Lead isotope analysis of crucibles and a metal droplet has revealed new information about the provenance of the lead and copper resources used at Zhengzhou Shang City during the Upper Erligang period. The crucibles were found to be divided into three types and associated with copper smelting/refining, leaded tin bronze alloying, and bronze pouring. The copper smelting/refining crucible contains common lead (206Pb/204Pb = 18.12) and low Pb content in its slag layer. In contrast, the bronze processing crucibles mostly contained highly radiogenic lead (206Pb/204Pb ≥ 19). One bronze pouring crucible was found to have an exceptionally low 206Pb/204Pb ratio (≤17.2), indicating that it was made with recycled bronze from an earlier period. This research is the first to reveal the lead isotope characteristics of the copper material used during the Upper Erligang period, which is strikingly different from the dominant highly radiogenic lead reported in previous research. The Middle Yangtze River Valley is tentatively proposed as the geological source. This result also shows that the Upper Erligang Shang people had a complex metal supply network, including at least southern copper, highly radiogenic lead, and recycled early bronze.
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