This study aims to investigate the characteristics of ash accumulation and slagging in boilers during low- and medium-load operation and to analyse the migration pattern of alkali metals in high-alkali coal. In this paper, the ash accumulation characteristics and slagging trend of the furnace interior under a 500 MW load were investigated using numerical simulation by comparing the ash accumulation and slagging characteristics under two different burner configurations, and analysing the slagging trend of the furnace with upper burner arrangement and lower burner arrangement by taking the deposition location on the furnace wall and the deposition rate and the temperature of the furnace wall as the indices. The existing formation of sodium in Jundong coal at different temperatures was investigated using computational methods; SiO2, Al2O3, and kaolin were doped separately; and the migration and transformation characteristics of their different additives on the sodium-based compounds in Jundong coal were explored. The results showed that, under a 500 MW load, the size of the tangent circle formed in the furnace by commissioning the upper burner condition was larger than the lower burner, and the main combustion zone was larger than the lower burner. The ash accumulation of coal ash particles in the boiler was mainly concentrated in the hearth region, and the deposition rate was higher at the height regions of 10 m and 25 m in the hearth. The solid-phase NaCl transition temperature was reduced to 350 °C after the doping of SiO2 in Jundong coal, and the doping of Al2O3 inhibited the transition of solid-phase NaCl, promoted the generation of gas-phase NaCl, and had certain inhibitory effects on the generation of sodium-based silica–aluminium compounds, the content of which at all temperatures was inversely proportional to the proportion of doping. The doping of kaolin promotes the transformation of solid-phase NaCl and inhibits the generation of gas-phase NaCl.
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