveness of this method are verified through two simulation examples.

Aceptabilidad de un modelo de formulación diagnóstica de casos clínicos como estrategia educativa en una residencia de psiquiatría del niño y del adolescente

IntroductionThe aim of the study is to analyze the acceptability of an Integrative and Multidimensional Case Formulation Model implemented as an educational strategy in the first year of a child and adolescent psychiatry residency by a clinical supervisor within a one-way mirror room. Materials and methodsA qualitative methodology is used through content analysis of interviews conducted with residents of the program who had participated consecutively in clinical supervision between 2018 and 2021. For the analysis, 5 theoretical constructs derived from the Theory of Planned Behavior and Fazio's MODE Model are used: attitudes, subjective norm, perceived behavioral control, motivation and opportunity. ResultsTwenty-six thematic codes that influence acceptability emerged from the analysis: 8 attitudinal codes (e.g. acceptability is favored by the usefulness of the Model to gain theoretical insight of the cases but with a high amount of time required); 4 normative codes (e.g. the approval or disapproval of the model by scholars outside the clinical supervision); 7 perceived behavioral control codes (e.g. the perceived self-efficacy increases over time); 4 motivational codes (e.g. the desire to learn) and 3 opportunity codes (e.g. joint deliberation with peers). ConclusionThe results show valuable information for the development of educational strategies in the specialty residency program by approaching significant cognitive and affective factors which influence learning during the training periods. Aspects of the strategy that stand out as favoring the educational process are identified, along with other aspects that can be improved for better acceptability of the educational strategy.

Effect of water and confining pressure on fault slip behaviors and rupture propagation

Pore fluid is ubiquitous within the Earth's crust and severely impacts shear rupture propagation and the slip behaviors of faults. We conducted triaxial experiments on sandstone to investigate the effects of crack damage, confining pressure, and water on fault slip behaviors and rupture propagation. Two loading configurations, conventional loading and increasing-amplitude cyclic loading, were conducted to compare the inelastic behavior and failure modes of sandstone samples. In addition to a macroscopic deformation and mechanical properties analysis, a noncontact optical scanner and magnetic resonance imaging technique were used to analyze the microstructural evolution of the sandstone. The results show that a higher confining pressure results in a more homogeneous fault plane. Fault slip behaviors can be divided into the slip-strengthening and slip-weakening stages. In the brittle regime, pore water reduces the brittle strength of rocks but does not induce different fault slip behaviors. When the confinement is high enough, rocks fail in the brittle–ductile transition regime where dynamic faulting is prohibited. In the brittle–ductile transitional regime, pore water enhances stabilization, and the slip behaviors distinctively differ from those occurring without water.

High-performance PCW-DFB laser diodes using offset quantum well epitaxial structures.

We demonstrated a high-performance partially corrugated waveguide distributed feedback (PCW-DFB) laser with high output power, low relative intensity noise (RIN) and narrow linewidth. By introducing offset quantum-well structure that provides enough threshold gain difference for single transverse mode operation, the laser can achieve single mode behavior with an 8-µm-wide ridge waveguide. The laser has been designed by the simulation model based on the coupled wave equations, and the fabricated PCW-DFB laser with the cavity length of 1.3 mm exhibited an output power higher than 190 mW. Stable single mode characteristics have been achieved with a side-mode suppression-ratio (SMSR) over 55 dB. The RIN was less than -160.5 dB/Hz at an injection current of 470 mA, and the linewidth reached 45 kHz.

A new experimental method for studying the single droplet breakup mode of diesel-water composite droplet fuel

Good atomization of the liquid phase fuel is a prerequisite for efficient combustion and micro-explosion can significantly increase the atomization. In order to study the influence of water content and ambient temperature on the breakup mode and combustion behavior of diesel-water composite droplet, a novel experimental method was proposed. Specifically, the required volume of water was placed at the end of the probe, and diesel was then dropped onto the outer surface of the water by free diffusion to form water-in-oil composite droplet. The experimental results indicated that compared with the combustion of pure diesel, the diesel-water composite droplet additionally experienced a fluctuating combustion stage, in which micro-explosion and puffing occurred. Water content and ambient temperature have dual effects on the breakup mode and combustion characteristics of composite droplet. When the water content exceeded 20%, the breakup mode of the droplet was converted from micro-explosion to puffing, which reduced the atomization performance of the fuel. The ignition time of the composite droplet was 50–60% lower than that of pure diesel, and the burnout time decreased by about 35%. The breakup mode of the droplet and the critical size results indicate that 10%water/90%diesel at 973 K is most conducive to combustion.

Mechanical properties and failure modes of additively-manufactured chiral metamaterials based on Euclidean tessellations: an experimental and finite element study

PurposeThe “chiralisation” of Euclidean polygonal tessellations is a novel, recent method which has been used to design new auxetic metamaterials with complex topologies and improved geometric versatility over traditional chiral honeycombs. This paper aims to design and manufacture chiral honeycombs representative of four distinct classes of 2D Euclidean tessellations with hexagonal rotational symmetry using fused-deposition additive manufacturing and experimentally analysed the mechanical properties and failure modes of these metamaterials.Design/methodology/approachFinite Element simulations were also used to study the high-strain compressive performance of these systems under both periodic boundary conditions and realistic, finite conditions. Experimental uniaxial compressive loading tests were applied to additively manufactured prototypes and digital image correlation was used to measure the Poisson’s ratio and analyse the deformation behaviour of these systems.FindingsThe results obtained demonstrate that these systems have the ability to exhibit a wide range of Poisson’s ratios (positive, quasi-zero and negative values) and stiffnesses as well as unusual failure modes characterised by a sequential layer-by-layer collapse of specific, non-adjacent ligaments. These findings provide useful insights on the mechanical properties and deformation behaviours of this new class of metamaterials and indicate that these chiral honeycombs could potentially possess anomalous characteristics which are not commonly found in traditional chiral metamaterials based on regular monohedral tilings.Originality/valueTo the best of the authors’ knowledge, the authors have analysed for the first time the high strain behaviour and failure modes of chiral metamaterials based on Euclidean multi-polygonal tessellations.