Super-resolution (SR) technology has shown great potential for improving the performance of the mapping and classification of multispectral satellite images. However, it is very challenging to solve ill-conditioned problems such as mapping for remote sensing images due to the presence of complicated ground features. In this paper, we address this problem by proposing a super-resolution reconstruction (SRR) mapping method called the mixed sparse representation non-convex high-order total variation (MSR-NCHOTV) method in order to accurately classify multispectral images and refine object classes. Firstly, MSR-NCHOTV is employed to reconstruct high-resolution images from low-resolution time-series images obtained from the Gaofen-4 (GF-4) geostationary orbit satellite. Secondly, a support vector machine (SVM) method was used to classify the results of SRR using the GF-4 geostationary orbit satellite images. Two sets of GF-4 satellite image data were used for experiments, and the MSR-NCHOTV SRR result obtained using these data was compared with the SRR results obtained using the bilinear interpolation (BI), projection onto convex sets (POCS), and iterative back projection (IBP) methods. The sharpness of the SRR results was evaluated using the gray-level variation between adjacent pixels, and the signal-to-noise ratio (SNR) of the SRR results was evaluated by using the measurement of high spatial resolution remote sensing images. For example, compared with the values obtained using the BI method, the average sharpness and SNR of the five bands obtained using the MSR-NCHOTV method were higher by 39.54% and 51.52%, respectively, and the overall accuracy (OA) and Kappa coefficient of the classification results obtained using the MSR-NCHOTV method were higher by 32.20% and 46.14%, respectively. These results showed that the MSR-NCHOTV method can effectively improve image clarity, enrich image texture details, enhance image quality, and improve image classification accuracy. Thus, the effectiveness and feasibility of using the proposed SRR method to improve the classification accuracy of remote sensing images was verified.