Mineral Matter Content Research Articles

Mineral matter in municipal solid waste

Municipal solid waste (MSW) contains mineral materials which are seldom considered as a potential resource. Currently, the waste management sector pays attention to recyclable parts, biodegradable material, waste-to-energy fraction, and residues after waste reuse and recycle. In contrast, this study focus as on the mineral matter in MSW. The aim was to analyze and discuss the sources of mineral matter in MSW, the impact which the minerals have on waste management technologies, and finally, the possibility to recycle the mineral matter. The contribution of inorganic matter in the MSW stream is significant (about 20 wt.%). In the years 2012-2015, the average content of mineral matter in mixed MSW in Poland ranged from 16 wt.% to 36 wt.%, and the content of organic in MSW ranged from 20 wt.% to 42 wt.%. Minerals in MSW have rather negative impact on waste management technologies and their final products, and can be sorted out from the MSW stream, either in the households or in a central sorting line. However, in central collection and separation systems it is difficult to obtain a mineral matter fraction in subsequent processing steps due to technological limitations (inefficiency of devices), high degree of waste fragmentation and pollution of mineral matter with other waste. This indicates a hampered ability to separate minerals in a form available for reuse, so an effective system should be based on improved segregation at the source.

Relationships between the biomass and production of bacterio- and phytoplanktonic communities

Quantitative ratios of the biomasses of bacterio- and phytoplankton, interrelation of their production characteristics, and association of the functional characteristics with environmental factors were studied for Lake Khanka, the Yenisei River and the Krasnoyarsk Reservoir. The ratio between the biomasses of bacterioplankton (Bb) and phytoplankton (Bp) in these water bodies was shown to vary within the range exceeding three orders of magnitude. Bacterioplankton biomass was relatively stable and varied from sample to sample by an order of magnitude. In more than 50% of the samples (total sample number, 495), bacterioplankton biomass exceeded that of the phytoplankton. The average Bb/Bp ratios for Lake Khanka, Yenisei River, and Krasnoyarsk Reservoir were 5.1, 2, and 1.4, respectively. Increased Bb/Bp ratios were found to correlate with elevated specific (per unit biomass) phytoplankton production. This finding indicated additional supply of biogenic elements to phytoplankton due to their recycling by bacterial communities. The ratio between bacterioplankton and phytoplankton production for Lake Khanka varied from year to year (0.07 to 0.76). For the Yenisei River and the Krasnoyarsk Reservoir these ratios were on average 0.19 and 0.27, respectively. According to the literature data for other water bodies, bacterial production may reach from 10 to over 100% of the primary production. The equilibrium density of bacterioplankton (maximal density of the population) in Lake Khanka was ~1.5 times higher than in the Yenisei River and the Krasnoyarsk Reservoir due to higher content of suspended mineral matter and associated organo-mineral detritus in the lake. The interaction between dissolved organic compounds sorbed of the surface of mineral particles results in chemical alteration of biochemically stable substrate into compounds which may be assimilated by aquatic micoorganisms.

Determination of the Content of Mineral Substances Applying Different Methods of Chemical Analysis

In the course of this study, we have determined the content of mineral matter of calcium, chlorides, sodium and potassium, by means of volumetric and instrumental analysis methods in infusion solutions. Infusion solutions that we used for analysis were purchased commercially in pharmacies in the Republic of Srpska. We have used volumetric methods, complexometry to determine calcium and Mohr method to determine chloride. Sodium and potassium were determined instrumentally, by flame photometry. Calcium was also determined by this method. The aim of the study was to demonstrate that the concentration of the aforementioned elements in infusion solutions corresponds to concentrations indicated on the label. Obtained results for content of sodium and chlorides do not deviate for more than allowed ±5%, in all three samples. Deviations occurred when content of calcium and potassium was determined by flame photometry.

The joint action of saline water and flotation reagents in stabilizing froth in coal flotation

The previous study indicates that both reagent usage and the variation of water conductivity affect froth stability and therefore coal flotation behavior. In this study, Central Composite Rotatable Design (CCRD) was conducted to investigate the interaction11A term in statistics meaning that the effect of two or more variables is not simply additive. of saline water with collector (diesel) and frother (MIBC) in controlling froth stability which was indicated by air recovery. The results show that a significant interaction (see footnote 1) existed between flotation reagents and water conductivity, which affected froth stability, combustible matter recovery and the mineral matter content of flotation concentrate. Frother and salt ions had a joint action in producing a more stable froth. On the other hand, collector and salt ions had a joint action in reducing the combustible matter content of flotation concentrate and the combustible matter recovery. A methodology was developed to avoid overly stable froth and maximize coal flotation performance by adjusting reagent additions based on water conductivity.

The quality of coal and hydrogeological characteristics in deposit 'Delici and Peljave-Tobut' near Ugljevik

Geological study of 'Delici and Peljave - Tobut' coal deposit, located in north-eastern part of the Republic of Srpska (B&H), has given a new insight into geological structure of coal-bearing series and quality of coal. Coal-bearing series was formed in a lower Miocene lake and has complex geological-tectonic structure and litho-facial diversity. Two coal seam are identified within this series - the older one, so-called the Main coal seam (developed throughout the deposit; with major coal reserves) and the younger one - Upper coal seam, which is of a restricted areal extent. Coal from this deposit has a variable ash content -34.91% on average in the Main seam and 44.58% on average in the Upper seam. This coal has an average sulfur content of 3.73% in the Main seam and 2.73% in the Upper seam. An average moisture content is 19.07% in the Main seam and 18.26% in the Upper seam. An average lower heating value is 111.671 kJ/kg for the Main seam and 7.952 kJ/kg for the Upper seam. Petrographic study of coal have shown that the coal of this deposit has high content of huminite, increased content of liptinite, low content of inertinite and increased content of mineral matter. Densinite is a dominant maceral of huminite group, while ulminite is less abundant. The content of other macerals of this group is low.

PCDDs, PCDFs and PCNs in products of microwave-assisted pyrolysis of woody biomass--Distribution among solid, liquid and gaseous phases and effects of material composition.

Microwave-assisted pyrolysis (MAP) of lignocellulosic biomass is a technique that could potentially be used to produce and upgrade renewable energy carriers. However, there is no available information about the formation of dioxins and other organic pollutants in MAP treatment of woody biomass. In this study, MAP experiments were conducted in lab-scale using virgin softwood, bark, and impregnated wood as feedstocks. The non-condensable gas, liquid (fractionated into aqueous and oil phases), and char fractions generated during pyrolysis were collected and analysed for polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs) and naphthalenes (PCNs). The concentrations of PCDDs, PCDFs and PCNs in the pyrolysis products ranged from 0.52 to 43.7 ng kg(-1). All investigated compound groups were most abundant in the oil fraction, accounting for up to 68% (w/w) of the total concentrations. The highest PCDD, PCDF and PCN concentrations were found from the pyrolysis of bark, which has relatively high contents of chlorine and mineral matter, followed by impregnated wood, which contains organic and metal-based preservatives. The homologue profiles of all three compound groups were dominated by the less chlorinated homologues. The homologue abundance decreased as the degree of chlorination increased. This trend was observed for all three feedstocks.

The effect of mineral matter on the physicochemical and sorption properties of brown coal-based activated carbons

A series of new carbonaceous adsorbents has been obtained by means of direct and physical activation of Polish brown coal, characterised by high mineral matter content. The influence of activation procedure on the porous structure development, acidic and basic surface groups generation as well as the sorptive properties of the adsorbents prepared toward liquid and gas pollutants was tested. Additionally the effect of mineral matter presence on the physicochemical and sorption properties of materials prepared was studied. The final products were micro/mesoporous activated carbons of medium developed surface area ranging from 407 to 674 m2/g, showing strongly basic or intermediate acidic-basic character of the surface. The results obtained during this study showed that direct and physical activation of low quality brown coal led to activated carbons with very good sorption capacity both toward gas contamination of acidic character (especially nitrogen dioxide) as well as toward methylene blue and inorganic pollutants of molecules of size similar to that of iodine molecules. It was also proved that demineralization of prepared activated carbons by hydrochloric acid significantly reduced their ability to toxic gases sorption, but simultaneously increased the efficiency of removing impurities from the liquid phase.

Characterization of Food Waste and Its Digestate as Feedstock for Thermochemical Processing

The products of a commercial one-stage anaerobic digestion and a laboratory-scale pyrolysis of raw food waste (RFW) and digestated food waste (DFW) were characterized to evaluate the treatment effect, product yield, and physicochemical properties. The pyrolysis of the RFW and DFW resulted in generation of 7.4 and 5.3 wt % of gas and 60.3 and 52.2 wt % of bio-oil, while biochar yields decreased with an increase in the pyrolysis temperature. Differential thermogravimetric tests of RFW and DFW show 20% in both solid residues produced at a temperature of 550 °C, indicating a relatively low impact of the digestion process on the RFW. The mineral matter content was found to be lower for RFW compared to DFW. The variation in the content of fixed carbon and volatile matter reflected the effect of anaerobic degradation of the food waste. The bio-oils showed a low concentration of phenols, esters, and derivatives of hydrocarbons for DFW compared to RFW. The specific heat capacities were determined for RFW and DFW, ...

Dry matter yield and forage quality traits of oat (Avena sativa L.) under integrative use of microbial and synthetic source of nitrogen

The natural microbes are potential contributor to build up soil nitrogen through transformation of molecular nitrogen to plant available forms. Therefore, in the present study, we investigated the contribution of biofertilizer to reduce the synthetic nitrogen application without deteriorating the yield and forage quality. The supplementary nitrogen rates included 0, 40, 80 and 120kgha−1 and the seed inoculation was carried out with the mixture of Azospirillum+Azotobacter spp. The experiment was laid out in randomized complete block design with factorial arrangement. The results indicated that organic matter contents and ether extractable fat were negatively associated with both nitrogen and inoculation factors. The inoculation produced 6.58%, 9.58%, 2.51%, 16.94%, 10.26%, 17.59%, 14.02%, 33.81% and 66.18% more No. tillers, plant height, leaf to stem ratio, dry matter yield, mineral matter contents, crude fibre, crude protein, crude protein yield and total digestible crude protein yield, respectively over uninoculation. The interactive effects indicated that inoculation alone without nitrogen application produced 19.16% and 6.87% more dry matter yield and crude protein (%), respectively. The beneficiary effects of biofertilizers on growth and dry matter of oat were more pronounced at intermediate level of inorganic nitrogen which was gradually decreased at higher nitrogen levels. The CP, CPY and DCPY achieved with inoculation alone were statistically equivalent to plots fertilized with 0 and 40kgNha−1. It is clear that plots sown with inoculated seeds must be fertilized with 80kgN to produce higher dry matter and economic returns. However, the highest protein contents in dry matter were recorded with highest fertilization level along with inoculation. By giving due attention to stimulatory effects of bacterial species in the present study, it is therefore, recommended to integrate the use of biofertilizers with supplemental dose of synthetic nitrogen source to sustain crop production.

Organo-refining of high-ash Indian coals at bench scale

Organo-refining is a process of solvent extraction through which organic matters are extracted from coal using organic solvents. Indian coals have high mineral matter content ranging from 25 to 45wt.% (dry basis). The ash in coal is highly disseminated, which makes it difficult to remove by physical beneficiation. Thus, chemical beneficiation is needed to remove the mineral matter. This study was conducted for high ash Indian coals at bench scale. The capacity of the bench scale plant was 40kg/batch feed basis. Coking coal, washery discards and thermal coals of bituminous origin were used as feed material. The mineral matter of these coals varied in the range of 27–36wt.% (db). The feed size of the particle was below −0.5mm. N-methyl-2-pyrrolidone (NMP) and ethylenediamine (EDA) were used as main solvent and co-solvent respectively. The extraction was done at 200°C with 1:6 coal to solvent ratio (by mass, wt./wt.) for 60min. Extraction was followed by solid–liquid separation, solvent recovery and washing of products. The feed and product materials were subjected to proximate analysis, ultimate analysis, and Free Swelling Index (FSI) tests. Organo-refining process produced clean coal yield in the range of 30–45% and clean coal mineral matter was less than 10% for coking as well as non-coking coals. Free Swelling Index (FSI) also improved from 1–5 range for feed coals to 7–8 for product clean coals. Two types of filter (basket and centrifuge) were also tried for separation of solid and liquid from different types of slurries. It was observed that cake moisture can be reduced by 6–12% points for these slurries using decanter centrifuge. The cake moisture reduced to 70% from 76% for clean coal slurry and 60% to 48% for reject slurry. The clean coal yield increased by 5 units (from 35% to 40%) with decanter centrifuge filter. In order to have better filtration and precipitation, the extraction was carried out by mixing of two different raw coals (TL and TC) in a certain ratio (1:1 to 1:3). Also, the extraction was done separately for TL and TC coals and then the clean coal extracts were mixed in 1:1 to 1:3 proportions. Mixing of two raw coals gives better results (36wt.% yield with 6.4% ash clean coal) than mixing of their extracts (30wt.% yield with 6.7% ash clean coal).

Mineral Matter in Nigerian Coals and Tar Sand and Their Implications in Binary Blend Formulation and Co-Carbonisation

Abstract In blend simulation for metallurgical applications, the knowledge of the type and amount of mineral matter in coal and other additives, as well as their derivatives as a result of combustion is important in assessing the coke quality and blast furnace efficiency. X-ray diffraction (XRD) and X-ray fluorescence (XRF) techniques were used in assessing the mineral matter contents and oxides produced up on combustion of the following Nigerian coals: Afuze (AFZ), Garin-Maiganga (GMG), Lamza (LMZ), Shankodi-Jangwa (SKJ), and Chikila (CHK) in addition to a tar sand from Ondo (OTS). Coal samples from Afuze (AFZ) and Chikila (CHK) were found to contain quartz, hematite, and anhydride as the dominant minerals. The Garin-Maiganga coal sample (GMG) was found to contain quartz, magnetite, anhydride, and magnesite. Quartz and hematite were dominant in Lamza coal (LMZ), while Shankodi-Jangwa coal (SKJ) is associated with dolomite and quartz. The bitumen was found to contain quartz, kaolinite, and rutile. The XRF analysis revealed the presence of sixteen elemental oxides: the most abundant being silicon dioxide, ferric oxide, aluminium oxide, sulphur trioxide, calcium oxide, and titanium oxide. Amongst the coal samples, CHK, AFZ and GMG coals have low acidic/basic and basic/acidic ratios, which indicate that cokes originating from them may form the least slag with the best blast furnace efficiency.

Mineral matter, major and trace element content of the Afşin–Elbistan coals, Kahramanmaraş, Turkey

The Afşin–Elbistan coal basin is one of the most important coal deposits of Turkey. The mineral matter, major and trace element concentrations of the Afşin–Elbistan coals and their modes of occurrence are discussed in this study. The coal seam is located within the Upper Miocene–Pliocene aged Ahmetcik Formation which is represented by fluvial–lacustrine facies. Thickness of the coal zone is 80m, but it reaches 105m in the Kışlaköy sector. A total of 86 samples were taken from the Kışlaköy open-pit mine and from the 14 boreholes drilled by the General Directorate of Mineral Research and Exploration (MTA) for coal exploration. The proximate, XRD, SEM-EDS, major and trace element analyses were conducted on the samples. The studied coals are characterized by relatively high moisture, ash, total sulfur, volatile matter contents and low gross calorific values. The mineral matters of the Afşin–Elbistan coal are represented by calcite, quartz, pyrite, feldspar, aragonite, opal-CT, gypsum, jarosite and clay minerals. Strontium, Rb, Sm, Zr, Hf, Nb, Mo, U, Zn, Pb, As, Mn, Co, Cr and Ni concentrations detected by EDP-XRF are higher than the world brown coal values. Many of the trace elements showing positive correlations with ash content imply inorganic affinity. The element concentrations of the coals are mainly related to the carbonate, silicate, sulfide, phosphate, ore minerals and fossil shells. However, some elements have also organic affinities.

Características nutricionais e perdas no processo fermentativo de silagens de milho, colhidas em diferentes estádios reprodutivos com diferentes processamentos de grãos

The aim of this study was evaluate the harvest of corn plant in different reproductive stages and different processing grain about losses and nutritive value of silages. Significant differences in the stage of harvest showed up in lower (P <0.05) for dry matter (26.70% against 34.78%) and higher values for contents of mineral matter (4.35 % against 3.87%), acid detergent fiber (32.63% vs. 23.36%) and neutral detergent fiber (52.06% against 42.07%) in the level of harvest dough (R3 ) compared to the level of hard grain (R5), respectively. High dry matter losses were found at stage R3, which are the dimensions of 14.59% and 20.06% respectively to silages with and without grain processor, significantly different (P> 0.05) results found for the R5 stage, which had an average loss of around 5.77%, demonstrating that silage harvested at R5 stage, allow greater dry matter recovery and hence greater savings for the farmer. Regarding the parameter of losses of crude protein, there were no significant differences for the effects of isolated or associated stages of harvesting and processing of grain in corn silage. Large differences can be perceived as the loss of neutral detergent fiber and loss of acid detergent fiber silage, justified by the increase in the levels of acid detergent fiber in the average share of 22.96% in the silage harvested at stage R3 and reduction in their concentration with an average of 4.60% for the R5 stage. No significant differences were observed (P <0.05) for the particle size as the different treatments, only significance being observed as the participation of whole grains in bulk, this ranging on average from 2.59% to 10.27% dry matter, respectively for stage R3 and R4-R5. In general, silage maize plant reproductive stage R5 provided smaller losses nutritious silage storage and greater accumulation of grains in bulk when compared to R3 stage.

Study of Washability Characteristics of Coals from Seam-IX of Jamadoba Colliery of the Jharia Basin, India

The present paper entails the results of investigations carried out on the coals of Seam-IX from Jamadoba colliery, Jharia basin to know their washability characteristics. The coal samples have been subjected to liberation study, sink-float tests, froth-floatation study and alternative process to obtain maximum clean coal fractions. To understand the nature of mineral matter occurrence, petro-chemical characteristics have also been studied. It is observed that −3 mm top-size fraction has a relatively better potentiality to produce clean coal compared to any other top-size fractions (−20, −15 and −10 mm). However, the crushing of ROM coal to fine size is more power consuming and will also generate more fines (−0.5 mm). This would require modification in the washing practices. This would eventually increase the cost of coal washing. The coal particles free from any mineral contamination is seen maximum (14.28%) in −3 mm top-size fraction and also the dispersed mineral matter is less in this (−3 mm) top-size fraction and the beneficiation is relatively easy. The optimum result of floatation is achieved at high dose of collector and medium dose of frother. Through petrographic study a substantial decrease in the mineral matter content is noticed from 29.2% in the raw coal sample to 8.2% in the washed coal. Similarly a concomitant fall in the ash yield was also recorded from 38.48% in the raw coal to 15.27% in the washed coal.

Effect of Replacement of Refined Wheat Flour with Buckwheat Flour on Quality Characteristics of Cookies

The investigation was carried out to study the effect of buckwheat flour incorporation on nutritional, mineral and quality characteristic of developed cookies. The cookies were prepared by adding 10, 20, 30 and 40 % level of buckwheat with refined wheat flour to evaluate acceptability and quality of cookies. Results revealed that buckwheat flour contained 11.35, 2.20, 10.41, 70.40, 1.68 and 2.67 per cent of moisture, fat, protein, carbohydrates, crude fiber and ash respectively. The higher ash content indicates higher mineral matter content of buckwheat. The values for iron, zinc, manganese and copper contents of buckwheat were recorded to be 2.67, 2.53, 1.52 and 0.49 mg/100 g flour respectively. Cookies were analyzed for their proximate composition and microminerals content. In terms of sensorial quality, cookies containing 20 per cent buckwheat flour were found to be superior. It is concluded that cookies with high mineral content can be prepared by partial replacement of refined wheat cookies with buckwheat flour.

Cyclic sedimentation pattern in Lake Veetka, southeast Estonia: a case study

Abstract A sediment core from Lake Veetka, southeast Estonia, 1077 cm in length and covering 10,500 calibrated years, was examined using loss-on-ignition, grain-size distribution and AMS 14C dating to reconstruct depositional dynamics. The studied core, recovered from the northern part of the lake, shows a cyclic pattern of organic and mineral matter concentration with cycle durations of 100-400 years. Cyclicity is displayed better in sediments laid down between 9,200 and 5,600 cal BP. Within two time windows (5,600-5,100 cal BP and from 1,200 cal BP to the present), sediment composition changed drastically on account of a high and fluctuating mineral matter content, obviously driven by different factors. Little Ice Age cooling is characterised by the highest proportion of mineral matter, and the Medieval Warm Period is typified by high organic matter content. The cyclic change of organic and mineral matter has been related to climate dynamics, most likely an alternation of wet and dry conditions, changes in the water level of the lake and differences in bioproduction

Influence of mineral matter content on static burning rate of Virginia tobacco from different production areas in Serbia

The aim of this study was to determine the influence of particular element of the minerals complex in Virginia tobacco, from different production areas, on value of static burning rate (SBR). Large leaf tobacco, type Virginia from five production areas in Serbia during year 2013, was used as a research material. Mineral content was determined by the atomic absorption spectrophotometer. Static burning rate was determined by the device Free Burning Rate Meter. Resulthad confirmed that the most important factors for mineral matter content in tobacco leaves are soil pH, organic matter content in soil and vicinity of large industrial centers. A very strong positive correlation between the content of Ca and Pb, a positive correlation of Mg and Na, and a strong negative correlation of Cd and both SBR values has been found.Virginia tobacco type grown at Senta area had the highest values for both speeds of combustion (4.99mm/min for SBRl and 69.97mg/min for SBRm). Virginia tobacco type grown at Sremska Mitrovica area had the lowest values for both speeds of combustion (3.95mm/min for SBRl and 49.11mg/min for SBRm).

Petrography and palynology of Late Oligocene and Middle Miocene coals in the Gelibolu peninsula, NW Turkey

In this study, coal samples from two different coal zones located close to each other were examined. They occur in the Late Oligocene Osmancık and Miocene Gazhanedere formations in the Gelibolu peninsula, in the SW part of the Thrace Basin (NW Turkey). This paper focuses on the organic-petrographic composition and depositional conditions of the two coal zones by using coal petrography, including maceral ratios, and palynology. The maceral composition of the Oligocene coal samples is similar to that of the Miocene coal samples. The coal samples from both locations are characterized by a high content of huminite group macerals, ranging from 46% to 78%. The prevailing maceral from this group is gelinite (31%-65%), which is indicative of a high degree of gelification of organic matter. Relatively low contents of liptinite (not exceeding 9%) and inertinite (not exceeding 8%) were also determined. The tissue preservation of organic matter was poor. The content of mineral matter is inferred from microscopic studies and is variable but generally high, varying from 6% to 46%, similar to that of other Turkish coals; it consists mostly of quartz, calcite, clay minerals, and pyrite. This input of mineral matter is probably related to periodic inundations of swamp. The mean reflectance values of samples ranged from 0.42% to 0.50% Ro, suggesting that the rank of coal is subbituminous according to ASTM classification. Low tissue preservation index (TPI) and high gelification index values suggest that both coal zones were deposited in a limnic environment. The presence of framboidal pyrite and low TPI reflect high pH values (pH 6-7) and reducing conditions during peat deposition. Two different palynological assemblages may be distinguished based on the percentages of palynomorphs. The first assemblage including the stratigraphical marker species Dicolpopollis kockelii (Calamus) suggests the Late Oligocene. The age of the second assemblage is probably the end of Middle Miocene.

Camel colostrum: Nutritional composition and improvement of the antimicrobial activity after enzymatic hydrolysis

Camel colostrum collected within 24 h after parturition was analyzed for physicochemical and microbiological composition. The average contents of fats, dry matter, mineral matter and proteins were 1.71±0.51, 199.55±16.93, 9.75±0.5 and 143.42±36.42 gL-1, respectively. Microbiological analysis of colostrum samples showed richness in yeasts and Lactic acid bacteria and absence of coliforms. The good microbial quality of camel colostrum is due to a number of antimicrobial molecules such as immunoglobulins and lactoferrin. The antimicrobial activity was evaluated against the pathogens Bacillus cereus, Staphylococcus aureus, Enterococcus faecium and Pseudomonas aeruginosa. At concentration of 20 g L-1, colostrum caused an important inhibition of growth of all tested bacteria. It therefore seemed interesting to assess whether the compounds inhibit the growth of tested strains present in camel colostrum are resisting to the action of digestive enzymes. An in vitro hydrolysis by pepsin and pancreatin was then conducted. Hydrolyzed camel colostrum was still active against all pathogenic strains with inhibition rate ranging from 15.8% to 24.18%. This finding highlights the presence of antimicrobial fragments/peptides released during proteolytic hydrolysis that may contribute to the antimicrobial activity in camel colostrum and play a significant role in the host defence system.

Estimating the limiting absolute sorption of carbon dioxide by coal for coal-bed storage of carbon dioxide

This paper estimates the limiting absolute sorption of carbon dioxide by five coals using the isotherm space transformation (IST) method. Estimating the maximum number of moles that can accumulate in a unit mass of sorbent, regardless of pressure and temperature is useful for estimation of the carbon dioxide storage capacity of an underground coal reservoir. The IST method captured the behaviour of the coal-carbon dioxide system for representative ranges of pressure and temperature and generated sorption isotherms for any temperature within the range. For the investigated pressure and temperature range, a good fit was found between the experimental points and the regression curve. It is reasonable to assume, therefore, that the equation well captured the behaviour of the coal-CO2 systems studied. The value of limiting absolute sorption was found to be inversely proportional to the mineral matter content. No relationship was established between the petrography of the investigated samples and the sorption (or storage) capacity of the coal. The results suggest that in the subcritical pressure range, the sorption capacity is not directly correlated with the limiting absolute sorption values. [Received: March 21, 2014; Accepted: September 17, 2014]