A diverse array/unique set of Dysprosium (Dy3+) activated alkali boro-tellurite glasses were synthesized for the current study using the conventional approach of glass fabrication, and its potential for photonic applications were explored utilizing optical absorption, emission, and decay measurement methods. In the interest of assessing the Rare Earth (RE) ions bonding behavior with the neighboring metal ligand site, and to establish the glasses ionic/covalence nature, bonding parameters (δ) and Nephelauxetic ratios were computed from the absorption band locations. For the as-prepared samples, the Judd-Ofelt parameters and oscillator strengths were determined in order to scrutinize the uniformity of the ligands surrounding Dy3+ ions. The calculated JO values consistently pursue Ω2 > Ω4 > Ω6 pattern for all samples, indicating their asymptotic character. When excited at 387 nm, the emission spectra demonstrate three intense transitions; 4F9/2→6H15/2, 4F9/2→6H13/2 and 4F9/2→6H11/2. Among them, strong yellow emission was observed owing to the increased transfer of electrons to 6H13/2 level. Besides, using JO parameters, radiative parameters were determined which was followed by lifetime studies to actualize the novel applications. The photoluminescence spectra were employed to estimate the CIE coordinates (x, y) and Yellow/Blue ratio, furthermore the (x, y) values were used to calculate the colour purity followed by colour correlated temperature (CCT). This demonstrates that the prepared samples have the ability to emit neutral white light.
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