Spin and mass properties provide essential clues in distinguishing the origins of coalescing black holes (BHs). With a dedicated semiparametric population model for the coalescing binary black holes (BBHs), we identify two distinct categories of BHs among the GWTC-3 events, which is favored over the one population scenario by a logarithmic Bayes factor (lnB) of 7.5. One category, with a mass ranging from ∼25M_{⊙} to ∼80M_{⊙}, is distinguished by the high spin magnitudes (∼0.75) and consistent with the hierarchical merger origin. The other category, characterized by low spins, has a sharp mass cutoff at ∼40M_{⊙}, which is natural for the stellar-collapse origin and in particular the pair-instability explosion of massive stars. We infer the local hierarchical merger rate density as 0.46_{-0.24}^{+0.61} Gpc^{-3} yr^{-1}. Additionally, we find that a fraction of the BBHs has a cosine-spin-tilt-angle distribution concentrated preferentially around 1, and the fully isotropic distribution for spin orientation is disfavored by a lnB of -6.3, suggesting that the isolated field evolution channels are contributing to the total population.
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