Basaltic Minerals Research Articles

Effect of basalt fiber on properties of asphalt and asphalt mixture

Asphalt mixture is the surface material of flexible pavement and semi-rigid pavement. It directly bears the influence of climate conditions and traffic load, and is prone to aging and fatigue damage. Therefore, using reinforcing agent to improve the performance of asphalt mixture is the long-term goal of researchers.This paper aims to study the effect of basalt fiber on asphalt viscosity and mechanical properties of asphalt mixture. Firstly, by testing the basic properties of asphalt binder with different fiber content, the viscosity characteristics of fiber + asphalt composites are analyzed by using the modified Einstein viscosity equation. The research shows that basalt fiber has obvious toughening effect on asphalt, and the penetration and softening point indexes are suitable to evaluate the viscosity properties of fiber + asphalt composites.Secondly, the effects of different fiber content on the water stability and splitting tensile strength of asphalt mixture are analyzed. The results show that the maximum content of basalt fiber should not be greater than 0.4%; With the increase of fiber content, the splitting strength of asphalt mixture increases, but the increase is not obvious when the content is > 0.30%, while the stiffness modulus continues to increase, indicating that the deformation resistance of asphalt mixture is enhanced after adding fiber. Based on the micromechanics theory of composite materials, the basic principle of basalt mineral fiber improving the strength performance of asphalt mixture is explained. The research shows that basalt mineral fiber can significantly improve the performance of asphalt mixture.

Nanoscale Mg-Depleted Layers Slow Carbonation of Forsterite (Mg2SiO4) When Water Is Limited

Passivation of silicate surfaces by accumulated reaction products is an obstacle to efficient CO2 mineralization. In this study, we investigate a unique passivation effect during the carbonation of the basalt mineral forsterite (Mg2SiO4) in humid supercritical CO2 (50 °C, 90 bar). Using in situ high-pressure infrared spectroscopy, we demonstrate that dissolution of forsterite into a thin water film slows significantly after reaction for ≈24 h, even under far-from-equilibrium conditions. 29Si magic angle spinning nuclear magnetic resonance spectroscopy detects a highly polymerized amorphous silica at this stage. On the basis of transmission electron microscopy and energy dispersive X-ray spectroscopy, we show that the silica is present as a Mg-depleted layer that is just 2–3 nm thick on the reacted forsterite particles. The decrease in the level of forsterite dissolution in the presence of an extraordinarily thin Mg-depleted layer can be strongly linked to properties of the thin fluid film at the surface, highlighting the importance of water during mineral carbonation. This study furthers our understanding of silicate mineral carbonation under select low-water, humidified fluid conditions relevant to basaltic geologic reservoirs, recovery of critical elements by carbonation of mafic ores, and sequestration of atmospheric CO2 by enhanced rock weathering.

Developments and Industrial Applications of Basalt Fibre Reinforced Composite Materials

Basalt mineral fibre, made directly from basalt rock, has good mechanical behavior, superior thermal stability, better chemical durability, good moisture resistance and can easily be recycled when compared to E-glass fibres (borosilicate glass is called ‘E-glass’ or ‘electric al-grade glass’ because of its high electrical resistance) which are traditionally used in structural composites for industrial applications. Industrial adoption of basalt fibre reinforced composites (FRC) is still very low mainly due to inadequate data and lower production volumes leading to higher cost. These reasons constrain the composites industry from seriously considering basalt as a potential alternative to conventional (e.g., E-glass) fibre reinforced composites for different applications. This paper provides a critical review of the state-of-the-art concerning basalt FRC highlighting the increasing trend in research and publications related to basalt composites. The paper also provides information regarding physico-chemical, and mechanical properties of basalt fibres, some initial Life cycle assessment inventory data is also included, and reviews common industrial applications of basalt fibre composites.

Source Lithology and Magmatic Processes Recorded in the Mineral of Basalts from the Parece Vela Basin

AbstractSince the Early Cenozoic, the Philippine Sea Plate (PSP) has undergone a complex tectonic evolution. During this period the Parece Vela Basin (PVB) was formed by seafloor spreading in the back‐arc region of the proto‐Izu‐Bonin‐Mariana (IBM) arc. However, until now, studies of the geological, geophysical, and tectonic evolution of the PVB have been rare. In this study, we obtained in situ trace element and major element compositions of minerals in basalts collected from two sites in the southern part of the PVB. The results reveal that the basalts from site CJ09‐63 were likely formed via ∼10% partial melting of spinel‐garnet lherzolite, while the basalts from site CJ09‐64 were likely formed via 15%–25% partial melting of garnet lherzolite. The order of mineral crystallization for the basalts from site CJ09‐64 was olivine, spinel, clinopyroxene, and plagioclase, while the plagioclase in the basalts from site CJ09‐63 crystallized earlier than the clinopyroxene. Using a plagioclase‐liquid hygrometer and an olivine‐liquid oxybarometer, we determined that the basalts in this study have high H2O contents and oxygen fugacities, suggesting that the magma source of the Parece Vela basalts was affected by subduction components, which is consistent with the trace element composition of whole rock.

Experiments on the reactivity of basaltic minerals and glasses in Venus surface conditions using the Glenn Extreme Environment Rig

AbstractClimate models for Venus rely heavily on theoretical modeling and laboratory experimentation due to the extreme surface conditions of the planet and limited in situ surface data. To better explore the relative importance of reactions between the surface and the atmosphere on Venus, we exposed representative volcanic glasses and basaltic minerals to a large‐scale simulation of Venus surface conditions with a realistic atmospheric composition. This study consistend of two experiments of 42 and 80 days that replicated both physical conditions and atmosphere composition derived from available in situ near‐surface data using the Glenn Extreme Environment Rig (GEER) at the NASA Glenn Research Center. These experiments revealed significant reactivity of common Ca‐bearing pyroxenes (diopside and augite) to form anhydrite. Olivine and labradorite showed minimal reactivity. Volcanic glasses, including both natural and synthetic samples, were exceptionally reactive, rapidly forming both anhydrite and thénardite (Na2SO4), as well as transition metal sulfates (i.e., Cu, Cr), halite (NaCl), and sylvite (KCl). Our results document chemical and textural alteration of sample surfaces and provide sufficient evidence for an active sulfur sink on multiple samples, with sulfates as the dominant secondary mineralogy. These experiments suggest likely surface mineralogies and solid phases present on Venus' surface with significant implications for upcoming missions and provide new data for comparison to high‐temperature mineral–gas reactions prevalent on Venus, Earth, and Io.

Burial Depths of Extensive Shallow Cryptomaria in the Lunar Schiller–Schickard Region

Quantifying the volumes and geologic nature of lunar volcanic eruptions is important for constraining the thermal and geologic evolution of the Moon. Cryptomaria are effusive, basaltic lava flows on the Moon that were subsequently buried, and therefore hidden, by higher-albedo basin and crater ejecta. Radar offers the ability to probe the subsurface for geologic units not otherwise apparent at the surface. We use Arecibo/Green Bank Observatory and Lunar Reconnaissance Orbiter Mini-RF radar data sets to characterize maria and cryptomaria within the Schiller–Schickard region. We find significant variability in the radar backscatter across the region that does not correspond to previously mapped boundaries of maria and cryptomaria in the literature. We use the characteristic low backscatter (due to the attenuating nature in radio waves of some basaltic minerals) to analyze the distribution of cryptomaria. We use the reduction in radar backscatter to estimate burial depths of cryptomaria across the area. We present a new map of Schiller–Schickard cryptomaria and the local variability in the thicknesses of the light plains that bury the basalts. We find burial depths ranging from >100 m in the deepest areas to just a few to tens of meters in areas with shallow cryptomaria (particularly prominent in the southeast). These areas are generally contiguous with maria, allowing us to track mare lava flow units into the subsurface at mare/highland margins. We propose that ∼67% of the region contains surface or buried basaltic volcanism, which represents over twice (2.7× increase) the areal extent of cryptomaria reported in previous studies.

The dynamics of the Sorol Trough magmatic system: Insights from bulk‐rock chemistry and mineral geochemistry of basaltic rocks

The Yap trench‐island arc system, where three tectonic plates (i.e., the Philippine Sea Plate, Pacific Plate, and Caroline Plate) interact, has undergone a relatively complicated geological evolution. East of the system, the Caroline Plateau are being subducted, and the plateau has been rifted into east and west Caroline ridges by the development of the Sorol Trough. However, until now, knowledge of the nature of the basement of the Sorol Trough is lacking, which limits our understanding of the complete tectonic evolution of the Yap island arc‐trench system and the Caroline Plateau. In this study, we performed petrological and mineral geochemical (in situ major element compositions and trace element compositions) analysis of newly acquired subducting basalt samples from the Sorol Trough segment, which is being subducted along the Yap Trench, and K‐Ar age of the Sorol basalts is 23.8 ± 0.7 Ma. The results show that phenocryst minerals of basalt from Sorol Trough are mainly olivine and plagioclase, with minor clinopyroxene microlites. The forsterite (Fo) values of the olivine phenocrysts in these rocks vary from 84.97 to 86.85, and plagioclase (Pl) phenocrysts are predominantly labradorite, with a few andesine plagioclase microlites. Bulk‐rock chemical compositions confirm that these rocks are intraplate alkaline basalts and show ocean island basalt (OIB)‐like geochemical characteristics. The mantle source of these basement basalts could be peridotite, and these Sorol Trough basalts may have been formed by 5–10% partial melting of mantle spinel lherzolite. The potential temperature of the mantle beneath the Sorol Trough was inferred to be 1,331–1,393°C, shows that there is no thermal anomaly in the mantle source. In addition, the crystallization temperatures of the clinopyroxenes (1,068–1,263°C) and plagioclase (702–1,216°C) and their compositional characteristics indicate that the magmatic processes have a conspicuously fast rate of magma upwelling. In conclusion, the basalts in the Sorol Trough were the products of low‐degree partial melting of a relatively enriched mantle source that passively upwelled as the Sorol Trough separated the Caroline Ridge into its western and eastern parts.

Orbital Observations of a Marker Horizon at Gale Crater

AbstractA dark‐toned, indurated, smooth horizon, and (or) bed (herein called “marker horizon”) is exposed across much of the northwestern, southwestern, and southeastern portions of Mount Sharp in Gale crater. Compact Reconnaissance Imaging Spectrometer for Mars spectra taken from the marker horizon exhibit evidence for the presence of high calcium pyroxene and other basaltic minerals in contrast to the hydrated sulfate signatures associated with strata above and below it. Mean dips for the marker horizon and sulfate‐bearing strata are 1–5° with almost all azimuths radially away from the center of Mount Sharp. The marker horizon thickness varies between <1 and 3 m and its elevation changes by 1.6 km across the mound. Surface slopes along the sulfate‐bearing strata above and below the marker horizon are typically 20°–40° compared to <5° surface slopes on the marker horizon. Features observed on the marker horizon include ridges, fractures, faults, layering, oval depressions, small craters, and possible yardangs/indurated bedforms. We interpret the marker horizon to be a single unit that formed contemporaneously across Mount Sharp during the same depositional sequence that created the sulfate‐bearing strata. Plausible formation mechanisms for the marker horizon include (1) emplacement of a more indurated sulfate unit, either from (a) primary deposition or (b) secondary diagenesis; (2) deposition of a more resistant sandstone unit during a brief drier period; (3) emplacement of a volcanic ash deposit laid down in the midst of the sulfate formation period; or (4) a lag deposit created during a drier period. Based on our observations, origins (1a) and (3) are the most plausible.

Transformation of the Sub-Continental Lithospheric Mantle Beneath the North China Craton (NCC): Constraints from the Geochemical Characteristics of Olivine Websterite Xenoliths and Their Minerals in the Cenozoic Basalts from Hannuoba

The sub-continental mantle beneath North China Craton (NCC) has attracted extensive attention in the past decades because of its dramatic transformation from an old, cold, thick, and refractory mantle to a juvenile, hot, thinner, and fertile mantle. However, the transformation mechanism remains largely controversial. The mantle xenoliths entrapped in basalts, as petrogenetic indicators, can provide an important window to reveal the evolution of the sub-continental lithospheric mantle. In this study, we present a systematical study on the geochemical characteristics of the olivine websterite xenoliths and their minerals in the Cenozoic basalts in the Hannuoba region located at the central orogenic belt of the NCC. The results, compared with the geochemical data of Paleozoic and Meosozic peridotites, the Cenozoic composite pyroxenites as well as the global cumulate pyroxenites, demonstrate that: (1) The source of the websterite is probably the lithospheric mantle, which is mainly newly accreted, but with small amounts of ancient mantle residues. The source may be contaminated by different degrees of crustal materials. The high Nb/Ta ratios (11.36–20.57) of the websterite indicate that the Ti-bearing minerals (such as rutile) are probably involved in the source; (2) The websterite is more likely to be produced as a result of interaction of mantle peridotite with the silica-rich melts that are mainly derived from the asthenospheric mantle and also contributed by the crustal materials; (3) The metasomatic crustal melts might be derived from the subducted Paleo-Pacific plate. These melts interacted with the lithospheric mantle can significantly transform the chemical composition of the lithospheric mantle, and consequently play an important role in the destruction of the NCC. An important implication for the destruction of the NCC is further discussed.

Enrichment and speciation of chromium during basalt weathering: Insights from variably weathered profiles in the Leizhou Peninsula, South China

Basalt-derived soils are widespread worldwide. Such soils contain high levels of heavy metals like chromium (Cr), which is a serious environmental concern. However, little is known regarding the enrichment and speciation of Cr during the basalt weathering process. Therefore, two basalt-derived soil profiles (Nitisol and Ferralsol) in the Leizhou Peninsula, south tropical China, were investigated to explore the redistribution and transformation of Cr during basalt weathering. All profiles could be divided into three layers: rocks, saprolites, and soils. The Nitisol and Ferralsol profiles exhibited strong (kaolinization) and extreme (laterization) degrees of weathering, respectively. Results showed that Cr concentrations in the saprolites (234 to 315 mg·kg−1) were higher than those in basalt rocks (139 to 159 mg·kg−1), indicating that Cr was enriched with the continuous loss of Si and other mobile macro-elements. While high levels of Cr were also enriched in the soils (178 to 430 mg·kg−1) accompanied with Fe. However, in the upper soils of the Ferralsol profile, the acidity and organic matter could promote the leaching of Cr. Geochemical fractions and EPMA mapping showed that chromite and olivine were the main Cr-bearing minerals in basalt, but Fe-oxides (e.g., goethite and hematite) contained the highest portion of Cr in weathered saprolites and soils. The availability of Cr in the soil was extremely low due to the high stability of Cr bound to Fe-oxides. However, the decreasing contents of Cr bound to Fe-oxides in the upper soils of the Ferralsol profile indicated that Cr could also be released during Fe leaching. In conclusion, the weathering of basalt can lead to the enrichment of Cr in Fe-(hydro)oxides, which are the main controlling minerals for Cr mobility in basalt-derived soils. Further research is needed to evaluate the effect of Fe-(hydro)oxide formation and dissolution on the release of soil Cr.

High temperature transformation of iron-bearing minerals in basalt: Mössbauer spectroscopy studies

Abstract The high temperature decomposition of basalt from Lower Silesia (Poland) was followed by Mössbauer spectroscopy investigation. The Fe content of the sample was ~9.0 at.%. The X-ray diffraction analysis shows that augite (37%) and olivine (12%) are major Fe-bearing mineral components. The sample also contains significant amount of anorthite (22%) and nepheline (17%). The sample was heated at various temperatures between 200°C and 1100°C for three hours. Up to a temperature of 500°C changes in contribution of Fe-bearing minerals are insignificant. Heating in the temperature range from 500°C to 1100°C leads to a systematic increase in contribution of iron oxides at the cost of contribution of silicate minerals, like augite and olivine. Mössbauer spectrum obtained after heating at 1100°C showed hematite as the main iron oxide phase. The ratio of Fe3+/Fetot in the non-heated sample was equal to 0.51 and after heating at 1100°C this ratio amounted to 0.89.

Biomass ashes as potential raw materials for mineral wool manufacture: initial studies of glass structure and chemistry

The energy intensive and CO2-generating nature of commercial mineral wool and glass production necessitates advances and changes in materials and processes. The derivation of raw materials from waste products arising from biomass energy generation offers the possibility of a two-fold environmental benefit: partial replacement of carbonate raw minerals in production, leading to lower CO2 release during melting; and the utilisation and valorisation of byproducts which may otherwise be sent to landfill. Glass samples with a basaltic mineral wool composition were produced with additions to the raw materials of 0, 1, 5 and 10 wt% of a fly ash and a bottom ash arising from biomass combustion. The resulting glasses were analysed by x-ray fluorescence, x-ray diffraction, dilatometry, 57Fe Mössbauer and Raman spectroscopies, and their densities, molar volumes and viscosity–temperature profiles were calculated and compared against benchmark glass samples. All biomass ash-containing glasses were closely similar in both composition and properties to the benchmark glass, with up to 10 wt% ash additions to the raw materials. In addition, the use of the biomass fly ash led to a reduction in batch CO2 content estimated to be 1·5 kg CO2 per tonne of batch for each 1 wt% addition. These initial results provide evidence supporting the further development of these ash materials as potential value-added raw materials for mineral wool manufacture.

40Ar/39Ar dating of basaltic rocks and the pitfalls of plagioclase alteration

40Ar/39Ar geochronology is one of the most important techniques for constraining the timing of basaltic events due to the paucity of suitable minerals in basalts for other geochronological techniques such as U–Pb (e.g., zircon, baddeleyite). Among a variety of materials from basaltic rocks that have been used for 40Ar/39Ar dating, plagioclase is the most important due to its common presence in basalts as a primary crystallizing phase, and its transparency so that fresh grains can be selected during sample preparation. However, plagioclase 40Ar/39Ar geochronology has often been compromised by alteration (e.g., sericitization by hydrothermal events), which, in practice, is difficult to identify using a petrographic microscope when the amount of alteration is low (e.g., <1%).We used laboratory step-heating experiments and theoretical simulations to characterize the 40Ar/39Ar age and Ca/K spectra of altered plagioclase so that 40Ar/39Ar dating results on altered samples can be identified and better interpreted. The step-heating experiments and theoretical simulations yielded consistent results, and show that with the presence of even a tiny amount of sericite (~0.01% for K-poor samples and ~0.1% for K-rich samples), the plagioclase samples yielded alteration plateau ages that are 3%–4% younger than the crystallization age. The difference between the alteration age of sericitized plagioclase and its crystallization age is primarily controlled by the time lapse between the crystallization and sericitization events, but also by the Ca/K ratios of the plagioclase. For plagioclase samples that experienced the same alteration event, the higher the Ca/K ratio is, the more sensitive the 40Ar/39Ar age is to alteration. We propose that the alteration signatures of plagioclase can be effectively identified through inspecting the 40Ar/39Ar age spectra, the Ca/K spectra, and the degassing curves. We also investigated the effect of sericitization of plagioclase microliths in basaltic groundmass and modelled the 40Ar/39Ar age and Ca/K spectra of altered groundmass samples. We validate our approach by revisiting published 40Ar/39Ar dating results for large igneous provinces, and showed that these dates should have been interpreted as alteration ages (minimum eruption ages) rather than crystallization ages. Finally, we demonstrate that with high degrees of alteration (~50% for K-poor and >70% for K-rich plagioclase samples), the age of hydrothermal alteration can be successfully dated.

Resolving the argument about volcanic bedrock under the West Antarctic Ice Sheet and implications for ice sheet stability and sea level change

We provide a test for recent arguments that the West Antarctic Ice Sheet (WAIS) is underlain by an extensive outcrop of volcanic rock (mainly basalt) by examining the non-clay and clay mineral composition of sediments collected in front of and under the Ross Ice Shelf. If the proposed large volume were present, then we posit that glacial erosion and transport would deliver sediments to the Ross Sea enriched in minerals diagnostic of alkaline basalt, namely olivine, pyroxene, and plagioclase, and no quartz. Using quantitative X-ray diffraction analysis, we determine the weight percent of minerals in West Antarctic alkaline basalt, dolerite, gneiss, and granite bedrock, and compare these with a suite of 49 surface and near-surface sediment samples from a 1400 km west to east transect across the Ross Sea. Fifty percent of the samples had quartz percentage values >25% and had very small wt percentages of diagnostic basalt minerals. A sediment unmixing algorithm, with basalt, dolerite, gneiss and granite bedrock, end members, showed that the sediment contained virtually no basalt, was dominated by granite compositions, but did show some samples with an admixture of material derived from the Ferrar dolerite, which crops out extensively in the Transantarctic Mountains. Indicators of possible late Cenozoic volcanic bedrock – pyroxene, forsterite, and smectite weight percentages – decrease from west to east across the Ross Sea opposite to the trend of the quartz weight percent. Our study provides no support for the presence of extensive basalt outcrop under the WAIS, hence indicates that any changes in ice stream stability will not be influenced by basal heat regime.

An experimental study of basalt–seawater–CO2 interaction at 130 °C

Over millions of years, the interaction of marine basalt with percolating seawater in low-temperature ocean floor hydrothermal systems leads to the formation of calcite and aragonite. The presence of these minerals in marine basalts provides evidence for substantial CO2 fixation in these rocks. Here, we report on laboratory experiments to study this process under enhanced CO2 partial pressures (pCO2) at 130 °C. Mid-ocean-ridge-basalt (MORB) glass was reacted with North Atlantic Seawater charged with CO2 in batch experiments lasting up to 7 months. For experiments initiated with seawater charged with ~2.5 bar pCO2, calcite and aragonite are the first carbonate minerals to form, later followed by only aragonite (±siderite and ankerite). For experiments initiated with seawater charged with ~16 bar pCO2, magnesite was the only carbonate mineral observed to form. In total, approximately 20% of the initial CO2 in the reactors was mineralized within five months. This carbonation rate is similar to corresponding rates observed in freshwater-basalt-CO2 interaction experiments and during field experiments of the carbonation of basalts in response to CO2-charged freshwater injections in SW-Iceland. Our experiments thus suggest that CO2-charged seawater injected into submarine basalts will lead to rapid CO2 mineralization. Notably, at pCO2 of tens of bars, magnesite will form, limiting the formation of Mg-rich clays, which might otherwise compete for the Mg cation and pore-space in the submarine basaltic crust. This suggests that the injection of CO2-charged seawater into subsurface basalts can be an efficient and effective approach to the long-term safe mineral storage of anthropogenic carbon.

Alteration and paragenesis of the basalt-hosted Au deposits, southwestern Guizhou Province, China: Implications for ore genesis and exploration

Carlin-type Au deposits are dominantly hosted in sedimentary rocks. Recent exploration has identified two deposits (Jiadi and Damaidi) hosted in the Emeishan basalt in southwestern Guizhou Province, China, that contain Carlin-type mineralization. In this study, ore and alteration minerals from the two deposits were examined, mineral parageneses were established through detailed petrography, whole-rock chemistry and mineralogical studies, and results were compared with the sediment-hosted Carlin-type Au deposits.In both deposits, pre-ore stage minerals are mainly igneous minerals in basalt, including orthopyroxene, clinopyroxene, plagioclase, magnetite, and minor ilmenite and apatite. These minerals formed during the eruption and formation of the Emeishan Large Igneous Province. The Au ore-stage mineral assemblage consists of arsenian pyrite, arsenopyrite, illite, jasperoid quartz, (Fe)-dolomite (locally Ca-Mg-siderite), rutile, and apatite. This transition indicates that pre-ore basalt was altered to minerals that characterize Carlin-type ore.Electron probe microanalysis and laser ablation-inductively coupled plasma-mass spectrometry analyses show that the arsenian pyrite and arsenopyrite contain ~457 ppm and ~556 ppm Au, respectively, and are enriched in As, Cu, Sb, Hg, and Tl. Gold is ionically bound in the disseminated arsenian pyrite and arsenopyrite which formed during sulfidation. During the late-ore stage, open space-filling realgar, calcite, quartz, stibnite, and orpiment precipitated as the hydrothermal system cooled and collapsed. Post-ore stage minerals include hematite and chlorite, reflecting post-ore oxidation.Comparison studies indicate the two deposits share remarkable similarities to the Guizhou sediment-hosted Carlin-type Au deposits. The basalt-hosted and sediment-hosted Au deposits in Dian-Qian-Gui area formed in response to the same widespread metallogenic event. This study confirms that basalt can host Carlin-type Au mineralization. Future exploration for Carlin-type Au deposits in Dian-Qian-Gui area can be expanded into regions dominated by basalt, especially the anticlines above the unconformity between the Maokou limestone and Emeishan basalt.

Visual level measurement system application in the technological process automated control system of the recuperative furnace bath

The paper considers the melted material level determining problem in the recuperative furnace bath melter in technological process automated control system for the basalt mineral fiber production. To solve this problem, it is proposed to use a visual level measurement system based on the analysis and processing of the melt boundary image. A block diagram of the visual level measurement system developed by the authors is presented, and an algorithm for determining the melt level using a modified Sobel edge detection method is proposed.

Igneous Rock Associations 27. Chalcophile and Platinum Group Elements in the Columbia River Basalt Group: A Model for Flood Basalt Lavas

The Columbia River Basalt Group is the youngest and best preserved continental Large Igneous Province on Earth. The 210,000 km3 of basaltic lavas were erupted between 16.6 and 5 Ma in the Pacific Northwest, USA. The peak of the eruptions occurred over a 700,000-year period when nearly 99% of the basalts consisting of the Steens, Imnaha, Picture Gorge, Grande Ronde and Wanapum Basalts were emplaced. In this study we examined the Platinum Group Elements (PGEs) Pt and Pd, and the chalcophile elements Cu and Zn in the Columbia River Basalt Group. The presence of Pt, Pd and Cu in the compositionally primitive Lower Steens, Imnaha and Picture Gorge Basalts suggests that the Columbia River Basalt Group magma was a fertile source for these elements. The PGEs are contained mainly in sulphides in the earliest formations based on their correlation with immiscible sulphides, sulphide minerals and chalcophile elements. Grande Ronde, Wanapum and Saddle Mountains Basalts are depleted in PGEs and chalcophile elements compared to earlier formations. Sulphur was saturated in many flows and much of it probably came from assimilation of cratonic rock from a thinned lithosphere. We propose a model where the presence or absence of PGEs and chalcophile elements results primarily from the interaction between an advancing plume head and the crust/lithosphere that it encountered. The early lavas erupted from a plume that had little interaction with the crust/lithosphere and were fertile. However, as the plume head advanced northward, it assimilated crustal/lithospheric material and PGE and chalcophile elements were depleted from the magma. What little PGE and chalcophile elements remained in the compositionally evolved and depleted Grande Ronde Basalt flows mainly were controlled by substitution in basalt minerals and not available for inclusion in sulphides.

Potential for CO2 Mineral Carbonation in the Paleogene Segamat Basalt of Malaysia

Geological storage of carbon dioxide (CO2) requires the host rock to have the capacity to permanently store CO2 with minimum post-storage monitoring. Mineral carbonation in geological formations is one of the most promising approaches to CO2 storage as the captured CO2 is converted into stable carbonated minerals (e.g., calcite and magnesite). In this study, we investigated the geochemical and mineralogical characteristics of Segamat basalt in the Central Belt of Malaysia and evaluated its potential for mineral carbonation by using laboratory analyses of X–ray fluorescence (XRF), X–ray diffraction analysis (XRD) and petrographic study. The XRF results showed that Segamat basalt samples contain a number of elements such as Fe (21.81–23.80 wt.%), Ca (15.40–20.83 wt.%), and Mg (3.43–5.36 wt.%) that can react with CO2 to form stable carbonated minerals. The XRD and petrographic results indicated that Segamat basalt contains the reactive mineral groups of pyroxene and olivine, which are suitable for the mineral carbonation process. The results of this study could help to identify the spatial distribution of elements and minerals in the Segamat basalt and to assess its mineral carbonation potential for geological storage in Malaysia.

In Situ Geochemical Compositions of the Minerals in Basaltic Rocks from the West Philippine Basin: Constraints on Source Lithology and Magmatic Processes

Abstract Since the early Cenozoic, the West Philippine Basin (WPB) and the whole Philippine Sea Plate (PSP) has undergone a complex geological evolution. In this study, we presented K-Ar ages, in situ trace element, and major element compositions of minerals of basalts collected from the Benham Rise and the Central Basin Fault (CBF) in the WPB, to constrain their magmatic process and regional geological evolution. Olivine phenocrysts and microlites in the alkali basalts (20.9 Ma) from the Benham Rise have forsterite (Fo) contents of 56.90%–76.10% and 53.13%-66.41%, respectively. The clinopyroxenes in the tholeiites (29.1 Ma) from the CBF is predominantly diopside and augite, and it is depleted in light rare earth elements (LREEs) (LaN/YbN=0.13–3.40) and large-ion lithophile elements (LILEs). The plagioclases in the basalts from both of the Benham Rise and the CBF are predominantly labradorite and andesine, with a minor amount of bytownite, and it is enriched in LREEs, Ba, Sr, and Pb and exhibits strong positive Eu anomalies. However, there exist obvious differences in plagioclase compositions between these two tectonic sites. The source lithology of the Benham Rise basaltic rocks could be garnet pyroxenite, and yet that of the CBF could be spinel-lherzolite. The calculated mantle potential temperature beneath the Benham Rise is 1439°C–1473°C, which is significantly higher than that beneath the CBF (1345°C–1381°C), suggesting there existed thermal anomaly beneath the Rise during basaltic magmatism. This study also calculated the temperature and pressure of the clinopyroxenes and plagioclases, which have been used to indicate magmatic processes. Finally, we suggest that the Benham Rise basaltic rocks may be related to a mantle plume (e.g., the Oki-Daito mantle plume), and the CBF was once located in a back-arc spreading center behind an active subduction zone. The extinction of the Oki-Daito mantle plume activity might be at about 20.9 Ma, and cessation of the back-arc spreading of WPB was at about 29.1 Ma or younger.