Methanation Reactor Research Articles

Passive thermal management of CO2 Methanation using phase change material with high thermal conductivity

CO2 methanation is a promising technology for fuel decarbonization. Since methanation is an exothermic reaction, thermal management of the reactor is an important issue. This study investigated the effect of applying metallic phase change material(PCM) for reactor thermal management. In this study, Zn-30 %Al alloy(melting point: 429–509 °C)-based PCM composites were mixed with catalysts in a bench scale reactor, then steady-state and transient methanation were examined. The results at steady state indicated peak temperature was reduced from 464 °C to 411 °C compared to conventional single-catalyst condition. This corresponded to 38 % reduction in the temperature difference between peak and base temperature. Furthermore, temperature distribution in the whole reactor was homogenized, achieving a dispersion of the local thermal stress. This was due to high thermal conductivity of metallic PCM. Then, transient thermal management of PCM was evaluated. Periods for temperature increase between 430 and 450 °C, including PCM melting point, was prolonged 45 min compared to the condition without PCM. This resulted 71 % suppression of exothermic speed. This was due to complex effects of latent heat and high thermal conductivity of metallic PCM, offering thermal buffer in case of catalyst thermal runaway. These results showed the introduction of metallic PCM into methanation reactor provides novel thermal management.

Adaptation of an additively manufactured reactor concept for catalytic methanation with in-situ tar co-reforming of biogenic syngas

The methanation of biogenic syngas for GreenLNG production is a promising alternative for fossil gas. The market price of renewable methane is currently still too high to compete with fossil LNG. One of the reasons for that is the extensive gas cleaning that is necessary for the methanation of syngas from the thermochemical gasification of biomass. A main cost factor is the removal of tar components. As part of the Horizon Europe project CarbonNeutralLNG, we propose a 3D-printed methanation reactor, which makes use of the freedom in design gained by the additive manufacturing process in order to adapt the reactor design for the in-situ co-reforming of tars. The reactor uses heat pipes and a conically widened reaction channel to effectively control local temperatures, suiting the needs of the methanation reaction. A temperature hot spot near the inlet provides the necessary conditions (high temperature, a suitable catalyst and sufficient residence time) for the reforming of tar species, that are present in the syngas. Two reactor concepts are proposed. ADDmeth3.1 uses a dedicated internal channel structure that serves as a counter-current heat exchanger for the feed gas, whereas ADDmeth3.2 is optimized to fill the triangular footprint of a scalable reactor module as best as possible. Both designs were subject to a preliminary feasibility study, to ensure sufficient heat removal and a finite element analysis regarding structural stability was performed. Minimum safety factors against yielding of 3.53 and higher were achieved even without the internal diamond lattice support structure. The triangular modular reactor cell can easily be scaled up by connecting multiple cells in parallel, since the triangular shape can be extended efficiently into a honeycomb pattern.

Utilization of dissolved CO2 to control methane and acetate production in methanation reactor

This study investigated the influence of dissolved CO2 on the selection of metabolic pathway using a methanation membrane bioreactor supplied with H2/CO2. Various ratios of H2/CO2 were applied (3.3, 3.8, 4.0, 4.5, and 5.0 (v/v)) to manipulate dissolved CO2 levels in the medium. The findings revealed a correlation between the concentration of dissolved CO2 and the production of CH4 (positive) and acetate (negative). Specifically, at a dissolved concentration of CO2 above 2.0 ± 0.2 mmol/L, production of CH4 was favored. At the opposite, acetate production was favored at lower dissolved CO2 concentrations, with a maximum concentration of 1.9 g/L observed at 0.9 mmol/L of dissolved CO2. This study demonstrates that the modification of dissolved CO2 levels in a methanation bioreactor can provide a strategy for the selection of metabolic pathways and microbial communities, thereby offering a promising opportunity for optimizing the conversion of CO2 into high-value products such as CH4 and acetate.

Design, multi-aspect investigation and economic advantages of an innovative CCHP system using geothermal energy, CO2 recovery using a cryogenic process, and methanation process with zero CO2 footprint

The significance of devoting attention to environmental pollution control strategies is widely recognized as an effective means of mitigating the harmful environmental effects caused by fossil fuels in industrial and power plant sectors. Carbon dioxide (CO2) capture and recovery technologies have opened up the possibility of utilizing this pollutant gas. Hence, the current study suggests a methodology for the CO2 hydrogenation of the flue gas leaving a power plant. This approach facilitates methane generation via a methanation reactor, subsequently is utilized as fuel for a power plant. For this purpose, a cryogenic method using liquefied natural gas cold energy facilitates CO2 recovery. Moreover, the whole system utilizes geothermal energy to launch a power plant for power generation and supply the power demands of a hydrogen production unit, relying on a water electrolysis process. The hydrogen generated is employed for CO2 hydrogenation, while the oxygen produced is utilized for the combustion reaction. Heating provider units and an absorption chiller are also included in the design. The system is modeled utilizing Aspen HYSYS software. This study incorporates a sensitivity analysis alongside energy, exergy, environmental, and economic assessments. The energy and exergy efficiencies, as determined by the thermodynamic analysis, are 30.87 % and 48.61 %, respectively. Additionally, according to the economic study, the levelized energy cost amounts to 16.65 $/MWh, demonstrating a substantial reduction of 87.6 % compared to the power generation mode. One notable merit of the suggested system lies in its zero CO2 footprint framework, showing a noteworthy supremacy when compared with previous studies.

Thermosiphon Cooling System for a Methanation Reactor: An Experimental Assessment

Abstract Operating the cooling system of a methanation reactor using an open-loop two-phase thermosiphon with evaporating water as the cooling liquid is an effective way to ensure safe operation as it does not rely on a recirculating pump. The aim of the reactor design is to co-generate methane and steam, the latter to be used in a solid-oxide electrolyzer to produce H2 to be injected in the reactor. The passive operation was analyzed to ensure a similar level of stability in the steam production compared to the active operation (i.e., with a pump). A total of 98% of the measured steam produced in passive cooling were within ±9.82% of the individual means, comparing well to ±9.5% for the active cooling operation.

Application of Analytical Solutions of the Reactive Transport Equation for Underground Methanation Reactors

Fluctuations in the production of renewable-based electricity have to be compensated by converting and storing the energy for later use. Underground methanation reactors (UMR) are a promising technology to address this issue. The idea is to create a controlled bio-reactor system in a porous underground formation, where hydrogen obtained from renewable energy sources by electrolysis and carbon dioxide from industrial sources are fed into the reactor and converted into methane. Microorganisms, known as methanogenic archaea, catalyze the chemical reaction by using the two non-organic substrates as nutrients for their growth and for their respiratory metabolism. The generated synthetic methane is renewable and capable to compete with the fossil methane. Mathematical models play an important role in the design and planning of such systems. Usually, a numerical solution of the model is required since complex initial-boundary problems cannot be solved analytically. In this paper, an existing bio-reactive transport model for UMR is simplified to such an extent that an analytical solution of the advection-dispersion-reaction equation can be applied. A second analytical solution is used for the case without dispersion. The analytical solutions are shown for both the educt (hydrogen) and the reaction product (methane). In order to examine the applicability of the analytical models, they are compared with the significantly more complex numerical model for a 1D case and a 3D case. It was shown that there is an acceptable agreement between the two analytical solutions and the numerical solution in different spatial plots of hydrogen and methane concentration and in the methane concentration in the withdrawn gas. The mean absolute error in the mole fraction is well below 0.015 in most cases. The spatial distribution of the hydrogen concentration in the comparison to the 3D case shows a higher deviation with a mean absolute error of approx. 0.023. As expected, the model with dispersion shows a slightly lower error in all cases, as only here the gas mixing resulting in smeared displacement fronts can be represented. It is shown that analytical modeling is a good tool to get a first estimation of the behavior of an UMR. It allows to help in the design of well spacing in combination with the injection rate and injected gas composition. Nevertheless, it is recommended to use more complex models for the later detailed analysis, which require a numerical solution.

Research on the optimal scheduling strategy of the integrated energy system of electricity to hydrogen under the stepped carbon trading mechanism

Under the guidance of energy-saving and emission reduction goals, a low-carbon economic operation method for integrated energy systems (IES) has been proposed. This strategy aims to enhance energy utilization efficiency, bolster equipment operational flexibility, and significantly cut down on carbon emissions from the IES. Firstly, a thorough exploration of the two-stage operational framework of Power-to-Gas (P2G) technology is conducted. Electrolyzers, methane reactors, and hydrogen fuel cells (HFCs) are introduced as replacements for traditional P2G equipment, with the objective of harnessing the multiple benefits of hydrogen energy. Secondly, a cogeneration and HFC operational strategy with adjustable heat-to-electricity ratio is introduced to further enhance the IES’s low-carbon and economic performance. Finally, a step-by-step carbon trading mechanism is introduced to effectively steer the IES towards carbon emission control.

Intensification of ex-situ biomethanation in a bubble column bioreactor by addition of colonized biochips

Biological methanation is a promising sustainable energy technology. To intensify ex-situ biomethanation, a 3-L bubble column reactor was operated continuously under thermophilic conditions, with and without colonized biochips. Studies in batch reactors showed biofilm formation on biochips, with an archaea:bacteria ratio of 5.7 compared to 3.2 in planktonic phase with Methanothermobacter being the dominant archaea. Using colonized biochips in the bubble column increased methane production rate (MPR) nearly threefold, achieving a steady MPR of 15.7 ± 0.5 NLCH4/Lr.d at 84.4 ± 0.9 % methane content. Gas retention time (GRT) was 0.3 h, with 97.4 % and 96.5 % conversion of H2 and CO2, respectively. Volatile fatty acid (VFA) production was under 40 mg/L per day, indicating dominant hydrogenotrophic methanogenic (HM) pathway. The results suggest biofilm formation significantly enhances MPR in ex-situ methanation reactors, advancing towards industrial application.

Low-carbon operation of integrated electricity–gas system with hydrogen injection considering hydrogen mixed gas turbine and laddered carbon trading

Green hydrogen produced by the power-to-gas facilities can be blended into the natural gas system, which is a promising way toward a low-carbon energy system. This paper proposes a laddered carbon trading-based operation model for integrated electricity–gas system with hydrogen injection considering the complex combustion properties of hydrogen mixed gas turbine (HMGT). The power-to-hydrogen, hydrogen methanation, and carbon emission processes are combined with the methane reactor and the flexible carbon capture, utilization and storage facility. Then, a HMGT combustion model based on the system thermodynamics and chemical reaction kinetics is introduced. The piecewise linearization technique is adopted to describe the varying hydrogen production efficiency of electrolysis system. Moreover, an energy balance based quasi-steady-state model to deal with the calorific value problem of the gas mixture is proposed and solved by an advanced sequential cone programming algorithm. Case studies are carried on a 30-bus-20-node system and a 197-bus-171-node practical system in Northwest China to illustrate the effectiveness of the proposed model.

Modeling the dynamic operation of a monolithic CO2 methanation reactor. Evaluation of the response to H2 load fluctuation

A full-scale, 2-D, axially symmetric, heterogeneous, and transient mathematical model is utilized to evaluate the dynamic operation of a honeycomb monolithic reactor during CO2 methanation. A base case is defined, which considers a step-type functionality for H2 load reduction (−20%) and a Ni catalyst. The impacts of the catalyst type (Ni vs Ru), the functionality of the H2 load disturbance, and the monolith's diameter on reactor performance are studied and compared to the base case. Results show that the use of Ru as catalyst, a ramp-type disturbance and a smaller reactor diameter generate a superior dynamic response to the H2 feed disturbance as well as favorable effects on thermal behavior. This is despite the higher temperature gradient generated when using Ru. These findings suggest that the monolithic reactor is a viable technological option for CO2 methanation under flow variations, such as those encountered when employing green hydrogen.

Oxidative conversion of methane: maximizing the carbon yield in natural gas valorization via the C123 process

The Oxidative Conversion of Methane (OCoM) reactor, within the C123 process, is a novel concept for methane valorization into a product stream with a molar C2H4/CO/H2 composition of 1/1/1, i.e., suitable for further hydroformylation. This overcomes the limitations traditionally encountered during the Oxidative Coupling of Methane in the pursuit of a maximum ethylene yield. An experimental assessment was performed using a MnNaW/SiO2 catalyst under industrially relevant conditions (T=850°C, ptot=100 kPa, Wcat/FCH4,in = 2–2.5 kgcat s mol-1, CH4/O2 inlet molar ratio = 3 – 5 mol mol-1 and inlet CO2 molar fraction <20%) as a basis for kinetic model development. Simultaneously pursuing a C2H4/CO/H2 molar ratio of 1/1/1 and a maximum C2 yield, the impact of the operating conditions on the OCoM performance was simulated. Three different real feedstocks were assessed: natural gas, shale gas and biogas. Shale gas exhibited the highest OCoM potential, with as optimal operating conditions T=850°C, Wcat/FCH4,in = 6.5 kgcat s mol-1, CH4/O2 inlet molar ratio = 10 mol mol-1. The achieved C2H4/CO/H2 molar ratio amounted to 1/1.1/3.7 with a carbon yield (ethylene + CO) of 28% mol mol-1 and ethylene yield of 19% mol mol-1. Last, the considerations to validate the C123 process viability are given.

Optimization of Integrated Energy System Considering Electricity and Hydrogen Coordination in the Context of Carbon Trading

In order to improve the consumption of renewable energy and reduce the carbon emissions of integrated energy systems (IESs), this paper proposes an optimal operation strategy for an integrated energy system considering the coordination of electricity and hydrogen in the context of carbon trading. The strategy makes full use of the traditional power-to-gas hydrogen production process and establishes a coupling model comprising cogeneration and carbon capture equipment, an electrolytic cell, a methane reactor, and a hydrogen fuel cell. Taking a minimum daily operating cost and minimal carbon emissions from the system as objective functions, a mixed-integer nonlinear optimal scheduling model is established. This paper designs examples based on MATLAB R2021b and uses the GUROBI solver to solve them. The results show that compared with the traditional two-stage operation process, the optimization method can reduce the daily operation cost of an IES by 26.01% and its carbon emissions by 90.32%. The results show that the operation mode of electro-hydrogen synergy can significantly reduce the carbon emissions of the system and realize a two-way flow of electro-hydrogen energy. At the same time, the addition of carbon capture equipment and the realization of carbon recycling prove the scheduling strategy’s ability to achieve a low-carbon economy of the scheduling strategy.

Biogas upgrading by intensified methanation (SESaR): Reaction plus water adsorption - desorption cycles with Ni-Fe/Al2O3 catalyst and LTA 5A zeolite

This work is conducted within the framework of the Power to Gas (PtG) technologies, focusing on the topic of “biogas upgrading”. The objective is to enhance the CH4 content of biogas streams by utilizing the CO2 present in these streams through the Sabatier reaction, thereby producing a renewable alternative to natural (fossil) gas. Referred to as “SESaR”(Sorption Enhanced Sabatier Reaction), this process employs a catalytic fixed-bed reactor, featuring selective water adsorption using LTA 5A zeolites, as an innovative approach to traditional methanation reactors. The catalyst used comprises Ni-Fe (7.5:2.5 wt/wt) as the active metallic phase supported on γ-Al2O3. Experimental work has been divided in two sets of trials. The first set focuses on the hydrogenation of CO2 as single reactant (H2 also supplied in the inlet with 4:1 = H2:CO2 molar ratio). The second set of experiments was carried out with a synthetic gas mixture representative of a sweetened biogas stream (molar ratio CH4:CO2 = 7:3). Maximum intensification behavior for CO2 conversion was found at 350 °C, also showing that CH4 presence in the inlet gas has negligible influence on the conversion of CO2. Selectivity to CO is minimized at temperatures exceeding 300 °C and remains constant after three consecutive cycles of methanation, water adsorption, and desorption. The Fe-Ni catalyst has demonstrated sustained performance throughout the experimental cycles, exhibiting no significant loss of activity.

A multi-step framework for the design of a flexible power-to-methane process

In this paper, a multi-step framework to design flexible power-to-methane processes is presented. The approach considers all crucial parts of the power-to-methane process, including the renewable energy source. The aim is to provide a design that allows for feasible operation under the fluctuating conditions induced by the renewable energy source at all times. For each part of the process, the operating windows are analyzed and optimized under different site-specific constraints, and recommendations for actions regarding the technical implementations are provided. The impact of the carbon dioxide source is scrutinized, and subsequent scheduling optimization is performed to determine necessary storage capacities. The framework is demonstrated on two carbon dioxide availability scenarios where the renewable energy source is a wind turbine coupled to a polymer exchange membrane electrolyzer that produces hydrogen, which is then converted to methane in a fixed-bed reactor. The results show that the feasible operation of the system strongly depends on the site-specific conditions. In particular, the availability of carbon dioxide impacts the flexibility of the methanation reactor. When the stochiometric ratio between hydrogen and carbon dioxide cannot be sustained, the operating window of the reactor deteriorates significantly. However, it is shown that appropriate integration and scheduling of storage capacities debottlenecks the reactor and enables the utilization of all electricity generated by the wind turbine.

Proposal and simulation of a geothermal-driven water electrolysis unit integrated with a CO2 methanation process toward a novel sustainable framework

This paper presents a novel multigeneration structure powered by geothermal energy, featuring a geothermal power plant, water electrolyzer unit, methanation reactor, fuel and utility production unit, supercritical-carbon dioxide cycle, and both high-temperature and low-temperature organic Rankine cycles. Simulated in Aspen HYSYS software and analyzed from energy, exergy, economic, and environmental (4E) perspectives, the process, under base operating conditions, is capable of producing 20,940 kW of power, 620.70 kg/h of hydrogen, 4,913 kg/h of oxygen, 12.35 kg/s of domestic hot water, 5.293 kg/s of chilled water, and 2.659 kg/s of carbon dioxide with over 99% mole purity. Efficiency assessments reveal energy, exergy, and electrical efficiencies of 10.69%, 48.53%, and 3.73%, respectively, with a total unit product cost of $3.11/GJ and a net present value of $67.40 million. The water electrolyzer unit, with an 88.94% exergy efficiency and a 10% contribution to total system irreversibility, is identified as the most efficient subsystem. The geothermal power plant accounts for the highest system irreversibility at 61%, while the combustor in the fuel and utility production unit contributes 11,250 kW of irreversibility. Environmentally, the system operates with zero emissions and significantly reduces annual CO2 emissions compared to coal, oil, biomass, and natural gas power plants by 453.14 × 106, 576.80 × 106, 111.92 × 106, and 344.10 × 106 kg, respectively.

Scaling up the advanced dry reforming of methane (DRM) reactor system for multi-walled carbon nanotubes and syngas production: An experimental and modeling study

Dry reforming of methane (DRM) offers an avenue for converting carbon dioxide (CO2) and methane (CH4)—the two major greenhouse gases—into syngas, a vital chemical precursor. However, DRM is constrained by high energy demands, catalyst deactivation, and an unfavorable H2/CO ratio. Previously, a unique dual-reactor system that produces multi-walled carbon nanotubes (MWCNTs) and syngas as products was proposed. This system offers at least 65 % CO2 conversion at 50 % of the energy demands of DRM. The present study experimentally proves and scales the concept from the milligram scale to the multi-gram scale and, ultimately to the multi-kilogram scale of MWCNT production. This study also introduces and experimentally validates a lumped Langmuir-Hinshelwood-Haugen-Watson (LHHW) kinetics model capturing a network of nine primary reactions involving CO, O2, H2, CH4, CO2, H2O, and solid carbon. The model performs within a 5 % error margin at the milligram scale for the carbon formation rate at 550 °C. The model is validated at 500 °C, 550 °C, and 600 °C on a multi-gram scale to capture the temperature effect. The CH4-conversion and CO2-conversion predictabilities at this scale are within 8 % and 30 % error margins, respectively. At a multi-kilogram scale, the model predicts the carbon formation rate within a 21 % error margin at 550 °C. Finally, characterization of the MWCNTs using Raman, SEM, TEM, STEM, and TGA-DTA confirms MWCNT quality consistency at all scales. This study, in summary, provides valuable experimental scale-up data and a kinetics model that can serve as a foundation for the development of future commercial-scale reaction systems.

High-capacity CO/CO2 methanation reactor design strategy based on 1D PFR modelling and experimental investigation

An in-depth analysis of oil-cooled and naturally ambient air-cooled fixed bed reactors for catalytic methanation of a feedgas containing CO and CO2 has been performed. Combined investigation of modelling and experiments showed, that small tube-to-pellet diameters ratios and optimized reactor cooling are beneficial for high-capacity CO/CO2 methanation. Very good model accuracy was proven with a 1D approach for small diameter reactor pipes. It is shown that the reactor design sweet spot under consideration of input gas capacity, methane output concentration, catalyst degradation and pressure loss can be assessed by the experimentally validated reactor model. The study reveals insights to the mechanism of combined CO and CO2 methanation showing that initial CO methanation is kinetically limited, while subsequent CO2 methanation is ruled by the kinetics of the reverse water gas shift reaction. Finally, this works aim is to provide a design strategy for effective and cheap high-capacity CO/CO2 methanation reactors for industrial scale using commercial pellet catalysts in oil-cooled tube-bundle-reactors.

Optimal Operation of Hydrogen Energy Coupling Integrated Energy System considering Green Certificate, Ladder-Type Carbon Joint Trading, and Dual-Incentive Demand Response

Under the “carbon peak and carbon neutrality” goal, the construction of an efficient, low-carbon, and economical energy supply system is of great significance for advancing a dual carbon strategy. In allusion to the integrated energy systems (IES) with hydrogen energy coupling, a hydrogen energy coupling IES low-carbon optimization operation strategy that took account of green certificate and ladder-type carbon joint trading and dual-incentive demand response was proposed in this paper. First, a hydrogen energy multiuse system composed of an electrolyzer, a hydrogen fuel cell, a methane reactor, and hydrogen energy storage was constructed to make full use of the low-carbon cleaning characteristics of hydrogen energy. Besides, a combined model of hydrogen mixed with natural gas was established to improve the utilization efficiency of hydrogen energy. Second, a dual-incentive demand response model including price incentives and subsidy incentives was constructed to fully use the ability to adjust demand-side resources. Next, in view of the carbon emission reduction mechanism of the green certificate, a green certificate and ladder-type carbon joint trading mechanism was constructed. In addition, a green certificate trading mechanism and a reward and punishment tiered carbon trading mechanism had been introduced separately in the IES optimization operation model to reduce carbon emissions of the system. The calculation simulation sets up different scenarios for comparative analysis. As shown by the results, the proposed model could effectively improve renewable energy consumption capacity and energy utilization efficiency. The effectiveness of hydrogen energy utilization, demand respond, and green certification carbon trading mechanism in improving system economy and low-carbon efficiency is verified.

Hybrid Reactor by the Combination of Water Electolyzer with Methanation Reactor Targeting the Space and Terrestrial Applications

Japan Aerospace Exploration Agency (JAXA) collaborates with Toyama University and Kyushu University to create the hybrid system where the water electrolyzer is directly combined with Sabatier reactor shown in Fig. 1.In order to generate oxygen, people use water electrolyzer. Under the micro-gravity condition, the specially designed gas-water separator is always needed to generate oxygen for breezing. The hydrogen which is the by-product from water electrolysis can also be used for the reduction reaction of carbon dioxide to generate methane and water. It is so called ‘Sabatier reaction’ which is very convenient for the water recovery in the closed environment.In general, the Sabatier reaction can be triggered with maintaining rather high temperature above 300 degrees C. However, the conversion of the reaction should become higher at lower temperature since the reaction is exothermic.We first focused our efforts to develop the catalysts which realizes the Sabatier reaction at around 200 degrees C.We then tried to transfer the heat generated from the Sabatier reaction to the water electolyzer.The novel internal structure of the water electolyzer was developed. Pressurized water without circulation is supplied to the water electrolyzer in which the interdigitated electrode locates. Water first contacts to the proton conducting electrolyte directly, and then diffuses to the electrode where the electrolysis reaction takes place. The electrode is covered with the hydrophobic materials so that only the gaseous material should pass through it without using any gas-water separation devices. The heat transferred from the Sabatier reaction enhances the efficiency of the water electrolysis reaction. By the combination, oxygen can be used for breezing, and hydrogen can be used for the reduction reaction of carbon dioxide to create water and methane as a unitized device.We successfully demonstrated the performance of the tandem device where the water electolyzer is combined with Sabatier reactor through both experiment and mathematical modeling.AcknowledgmentsThis work was partially supported by JST CREST and NEDO Green Innovation Fund Projects. Figure 1

Thermoelectric optimization of integrated energy system considering wind-photovoltaic uncertainty, two-stage power-to-gas and ladder-type carbon trading

Integrated energy system (IES) coupled with renewable energy generation and power-to-gas (P2G) technology provides an effective solution to alleviate the current urgent carbon peak demand. Therefore, This paper develops a novel IES low-carbon economic operation strategy incorporating market mechanism. Firstly, a 24-h joint wind turbine and photovoltaic (WT-PV) output scenario generation method is proposed based on the time-varying Copula function. Secondly, the introduction of carbon capture technology (CCT), electrolyzer (EL), methane reactor (MR) and hydrogen fuel cell (HFC) refines the operation process of p2g into two stages. The combined heat and power (CHP) and HFC variable power operation strategy with adjustable thermoelectric ratio is proposed. Finally, the ladder-type carbon trading mechanism is used to guide IES to control carbon emission. The results of case study show that 1) The time-varying Copula function is effective in improving the scenario accuracy and fitting the data closely to reality 2) The introduction of hydrogen improves the energy utilization efficiency while promoting the consumption of WT-PV. 3) The variable power operation reduces the total cost and carbon emission by 2.4 % and 3.14 %, respectively, compared with the constant thermoelectric ratio. 4) The proposed IES operates reliably and economically under reasonable carbon trading parameters.