In this paper, a comprehensive investigation was conducted to the factors affecting the crystal structure and microwave dielectric properties of the SrLn2O4 (Ln= Ho, Tm) ceramics. Rietveld refinement results of the XRD patterns conclude that SrLn2O4 (Ln= Ho, Tm) ceramics belong to orthorhombic system with Pnam symmetry. The effects of porosity, packing fraction and lattice energy on the properties of SrLn2O4 (Ln= Ho, Tm) ceramics were precisely analyzed. Excellent properties for SrTm2O4 ceramics (εr = 14.49, Q×f = 41138GHz, τf = -36.69 ppm/℃) and SrHo2O4 ceramics (εr = 14.87, Q×f = 24021GHz, τf = -17.03 ppm/℃) can be achieved due to good densities and high packing fraction and lattice energy. In addition, CaTiO3 is proved to be well compatible with SrLn2O4 (Ln= Ho, Tm) ceramics. Near-zero τf were obtained in SrTm2O4 + 1.8wt% CaTiO3 ceramic and SrHo2O4 + 1.2wt% CaTiO3 ceramic, making them ideal candidates for applications in microwave band.
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