To improve the complexity of the chaotic system and achieve the effective transmission of image information, in this paper, a five-dimensional memristive chaotic system with cubic nonlinear terms is constructed, which has four pairs of symmetric coordinates. First, the cubic nonlinear memristive chaotic system is analyzed using the Lyapunov exponential map, bifurcation map, and attractor phase diagram. The experimental results show that under four pairs of symmetric coordinates, the system exists not only parameter-dependent symmetric rotational coexisting attractor and transient chaotic phenomena but also exists super-multistationary with alternating chaotic cycles dependent on the initial value of the memristor. Then, it is proposed to add a constant term to the linear state variable to explore the effect of the offset increment of the linear state variable on the system in four pairs of symmetric coordinates, while circuit simulation of the five-dimensional chaotic system is carried out using Simulink to verify its existence and realisability. Finally, the synchronization of the dimensionality reduction system and the confidential transmission of the image are achieved, using the control voltage of the system to replace the internal state variables of the memristor to achieve the one-dimensional reduction process, and an adaptive synchronization controller is designed to synchronize the system before and after the dimensionality reduction. Based on the above, an image to be transmitted is modulated into a one-dimensional array and then subjected to the fractional and cyclic operations and combined with the linear encryption and decryption functions and the chaotic masking technique, the simple encryption and decryption of the image processes are realized.