Modal Composition Research Articles

Petrography and geochemistry of Oligocene to Lower Miocene sandstones in the Baiyun Sag, Pearl River Mouth Basin, South China Sea: Provenance, source area weathering, and tectonic setting

There is a controversy regarding the source area and weathering intensity of Oligocene to Lower Miocene sediments in the Baiyun Sag of the Pearl River Mouth Basin. Detrital modes, geochemistry, heavy mineral data, and detrital zircon U–Pb ages were analysed to understand the provenance, source area weathering, and tectonic setting of Oligocene to Lower Miocene sandstones in the Baiyun Sag. Petrographic data reveal that the sandstones were derived from a recycled orogen. With increasing transport distance, sediment maturity increased correspondingly. The Oligocene to Lower Miocene sandstones in the Baiyun Sag have low compositional maturity and have experienced low to moderate weathering. The sediments of the Zhuhai Formation have experienced relatively strong weathering intensity compared with those of the Enping and lower Zhujiang formations. Due to low degree of illitization and differences in the geochemical compositions of the sediments, the continental island arc data from different boreholes in the Baiyun Sag are more irregularly distributed in the A‐CN‐K plot. The modal composition (e.g., quartz, feldspar, and lithic fragments) and geochemical indices (Al2O3/TiO2 ratio; Al2O3‐TiO2 diagram; discriminant F1‐F2 diagram; Eu/Eu*, La/Sc, La/Co, Th/Sc, and Th/Co ratios; Hf‐La/Th and La/Sc‐Co/Th diagrams; and rare earth element patterns) indicate that the sediments in the Baiyun Sag are mainly derived from felsic source rocks. Although the uplift around the Baiyun Sag includes multistage magmatism and basic rocks, it has little influence on the sediment in the depression, and no sediments were transported by the Han River to the Baiyun Sag. Geochemical data and detrital zircon U–Pb ages suggest that the Pearl River was formed in the Early Oligocene and became the main source for the sediments in this area. The river carried felsic material from the South China Coast forming a large delta on the northern slope of the Baiyun Sag. The ratios of Eu/Eu*, La/Sc, La/Co, Th/Sc and Th/Co, and heavy mineral data indicate that the sediments transported by the Pearl River to the Baiyun Sag were changed from the arc‐dominated coastal zone to the interior of the South China Block during the Late Oligocene to Early Miocene and even reached the south‐eastern margin of the Tibetan Plateau (West Yunnan Plateau). The La‐Th‐Sc and Th‐Sc‐Zr/10 diagrams suggest that the provenance of these sandstones is evolved continental island arc or an active continental margin setting.

Granito Aragão — Suíte intrusiva Nhandú — um granito oxidado, tipo A2, de 1967 a 1964 Ma na Província Aurífera Alta Floresta — Cráton Amazônico

O Granito Aragão, localizado na Província Aurífera Alta Floresta (PAAF), consiste de um stock granítico de ~ 80 km2, de granulação média a grossa, textura porfirítica e composição modal monzogranítica a sienogranítica. Os dados geoquímicos indicam afinidade com magmas graníticos tipo-A2, similares àqueles gerados em margens continentais ativas evoluídas. As idades de cristalização U-Pb SHRIMP em zircão de 1964 ± 11 Ma e 1967 ± 2 Ma permitem incluí-lo na Suíte Intrusiva Nhandú (SINH) e correlacioná-lo com a Suíte Intrusiva Creporizão (SIC) na Província Mineral do Tapajós (PMT), no Pará. Associado ao Granito Aragão ocorre um megaenclave fanerítico médio a grosso, de textura porfirítica e composição modal granodiorítica a monzogranítica. O enclave apresenta padrão geoquímico semelhante a magmas graníticos shoshoníticos, e sua idade de cristalização U-Pb SHRIMP em zircão (1995 ± 5 Ma) indica relação com granitoides do Complexo Cuiú-Cuiú. O Granito Aragão ocorre alojado em granitoides foliados com idade de cristalização U-Pb SHRIMP de 2009 ± 4 Ma. Estes resultados sugerem que as rochas hospedeiras do Granito Aragão fazem parte do Complexo Cuiú-Cuiú. As correlações estratigráficas estabelecidas no presente trabalho indicam que a porção leste da PAAF representa a extensão da Província Tapajós-Parima, ao sul do Gráben do Cachimbo, norte do Estado de Mato Grosso.

Cascaded Raman and Intermodal Four-Wave Mixing in Conventional Non-Zero Dispersion-Shifted Fiber for Versatile Ultra-Broadband Continuum Generation

We demonstrate an efficient ultra-broadband supercontinuum generation in telecom-grade optical fiber by pumping Q-switched subnanosecond laser pulses (0.77 ns) at 1064 nm in the normal dispersion region of the fiber. The fiber supports several spatial modes at this pump wavelength. Multiple sidebands with six Raman stokes spanning over more than 1100 nm (starting well below 600 nm and extending beyond 1700 nm) are generated using very low input pump power (average 57 mW). Theoretical analysis shows that cascaded Raman and cascaded intermodal four-wave mixing processes can account for the generation of multiple sidebands. We also demonstrate that the modal composition of the input pump profile can provide an extra degree of freedom in tailoring the multiple Raman peaks in the output spectrum.

Rare Earth Elements (La, Ce, Pr, Nd, and Sm) from a Carbonatite Deposit: Mineralogical Characterization and Geochemical Behavior

Geochemical characterization including mineralogical measurements and kinetic testing was completed on samples from the Montviel carbonatite deposit, located in Quebec (Canada). Three main lithological units representing both waste and ore grades were sampled from drill core. A rare earth element (REE) concentrate was produced through a combination of gravity and magnetic separation. All samples were characterized using different mineralogical techniques (i.e., quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN), X-ray diffraction (XRD), and scanning electron microscopy with X-ray microanalysis (SEM-EDS)) in order to quantify modal mineralogy, liberation, REE deportment and composition of REE-bearing phases. The REE concentrate was then submitted for kinetic testing (weathering cell) in order to investigate the REE leaching potential. The mineralogical results indicate that: (i) the main REE-bearing minerals in all samples are burbankite, kukharenkoite-Ce, monazite, and apatite; (ii) the samples are dominated by REE-free carbonates (i.e., calcite, ankerite, and siderite); and (iii) LREE is more abundant than HREE. Grades of REE minerals, sulfides and oxides are richer in the concentrate than in the host lithologies. The geochemical test results show that low concentrations of light REE are leached under kinetic testing conditions (8.8–139.6 µg/L total light REE). These results are explained by a low reactivity of the REE-bearing carbonates in the kinetic testing conditions, low amounts of REE in solids, and by precipitation of secondary REE minerals.

Quantitative analysis of crystal-interface frequencies in granitoids: Implications for modelling of parent-rock texture and its influence on the properties of plutoniclastic sands

Generation of sediments from crystalline rocks is the result of a complex and incompletely understood suite of processes. The time evolution of the rock-fragment assemblage in sands derived from granitoids is determined by the relative strengths of crystal interfaces and their abundances in the parent rock. In this study we highlight the role of crystal-interface frequencies in granitoids. Strong evidence for non-random texture with significant implications for predicted interface frequencies have been reported in previous studies. We analysed available interface-frequency data from granitoids using methods of compositional data analysis, and connected our results to existing texture classifications. On average, granitoids display a high degree of ordering with significant depletion of isomineralic interfaces relative to expectations based on random texture. Analysis of 210 normalized interface frequency distributions from nine different granitoids reveals a consistent pattern of variation among interface frequencies, which suggests a single underlying petrogenetic process related to the combined effects of nucleation and textural equilibration (“coarsening”).In view of the large scatter of relative interface frequencies within and among granitoids, we propose to model their distribution empirically for the purpose of calibrating sediment-generation studies. Multivariate normal distributions of centred log-ratio transformed relative frequencies are capable of capturing ~95% of the observed variability with a limited number of dimensions. As a rule of thumb, the number of dimensions needed to approximate interface-frequency counts can be taken equal to the number of mineral classes, which is (much) smaller than the number of interface classes. Mathematical analysis shows that the joint variability of rock texture and composition may be factorized into three statistically independent measures: modal composition, crystal-size probability density functions, and normalized interface frequencies. The potential independence of these measures permits objective identification of petrogenetically significant correlations among them, which will be indicated by statistically significant cross-covariances. At this stage, inferences from microscopic texture analysis cannot be extrapolated to the scale of entire drainage basins in which sediments are generated, because insufficient data are available on the large-scale spatial heterogeneity of texture and composition of granitoid parent rocks.

Reworking of Archean mantle in the NE Siberian craton by carbonatite and silicate melt metasomatism: Evidence from a carbonate-bearing, dunite-to-websterite xenolith suite from the Obnazhennaya kimberlite

The Obnazhennaya kimberlite in the NE Siberian craton hosts a most unusual cratonic xenolith suite, with common rocks rich in pyroxenes and garnet, and no sheared peridotites. We report petrographic and chemical data for whole rocks (WR) and minerals of 20 spinel and garnet peridotites from Obnazhennaya with Re-depletion Os isotope ages of 1.8–2.9 Ga (Ionov et al., 2015a) as well as 2 pyroxenites. The garnet-bearing rocks equilibrated at 1.6–2.8 GPa and 710–1050 °C. Some xenoliths contain vermicular spinel-pyroxene aggregates with REE patterns in clinopyroxene mimicking those of garnet. The peridotites show significant scatter of Mg# (0.888–0.924), Cr2O3 (0.2–1.4 wt.%) and high NiO (0.3–0.4 wt.%). None are pristine melting residues. Low-CaO-Al2O3 (≤0.9 wt.%) dunites and harzburgites are melt-channel materials. Peridotites with low to moderate Al2O3 (0.4–1.8 wt.%) usually have CaO > Al2O3, and some have pockets of calcite texturally equilibrated with olivine and garnet. Such carbonates, exceptional in mantle xenoliths and reported here for the first time for the Siberian mantle, provide direct evidence for modal makeover and Ca and LREE enrichments by ephemeral carbonate-rich melts. Peridotites rich in CaO and Al2O3 (2.7–8.0 wt.%) formed by reaction with silicate melts.We infer that the mantle lithosphere beneath Obnazhennaya, initially formed in the Mesoarchean, has been profoundly modified. Pervasive inter-granular percolation of highly mobile and reactive carbonate-rich liquids may have reduced the strength of the mantle lithosphere leading the way for reworking by silicate melts. The latest events before the kimberlite eruption were the formation of the carbonate-phlogopite pockets, fine-grained pyroxenite veins and spinel-pyroxene symplectites. The reworked lithospheric sections are preserved at Obnazhennaya, but similar processes could erode lithospheric roots in the SE Siberian craton (Tok) and the North China craton, where ancient melting residues and reworked garnet-bearing peridotites are absent.The modal, chemical and Os-isotope compositions of the Obnazhennaya xenoliths produced by reaction of refractory peridotites with melts are very particular (high Ca/Al, no Mg#-Al correlations, highly variable Cr, low 187Os/188Os, continuous modal range from olivine-rich to low-olivine peridotites, wehrlites and websterites) and distinct from those of fertile lherzolites in off-craton xenoliths and peridotite massifs. These features argue against the concept of ‘refertilization’ of cratonic and other refractory peridotites by mantle-derived melts as a major mechanism to form fertile to moderately depleted lherzolites in continental lithosphere. The Obnazhennaya xenoliths represent a natural rock series produced by ‘refertilization’, but include no rocks equivalent in modal, major and trace element to the fertile lherzolites. This study shows that ‘refertilization’ yields broad, continuous ranges of modal and chemical compositions with common wehrlites and websterites that are rare among off-craton xenoliths.

A proposal for the definition, nomenclature, and classification of soapstones

Currently, the term “soapstone” often refers to both talc-bearing ultramafic metamorphic rocks and other rocks having a wide range of variation in mineral composition. As a result, the name provides little information on the major mineral constituents in the rock. This proposal for the classification and nomenclature of soapstones is based on the absolute and relative modal mineral compositions. It does not consider textural attributes. According to the International Union of Geological Sciences, Subcommission on the Systematic of Metamorphic Rocks (IUGS-SCMR), rock names should be understood uniquely and without ambiguity. Therefore, we recommend: (1) soapstone has to contain 35–75% talc, (2) soapstone cannot contain more than 35% hard silicates. Further division is made based on the ratios of oxide, chlorite, and carbonate. Finally, the name of the additional hard silicate is considered as a prefix, if its content exceeds 5%.

Mineralogy of silicate inclusions in the Elga IIE iron meteorite

The petrography, mineral modal data and major and trace element compositions of 15 silicate inclusions in the Elga iron meteorite (chemical group IIE) show that these inclusions represent chemically homogeneous zoned objects with highly variable structures, reflecting the sequence of crystallization of a silicate melt during cooling of the metal host. The outer zones of inclusions at the interface with their metal host have a relatively medium-grained hypocrystalline texture formed mainly by Cr-diopside and merrillite crystals embedded in high-silica glass, whereas the central zones have a fine-grained hypocrystalline texture. Merrillite appears first on the liquidus in the outer zones of the silicate inclusions. Na and REE concentrations in merrillite from the outer zones of inclusions suggest that it may have crystallized as α-merrillite in the temperature range of 1300–1700°С. Merrillite tends to preferentially accumulate Eu without Sr. Therefore, strongly fractionated REE patterns are not associated with prolonged differentiation of the silicate melt source but depend on crystallization conditions of Н-chondrite droplets in a metallic matrix. The systematic decrease in Mg# with increasing Fe/Mn in bronzite may indicate partial reduction of iron during crystallization of the inclusion melt. The modal and bulk compositions of silicate inclusions in the Elga meteorite, as well as the chemical composition of phases are consistent with the model equilibrium crystallization of a melt, corresponding to 25% partial melting of H-chondrite, and the crystallizing liquidus phase, merrillite, and subsequent quenching at about 1090°С. Despite a high alkali content of the average weighted bulk inclusion composition, La/Hf and Rb/Th fall within the field of H chondrites, suggesting their common source. Our results reveal that silicate inclusions in the Elga (IIE) iron meteorite originated by mixing of two impact melts, ordinary chondrite and Ni-rich iron with а IIE composition, which were produced by impact event under near-surface conditions on a partially differentiated parent asteroid.

Basin classification and tectonic framework of the Nam Pat Group, Uttaradit Province, Thailand: Implications for the Nan Suture Zone

The Nam Pat Group of the Nam Pat Basin, Uttaradit Province, Thailand is situated in the Nan Suture Zone. Two contrasting tectonic framework models of the Nan Suture have previously been proposed: as a main Paleo-Tethyan suture and as a remnant of a closed back-arc basin. The goal of this study is to analyze the tectonic framework of the Nan Suture and reevaluate the existing tectonic models. This research infers the tectonic setting of the basin based on basin-filled lithofacies distributions, provenance, and paleocurrents. Three facies groups are identified. Facies A, B, and C are polymictic conglomerate, interbedded sandstone and mudstone, and mudstone with thin-bedded sandstone, respectively. Generally, the strata strike NE-SW, steeply dip NW, and fine toward the SE. Petrographic results of sandstone samples show that the majority of lithic fragments are volcanic rocks with lesser amount of metamorphic rocks and sedimentary rocks. The modal compositions of sandstones are analyzed on QFL, QmFLt, QmPK, LmLvLs, and QpLvmLsm ternary diagrams. The plots indicate that the sandstones of the Nam Pat Group have high proportions of volcanic-arc detritus. Paleocurrents, determined from the orientation of clast imbrications and cross-stratification, are toward the SE. The results suggest that large quantities of sediment traveled southeastward from a nearby volcanic arc into the basin. The Nam Pat Group stratigraphically overlies the Pak Pat Volcanics. The chemical features of the Pak Pat Volcanics, located to the west of the basin, show that they are andesitic volcanic rocks formed as a magmatic arc. Thus, the nearby Pak Pat Volcanics are the main sediment source of the Nam Pat Group, and the basin is best interpreted as back-arc basin rather than as a forearc basin.

Provenance of the Miocene Slovenj Gradec Basin sedimentary fill, Western Central Paratethys

The Slovenj Gradec Basin represents one of the marginal western basins of the Neogene Pannonian Basin system. Its sedimentary succession is investigated by combination of field, petrographic and geochemical methods. The succession is at least 540m thick and characterised by frequent alternation of conglomerate, sandstone, siltstone and marlstone deposited in terrestrial, brackish and shallow marine environments. Modal composition of the sandstones indicates that they originated from recycled orogen, namely from quartzose sedimentary rocks of the Eastern Alps, and show moderate to absent chemical weathering. The results indicate two different tectonic settings: a collisional, which correlates well with the end-Mesozoic and Cenozoic Alpine collision, resulting in orogeny and thrusting of the Austroalpine nappes, and a passive margin related to the early Neogene lithospheric extension and subsidence as the result of slab retreat in the Carpathian subduction zone, which was responsible for the formation of the Pannonian Basin system.In this area, where the sediments were subjected to various tectonic events, discriminant function diagrams of Verma and Armstrong Altrin are found to be a good tool for their identification and differentiation.

Petrographic-geochemical types of Triassic alkaline ultramafic rocks in the Northern Anabar province, Yakutia, Russia

A classification suggested for alkaline ultramafic rocks of the Ary-Mastakh and Staraya Rechka fields, Northern Anabar Shield, is based on the modal mineralogical composition of the rocks and the chemical compositions of their rock-forming and accessory minerals. Within the framework of this classification, the rocks are indentified as orangeite and alkaline ultramafic lamprophyres: aillikite and damtjernite. To estimate how much contamination with the host rocks has modified their composition when the diatremes were formed, the pyroclastic rocks were studied that abound in xenogenic material (which is rich in SiO2, Al2O3, K2O, Rb, Pb, and occasionally also Ba) at relatively low (La/Yb)PM, (La/Sm)PM, and not as much also (Sm/Zr)PM and (La/Nb)PM ratios. The isotopic composition of the rocks suggests that the very first melt portions were of asthenospheric nature. The distribution of trace elements and REE indicates that one of the leading factors that controlled the diversity of the mineralogical composition of the rocks and the broad variations in their isotopic–geochemical and geochemical characteristics was asthenosphere–lithosphere interaction when the melts of the alkaline ultramafic rocks were derived. The melting processes involved metasomatic vein-hosted assemblages of carbonate and potassic hydrous composition (of the MARID type). The alkaline ultramafic rocks whose geochemistry reflects the contributions of enriched vein assemblages to the lithospheric source material, occur in the northern Anabar Shield closer to the boundary between the Khapchan and Daldyn terranes. The evolution of the aillikite melts during their ascent through the lithospheric mantle could give rise to damtjernite generation and was associated with the separation of a C–H–O fluid phase. Our data allowed us to distinguish the evolutionary episodes of the magma-generating zone during the origin of the Triassic alkaline ultramafic rocks in the northern Anabar Shield.

Spin pumping and probe in permalloy dots-topological insulator bilayers

We present a ferromagnetic resonance (FMR) spin pumping experiment at room temperature in periodic arrays of permalloy nanodots of different radii deposited onto a 3D topological insulator Bi2Se3 film. We measure the dc voltage signal generated by spin-to-charge conversion of the pumped spin current due to the spin-orbit coupling in the bulk of Bi2Se3. In the nanostructured samples, two resonance peaks are observed, associated with Kittel and inhomogeneous edge modes, respectively. This more complex modal composition in comparison to continuous systems may provide additional advantages for development of prospective spintronic devices. We support our experimental results by theoretical calculations, which are based on micromagnetic modeling of the magnetization dynamics under FMR excitation in a nanodot. A numerical approach to the calculation of the spin-pumping voltage is proposed, and the efficiency of spin-to-charge conversion is estimated for two nanostructured samples with different dot sizes.

Modal composition and tectonic provenance of the sandstones of Ecca Group, Karoo Supergroup in the Eastern Cape Province, South Africa

AbstractPetrography of the sandstones of Ecca Group, Karoo Supergroup in the Eastern Cape Province of South Africa have been investigated on composition, provenance and influence of weathering conditions. Petrographic studies based on quantitative analysis of the detrital minerals revealed that the sandstones are composed mostly of quartz, feldspar and lithic fragments of metamorphic and sedimentary rocks. The sandstones have an average framework composition of 24.3% quartz, 19.3% feldspar, 26.1% rock fragments, and 81.33% of the quartz grains are monocrystalline. These sandstones are generally very fine to fine grained, moderate to well sorted, and subangular to subrounded in shape. In addition, they are compositionally immature and can be classified as feldspathic wacke and lithic wacke. The provenance characteristics suggest the influence of plutonic and metamorphic terrains (meta-magmatic arc) as the main source rock with minor debris derived from recycled sedimentary rocks. The latter revealed that the compositional immaturity of the sandstones is a result of weathering or recycling and short transport distance. The weathering diagrams and semi-quantitative weathering index indicate that the Ecca sandstones are mostly from a plutonic source area, with climatic conditions ranging from arid to humid. The detrital modal compositions of these sandstones are related to back arc to island and continental margin arc. These results, therefore, support previous studies that infer foreland basin setting for the Karoo Basin.

Petrography and geochemistry of the Lower Miocene Moghra sandstones, Qattara Depression, north Western Desert, Egypt

The petrographic and geochemical compositions of the Lower Miocene Moghra siliciclastic sediments in the Qattara Depression, north Western Desert, were investigated to infer their provenance, tectonic setting, palaeoweathering conditions, and diagenetic history. The Moghra Formation (~200 m thick) is dominated by sandstones intercalated with mudstone and carbonates. X‐ray diffraction analysis revealed that smectite, kaolinite, and illite are the dominant clay minerals found in mudstones. The sandstones are mainly subarkose, sublitharenite, and quartzarenite types with an average modal composition of Q89F6L5. The sandstones possess various diagenetic overprints including mechanical infiltration of clay, compaction, cementation, dissolution, and replacement. Major and trace element concentrations suggested that the parent rocks are intermediate to felsic in composition derived from the Neoproterozoic Arabian Nubian Shield. The weathering indices such as the chemical index of alteration and the plagioclase index of alteration implied that the intensity of chemical weathering in the source area was moderate under semi‐arid climatic conditions. On the other hand, the index of chemical variability indicates a low compositional maturity. The tectonic discrimination diagrams demonstrated a collision setting for the Arabian Nubian Shield, which represents the main supplier of sediments to the study area. Statistical parameters, sedimentary structures, and ichnofossil contents suggested that the Moghra sediments were deposited in a tidally‐influenced fluvial environment.

Arc magmatism witnessed by detrital zircon U-Pb geochronology, Hf isotopes and provenance analysis of Late Cretaceous-Miocene sandstones of onshore western Makran (SE Iran)

The present work aims to contribute to the Cenozoic tectonic setting of the western part of the Makran Accretionary Wedge in SE Iran. We determine the provenance of both deep marine turbiditic and deltaic-shelf Late Cretaceous-Miocene sandstones, describe the sandstone modal framework and heavy minerals and report a new geochronological and isotopic study including 2307 detrital zircons U-Pb ages and 204 in-situ Hf isotopic analyses. Modal sandstone framework compositions indicate that a magmatic arc and recycled accreted sediments were the main sources of Eocene-Oligocene and Miocene sandstones. Cr-spinel and heavy mineral assemblages indicate ultramafic rocks, likely ophiolitic mantle, as a subsidiary source. Detrital zircon U-Pb ages cluster in five main age groups: (1) Neoproterozoic grains suggesting a continental crust provenance within the Central Iran blocks, (2) Jurassic grains with Hf isotopic compositions of continental crust, suggesting a rifting related magmatic provenance, (3) Late Cretaceous and (4) Eocene grains, with Hf isotopic compositions typical of continental crust and non-depleted mantle, suggesting a continental magmatic arc provenance, and (5) Early Miocene grains. The new U-Pb age and Hf isotopic ratios correspond to those obtained in the east Iranian Makran. They fit tectonic reconstructions with Middle Jurassic intracontinental rift, Early Cretaceous to Eocene subduction below Central Iran forming a continental arc to the north of Makran and closure of the related oceanic in the Paleogene. Erosional products of the corresponding magmatic arc are found in the Makran Basin. Our data disprove that provenance characteristics of the Makran sedimentary rocks are consistent with derivation from the Himalayan sources.

Integrated Petrographic, Mineralogical, and Geochemical Study of the Upper Kaimur Group of Rocks, Son Valley, India: Implications for Provenance, Source Area Weathering and Tectonic Setting

ABSTRACT The upper Kaimur Group (UKG) of the Vindhyan Supergroup in central India, primarily consists of three rock types-Dhandraul sandstone, Scarp sandstone and Bijaigarh shale. The present study aims to reconstruct the parent rock assemblages, their tectonic provenance, mineralogy, weathering intensity, hydraulic sorting and depositional tectonic setting. Samples from the UKG rocks representing the Dhandraul sandstone, Scarp sandstone and Bijaigarh shale were studied using a combination of petrographic, mineralogical, and geochemical techniques. Texturally, medium to coarse grained UKG sandstones are mature and moderate to well sorted. Deficiency of feldspars in these sandstones indicates that the rocks are extensively recycled from distant sources. Their average modal composition for Scarp (avg. Qt99F0.2L0.8) and Dhandraul (avg. Qt99 F0.1L0.8) sandstones, classifies them as quartz arenite to sub-litharenite types, which is consistent with geochemical study. Major element concentrations revealed that sandstones have high SiO2, K2O > Na2O, and low Fe2O3, which are supported by the modal data. On the other hand, sandstone samples are enriched in most trace elements such as Ce, Sr, V, Sc and Zr and depleted in U and Th. The CIA values (43.17-76.48) of the UKG rocks indicate low to moderate weathering, either of the original source or during transport before deposition, which may have related to low-relief and humid climatic conditions in the source area. Further, petrographic and geochemical interpretations indicate that they are derived from craton interior to quartzose recycled sedimentary rocks and deposited in a passive continental margin. Therefore, granitic and low grade metamorphic rocks of Mahakoshal Group and Chotanagpur granite-gneiss, situated on the southern and south-eastern side of the Vindhyan basin are suggested as possible provenance for the UKG rocks.

The Jeffers Brook diorite–granodiorite pluton: style of emplacement and role of volatiles at various crustal levels in Avalonian appinites, Canadian Appalachians

Small appinite plutons ca. 610 Ma outcrop in the peri-Gondwanan Avalon terrane of northern Nova Scotia, with different structural levels exposed. Field mapping shows that the Jeffers Brook pluton is a laccolith emplaced along an upper crustal thrust zone, likely in a dilational jog in a regional dextral strike-slip system. The oldest rocks are probably mafic sills, which heated the area facilitating emplacement of intermediate magmas. Cross-cutting relationships show that both mafic and intermediate magmas were supplied throughout the history of pluton emplacement. The modal composition, mineral chemistry, and bulk chemistry of gabbro, diorite, tonalite, granodiorite, and granite have been studied in the main plutonic phases, dykes, and sills, and mafic microgranular enclaves. As with the type appinites in the Scottish Caledonides, the pluton shows evidence of high water content: the dominance of hornblende, locally within pegmatitic texture; vesicles and irregular felsic patches in enclaves; and late aplite dykes. Analyzed mafic microgranular enclaves are geochemically similar to larger diorite bodies in the pluton. Tonalite–granodiorite is distinct from the diorite in trace-element geochemistry and radiogenic isotopes. Elsewhere to the east, similar rocks of the same age form vertically sheeted complexes in major shear zones; hornblende chemistry shows that they were emplaced at a deeper upper crustal level. This implies that little of the observed geochemical variability in the Jeffers Brook pluton was developed within the pluton. The general requirements to form appinites are proposed to be small magma volumes of subduction-related magmas that reach the upper crust because of continual heating by mafic magmas moving through strike-slip fault pathways and trapping of aqueous fluids rather than venting through volcanic activity.

Optical properties of metamorphic hybrid heterostuctures for vertical-cavity surface-emitting lasers operating in the 1300-nm spectral range

The possibility of fabricating hybrid metamorphic heterostructures for vertical-cavity surfaceemitting lasers working in the 1300-nm spectral range is demonstrated. The metamorphic semiconductor part of the heterostructure with a GaAs/AlGaAs distributed Bragg reflector and an active region based on InAlGaAs/InGaAs quantum wells is grown by molecular-beam epitaxy on a GaAs (100) substrate. The top dielectric mirror with a SiO2/Ta2O5 distributed Bragg reflector is formed by magnetron sputtering. The spectra of the room-temperature microphotoluminescence of these vertical-cavity surface-emitting laser heterostructures are studied under 532-nm excitation in the power range of 0–70 mW (with a focused-beam diameter of ~1 μm). The superlinear dependence of the photoluminescence intensity on the excitation power, narrowing of the photoluminescence peaks, and a change in the modal composition may be indications of lasing. The results obtained give evidence that the technology of the metamorphic growth of heterostructures on GaAs substrates can be used for the fabrication of vertical-cavity surface-emitting lasers working in the 1300- nm spectral range.

Characteristics of deep crustal seismic anisotropy from a compilation of rock elasticity tensors and their expression in receiver functions

AbstractRocks in the continental crust are long lived and have the potential to record a wide span of tectonic history in rock fabric. Mapping rock fabric in situ at depth requires the application of seismic methods. Below depths of microcrack closure seismic anisotropy presumably reflects the shape and crystallographic preferred orientations influenced by deformation processes. Interpretation of seismic observables relevant for anisotropy requires assumptions on the symmetry and orientation of the bulk elastic tensor. We compare commonly made assumptions against a compilation of 95 bulk elastic tensors from laboratory measurements, including electron backscatter diffraction and ultrasound, on crustal rocks. The majority of samples developed fabric at pressures corresponding to middle to lower crustal condition. Tensor symmetry is a function of mineral modal composition, with mica‐rich samples trending toward hexagonal symmetry, amphibole‐rich samples trending toward an increased orthorhombic symmetry component, and quartz‐feldspar‐rich samples showing a larger component of lower symmetries. Seventy‐seven percent of samples have a best fit hexagonal tensor with slow‐axis symmetry, as opposed to mantle deformation fabric that usually has fast‐axis symmetry. The best fit hexagonal approximation for crustal tensors is not elliptical but deviates systematically from elliptical symmetry with increasing anisotropy, an observation that affects the magnitude and orientation of anisotropy inferred from receiver function and surface wave observations. We present empirical linear relationships between anisotropy and ellipticity for crustal rocks. The maximum out‐of‐plane conversion amplitudes in receiver functions scale linearly with degree of anisotropy for nonelliptical symmetry. The elliptical assumption results in a bias of up to 1.4 times true anisotropy.

Volcanic glass in Cretaceous dacites and rhyolites of the Paraná Magmatic Province, southern Brazil: Characterization and quantification by XRD-Rietveld

Acidic rocks are a significant component of the Cretaceous Paraná Magmatic Province, occurring in different stratigraphic positions, and often forming deposits of complex and as yet poorly defined architecture. Vitrophyric varieties are surprisingly abundant for a volcanic sequence of this age, and are composed of predominant glass plus plagioclase (labradorite-andesine), pyroxenes (augite±pigeonite and orthopyroxene), Ti-rich magnetite, and traces of apatite. Hypocrystalline rocks, largely derived from devitrification, additionally contain sanidine, cristobalite, and quartz. The negative correlation between the abundance of these minerals and the amount of glass suggests that these latter phases formed by devitrification. Modal analysis using a combined XRD Rietveld-RIR method detected glass contents between 0 and 85wt% % in a set of representative samples of Palmas-type acidic rocks from southern Brazil with dacite to rhyolite composition. Modal compositions determined by XRD and by scanning electron microscope are in good agreement with each other, and were checked against whole-rock XRF chemical data. Water contents up to 4wt% show a positive linear correlation with the amount of glass, and are inferred to be mostly secondary, as original (pre-eruptive) H2O dissolved in melts is inferred to have been <1.5wt% in all rocks. Glass is the only water bearing phase in the studied samples, which lack low temperature hydrated phases. Water loss during devitrification appears to have occurred along fractures, and was accompanied by Na loss and, in some samples, also Ca, Rb and Sr loss. The rapid and inexpensive method of modal analyses of glassy rocks developed here may be a useful tool for mapping acidic volcanic rocks in southern Paraná Magmatic Province, and also to identify the architecture of these deposits.