Metamorphic Stages Research Articles

Effect of coal quality and preparation on the stamping performance and quality of coke.

This article presents the results of the research on real coal charges of different compositions intended for coking with loading into the chamber by the stamping method. The results of the study established that with an increase in the content of coal at a low stage of metamorphism and a decrease in the content of coal at a high stage of metamorphism in the charges, a decrease in the quality indicators of the coke obtained from them leads to a decrease in the yield of coke. At the same time, there is a gradual decrease in the compaction of the charges from 22.5 to 21.1kPa; their expansion pressure decreases from 6.8 to 5.9kPa; and the work of stamping decreases from 8966 to 6822J. It was also discovered that with the increase in the degree of grinding of the charge, and, accordingly, with the decrease in the average diameter of its particles, the work of stamping coal charges decreases from 7407 to 6238J. The results can be used in the manufacturing of blast furnace coke by stamping coal charges.

Immune defense adaptation of Strauchbufo raddei population in heavy metal polluted area: Insights from developmental and environmental perspectives

The adjustment of immune defense mechanisms is a crucial aspect of biological adaptation to stressful environments. Amphibians, with their unique metamorphic process, experience distinct life stages and exhibit diverse immune defense components. While previous studies have focused on specific immune changes during particular life stages under stress, this research addresses a critical gap by exploring the adaptive immune defense strategies of Strauchbufo raddei in heavy metal-polluted environments. We conducted laboratory experiments, exposing offspring from both polluted and unpolluted areas to control and heavy metal treatments, while continuously monitoring changes in immune components during key metamorphic stages. Notably, we examined the role of the skin microbiome, a crucial but often overlooked barrier against pathogens. The results indicated that individuals from polluted areas exhibited some tolerance to heavy metal exposure, though overall immune function remained diminished. During metamorphosis, when immune defenses are most vulnerable, the skin microbiome rapidly enriched beneficial bacteria, preventing pathogenic colonization and playing a pivotal role in maintaining immune defense in contaminated environments. Moreover, our research highlights energy allocation strategies involving corticosterone and body fat content, enabling populations to maintain development despite immune compromise. The immune adaptations observed may be fixed through genetic assimilation, suggesting a rapid evolutionary response to environmental stress. However, this reduces phenotypic plasticity, making populations more vulnerable to future environmental changes. This study provides key insights into the survival strategies of amphibian populations in heavy metal-contaminated areas, laying the foundation for future research on molecular and evolutionary adaptations.

Metamorphism and Partial Melting at UHP Conditions Revealed by Microdiamonds and Melt Inclusions in Metapelitic Gneiss from Heia, Arctic Caledonides, Norway

Abstract Primary multiphase inclusions trapped in host minerals such as garnet may provide important information about the nature of fluids and melts and their crystallization products. The occurrence of melt and fluid inclusions in the same cluster suggests primary fluid-melt immiscibility during partial melting. Here we report the coexistence of diamond-bearing fluid inclusions with melt inclusions in metasedimentary UHP rocks of the Nordmannvik Nappe at Heia, in the Arctic Caledonides of Norway. Multiphase fluid inclusions (Type I) and primary melt inclusions (Type II) have been identified in garnet and studied in detail. Microscopic observations, Raman spectroscopy, FIB-SEM, and EDS analysis show that microdiamonds occur in situ, in multiphase fluid inclusions (Type I) distributed in clusters in the garnet mantle. The Raman spectra suggest partial transformation of diamond to disordered sp2-bonded carbon structure. Along with diamond, Type I inclusions contain (i) rutile and apatite as trapped solid phases, (ii) carbonates (magnesite-siderite) and Al-phyllosilicates (white mica, phlogopite, pyrophyllite) as daughter or step-daughter minerals, and (iii) CO2 as a residual fluid phase. Former melt inclusions (Type II) occur in the same microstructural position in the host garnet. They contain muscovite, paragonite, phlogopite, K-feldspar, plagioclase, albite and quartz as solid phases crystallized from a melt, and kyanite as accidentally trapped mineral. The occurrence of melt inclusions in the inner part of garnets thus suggests that garnet was growing in the presence of melt. Garnet is nearly homogeneous with respect to major elements Mg, Fe, Ca and Mn, expressed by pyrope (0.18–0.22 XPrp), grossular (0.09–0.12 XGrs), almandine (0.67–0.70 XAlm) and spessartine (0.01–0.03 XSps) except local Ca enrichment in the rim. Trace elements show decreasing HREE and Y patterns from the core to the mantle suggesting garnet growth according to the Rayleigh fractionation model. Phosphorus shows an elevated content in the core and mantle. A positive correlation between P and Na indicates a coupled NaPM2+−1Si−1 substitution in garnet. Minimum P–T conditions of 3.7 to 3.8 GPa and 840°C to 870°C for the peak metamorphic stage were estimated from garnet composition (XPrp = 0.22), zirconium-in rutile thermometry of rutile inclusions in garnet (747–977 ppm of Zr) and diamond/graphite stability boundary. Partial melting on a prograde P–T path was controlled by the decomposition of phengite in the presence of C–O–H fluid, producing peritectic garnet ± kyanite along with melt, in the diamond stability field. The coexistence of diamond-bearing multiphase fluid inclusions with melt inclusions suggests primary fluid-melt immiscibility at UHP conditions. During exhumation, the rock underwent decompression and second partial melting, leading to enrichment in Ca, Y, Cr and Sc of garnet rims. Microdiamonds found in metasedimentary crustal rocks at Heia provide new evidence of UHP metamorphism in the Nordmannvik Nappe of the Arctic Caledonides. The results favour a correlation with the pre-Scandian subduction and arc–continent collision events of the Caledonian Orogeny.

Investigation of the sorption activity of native coals to air oxygen

The influence of the gaseous medium during sample preparation, the granulometric composition, the duration of contact with air and the stage of metamorphism on the process of oxygen sorption from the air was established. It is shown that conducting sample preparation in an air atmosphere leads to primary oxidation of the outer surface of the coals, which introduces an error in determining the oxygen sorption rate constant. Fine coal fractions (0-0.2 mm) with a more developed outer surface have increased oxygen absorption activity. The rate of oxygen sorption is maximal at the initial moment of the interaction of active carbons with air and decreases with the duration of contact. The least metamorphosed hard coals of the D brand with a high content of reactive functional groups and a developed porous structure are characterized by the greatest chemisorption activity.

The tectonic implications of a rare metamorphic event in eastern China during the Earth's “middle age”

The Mesoproterozoic Era has long been considered a relatively stable, silent, and even "boring" period in Earth's history, during which the lithosphere was tectonically inactive. However, an increasing amount of evidence suggests that metamorphism and magmatism were much more widespread and intense than previously thought, implying that this period was dynamic. Here we report metamorphism around ca. 1.4 Ga along the southeastern margin of the North China Craton, eastern China. We conduct TIMA, EMPA, and zircon SHRIMP and LA-ICP-MS U-Pb dating on garnet amphibolites and their country rocks. The detailed mineral composition of a representive garnet amphibolite sample is identified and determined by TIMA. Phase equilibria modelling using pseudosections combined with EMPA data indicates the peak metamorphism stage (M 2 ) of the garnet amphibolites at a P-T condition of 10.6-11.2 kbar/820 ℃. SHRIMP Zircon U-Pb analysis yields an age of 1366 ± 17 Ma for the garnet amphibolites, which is slightly younger than that of its country rock schist (1376 ± 22 Ma). Integrating the metamorphic event with geochemical signatures, magmatic records, and sedimentation patterns in analogous geological settings on other continents, our findings collectively demonstrate a protracted and pervasive orogenic process along the periphery of the Columbia supercontinent.

Microwave-induced alterations in the structure of coals at different metamorphic stages

Despite the global trend toward decarbonization, coal continues to play a significant role in energy production, as current renewable energy sources cannot fully meet the increasing global energy demand. The main objective of decarbonization is to reduce greenhouse gas emissions, especially carbon dioxide. Enhancing coal usage efficiency can help decrease these emissions. Electromagnetic activation of bituminous coal is already employed for dehydration, ash removal, desulfurization, and improving the grinding process of raw coal. This research aims to study the specifics of coal electromagnetic activation using microwave radiation and its effects on the physical and chemical processes occurring in coals at different metamorphic stages. The results suggest that this electromagnetic treatment leads to the destruction of hydroxyl groups and the formation of free hydrogen. Coals at higher metamorphic stages heat up faster due to their higher structural density. Coals at lower metamorphic stages take longer to heat up and require more processing time to be effective, while lower power levels are necessary to avoid mechanical breakdown. Activation time and coal particle size are significant factors; their optimal combination provides the maximum effect. These findings contribute to optimizing microwave treatment parameters for different coal types, potentially enhancing coal utilization efficiency and reducing environmental impact.

Metamorphism and geochronology of the Foping gneiss dome: Insights into Early Triassic collision of the Qinling Orogen, Central China

The Foping gneiss dome, which outcrops in the narrowest part of the Qinling Orogen, contains high-grade metamorphic rocks that record the collision between the North China Block (NCB) and South China Block (SCB). Herein, petrography, mineral chemistry, phase equilibria modeling and UPb geochronology are used to constrain the collision events responsible for the high-grade metamorphism and exhumation of the Foping gneiss dome. The pelitic and mafic granulites sampled from the dome reveal peak metamorphism at P/T conditions of 6.2–7.4 kbar/ 805–855 °C, and document clockwise P-T-t paths with retrograde metamorphism of amphibolite-facies at 3.4–4.7 kbar/ 605–715 °C. While the pelitic schist from the rim of this dome witnessed peak metamorphism at P/T conditions of 4.9–5.1 kbar/ 590–605 °C and retrograde metamorphism at 3.5–3.7 kbar/ 510–520 °C. UPb dating of zircon and monazite confirm ages of ∼247–240 Ma for peak metamorphism with granulite-facies, ages of ∼208–198 Ma for retrograde metamorphism. The two metamorphic stages may record the transition from crustal thickening to dome exhumation, and the age of peak metamorphism probably marks the timing of the collision between the NCB and SCB along the Qinling Orogen in the Early Triassic. The collision probably terminated in the Late Triassic. The new discovery of the Triassic metamorphic event in the Qinling, combined with previously reported collision event of the Dabie Orogen to the east, supports the idea that the continental collision between the NCB and SCB along the Qinling-Dabie Orogen was synchronous.

Variscan basement tectonics and Alpine shear zones in the external Balkanides: Structural data from the Vezhen Massif, Central Stara Planina Mts., Bulgaria

The Alpine Balkanides in Bulgaria are developed over Variscan orogenic fragments, which are variously affected by late-stage thick-skinned thrust tectonics. Often, these fragments hold both Variscan and Alpine structural records. А key area to shed light on important aspects of the tectonic evolution of the external parts of the Alpine Balkanide orogen is the Vezhen Massif in the Central Stara Planina Mountains. Although it is built exclusively of Paleozoic crystalline rocks, its structure was long considered as an example of intense mid Eocene to early Oligocene (Late Alpine) shortening. Detailed fieldwork in the area shows a more complicated tectonic framework and provides evidence of a polyphase structural evolution, involving an important stage of Variscan metamorphism and deformation and two stages of north-vergent Alpine shortening. The Stargel-Boluvanya Tectonic Zone that affects the western Vezhen Massif is one of the most important Variscan structures in the Balkan fold-and-thrust belt. Structural data indicate that the metamorphic basement records initial top-to-north thrusting, followed by further shortening, which led to folding and localized strike-slip deformation. The Variscan syn-metamorphic fabric is cross-cut by several post-kinematic igneous bodies of late Carboniferous to Permian ages. The tectonic history continues with a development of a network of greenschist facies north-vergent mylonitic zones for which an Early Alpine (post-late Permian but pre-Late Cretaceous) age is assumed. Late Alpine north-vergent thrusting is evident only on the eastern and northern flanks of the Vezhen Massif. In a broad structural context, the documented record in the basement rocks of the Vezhen Massif is comparable with those of the external massifs of the Alps and Iberia.

The composite metamorphic sequence in the Jiajika gneiss dome, Songpan-Ganze orogenic belt, eastern Tibet: P-T-D-t evolution and implications for lithium mineralization

The metamorphic host rocks of pegmatites can help to decipher their geodynamic setting and emplacement conditions. The Jiajika lithium deposit, located in the Songpan-Ganze orogenic belt, eastern Tibet, is one of the largest hard-rock type lithium deposits in China. The lithium-enriched pegmatites in Jiajika are hosted in the amphibolite facies metasedimentary rocks in the mantle of the Jiajika gneiss dome. However, the metamorphic evolution of Jiajika is poorly constrained. In this study, we carried out detailed fieldwork, petrological observation, mineral chemical analysis, phase equilibria modeling, and geochronological studies on the Jiajika gneiss dome and the borehole JSD-1 (with a total depth of 3211 m) of the Jiajika Scientific Drilling Project (JSD). Structural data outlined two subdomes within the Jiajika gneiss dome. Two main stages of regional metamorphism and deformation are documented in Jiajika: an early Barrovian metamorphism (M1) in ca. 237−221 Ma caused by crustal thickening (D1), which has a peak condition of 6.7−8.3 kbar and 649−694 °C; a late Buchan metamorphism (M2) induced by the emplacement of granites and pegmatites during doming (D2) with a peak condition of 3.4−4.3 kbar and 570−612 °C at 210−206 Ma. The superimposition of the M2 isograds upon the M1 isograds resulted in a composite metamorphic sequence around the Jiajika gneiss dome. The overlapping of the Barrovian metamorphism and the Buchan metamorphism is related to crustal thickening during continental collision and later decompression through doming, which facilitated lithium mineralization.

Natural modulation of redox status throughout the ontogeny of Amazon frog Physalaemus ephippifer (Anura, Leptodactylidae)

During their development, amphibians undergo various physiological processes that may affect their susceptibility to environmental pollutants. Naturally occurring fluctuations caused by developmental events are often overlooked in ecotoxicological studies. Our aim is to investigate how biomarkers of oxidative stress are modulated at different stages of larval development in the Amazonian amphibian species, Physalaemus ephippifer. The premetamorphosis, prometamorphosis and metamorphic climax stages were used to analyze total antioxidant capacity (ACAP), glutathione S-transferase (GST) activity, lipid peroxidation (LPO) levels and the expression of genes nrf2, gst, gsr (glutathione reductase) and gclc (glycine-cysteine ligase, catalytic subunit). Although there was no difference in ACAP and the genes expression among the studied stages, individuals from the premetamorphosis and prometamorphosis showed higher GST activity than ones under the climax. LPO levels were highest in individuals from the metamorphic climax. The present study suggests that the oxidative status changes during ontogeny of P. ephippifer tadpoles, especially during the metamorphic climax, the most demanding developmental phase. Variations in the redox balance at different developmental stages may lead to a divergent response to pollution. Therefore, we recommend that studies using anuran larvae as biomonitors consider possible physiological differences during ontogeny in their respective analyses.

A ~957 Ma Metamorphism in the Mesoarchaean Hindoli Group Supracrustal Rocks from the Jahazpur Shear Zone, East Rajasthan (India): Constraints from Sm-Nd Dating and Phase Equilibria Modeling

ABSTRACT A petrological-chronological investigation of the Hindoli Group of rocks within the Jahazpur Shear Zone in the eastern segment of the Aravalli Delhi Fold Belt (ADFB), NW India, has been conducted. We infer two stages of deformation (D1 and D2) and metamorphism (M1 and M2) for the garnet - muscovite - biotiteschists interleaved with meta dolomite, Banded Iron Formation (BIF) amphibolite, and foliated granite. The D2 deformation corresponds to the northeast-trending Jahazpur shear zone on a regional scale. Garnet porphyroblasts, syntectonic with the D2 deformation, are chemically zoned with spessartine-rich cores. Geothermobarometry and pseudosection analyses yield peak P-T conditions of ~7.5 kbar, 580°C, followed by decompression and cooling along a clockwise P-T path. The Sm-Nd isotope analysis of the whole rock yields a date of ~3.0 Ga from an amphibolite. This data is interpreted as the age of formation of the litho-units of the Hindoli Group. Sm-Nd analyses of garnet grains yield an age of ~957 Ma. This date corresponds with the age of nucleation of the Jahazpur shear zone. A good correlation is established between the Neoproterozoic crustal segments of the Jiangnan Fold Belt of the South China Craton and that of the ADFB during the formation of the Rodinia Supercontinent.

Development of the insect adult fat body relies on glycolysis, lipid synthesis, cell proliferation, and cell adhesion.

The fat body of the holometabolous insect is remodeled by the degradation of the larval fat body and the development of the adult fat body during metamorphosis. However, the mechanism of adult fat body development is quite unclear. Using the agricultural pest Helicoverpa armigera, the cotton bollworm, as a model, we revealed that the development of adult fat body was regulated by glycolysis, triglyceride (triacylglycerol [TAG]) synthesis, cell proliferation, and cell adhesion. RNA sequencing detected a set of genes that were upregulated in the 8-d late pupal fat body at a late metamorphic stage compared with the 2-d pupal fat body at an earlier metamorphic stage. The pathways for glycolysis, TAG synthesis, cell proliferation, and cell adhesion were enriched by the differentially expressed genes, and the key genes linked with these pathways showed increased expression in the 8-d pupal fat body. Knockdown of phosphofructokinase (Pfk), acetyl-CoA carboxylase (Acc1), phosphatidylinositol 4,5-bisphosphate 3-kinase catalytic subunit (P110) and collagen alpha-1(IV) chain (Col4a1) by RNA interference resulted in abnormal eclosion and death at pupal stages, and repressed lipid droplets accumulation and adult fat body development. The expression of Acc1, P110, and Col4a1 was repressed by the insect steroid hormone 20-hydroxyecdysone (20E). The critical genes in the 20E pathway appeared to decrease at the late pupal stage. These data suggested that the development of the insect adult fat body is regulated by glycolysis, lipids synthesis, cell proliferation, and cell adhesion at the late pupal stage when the 20E signal decreases.

Metamorphic origin of large nuggets of platinum-group metals: evidence from multiphase inclusions in Os-Ir-Ru alloys from the Adamsfield placer, Tasmania

Abstract Platinum-group elements (PGE) are most effectively concentrated via sulfide-silicate melt immiscibility; however, under sulfide-undersaturated conditions, PGE may exhibit highly-siderophile behaviour and occur as native metals and alloys. In this case, they can form μm-size inclusions within Cr-spinel, but also large nuggets (up to several kilograms), found in chromitites and related placer deposits. The exact formation mechanism of such large nuggets and accumulations of PGE unrelated to sulfide melts remains controversial due to mass balance issues. In this study of multiphase inclusions in Os-Ir-Ru nuggets from the Adamsfield placer district (Tasmania, Australia), we constrain their crystallization environment. Multiphase inclusions comprise variable proportions of hornblende, enstatite, quartz, anthophyllite, anorthite, chlorite and native iridium and coexist with single-phase olivine and Cr-spinel inclusions. The heterogeneity in phase and chemical composition of the inclusions indicates a complex origin from an inhomogeneous source media. This is corroborated by grain scale disequilibrium mineral assemblages, where forsterite and quartz are both included within a single osmium grain. Our proposed multi-stage origin of Adamsfield Os-Ir-Ru nuggets involved magmatic olivine-Cr-spinel-Os-Ir-Ru cumulates in peridotite bodies that were subsequently overprinted by various hydrothermal and metamorphic processes, including serpentinization or growth of Os-Ir-Ru from supercritical fluids. The final metamorphic stage resulted in the obliteration of Os-Ir-Ru zonation, culminating in the current assemblage of inclusions.

Single‐Stage Synchronous India‐Asia Collision Model Revealed by Himalayan High‐Pressure Metamorphic Rocks

AbstractDespite a half‐century of intense research, the timing and diachroneity of initial collision between India and Asia remain highly debated, largely due to different definitions of “initial collision” and correspondingly different methods adopted. This study focuses on high‐pressure pelitic granulites of the Eastern Himalayan Syntaxis (EHS) to elucidate their metamorphic evolution and provide new constraints on the timing of initial India‐Asia collision. Petrological examination and phase equilibria modeling show that high‐pressure pelitic granulites have undergone four metamorphic stages, with the peak assemblage of garnet + K‐feldspar + kyanite + biotite ± plagioclase ± rutile + ilmenite + quartz at P‐T conditions of 13.1–15.7 kbar and 790–850°C. Clockwise P‐T paths suggest that the Indian continent underwent tectonometamorphic processes of initial collision and subsequent continent subduction. Zircon and monazite dating results indicate that the metamorphic ages of pelitic granulites range from 60 to 15 Ma, with the oldest ones clustered at 60–58 Ma. The oldest metamorphic ages of high‐ to ultrahigh‐pressure Himalayan metamorphic rocks can provide an upper age limit of the initial collision. Therefore, the initial India‐Asia collision must have occurred before 60–58 Ma in the EHS, roughly consistent with ca. 57 Ma in the western Himalaya and 63–60 Ma in the central Himalaya. Collectively, we conclude that the northern margin of India most likely underwent a single‐stage synchronous collision with the southern margin of Asia initially at around 60 Ma along the entire Yarlung‐Tsangpo suture zone.

Effect of the killing method and developmental stage on cricket (Acheta domesticus) composition and chitin recovery

Abstract After receiving a positive safety assessment as a novel food by the European Food Safety Authority, Acheta domesticus (house cricket) was extensively studied due to its recognised high nutritional value. However, the nutritional quality of crickets depends on several factors related to the insect itself (e.g. metamorphic stage, gender, habitat, and diet) or processing (e.g. killing methods). These variables also influence the isolation of the insect’s main components: proteins, lipids, and chitin. Notably, chitin purification is particularly challenging in insects. This study aimed to evaluate the influence of two killing methods (blanching and freezing) and five developmental stages (hatching, three nymphs, and adult) on the nutritional composition of crickets. The impact of these factors was also assessed in terms of chitin purification. Different macronutrients were found to be maximised at different developmental stages, suggesting that the stage can be selected based on the target nutritional value. Chitin with a higher purity was obtained from 28-day crickets because of the lowest percentage of protein bound to chitin. In the chitin samples of the crickets in the middle stages killed by blanching, the proteins bound to chitin were lower than in the freezing one, possibly due to lower activation of the melanisation and sclerotization pathways. In addition, these residual proteins had a defined amino acid composition, suggesting the presence of cuticular proteins capable of binding chitin.

Characterization of Co-bearing pyrite from the SEDEX Tuolugou Co(Au) deposit, northern Qinghai-Tibet Plateau, China

The Tuolugou sedimentary-exhalative (SEDEX) Co-Au deposit is located in the eastern Kunlun metallogenic belt of the northern Qinghai-Tibet Plateau in China. Pyrite is the prevalent Co-hosting sulfide mineral that occurs in the Tuolugou deposit. In this study, we investigated mineral characteristics of Co-bearing pyrite and effect of Co on crystal structure of the pyrite to obtain a better understanding of Co mineralization. Three pyrite generations were identified, including Co-barren pyrite (Py-1, formed during the early mineralization stage I, with Co content of 1-3844 ppm), Co-rich pyrite (Py-2, formed during the sedimentary-exhalative stage II, Co content 15–36522 ppm), and Co-rich pyrite (Py-3, formed during metamorphic stage III, with Co contents of 448–10505 ppm in Py-3A, and 1371–14904 ppm in Py-3B). As Co enters the pyrite structure, it is discovered that the octahedrons in pyrite is twisted and tilted, the lattice parameters (a0) rise, and the sulfur atom positions alter. The Co-rich Py-2 shows a similar REE and trace element distribution as those in quartz albitite, which indicates that Co mineralization is related to SEDEX genesis. Subsequent metamorphism resulted in additional Co enrichment. This detailed study of Co-bearing pyrite provides insights on the details of isomorphism Co in pyrite similar to the situation of this deposit as medium–low Co grade.

Tectono-thermal Evolution of the Proterozoic Mahakoshal Belt along the Northern Margin of Central Indian Tectonic Zone: Constraints from Geochemistry, Phase Equilibria Modelling and in-situ Monazite Dating from a Metapelite Sequence around Jabalpur

ABSTRACT In this contribution, geochemical signatures and petrological evolution of a folded sequence of mica schist from the Jabalpur area of the Mahakoshal Belt in the northern Central Indian Tectonic Zone (CITZ) are described. Multiple tectonic discrimination diagrams incorporating both major and trace element concentrations have constrained back-arc settings for deposition of the sedimentary units. S1 foliation formation marks the beginning of the M1 metamorphic stage. In contrast, the later M2 metamorphic event resulted in garnet and andalusite formation during heating at 2-3 kbar, followed by staurolite-sillimanite, garnet-staurolite assemblages at peak P-T conditions of 5.4 kbar, 550-600°C. Textural evidence suggests that M2 is pre-syn tectonic to D2 deformation, resulting in formation of the NE-SW trending S2 axial planar foliation. From the isopleth thermobarometry, a clockwise P-T path with near-isothermal decompression has been determined for M2. Similar results have been obtained from conventional thermo-barometry performed on multiple samples. Monazite dating (EPMA) of one of the samples suggests 1.9 Ga, age for D1-M1 event. M2 is correlated with the younger age population of monazites yielding 1.5 Ga. A clockwise P-T path constrained for M2 suggests collisional tectonics along the northern margin of the CITZ, as recorded from its southern margin.

Особенности сжигания композиционных водоугольных топлив

Russia has large coal reserves, on the average up to 173 billion tons. Although, the share of coal generation in Russia is relatively small (about 20–22 %), it reaches 65 % in the Siberian Federal District. Russia cannot deny coal, but it is necessary to update and improve energy efficiency of Thermal Power Plants (TPP) and boiler houses that burn coal. Currently, technologies have been developed to produce and use composite coal-water fuel (CWF) with various additives, primarily of organic origin to improve its target characteristics. A study of the characteristics of such coal-water suspensions has proved the promising outlook of their use as fuel in large and small Thermal Power Plants, both from an economic and environmental safety points of view. However, the lack of experimental data on the issues of combustion of composite coal-water fuel in bench-scale and semi-industrial conditions hinders the further development of CWF technology. Thus, it is relevant to study the features of combustion of composite coal-water fuels from coals of varying degrees of metamorphism. To prepare experimental batches of composite CWF, raw coals and coal slurries of various stages of metamorphism (grades D, SS, T) have been used. They were burned in a bench-scale semi-industrial plant. The research results have been processed using the methods of mathematical statistics and regression analysis. The influence of mechanical activation of CWF on the viscosity and temperature of its ignition and combustion has been established. The features of combustion of composite coal-water fuel using pneumomechanical injectors of two types are determined. The composition of harmful emissions during the combustion of CWF has been determined. The possibility to use composite coal-water fuel to ignite high-power boilers has been established. It has been proved that the combustion of CWF is environmentally safer compared to the combustion of coal and other types of fuel.

Characteristics of Metamorphic Rocks and the Deformation and Metamorphism Period in Northern Lhasa,Tibet

The study of metamorphic rocks and deformation and metamorphic features in Gangdise-Lhasa metamorphic zone is helpful for the establishment of regional tectonic framework and the discussion of the evolution history of the region, which will provide new basic data for the study of geological structure evolution in the Qinghai-Tibet Plateau. There are few studies on metamorphic rocks in the northern area of Lhasa, Tibet. This paper summarizes and studies them from the perspective of petrography, and briefly discusses the stages of deformation and metamorphism. The area is divided into two metamorphic belts, which are divided into Yebagou-Gandansi metamorphic belt and Shexing-Binjiaolin metamorphic belt from south to north. The types of metamorphic rocks are slate, kyanite and schist. The dynamic metamorphism is manifested as brittle deformation and ductile deformation. The dynamic metamorphic rock belt developed in the area is several kilometers long, which basically belongs to the low green schist facies belt. The metamorphism in the area occurs under the geological background of the northward subduction, subduction and collision of the Neotethys oceanic crust plate. And with the change of tectonic environment and heat flow, different metamorphisms are produced in different geological development stages.

On the Nature of the Kharamatolou Structure and the Ratio of the Amount of Ultramafic Rocks of the Voykar-Synya Massif to That of the Ray-Iz Massif, Polar Urals

There have been petrographic, geochemical, geochronological (Rb-Sr, Ar-Ar) and isotopic (Sm-Nd) studies done on the metamorphic formations of the Kharamatolou structure of the Polar Urals, which were usually assigned to the Precambrian. The temperatures of metamorphism have been shown to range from 450 to 626 °C, and the pressures – from 3.7–9.1 kbar once PT-conditions reached the amphibolite facies. The amphibolites of the Kharamatolou formation are geochemically divided into two groups. According to the distribution spectra of lanthanides and Nd isotope composition, one group has the characteristics similar to depleted N-MORB basalts εNd(0)=+7.0, and another group – those similar to moderately enriched E-MORB basalts εNd(0)=+(4.5–2.4). It has been found that the Kharamatolou structure is probably composed of the Early to Middle Paleozoic continental rise deposit of the Russian Platform, which passed the main stage of folding and metamorphism in the Late Devonian (Rb-Sr, 366±11 Ma). The gabbro-ultrabasic Ray-Iz and Voykar-Synya massifs have been shown to be one during most of their Pre-Triassic history. Now these ultrabasite massifs are separated by the young (Triassic) Kharamatolou uplift which is an erosive-tectonic semi-window where ultrabasic rocks of the Polar-Ural belt are exposed at the base of the thrust fault. The Kharamatolou structure is one of the transverse uplifts of the Urals which probably resulted from the Middle to Late Triassic compression therealong. As a result of the Middle to Late Triassic uplift of the Haramatolou metamorphites, the overlying ultrabasites were washed away by erosion. The mélange serpentinites observed in the center of the Kharamatolou structure are uneroded remnants of the link that once existed between the Ray-Iz and Voikar-Synya massifs. This significantly increases the metallogenic potential of the Voikar-Synya massif, as the Ray-Iz hosts the largest known chromite deposits in Russia.