Metal Nanocavities Research Articles

Absolute Photoluminescence Quantum Yield Measurement in a Complex Nanoscopic System with Multiple Overlapping States.

Using a metal nanocavity, we measure absolute values of the photoluminescence quantum yield in a mixture of different types of chromophores (dye molecules and semiconductor nanocrystals). We show that measurements can be performed in an attoliter volume, both in liquid and solid phases, even if both types of chromophores absorb and emit light in the same spectral range. The method is based on recording photoluminescence decay curves of the chromophore mixture as a function of the cavity length. Changing the distance between the cavity mirrors modifies the local density of states of the electromagnetic field and thus, the radiative transition rate of the enclosed emitters. By extracting individual decay components, corresponding to the different types of the emitters, we determine their quantum yield values separately and simultaneously. The nanocavity-based method opens up new perspectives for studying quantum emitters in complex photophysical systems, for instance, multichromophoric thin films, fluorescent proteins, or dyes incorporated into a lipid bilayer.

“Seeing” the Resonant SPP Modes Confined in Metal Nanocavity via Cathodoluminescne Spectroscopy

ABSTRACT:Surface plasmon polaritons (SPPs), which are coupled excitations of electrons bound to a metal-dielectric interface, show great potential for application in future nanoscale photonic systems due to the strong field confinement at the nanoscale, intensive local field enhancement, and interplay between strongly localized and propagating SPPs. The fabrication of sufficiently smooth metal surface with nanoscale feature size is crucial for SPPs to have practical applications. A template stripping (ST) method combined with PMMA as a template was successfully developed to create extraordinarily smooth metal nanostructures with a desirable feature size and morphology for plasmonics and metamaterials. The advantages of this method, including the high resolution, precipitous top-to bottom profile with a high aspect ratio, and three-dimensional characteristics, make it very suitable for the fabrication of plasmonic structures. By using this ST method, boxing ring-shaped nanocavities have been fabricated and the confined modes of surface plasmon polaritons in these nanocavities have been investigated and imaged by using cathodoluminescence (CL) spectroscopy, which has been turned out to be a powerful means to characterize the resonant SPPs modes confined in metal nanocavities [1∼5] . The mode of the out-of-plane field components of surface plasmon polaritons dominates the experimental mode patterns, indicating that the electron beam locally excites the out-of-plane field component of surface plasmon polaritons. Quality factors can be directly acquired from the spectra induced by the ultrasmooth surface of the cavity and the high reflectivity of the silver (Ag) reflectors. Because of its three-dimensional confined characteristics and the omnidirectional reflectors, the nanocavity exhibits a small modal volume, small total volume, rich resonant modes, and flexibility in mode control. Numerous applications, such as plasmonic filter, nanolaser, and efficient light-emitting devices, can be expected to arise from these developments.

Hybridization of Localized and Guided Modes in 2D Metal–Insulator–Metal Nanocavity Arrays

This article describes the angle-dependent optical responses of 2D metal–insulator–metal (MIM) nanocavity arrays. Through a combination of soft nanolithography and template stripping, we fabricated arrays of plasmonic MIM nanostructures with subwavelength spacings over square centimeter areas. We controlled the coupling between the localized surface plasmon and guided modes as well as engineered the optical band structure by tuning the insulator thickness. Rabi splitting of hybridized modes strongly depended on the spatial overlap of the near-fields of the localized and guided modes.

A surface-emitting 3D metal-nanocavity laser: proposal and theory

A novel three-dimensional (3D) metal-nanocavity (or nano-coin) semiconductor laser suitable for electrical injection is proposed and analyzed. Our design uses metals as both the cavity sidewall and the top/bottom reflectors (i. e., a fully metal encapsulated nanolaser) and maintains the surface-emitting nature. As a result of the large permittivity contrast between the dielectric and metal, the optical energy can be well-confined inside the metal nanocavity. With a proper design and the choice of the HE111 mode, which has the best top surface radiation pattern, a laser with a physical size smaller than 0.01λ(0)(3) is achievable at 1.55 μm wavelength with a reasonable semiconductor gain at room temperature. We provide a detailed theoretical model starting from the waveguide analysis to full 3D structure simulations by taking into account both geometry and metal dispersion. We show a systematic procedure for analyzing this class of 3D metal-cavity (or nano-coin) lasers with discussions on the optimization of the performance such as light output power, threshold reduction, and output beam shaping.

Plasmonic Electro-Optical Switches Operating at Telecom Wavelengths

Electro-optical (EO) switches with a subwavelength device length based on metal–dielectric–metal nanocavities waveguide combined with organic EO materials have been proposed and numerically investigated. The finite difference time domain (FDTD) method with perfectly matched layer absorbing boundary condition is adopted to simulate and study their properties. The FDTD simulation results reveal that these structures filled with EO materials can realize the function of switch with low-driving voltage. The wavelength conversion switch structure might become a choice for the design of integrated architectures for optical computing and communication, especially in WDM systems in the nanoscale.

Plasmon Line Shaping Using Nanocrosses for High Sensitivity Localized Surface Plasmon Resonance Sensing

The detection of small changes in the wavelength position of localized surface plasmon resonances in metal nanostructures has been used successfully in applications such as label-free detection of biomarkers. Practical implementations, however, often suffer from the large spectral width of the plasmon resonances induced by large radiative damping in the metal nanocavities. By means of a tailored design and using a reproducible nanofabrication process, high quality planar gold plasmonic nanocavities are fabricated with strongly reduced radiative damping. Moreover, additional substrate etching results in a large enhancement of the sensing volume and a subsequent increase of the sensitivity. Coherent coupling of bright and dark plasmon modes in a nanocross and nanobar is used to generate high quality factor subradiant Fano resonances. Experimental sensitivities for these modes exceeding 1000 nm/RIU with a Figure of Merit reaching 5 are demonstrated in microfluidic ensemble spectroscopy.

The Single Molecule Probe: Nanoscale Vectorial Mapping of Photonic Mode Density in a Metal Nanocavity

We use superresolution single-molecule polarization and lifetime imaging to probe the local density of states (LDOS) in a metal nanocavity. Determination of the orientation of the molecular transition dipole allows us to retrieve the different LDOS behavior for parallel and perpendicular orientations with respect to the metal interfaces. For the perpendicular orientation, a strong lifetime reduction is observed for distances up to 150 nm from the cavity edge due to coupling to surface plasmon polariton modes in the metal. Contrarily, for the parallel orientation we observe lifetime variations resulting from coupling to characteristic lambda/2 cavity modes. Our results are in good agreement with calculations of the nanoscale variations of the projected LDOS, which demonstrates the potential of single molecules as nonperturbative, nanoscale vectorial point probes in photonic and biological nanostructures.