ABSTRACT The present study validates the accuracy of water quality analysis for twenty geo-referenced water samples from a watershed of Gaya district, Bihar, using ion balancing and electrochemical approaches. Analytical data were presented using box plots, Gibbs diagram and descriptive statistics. Regression equations of various chemical parameters and ionic strength with electrical conductivity (EC) are reported for routine conversion and outlined mathematical equations for data validation. The pH and EC of the water samples varying from 4.9 to 8.7 and 190 to 800 µS cm−1, respectively. Calcium (Ca2+), magnesium (Mg2+), sodium (Na+) and potassium (K+) varied from 0.88 to 2.53, 0.4 to 1.6, 0.8 to 3.75, and 0.01 to 0.22 meq L−1 whereas, bicarbonate (HCO3 –), chloride (Cl–) and sulphate (SO4 2–) ranged from 1.3 to 6.0, 0.25 to 1.5 and 0.01 to 0.6 meq L−1, respectively. Consistency between calculated and measured values judged the correctness based upon relative error (RE %) of the water analysis data. Overall RE on an average of ca. 6% and 5% is reported regarding consistency between the calculated and measured specific conductivity ( calc. and .) and ionic strength ( calc. and .), respectively and difference was statistically non-significant. The ion balancing method showed very good to good analytical data quality for 80% of water samples, while electrochemical approaches (EC and ionic strength) indicated good to moderately good analytical data quality for 85% of the investigated samples. Taking cognisance of the outcome of all validation approaches, an overall 20% rechecking of water samples including (sample ID S3, S8, S13 and S14) is proposed for better analytical data quality for further data mining operations.
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