Enhancement Of Mechanical Properties Research Articles

Amyloid peptide - synthetic polymer blends with enhanced mechanical and biological properties.

Interest in utilizing amyloids to develop biomaterials is increasing due to their potential for biocompatibility, unique assembling morphology, mechanical stability, and biophysical properties. However, challenges include the complexity of peptide chemistry and the practical techniques required for processing amyloids into bulk materials. In this work, two decapeptides with fibrillar and globular morphologies were selected, blended with poly(ethylene oxide), and fabricated into composite mats via electrospinning. Notable enhancements in mechanical properties were observed, attributed to the uniform distribution of the decapeptide assemblies within the PEO matrix. Morphological differences, such as the production of thinner nanofibers, are attributed to the increased conductivity from the zwitterionic nature of the decapeptides. Blend rheology and post-processing analysis revealed how processing might affect the amyloid aggregation and secondary structure of the peptides. Both decapeptides demonstrated good biocompatibility and strong antioxidant activity, indicating their potential for safe and effective use as biomaterials. By evaluating these interdependencies, this research lays the foundation for understanding the structure-property-processing relationships of peptide-polymer blends and highlights the strong potential for developing applications in biotechnology.

Modification of biodegradable thermoplastic cassava starch/kapok fiber incorporated by tartaric acid and processed by compression molding technique

Thermoplastic starch has been attracted due to its availability, biodegradability, and processability. However, its poor tensile properties, high hydrophilicity and lack of antibacterial activity are still the major concerns for many applications. In current study, several thermoplastic cassava starch samples (THPCS), reinforced with kapok (KP) fibers and modified by varying levels of tartaric acid (TA), a natural organic acid, were prepared to enhance their limitations. All samples were mixed and shaped using an internal mixer and a compression molding machine, respectively. The modified THPCS samples were characterized using analytical techniques such as FTIR, SEM and TGA. Morphology, water uptake, mechanical properties, biodegradability, and antimicrobial performance of various samples were also evaluated. IR peak positions of O–H stretching as well as O–H bending were clearly observed for shifting to lower wavenumbers with the addition of KP fibers or KP fibers/TA, indicating of new H-bond formation. In addition, the use of KP fibers caused the enhancement of mechanical strength and thermal properties including the reduction of water uptake. Moreover, THPCS/KP fiber sample modified by TA presented surface smoothness, good biodegradability, and antibacterial performance against both Staphylococcus aureus and Escherichia coli.

A sulfonated hyperbranched bio-based waterborne polyurethane sizing coating for the enhancement of mechanical properties and surface wettability of carbon fibres

Wet-weaving and cluster braiding in industrial production processes generate irreversible defects and grooves in carbon fibre (CF) filaments, which reduce the service life and mechanical properties of the fibres. Additionally, the fibre surface covered with numerous inactive carbon-containing groups and presents chemical inertness, which limits the prospects of CF applications. Hence, the hyperbranched bio-based waterborne polyurethanes (SWPU) possessing the synergism of sulfamate and carboxylate complex hydrophilic units were adopted as sizing coatings to improve the flexural and tensile strengths of CF, as well as fibre surface roughness and wettability. The SWPU is designed on dihydroxymethylbutyric acid and sulfamates (A95) as per- and post-chain extenders, respectively, trimethylolpropane (TMP) as an intramolecular cross-linker, and plant-extracts castor oil (CO) replacing petroleum-based petrochemicals as the soft-segments. The construction of CO-TMP hyperbranched cross-linking networks and the strengthened hydrogen-bonding effects of the polar sulfamates positively affect the intermolecular interactions and configuration stability of SWPU sizing coatings. SWPU revealed favourable thermo-mechanical properties achieving a T5% decomposition temperature and toughness of 297.83 °C and 35.24 MJ/m3. The coating effects of the bio-based sizing agents not only repaired defects and improved surface roughness on CF, but the polar groups in SWPU comprising SO3Na, carbamate and polyurea promoted the chemotactic activity and wettability of the fibres. The surface energy and tensile strength of the SWPU sized CF reached 43.75 mN/m and 5.68 GPa, respectively, which were 45.4 % and 30.7 % higher compared to original CF. The research contributes to the development and industrial production of high-performance, eco-friendly bio-based sizing coatings.

Wire-arc directed energy deposition of high performance heat treatment free Al-6Mg-0.3Sc alloy

The release of residual stress during heat treatment of additively manufactured components could lead to significant deformation, particularly for those with thin-wall features and variable cross-sections. In this study, high performance heat treatment free Al-6Mg-0.3Sc alloy components were fabricated using the wire-arc directed energy deposition (DED) technique, achieving a yield strength of 223.0 ± 0.9 MPa, tensile strength of 408.5 ± 3.2 MPa, and elongation of 20.6 ± 1.7 %. The results indicate that compared to the CMT arc mode, the CMT + PA arc mode leads to a more pronounced bimodal microstructure, resulting in improved elongation. The mechanical property enhancement mechanism relies more on solid solution strengthening and grain boundary strengthening than on precipitation strengthening. Additionally, this study establishes for the first time a correlation between droplet transition and microstructure evolution. The research presented herein lays a theoretical foundation for wire-arc DED in the direct manufacturing of large thin-walled components without the need for heat treatment.

Enhanced mechanical properties and electromagnetic interference shielding effectiveness in Mg‐6Zn‐1Y‐1La‐0.5Zr alloy sheet by hot deformation

Striking a balance between the mechanical properties and electromagnetic interference shielding effectiveness (EMI SE) of Mg alloys stands as a critical concern within the realm of electronics and communications. This study endeavors to optimize the mechanical properties and EMI SE of Mg alloy sheets through a combination of extrusion and rolling (E-R). OM, SEM, XRD, EBSD, and TEM obtained the microstructures of Mg‐6Zn‐1Y‐1La‐0.5Zr alloys under extrusion and different rolling strain treatments, and the effects of the microstructures on the mechanical properties and EMI SE were revealed. The microstructure of the as-extruded Mg‐6Zn‐1Y‐1La‐0.5Zr (abbreviated as ZKL611K) alloy exhibited a distinct bimodal microstructure, with refined dynamically recrystallized (DRXed) grains surrounding coarse unDRXed regions. Subsequent rolling treatments induced a decrease in the aspect ratio of the unDRXed regions, a rapid reduction of DRXed grains, and the accumulation of dislocations within the as-rolled alloy. Statistical analysis of mechanical properties and EMI SE revealed that an optimal balance in the sheets subjected to “extrusion + 37 % rolling reduction”, yield strength (YS) of 319 MPa, ultimate tensile strength (UTS) of 375 MPa, and elongation of 12.3 %. Furthermore, the EMI SE ranged from 81 dB to 114 dB within the frequency range of 30–1500 MHz. However, further increments in rolling reduction adversely affected mechanical properties while improving EMI SE. The observed enhancement in mechanical properties can be primarily attributed to the synergistic effects of grain size, second phase, dislocations, low-angle grain boundaries (LAGBs), and texture. Meanwhile, the improved EMI SE can be mainly attributed to the diffuse distribution of the second phase at multiple scales and the modulation of the texture through E-R treatments.

Fabrication and control architecture of novel hybrid metal additive manufacturing incremental forming technology

Hybrid manufacturing processes redefine production dynamics by harnessing the synergistic interplay between process mechanisms, energy sources, and tools to impact manufacturing quality, productivity, and sustainability significantly. Accordingly, this article focuses on hybrid additive manufacturing incremental forming, where additive manufacturing and incremental forming are integrated in a unified setup, driven by a single power source. This integration opens avenues for innovative component and production design, capitalizing on the strengths of both methods while mitigating drawbacks. The fabrication of the hybrid additive manufacturing incremental forming setup involves crucial components like a hybrid extrusion forming unit, supporting plates, hopper-barrel assembly, band heaters, solenoid setup, and a comprehensive control architecture. Addressing challenges, particularly overheating in the hopper, and feeding zone, ensures effective material transformation with the hybrid extrusion forming unit. The subsequent section provides analytical analysis and validation of the hybrid extrusion unit. This technology enhances the entire process and addresses issues related to metal additive manufacturing, such as porosity and material shrinkage. The maximum tensile force sustained in hybrid additive manufacturing incremental forming before fracture demonstrates a notable enhancement of about 20% from 670 N in additive manufacturing to 805 N in hybrid additive manufacturing incremental forming. It also removes micro-cracks, and voids, and improves the inter-layer bonding, as observed through scanning electron microscopy. The results highlight hybrid additive manufacturing incremental forming's superior enhancement of mechanical properties and surface quality compared to traditional additive manufacturing approaches.

Friction Stir Channeling in Heat Sink Applications: Innovative Manufacturing Approaches and Performance Evaluation

The fabrication of compact heat exchangers with precisely designed micro- and mini-channels is crucial for enhancing the efficiency of thermal management systems. Friction stir channeling (FSC) emerges as a cost-effective advanced manufacturing process to create complex integral channels, offering channel shape and size flexibility. This review article highlights the pivotal role of processing parameters in channel formation and maintaining their integrity, necessitating a comprehensive understanding of material flow dynamics. A rigorous assessment has been conducted on the channel under mechanical stresses, including tension, bending, and fatigue. The paper emphasizes the potential of FSC to revolutionize heat sink applications by exploring the fundamental concepts, governing parameters, ongoing enhancements in tool design, microstructural and mechanical properties, and heat transfer performance.

Formation of lamellar eutectic structure and improved mechanical properties of directional solidified Al0.9CoCrNi2.1 high-entropy alloy

In this study, Al0.9CoCrNi2.1 EHEA was prepared by directional solidification at various withdrawal rates from 6 to 120 μm/s. The lamellar eutectic structure is formed containing FCC (L12) and BCC (B2) at different withdrawal rates during directional solidification. The solid-liquid interface of the alloy transfers from nearly-planer to cellular eutectic interface and the lamellar spacing decreases from 7.17 μm to 1.65 μm as the withdrawal rate increases. The lamellar spacing is negatively correlated with withdrawal rates which was identified by the Jackson-Hunt model and its growth rate index (0.484) is closely related to the theoretical value (0.5). The tensile experiment demonstrates that the structure of Al0.9CoCrNi2.1 EHEA is finer and the ultimate tensile strength and elongation increase as the withdrawal rate increases. The elongation of Al0.9CoCrNi2.1 EHEA is two times higher than that of the as-cast alloy at the withdrawal rate of 120 μm/s. It is concluded that the formation of the L12 phase and Cr-rich precipitated phases in the directional solidified eutectic structure are associated with the enhancement of mechanical properties due to grain refinement at high withdrawal rates.

Optimized mechanical properties of the hot forged Ti–6Al–4V alloy by regulating multiscale microstructure via laser shock peening

The hot forged Ti–6Al–4V alloy demonstrates well constructed microstructure and balanced mechanical properties, which promotes its wide application in aviation field. However, its relative poor resistance to wear and foreign object impact usually leads to the cumulative damage, causing sudden failure and serious accident. Laser shock peening (LSP) is a novel surface plastic deformation technique, which could strengthen the surface layer of components through gradient grain structure. Nevertheless, the specific mechanism of microstructure evolution and mechanical properties enhancement of LSP processed hot forged Ti–6Al–4V alloy is still obscure, and its corresponding explanation would help the wide application. In the present research, the hot forged Ti–6Al–4V alloy was processed by LSP to regulate its superficial microstructure and improve mechanical properties, helping to understand the inner mechanism. The results reveal that LSP could simultaneously result in the merging of ultrafine α-Ti grains and refinement of coarse α-Ti grains, which reconstruct the dual-size grain structure. The crystal tilting and transformation promoted by the generation and movement of dislocations benefit the merging of ultrafine grains. Due to the different slip systems in dual phases, β-Ti phases exhibit much greater response to slip under surface plastic deformation, which are enforced to deform and construct the shell structure by sliding and phase transformation, while the α-Ti phases act as the core to synergistically construct ‘core-shell’ like structure. The increase of LSP impact time promotes the well wrapping of the ‘core-shell’ like structure and strengthens it by abundant dislocations, which also forms the gradient grain structure from surface to inner. Since the microstructure regulation and crystal defects engineering, the LSP improves the surface damage resistance and mechanical properties of the hot forged Ti–6Al–4V alloy obviously. Such results indicate a new technology to increase the properties of the hot forged Ti–6Al–4V alloy component further.

Improving the Interfacial Adhesion of Long Carbon Fiber-Reinforced Polyamide 6 Composites by Electrochemical Oxidation and Polyethylenimine-Carboxymethyl Cellulose Grafting.

Carbon fiber (CF)-reinforced thermoplastic composites have notable ascents in various sectors and applications. For high-performance composites, strong interfacial adhesion between the polymer matrix and the CF is crucial. This is achieved by introducing functional groups on the CF surface. In this paper, a water-based surface treatment was applied to long carbon fibers to enhance the interfacial bonding with the polyamide 6 (PA6) matrix. For that, PEI and CMC were grafted onto the surface of carbon fibers after electrochemical oxidation. The PEI-CMC sizing reduced the carbon fiber/water contact angle to 26.42° from 111.69°. The clear improvement in wettability resulted in a 164.8% increase in the interfacial strength of 26.7 MPa after the application of PEI-CMC sizing on carbon fibers (CFs). The resultant tensile and flexural strength increased by 19.3 and 11.7% from 2009.6 and 378.3 MPa for desized CF/PA6 composites to 250.3 and 422.7 MPa for PEI-CMC-sized CF/PA6 composites, respectively. Moreover, the fractured surface morphologies were also investigated to confirm the enhancement of mechanical properties. The proposed one-step electrochemical oxidation and water-based sizing procedure is found to be promising for the production of high-performance long-fiber-reinforced thermoplastic composites.

The mechanics of tissue-engineered temporomandibular joint discs: Current status and prospects for enhancement.

The temporomandibular joint (TMJ) disc is an essential protective but vulnerable fibrocartilage. Their high mechanical strength is vital in absorbing loads, reducing friction, and protecting the condylar surface. Many diseases can lead to the destruction or degeneration of the mechanical function of the TMJ disc. Unfortunately, conservative treatment is ineffective in restoring the defective mechanical properties of the discs. Tissue engineering has been investigated as a promising alternative treatment approach to approximate the properties of native tissue. However, it is difficult for tissue-engineered discs to obtain sufficient mechanical properties. Several approaches have been proposed to improve the mechanical properties of tissue-engineered constructs. In this review, we summarized the mechanical properties of native TMJ discs and discussed the current mechanical testing methods. We then summarized the current advances in improving the mechanical properties of TMJ disc tissue-engineered constructs. Moreover, existing challenges and outbreak directions are discussed. This review assists future research in better understanding the mechanical properties of both native and tissue-engineered TMJ discs. It provides new insights into future mechanical property enhancement for TMJ disc tissue engineering.

Fabrication and characteristics of functional hydrogels based on dopamine‐grafted gelatin and oxyglucan with incorporation of dipotassium glycyrrhizinate potential for wound dressings

AbstractHydrogel have been widely used to promote skin tissue regeneration and accelerate wound healing. The development of injectable hydrogels with multi‐functional integration is a priority, especially with antibacterial properties and cytocompatibility. Here, we reported a simple, and versatile method to fabricate a functional hydrogel with potential for wound dressing applications. The dopamine‐grafted gelatin (GT‐DA) and oxidized dextran (oxyglucan, ODex) were synthesized, and dipotassium glycyrrhizinate (DG) was in situ incorporated to fabricate the composite hydrogels (GDO) through the Schiff base reaction. SEM images revealed that hydrogel has a porous structure. By increasing the ratio of GT‐DA to ODex from 1 to 4, the storage modulus (G') and hydrogel network stability nearly doubled, reaching 900 Pa and 220% strain, respectively. The enhancement in mechanical properties could be attributed to the higher cross‐linking density resulting from increased Schiff base bonds in the GDO hydrogels. Furthermore, the GDO hydrogel exhibited antioxidant activity and antibacterial effects on Escherichia coli and Staphylococcus aureus. Moreover, the hydrogel demonstrated cytocompatibility after culturing with human umbilical vein endothelial cells (HUVECs). The results proved that the fabricated GDO hydrogels have the potential to be used as wound dressings.

Investigation of the microstructure evolution and mechanical properties of cast Ti–47Al–2Cr–2Nb alloy during ultra-high pressure heat treatment

TiAl alloy is a high-temperature and lightweight material with superior properties, which has been widely used in aerospace industry. and casting is an economical method for its production. However, casting defects has hindered its direct applications in aerospace turbine blades. To minimize casting defects and achieve alloy strengthening, this paper proposed a novel single heat treatment process under ultra-high pressure (UHP) to regulate the microstructure and mechanical properties of the Ti–47Al–2Cr–2Nb alloy. The results indicated that the microstructure achieved overall grain refinement, high temperature and ultra-high pressure stresses jointly induced the γ→α2 phase transformation. After the UHP heat treatment, the hardness of the alloy increased from 287HV to 381HV, and the yield strength and ultimate strength increased by 53 % and 20 %, respectively, without significantly affecting the strain to fracture. Based on the phase transformation behavior and strengthening mechanism, these enhancements in mechanical properties were mainly attributed to the precipitation strengthening of α2 grains and the reduction of lamellar thickness. This suggested that UHP heat treatment was an effective method to improve cast TiAl alloys.

Mechanical properties of additively manufactured ultrafine grain stainless steel-titanium boride (SS–TiB2) nanocomposites

Stainless-steel, particularly the 316L alloy, is extensively utilized across diverse industrial sectors. Nonetheless, its inherent limitation of low yield strength poses a significant challenge. In this study, we propose a novel method to address this limitation by incorporating trace quantities of TiB2 nanoparticles into the 316L matrix. The methodology involves a combination of low-energy ball milling for the preparation of the powder feedstock, followed by selective laser melting (SLM) for the fabrication of nanocomposites. The resulting stainless-steel nanocomposite exhibits a nearly-full dense structure characterized by the uniform dispersion of TiB2 nanoparticles (30–40 nm in diameter) within the matrix grain interiors and at grain boundaries. This leads to a substantial refinement in the matrix grain and a remarkable enhancement in mechanical properties. Specifically, the incorporation of 3 vol% TiB2 nanoparticles results in substantial enhancements in tensile yield strength (90.5 %), microhardness (81.4 %), ultimate strength (78.03 %) and bulk modulus (75.2 %) at room temperature compared to plain SLMed stainless-steel. This notable enhancement arises from the uniform dispersion of TiB2 nanoparticles and grain refinement, achieved without discernible processing defects such as agglomeration or interface microcracks. These findings offer a promising avenue for enhancing the mechanical characteristics of stainless-steel-based nanocomposites, thereby expanding their applicability in demanding engineering environments.

Enhancement of Mechanical Properties of PCL/PLA/DMSO2 Composites for Bone Tissue Engineering

Bone tissue engineering shows potential for regenerating or replacing damaged bone tissues by utilizing biomaterials renowned for their biocompatibility and structural support capabilities. Among these biomaterials, polycaprolactone (PCL) and polylactic acid (PLA) have gained attention due to their biodegradability and versatile applications. However, challenges such as low degradation rates and poor mechanical properties limit their effectiveness. Dimethyl sulfone (DMSO2) has emerged as a potential additive to address these limitations, offering benefits such as reduced viscosity, increased degradation time, and enhanced surface tension. In this study, we investigate tailored composites comprising PLA, PCL, and DMSO2 to enhance mechanical properties and hydrophilicity. Through material characterization and mechanical testing, we found that the addition of DMSO2 led to improvements in the yield strength, modulus, and hydrophilicity of the composites. PCL and DMSO2 10, 20, and 30 wt% were premixed, and 20 wt% PCL + 10, 20, and 30 wt% DMSO2 were mixed with PLA. Specifically, PLA/PCL/DMSO2 composites exhibited higher yield strengths and moduli compared to pure PLA, pure PCL, and PLA/PCL composites. Moreover, the hydrophilicity of the composites increased with DMSO2 concentration, facilitating cell attachment. Fourier-transform infrared spectroscopy (FTIR) confirmed the presence of –COOH and –COH bands in PLA/PCL/DMSO2 composites, indicating chemical interactions between DMSO2 and the polymer matrix. Fractography analysis revealed enhanced interface adhesion in PLA/PCL/DMSO2 composites due to the hydrogen bonding. Overall, this study demonstrates the potential of PLA/PCL/DMSO2 composites in bone tissue engineering applications, offering improved mechanical properties and enhanced cell compatibility. The findings contribute to the advancement of biomaterials for additive manufacturing in tissue engineering and regenerative medicine.

Energy-saving approach for mechanical properties enhancement of recycled PET additively manufactured by MEX

This study investigates the recycling of polyethylene terephthalate (PET) water bottles by material extrusion (MEX), an additive manufacturing (AM) technique, with a focus on characterising energy consumption and mechanical properties throughout the recycling process. The process encompasses shredding of the bottles, filament production, and the printing of tensile specimens. A full factorial design of experiment (DoE) was used to investigate the impact of various process parameters on product quality from an energy-saving perspective. The results provide important insights into energy efficiency and mechanical performance, identifying the optimal production conditions that balance environmental sustainability and material functionality. The results show that by optimizing printing parameters, energy consumption can be reduced by up to 30%, while the tensile strength of the printed samples can be increased by 20%. This research contributes to a broader understanding of the potential for AM in PET recycling, providing a pathway towards more localized and sustainable manufacturing practices.

Metal ion-crosslinked thermoconductive sugar-functionalized graphene fluoride-based cellulose papers with enhanced mechanical properties and electrical insulation

Thermally conductive papers with electrical insulation and mechanical robustness are essential for efficient thermal management in modern electronics. In this study, we introduced a metal ion-assisted interfacial crosslinking strategy to strengthen sugar-functionalized graphene fluoride (SGF) and cellulose nanofibers (CNF) by hydrogen bonding and metal ion crosslinking that leads to simultaneous enhancements in thermal conductivity and mechanical properties. The facile sugar-assisted ball-milling exfoliation method was developed to achieve the exfoliation of graphite fluoride and hydroxyl group functionalization on the surface of graphene fluoride. Thanks to the good dispersibility of the SGF sheets in water, the flexible SGF/CNF composite papers with hydrogen bonding were prepared via vacuum-assisted filtration. We introduced hydrogen bonding and metal ion crosslinking into SGF/CNF papers to obtain densely packed composite papers. Ca2+ or Al3+ ion-crosslinked SGF/ CNF papers exhibited superior thermal and mechanical properties owing to hydrogen bonding and metal ion crosslinking. SGF/CNF-Ca2+ and SGF/CNF-Al3+ papers at 50 wt% of SGF yield in-plane thermal conductivities of 72.93 and 75.02 W m–1 K–1, and tensile strengths of 121.5 and 135.7 MPa, respectively. A thermal percolation value was observed at 12.6 vol% of SGF filler content. In addition, the SGF/CNF papers exhibited electrical insulation properties. These remarkable characteristics of the metal ion-crosslinked SGF/CNF papers are attributed to the densely packed structures caused by the strong interfacial interactions from hydrogen bonding as well as metal ion-crosslinking that could promote phonon transport. High-performance metal ion-crosslinked SGF/CNF papers with these fascinating advantages offer great potential for the thermal management of flexible electronics.

Effects of recrystallization on interfacial microstructure evolution and shear strength of TiAl alloy joints

The effects of dynamic recrystallization (DRX) and post-bonding heat treatment (PBHT) on the interfacial microstructure evolution and mechanical properties enhancement of Ti-43Al-4Nb-1Mo-0.2B alloy joints, subjected to various bonding parameters, were thoroughly investigated through detailed microstructural characterization and shear performance tests. A strip-like DRX area was observed at the interface when bonding at 1100 °C, ≥30 MPa, for 60 min. Equiaxial- γ grains underwent discontinuous dynamic recrystallization during the bonding process, and tended to form flat grains parallel to the lamellae direction during recrystallization annealing (1000 °C/6 h) owing to the hindrance imposed by the lamellae on both sides. The orientations of lamellae on the both sides of bonding interface affects the lamellae's stress distribution and deformation behavior at the bonding interface, subsequently influencing the DRX behavior and the width of the DRX zone. Static recrystallization (SRX) during the recrystallization annealing treatment can eliminate bonding defects of joints bonding at lower pressures or temperatures. Optimal joints with fully lamellar interfacial microstructure and excellent shear properties can be obtained through single-α phase annealing treatment. Lamellae microstructure tailored through PBHT can significantly enhance the quality of joints, attributed to the homogeneity of the microstructure between the interface and matrix. The highest shear strength of 478 MPa, accounting for 82 % of the matrix strength, was obtained under the bonding parameters of 1100 °C/30 MPa/60 min-1290 °C/15 min. This work provides important DB process parameters for fabricating of complex structural parts of TiAl alloy.

Modification of the Structure and Mechanical Properties of Cu-30%Zn alloy with Cerium and Silicon

This study investigates how the introduction of cerium and silicon influences the structure and mechanical characteristics of Cu-30%Zn alloy. The examined properties included tensile strength, hardness, and impact resistance. The tensile strength of the developed alloys was determined using an automated JPL tensile strength tester (Model: 130812) with a capacity of 100 kilonewtons, following the ASTM D638 standard. The impact strength was assessed by the ASTM D256 standard using a pendulum impact testing machine (Model: U1820). Additionally, hardness testing was conducted using a Brinell tester. The Brinell hardness test was performed with a portable dynamic hardness tester (Model: DHT-6) by the British Standard (BS EN ISO 6505-1:2014). Specimens were prepared by incorporating cerium and silicon into the Cu-30%Zn alloy at concentrations of 0.1wt%, 0.3wt%, 0.5wt%, 1.0wt%, 3.0wt% 5.0wt% ranging from 0.1% to 5.0%, with increments of 0.2% for micro addition and 2.0% for macro addition. Microstructural analysis was performed using an L2003A reflected light metallurgical microscope. Scanning Electron Microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were also utilized to characterize the cast specimens. The findings revealed a proportional increase in tensile strength, impact strength, and hardness strength with the rise in dopant concentrations up to 3.0wt% for cerium and silicon. Also, the analysis uncovered the presence of. primary α-phase, β-phase (intermetallic phases), and fine stable phase. These phase modifications contributed to the enhancement of mechanical properties. Cu-30wt%Zn enriched with 3.0% cerium and silicon demonstrated heightened tensile strength, impact strength, and hardness, making it a recommended choice for engineering applications.

Advances and Significances of Nanoparticles as Concrete Additives: A Comprehensive Review

Nanotechnology, a significant technological advancement in the current century, has brought about revolutionary changes in numerous fields by manipulating matter at the nanoscale. This review paper examines the various applications of nanoparticles in the concrete industry, emphasizing their potential to improve mechanical qualities, thermal performance and sustainability. This study investigates multiple synthesis strategies, such as grafting, sol–gel, chemical and biological procedures, which offer concrete engineers a diverse range of options to tailor the properties of nanoparticles. The utilization of this particular material results in notable enhancements in many mechanical properties of concrete, including its compressive and flexural strength, toughness, thermal conductivity and self-sensing capabilities. These improvements ultimately contribute to the overall enhancement of the concrete’s structural integrity and energy efficiency. Adding nanoparticles to concrete has also been shown to help it develop self-healing properties. This means that structures last longer and require less maintenance. Making building materials more resistant to chemical corrosion, wear and environmental forces is also a big step in making them last longer. The growing emphasis on sustainability within the building industry has generated heightened attention toward utilizing self-healing concrete, which frequently incorporates nanoparticles. To make the building industry more environmentally friendly, using less traditional cement and recycling personal safety equipment (PPE) like vinyl and latex gloves can help protect the environment. This review also highlights the significant problems in employing nanoparticles in concrete: obtaining equal dispersion, handling-costs and addressing environmental and health concerns. However, nanotechnology is advancing construction concrete research to improve mechanical properties and durability.