Enhancement Of Mechanical Properties Research Articles

Characterization, impact and wear properties of treated and as-received graphene nanosheets reinforcement in epoxy resin composites

PurposeThis study aims to explore the enhancement of mechanical properties in epoxy resin composites through the incorporation of graphene nanoparticles, focusing on their impact and wear resistance. It investigates the role of graphene, both treated and untreated, as a reinforcing agent in composites, highlighting the significance of nanoparticle dispersion and surfactant treatment in optimizing mechanical performance.Design/methodology/approachEmploying a novel dispersion technique using a drawing brush, this research contrasts with traditional methods by examining the effects of graphene nanoparticle concentrations treated with surfactants – Polyvinylpyrrolidone (PVP) and Sulphonated Naphthalene Formaldehyde (SNF) – on the mechanical properties of epoxy resin composites. The methodology includes conducting a series of impact and wear tests to assess the influence of graphene reinforcement on the composites' performance.FindingsThe findings reveal a marked enhancement in the composites impact resistance and energy absorption capabilities, which escalate with an increase in graphene content. Additionally, the study demonstrates a significant improvement in wear resistance, attributed to the superior mechanical properties, robust interface adhesion and effective dispersion of graphene. The use of surfactants for graphene treatment is identified as a crucial factor in these advancements, offering profound insights into the development of advanced composite materials for diverse industrial uses.Originality/valueThis study introduces a unique dispersion technique for graphene in epoxy composites, setting it apart from conventional methods. By focusing on the critical role of surfactant treatment in enhancing the mechanical properties of graphene-reinforced composites, it provides a novel insight into the optimization of impact and wear resistance.

Superior Enhancement in Mechanical Properties of Polyurethane‐Based Multifunctional GAP Partially Grafted with Fluorinated Polyether via Catalyst‐Free Click Reaction

AbstractDifunctional glycidyl azide polymer (GAP) is an energetic binder promising for propellant formulations. The multifunctional fluorine‐containing GAP has been synthesized to enhance its mechanical properties. This work outlined multifunctional GAP partially grafted with 1,2,3‐triazole‐5‐(α‐hydroxyl)‐fluorinated polyether (GAP‐g‐3F) synthesized by thermal and catalyst‐free azide‐alkyne cycloaddition reaction, in which the azide groups were from GAP and electron‐deficient alkynes from β‐propargyl‐α‐hydroxyl poly (tri‐fluoropropane glycidyl ether) (PHP3F). PHP3F was synthesized via the typical cationic ring‐opening polymerization of 2‐((2,2,2‐trifluoroethoxy) methyl) oxirane and propargyl alcohol as the initiator. The chemical structures, molecular weight, and thermal properties were characterized by FTIR, NMR, GPC, DSC, and TGA, respectively. HNMR results showed that 8 % of total azide groups in GAP were grafted. GAP‐g‐3F had a slightly higher glass transition temperature than that of GAP. The results of TGA showed that GAP‐g‐3F had suitable thermal decomposition resistance up to 200 °C. The thermal properties, mechanical properties, cross‐linking network structures, and microstructures of the polyurethane networks cured with hexamethylene diisocyanate trimer as a crosslinking agent were determined and compared by TGA, universal tensile test, swelling measurement, and SEM, respectively. The initial decomposition temperature of GAP‐g‐3F‐based polyurethane networks (GAP‐g‐3F‐PU) was around 220 °C, thus meeting the requirements for propellants. In addition, GAP‐g‐3F‐PU exhibited superior mechanical properties, showing an almost twelvefold increase in tensile strength to 16.9 MPa compared with difunctional GAP‐PU with 1.4 MPa tensile strength. The results of the swelling measurement revealed that the GAP‐g‐3F‐PU sample showed a higher crosslinking density in comparison to the GAP‐PU sample. SEM results indicated that the multifunctional fluorine‐containing GAP could enhance compatibility between the soft and hard segments of polyurethanes, leading to a decrease in their separation degree. This finding showed that the synthesis of a multifunctional GAP partially grafted with fluorinated polyether via a triazole ring may be a promising solution to decrease the separation degree increase of PUs, thereby improving the mechanical properties.

Laser transmission welding of Polyphenylsulfone resin using Sn film absorbent: Weld formation control and mechanical properties enhancement

Polyphenylsulfone resin (PPSU), holding significance across various domains, was successfully welded by the laser transmission welding (LTW). In order to optimize the morphology and mechanical properties of the weld seam, the Sn film was chosen as an intermediate layer and the mechanism governing the formation control and mechanical performance was unveiled. Without the addition of Sn film, weld formation was subpar, marked by defects such as bubbles occurring in the weld seam, particularly under moderate power conditions. After introducing Sn film as a metal absorbent, the molten pool pores were stabilized and the temperature distribution was optimized during LTW process, which promoted the welding process stability and facilitated the mixing and agitation of the molten pool. The Energy-dispersive X-ray Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) were conducted on cross-sections of the weld seam. Analysis revealed the formation of newly forged metallic bonds (SnC) between the metal and the PPSU, which were instrumental in bolstering the shear strength of the weld seam. After using the Sn as intermediate layer, the shear strength of welding joints increased from 23.21 MPa to 29.14 MPa. At optimal intermediate-layer thickness, the shear fracture exhibited predominantly a plastic tearing micro-pit morphology instead of brittle fracture rock pattern.

Effect of Heat Treatment on the Mechanical Property Enhancement of 17-4 PH Stainless Steel for Sheet Forming Applications

Effect of Heat Treatment on the Mechanical Property Enhancement of 17-4 PH Stainless Steel for Sheet Forming Applications

New approach to $${\upalpha }$$-titanium mechanical properties enhancement by means of thermoplastic deformation in mid-temperature range

AbstractPure titanium due to its high corrosion resistance, low stiffness and good mechanical properties is commonly used in medicine for orthopaedic applications. However, its material properties (especially in the case of $${\upalpha }$$ α -titanium) require a further enhancement to fulfil its role. The thermoplastic deformation in mid-temperature is proposed as a method for microstructure improvement. Titanium samples were compressed in different temperatures and strain rates to determine the best conditions for grain fragmentation—the main factor responsible for strength and hardness increase. The thermoplastic stress–strain curves were registered. Then microstructure observations and electron backscatter analysis were performed on the chosen samples. Finally, mechanical response of the previously deformed material was obtained in room temperature compression tests. A significant grain fragmentation was recorded for the material deformed in 400 $$^{\circ }\hbox {C}$$ ∘ C , at 0.1/s and 1/s strain rates. Desirable results were also noticed for the deformation performed at 500–600 $$^{\circ }\hbox {C}$$ ∘ C . However, high temperatures (700–800 $$^{\circ }\hbox {C}$$ ∘ C ) and strain rates (10/s) resulted in dynamic recrystallization, causing undesirable grain growth. An increase in hardness was observed in all cases, with higher values recorded in lower deformation temperatures. Room temperature compression tests revealed slight increase of ductility.

Design, manufacturing and experimental validation of additive manufacturing cores for bearing seats in carbon fibre reinforced polymer structures.

The integration of carbon-fibre reinforced polymers (CFRP) in structural applications offers significant advantages due to their high strength-to-weight ratio. However, these materials exhibit limitations under out-of-plane loads, particularly in bearing applications. This study explores an innovative approach to enhance the performance of CFRP structures in such scenarios by incorporating annular polyamide inserts manufactured via additive manufacturing (AM).To evaluate the mechanical performance of the AM inserts, a novel ring tensile test is designed to emulate the bearing load conditions. This test also enables the analysis of the impact of several design and manufacturing parameters of the AM inserts, including surface geometry, surface treatment, internal structure, and curing process. These are then compared with specimens made of carbon fibre sheet moulding compounds (CF-SMC), commonly used to support bearing loads. The study reveals that AM inserts provide a viable alternative to state-of-the-art CF-SMC, offering a significant enhancement in mechanical properties under specific bearing loading conditions. The test results indicate a 17.7% improvement in the first failure limit and an 8.6% increase in the ultimate strength for AM inserts compared to CF-SMC.Additionally, the study develops a simplified analytical model to predict stress distributions and potential failure mechanisms, validating its efficacy through experimental data with discrepancies of less than 6%. Economic analysis underscores the cost benefits of AM inserts due to reduced labour and higher repeatability. This research demonstrates the potential of AM inserts to improve the stability and strength of CFRP structures, paving the way for their broader application in demanding load-bearing environments.

Physical and mechanical properties enhancement of beaten oil palm trunk pulp and paper by optimizing starch addition: Towards sustainable packaging solutions

Paper is a commonly utilized material in various aspects of daily life. However, the pulp and paper industry face environmental challenges related to pollution and deforestation. The utilization of non-wood fibres, such as agricultural waste of oil palm (Elaeis guineensis Jacq.) from oil palm trunk (OPT), may offer sustainable alternatives to wood-based pulp. However, the mechanical properties of OPT paper in this study need improvement to compete with wood-based paper. Incorporating starch as an additive can enhance the mechanical and physical properties of OPT paper. This study aimed to develop and characterize the unbleached OPT paper prepared via kraft and soda pulping methods and beating treatment. The mechanical properties are enhanced by adding starch at 5,10,15, and 20 %. Findings exhibited that the addition of starch increased the tensile strength of OPT papers but decreased tear resistance. Hence, the papers have a high potential to be applied as non-woody pulp source-sustainable alternative raw materials for packaging.

Modification of biodegradable thermoplastic cassava starch/kapok fiber incorporated by tartaric acid and processed by compression molding technique

Thermoplastic starch has been attracted due to its availability, biodegradability, and processability. However, its poor tensile properties, high hydrophilicity and lack of antibacterial activity are still the major concerns for many applications. In current study, several thermoplastic cassava starch samples (THPCS), reinforced with kapok (KP) fibers and modified by varying levels of tartaric acid (TA), a natural organic acid, were prepared to enhance their limitations. All samples were mixed and shaped using an internal mixer and a compression molding machine, respectively. The modified THPCS samples were characterized using analytical techniques such as FTIR, SEM and TGA. Morphology, water uptake, mechanical properties, biodegradability, and antimicrobial performance of various samples were also evaluated. IR peak positions of O–H stretching as well as O–H bending were clearly observed for shifting to lower wavenumbers with the addition of KP fibers or KP fibers/TA, indicating of new H-bond formation. In addition, the use of KP fibers caused the enhancement of mechanical strength and thermal properties including the reduction of water uptake. Moreover, THPCS/KP fiber sample modified by TA presented surface smoothness, good biodegradability, and antibacterial performance against both Staphylococcus aureus and Escherichia coli.

Wire-arc directed energy deposition of high performance heat treatment free Al-6Mg-0.3Sc alloy

The release of residual stress during heat treatment of additively manufactured components could lead to significant deformation, particularly for those with thin-wall features and variable cross-sections. In this study, high performance heat treatment free Al-6Mg-0.3Sc alloy components were fabricated using the wire-arc directed energy deposition (DED) technique, achieving a yield strength of 223.0 ± 0.9 MPa, tensile strength of 408.5 ± 3.2 MPa, and elongation of 20.6 ± 1.7 %. The results indicate that compared to the CMT arc mode, the CMT + PA arc mode leads to a more pronounced bimodal microstructure, resulting in improved elongation. The mechanical property enhancement mechanism relies more on solid solution strengthening and grain boundary strengthening than on precipitation strengthening. Additionally, this study establishes for the first time a correlation between droplet transition and microstructure evolution. The research presented herein lays a theoretical foundation for wire-arc DED in the direct manufacturing of large thin-walled components without the need for heat treatment.

Enhanced mechanical properties and electromagnetic interference shielding effectiveness in Mg‐6Zn‐1Y‐1La‐0.5Zr alloy sheet by hot deformation

Striking a balance between the mechanical properties and electromagnetic interference shielding effectiveness (EMI SE) of Mg alloys stands as a critical concern within the realm of electronics and communications. This study endeavors to optimize the mechanical properties and EMI SE of Mg alloy sheets through a combination of extrusion and rolling (E-R). OM, SEM, XRD, EBSD, and TEM obtained the microstructures of Mg‐6Zn‐1Y‐1La‐0.5Zr alloys under extrusion and different rolling strain treatments, and the effects of the microstructures on the mechanical properties and EMI SE were revealed. The microstructure of the as-extruded Mg‐6Zn‐1Y‐1La‐0.5Zr (abbreviated as ZKL611K) alloy exhibited a distinct bimodal microstructure, with refined dynamically recrystallized (DRXed) grains surrounding coarse unDRXed regions. Subsequent rolling treatments induced a decrease in the aspect ratio of the unDRXed regions, a rapid reduction of DRXed grains, and the accumulation of dislocations within the as-rolled alloy. Statistical analysis of mechanical properties and EMI SE revealed that an optimal balance in the sheets subjected to “extrusion + 37 % rolling reduction”, yield strength (YS) of 319 MPa, ultimate tensile strength (UTS) of 375 MPa, and elongation of 12.3 %. Furthermore, the EMI SE ranged from 81 dB to 114 dB within the frequency range of 30–1500 MHz. However, further increments in rolling reduction adversely affected mechanical properties while improving EMI SE. The observed enhancement in mechanical properties can be primarily attributed to the synergistic effects of grain size, second phase, dislocations, low-angle grain boundaries (LAGBs), and texture. Meanwhile, the improved EMI SE can be mainly attributed to the diffuse distribution of the second phase at multiple scales and the modulation of the texture through E-R treatments.

Fabrication and control architecture of novel hybrid metal additive manufacturing incremental forming technology

Hybrid manufacturing processes redefine production dynamics by harnessing the synergistic interplay between process mechanisms, energy sources, and tools to impact manufacturing quality, productivity, and sustainability significantly. Accordingly, this article focuses on hybrid additive manufacturing incremental forming, where additive manufacturing and incremental forming are integrated in a unified setup, driven by a single power source. This integration opens avenues for innovative component and production design, capitalizing on the strengths of both methods while mitigating drawbacks. The fabrication of the hybrid additive manufacturing incremental forming setup involves crucial components like a hybrid extrusion forming unit, supporting plates, hopper-barrel assembly, band heaters, solenoid setup, and a comprehensive control architecture. Addressing challenges, particularly overheating in the hopper, and feeding zone, ensures effective material transformation with the hybrid extrusion forming unit. The subsequent section provides analytical analysis and validation of the hybrid extrusion unit. This technology enhances the entire process and addresses issues related to metal additive manufacturing, such as porosity and material shrinkage. The maximum tensile force sustained in hybrid additive manufacturing incremental forming before fracture demonstrates a notable enhancement of about 20% from 670 N in additive manufacturing to 805 N in hybrid additive manufacturing incremental forming. It also removes micro-cracks, and voids, and improves the inter-layer bonding, as observed through scanning electron microscopy. The results highlight hybrid additive manufacturing incremental forming's superior enhancement of mechanical properties and surface quality compared to traditional additive manufacturing approaches.

Friction Stir Channeling in Heat Sink Applications: Innovative Manufacturing Approaches and Performance Evaluation

The fabrication of compact heat exchangers with precisely designed micro- and mini-channels is crucial for enhancing the efficiency of thermal management systems. Friction stir channeling (FSC) emerges as a cost-effective advanced manufacturing process to create complex integral channels, offering channel shape and size flexibility. This review article highlights the pivotal role of processing parameters in channel formation and maintaining their integrity, necessitating a comprehensive understanding of material flow dynamics. A rigorous assessment has been conducted on the channel under mechanical stresses, including tension, bending, and fatigue. The paper emphasizes the potential of FSC to revolutionize heat sink applications by exploring the fundamental concepts, governing parameters, ongoing enhancements in tool design, microstructural and mechanical properties, and heat transfer performance.

Formation of lamellar eutectic structure and improved mechanical properties of directional solidified Al0.9CoCrNi2.1 high-entropy alloy

In this study, Al0.9CoCrNi2.1 EHEA was prepared by directional solidification at various withdrawal rates from 6 to 120 μm/s. The lamellar eutectic structure is formed containing FCC (L12) and BCC (B2) at different withdrawal rates during directional solidification. The solid-liquid interface of the alloy transfers from nearly-planer to cellular eutectic interface and the lamellar spacing decreases from 7.17 μm to 1.65 μm as the withdrawal rate increases. The lamellar spacing is negatively correlated with withdrawal rates which was identified by the Jackson-Hunt model and its growth rate index (0.484) is closely related to the theoretical value (0.5). The tensile experiment demonstrates that the structure of Al0.9CoCrNi2.1 EHEA is finer and the ultimate tensile strength and elongation increase as the withdrawal rate increases. The elongation of Al0.9CoCrNi2.1 EHEA is two times higher than that of the as-cast alloy at the withdrawal rate of 120 μm/s. It is concluded that the formation of the L12 phase and Cr-rich precipitated phases in the directional solidified eutectic structure are associated with the enhancement of mechanical properties due to grain refinement at high withdrawal rates.

Optimized mechanical properties of the hot forged Ti–6Al–4V alloy by regulating multiscale microstructure via laser shock peening

The hot forged Ti–6Al–4V alloy demonstrates well constructed microstructure and balanced mechanical properties, which promotes its wide application in aviation field. However, its relative poor resistance to wear and foreign object impact usually leads to the cumulative damage, causing sudden failure and serious accident. Laser shock peening (LSP) is a novel surface plastic deformation technique, which could strengthen the surface layer of components through gradient grain structure. Nevertheless, the specific mechanism of microstructure evolution and mechanical properties enhancement of LSP processed hot forged Ti–6Al–4V alloy is still obscure, and its corresponding explanation would help the wide application. In the present research, the hot forged Ti–6Al–4V alloy was processed by LSP to regulate its superficial microstructure and improve mechanical properties, helping to understand the inner mechanism. The results reveal that LSP could simultaneously result in the merging of ultrafine α-Ti grains and refinement of coarse α-Ti grains, which reconstruct the dual-size grain structure. The crystal tilting and transformation promoted by the generation and movement of dislocations benefit the merging of ultrafine grains. Due to the different slip systems in dual phases, β-Ti phases exhibit much greater response to slip under surface plastic deformation, which are enforced to deform and construct the shell structure by sliding and phase transformation, while the α-Ti phases act as the core to synergistically construct ‘core-shell’ like structure. The increase of LSP impact time promotes the well wrapping of the ‘core-shell’ like structure and strengthens it by abundant dislocations, which also forms the gradient grain structure from surface to inner. Since the microstructure regulation and crystal defects engineering, the LSP improves the surface damage resistance and mechanical properties of the hot forged Ti–6Al–4V alloy obviously. Such results indicate a new technology to increase the properties of the hot forged Ti–6Al–4V alloy component further.

Improving the Interfacial Adhesion of Long Carbon Fiber-Reinforced Polyamide 6 Composites by Electrochemical Oxidation and Polyethylenimine-Carboxymethyl Cellulose Grafting.

Carbon fiber (CF)-reinforced thermoplastic composites have notable ascents in various sectors and applications. For high-performance composites, strong interfacial adhesion between the polymer matrix and the CF is crucial. This is achieved by introducing functional groups on the CF surface. In this paper, a water-based surface treatment was applied to long carbon fibers to enhance the interfacial bonding with the polyamide 6 (PA6) matrix. For that, PEI and CMC were grafted onto the surface of carbon fibers after electrochemical oxidation. The PEI-CMC sizing reduced the carbon fiber/water contact angle to 26.42° from 111.69°. The clear improvement in wettability resulted in a 164.8% increase in the interfacial strength of 26.7 MPa after the application of PEI-CMC sizing on carbon fibers (CFs). The resultant tensile and flexural strength increased by 19.3 and 11.7% from 2009.6 and 378.3 MPa for desized CF/PA6 composites to 250.3 and 422.7 MPa for PEI-CMC-sized CF/PA6 composites, respectively. Moreover, the fractured surface morphologies were also investigated to confirm the enhancement of mechanical properties. The proposed one-step electrochemical oxidation and water-based sizing procedure is found to be promising for the production of high-performance long-fiber-reinforced thermoplastic composites.

The mechanics of tissue-engineered temporomandibular joint discs: Current status and prospects for enhancement.

The temporomandibular joint (TMJ) disc is an essential protective but vulnerable fibrocartilage. Their high mechanical strength is vital in absorbing loads, reducing friction, and protecting the condylar surface. Many diseases can lead to the destruction or degeneration of the mechanical function of the TMJ disc. Unfortunately, conservative treatment is ineffective in restoring the defective mechanical properties of the discs. Tissue engineering has been investigated as a promising alternative treatment approach to approximate the properties of native tissue. However, it is difficult for tissue-engineered discs to obtain sufficient mechanical properties. Several approaches have been proposed to improve the mechanical properties of tissue-engineered constructs. In this review, we summarized the mechanical properties of native TMJ discs and discussed the current mechanical testing methods. We then summarized the current advances in improving the mechanical properties of TMJ disc tissue-engineered constructs. Moreover, existing challenges and outbreak directions are discussed. This review assists future research in better understanding the mechanical properties of both native and tissue-engineered TMJ discs. It provides new insights into future mechanical property enhancement for TMJ disc tissue engineering.

Fabrication and characteristics of functional hydrogels based on dopamine‐grafted gelatin and oxyglucan with incorporation of dipotassium glycyrrhizinate potential for wound dressings

AbstractHydrogel have been widely used to promote skin tissue regeneration and accelerate wound healing. The development of injectable hydrogels with multi‐functional integration is a priority, especially with antibacterial properties and cytocompatibility. Here, we reported a simple, and versatile method to fabricate a functional hydrogel with potential for wound dressing applications. The dopamine‐grafted gelatin (GT‐DA) and oxidized dextran (oxyglucan, ODex) were synthesized, and dipotassium glycyrrhizinate (DG) was in situ incorporated to fabricate the composite hydrogels (GDO) through the Schiff base reaction. SEM images revealed that hydrogel has a porous structure. By increasing the ratio of GT‐DA to ODex from 1 to 4, the storage modulus (G') and hydrogel network stability nearly doubled, reaching 900 Pa and 220% strain, respectively. The enhancement in mechanical properties could be attributed to the higher cross‐linking density resulting from increased Schiff base bonds in the GDO hydrogels. Furthermore, the GDO hydrogel exhibited antioxidant activity and antibacterial effects on Escherichia coli and Staphylococcus aureus. Moreover, the hydrogel demonstrated cytocompatibility after culturing with human umbilical vein endothelial cells (HUVECs). The results proved that the fabricated GDO hydrogels have the potential to be used as wound dressings.

Effects of recrystallization on interfacial microstructure evolution and shear strength of TiAl alloy joints

The effects of dynamic recrystallization (DRX) and post-bonding heat treatment (PBHT) on the interfacial microstructure evolution and mechanical properties enhancement of Ti-43Al-4Nb-1Mo-0.2B alloy joints, subjected to various bonding parameters, were thoroughly investigated through detailed microstructural characterization and shear performance tests. A strip-like DRX area was observed at the interface when bonding at 1100 °C, ≥30 MPa, for 60 min. Equiaxial- γ grains underwent discontinuous dynamic recrystallization during the bonding process, and tended to form flat grains parallel to the lamellae direction during recrystallization annealing (1000 °C/6 h) owing to the hindrance imposed by the lamellae on both sides. The orientations of lamellae on the both sides of bonding interface affects the lamellae's stress distribution and deformation behavior at the bonding interface, subsequently influencing the DRX behavior and the width of the DRX zone. Static recrystallization (SRX) during the recrystallization annealing treatment can eliminate bonding defects of joints bonding at lower pressures or temperatures. Optimal joints with fully lamellar interfacial microstructure and excellent shear properties can be obtained through single-α phase annealing treatment. Lamellae microstructure tailored through PBHT can significantly enhance the quality of joints, attributed to the homogeneity of the microstructure between the interface and matrix. The highest shear strength of 478 MPa, accounting for 82 % of the matrix strength, was obtained under the bonding parameters of 1100 °C/30 MPa/60 min-1290 °C/15 min. This work provides important DB process parameters for fabricating of complex structural parts of TiAl alloy.

Modification of the Structure and Mechanical Properties of Cu-30%Zn alloy with Cerium and Silicon

This study investigates how the introduction of cerium and silicon influences the structure and mechanical characteristics of Cu-30%Zn alloy. The examined properties included tensile strength, hardness, and impact resistance. The tensile strength of the developed alloys was determined using an automated JPL tensile strength tester (Model: 130812) with a capacity of 100 kilonewtons, following the ASTM D638 standard. The impact strength was assessed by the ASTM D256 standard using a pendulum impact testing machine (Model: U1820). Additionally, hardness testing was conducted using a Brinell tester. The Brinell hardness test was performed with a portable dynamic hardness tester (Model: DHT-6) by the British Standard (BS EN ISO 6505-1:2014). Specimens were prepared by incorporating cerium and silicon into the Cu-30%Zn alloy at concentrations of 0.1wt%, 0.3wt%, 0.5wt%, 1.0wt%, 3.0wt% 5.0wt% ranging from 0.1% to 5.0%, with increments of 0.2% for micro addition and 2.0% for macro addition. Microstructural analysis was performed using an L2003A reflected light metallurgical microscope. Scanning Electron Microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were also utilized to characterize the cast specimens. The findings revealed a proportional increase in tensile strength, impact strength, and hardness strength with the rise in dopant concentrations up to 3.0wt% for cerium and silicon. Also, the analysis uncovered the presence of. primary α-phase, β-phase (intermetallic phases), and fine stable phase. These phase modifications contributed to the enhancement of mechanical properties. Cu-30wt%Zn enriched with 3.0% cerium and silicon demonstrated heightened tensile strength, impact strength, and hardness, making it a recommended choice for engineering applications.

Advances and Significances of Nanoparticles as Concrete Additives: A Comprehensive Review

Nanotechnology, a significant technological advancement in the current century, has brought about revolutionary changes in numerous fields by manipulating matter at the nanoscale. This review paper examines the various applications of nanoparticles in the concrete industry, emphasizing their potential to improve mechanical qualities, thermal performance and sustainability. This study investigates multiple synthesis strategies, such as grafting, sol–gel, chemical and biological procedures, which offer concrete engineers a diverse range of options to tailor the properties of nanoparticles. The utilization of this particular material results in notable enhancements in many mechanical properties of concrete, including its compressive and flexural strength, toughness, thermal conductivity and self-sensing capabilities. These improvements ultimately contribute to the overall enhancement of the concrete’s structural integrity and energy efficiency. Adding nanoparticles to concrete has also been shown to help it develop self-healing properties. This means that structures last longer and require less maintenance. Making building materials more resistant to chemical corrosion, wear and environmental forces is also a big step in making them last longer. The growing emphasis on sustainability within the building industry has generated heightened attention toward utilizing self-healing concrete, which frequently incorporates nanoparticles. To make the building industry more environmentally friendly, using less traditional cement and recycling personal safety equipment (PPE) like vinyl and latex gloves can help protect the environment. This review also highlights the significant problems in employing nanoparticles in concrete: obtaining equal dispersion, handling-costs and addressing environmental and health concerns. However, nanotechnology is advancing construction concrete research to improve mechanical properties and durability.