Water Vapor Measurements Research Articles

Characteristics of supersaturation in midlatitude cirrus clouds and their adjacent cloud-free air

Abstract. Water vapor measurements of midlatitude cirrus clouds, obtained by the WAter vapour Lidar Experiment in Space (WALES) lidar system during the Mid-Latitude Cirrus (ML-CIRRUS) airborne campaign, which took place in the spring of 2014 over central Europe and the NE Atlantic Ocean, are combined with model temperatures from the European Centre for Medium-Range Weather Forecasts (ECMWF) and analyzed. Our main focus is to derive the distribution and temporal evolution of humidity with respect to ice within cirrus clouds and in their adjacent cloud-free air. We find that 34.1 % of in-cloud data points are supersaturated with respect to ice. Supersaturation is also detected in 6.8 % of the cloud-free data points. When the probability density of the relative humidity over ice (RHi) is calculated with respect to temperature for the in-cloud data points from the ML-CIRRUS dataset, there are two peaks: one around 225 K and close to saturation, RHi = 100 %, and a second one at colder temperatures around 218 K in subsaturation, RHi = 79 %. These two regions seem to represent two cirrus cloud categories: in situ formed and liquid origin. Regarding their vertical structure, most clouds have higher supersaturations close to the cloud top and become subsaturated near the cloud bottom. Finally, we find that the vertical structure of RHi within the clouds is also indicative of their life stage. RHi skewness tends to go from positive to negative values as the cloud ages. RHi modes are close to saturation in young clouds, supersaturated in mature clouds and subsaturated in dissipating clouds.

Measuring Water Vapor Sorption Hysteresis of Cement Paste through an Optical Fiber Sensor

Water vapor sorption is a powerful tool for the analysis of cement paste, one of the most used substances by mankind. The monitoring of cementitious materials is fundamental for the improvement of infrastructure resilience, which has a deep impact on the economy, the environment, and on society. In this work, a multimode fiber was embedded in cement paste for real-time monitoring of cement paste water vapor sorption. Changes in the reflected light intensity due to the build-up of water in the cement paste’s pores were exploited for this purpose. The sample was 7-day moist cured, and the relative humidity was controlled between 8.9% and 97.6%. Reflected light intensity was converted into a specific surface area of cement paste (133 m2/g) and thickness of water through the Brunauer-Emmett-Teller (BET) method and into a pore size distribution through the Barret-Joyner-Halenda (BJH) method. The results achieved through reflected light intensity agree with those found in the literature, validating the usage of this setup for the monitoring of water vapor sorption, breaking away from standard gravimetric measurements.

Fabrication of a Low-Cost, Fiber-Coupled, and Air-Spaced Fabry-Pérot Etalon.

Fabry-Pérot etalons (FPE) have found their way into many applications. In fields such as spectroscopy, telecommunications, and astronomy, FPEs are used for their high sensitivity as well as their exceptional filtering capability. However, air-spaced etalons with high finesse are usually built by specialized facilities. Their production requires a clean room, special glass handling, and coating machinery, meaning commercially available FPEs are sold for a high price. In this article, a new and cost-effective method to fabricate fiber-coupled FPEs with standard photonic laboratory equipment is presented. The protocol should serve as a step-by-step guide for the construction and characterization of these FPEs. We hope thiswill enable researchers to conduct fast and cost-effective prototyping of FPEs for various fields of application. The FPE, as presented here, is used for spectroscopic applications. As shown in the representative results section via proof of principle measurements of water vapor in ambient air, this FPE has a finesse of 15, which is sufficient for the photothermal detection of trace concentrations of gases.

Effect of nanoclay and nano-calcium carbonate content on the properties of polybutylene succinate/nanoparticle composites

How nanoparticle type and content affect polybutylene succinate (PBS) properties were investigated by varying nanoclay and calcium carbonate nanoparticles (nanoCaCO3) from 0 to 15 wt%. PBS/nanoparticle composites were prepared by compounding with a co-rotating twin-screw extruder and forming them with a compression molding machine. Their mechanical properties, filler dispersion, crystallinity, and permeability were evaluated using tensile testing, energy dispersive X-ray analysis, transmission electron microscopy, differential scanning calorimetry, X-ray diffraction, and water vapor and gas permeability measurements. The results showed that adding nanoclay and nanoCaCO3 enhanced the PBS stiffness. In comparison to neat PBS, the highest tensile moduli were 46% higher at 15 wt% nanoclay and 30% higher at 15 wt% nanoCaCO3. The ultimate tensile strength (UTS) for the PBS/nanoclay composites tended to decrease as the nanoclay content increased. Nanoclay dispersion was poor in composites containing more than 5 wt% nanoclay. Surface treating the nanoCaCO3 particles with a fatty acid resulted in similar UTS values and reduced the elongation at break to 15% from 225% for the neat PBS. The decrease in ductility resulted from PBS chain scission. The nanoclay and nanoCaCO3 at low content enhanced the PBS crystallization. The nanoplatelet-shaped nanoclay led to greater agglomeration than the cubic-shaped nanoCaCO3, but the nanoclay was more effective than the nanoCaCO3. The water vapor barrier properties improved with the added nanoclay, with about a 52% reduction in water vapor permeability as compared to neat PBS. The water vapor and oxygen barrier properties of nanoclay were more effective than the nanoCaCO3.

Spectrometric fluorescence and Raman lidar: absolute calibration of aerosol fluorescence spectra and fluorescence correction of humidity measurements

Abstract. RAMSES is the operational spectrometric fluorescence and Raman lidar at the Lindenberg Meteorological Observatory. It employs three spectrometers, with the UVA spectrometer (378–458 nm spectral range) being the latest to be implemented in 2018. The UVA spectrometer extends the fluorescence measurement range to shorter wavelengths than previously accessible, and its water vapor measurements can be corrected for fluorescence effects. First the new experimental setup of the RAMSES near-range receiver, which integrates the UVA spectrometer, is described. Then it is detailed how the fluorescence measurement with the UVA spectrometer is absolutely calibrated and how the fluorescence spectra are merged with those obtained with the second fluorescence spectrometer (440–750 nm spectral range). The second part of this study is dedicated to the effect of aerosol fluorescence on water vapor measurements with Raman lidars. When aerosols are present, a fluorescence-induced error always arises and therefore requires thorough analysis, even though it is particularly significant (in relative terms) only when the atmosphere is dry, the fluorescence signal strong, or the bandwidth of the Raman detection channels wide. For moisture measurements with the UVA spectrometer, a method is introduced that effectively eliminates the systematic fluorescence error. However, the increase in trueness comes at the expense of precision. The investigations further show that an accurate correction for fluorescence is impossible when the Raman lidar is not equipped with a spectrometer but with a single fluorescence receiver channel only, at least for biomass burning aerosol, because for a given fluorescence backscatter coefficient at the wavelength of the auxiliary detection channel, the induced error in humidity can vary widely due to the changing shape of the fluorescence spectrum, which depends on aerosol type and atmospheric state and possibly also on other factors.

Comb-assisted cavity ring-down spectroscopy for ultra-sensitive traceable measurements of water vapour in ultra-high purity gases

We report on the development of a comb-assisted cavity ring-down spectrometer for trace water mole fraction determinations in high purity gases. By tuning the laser light in coincidence with a H2O absorption line at 1.3946 µm, we were able to determine sub-ppm relative concentrations of water vapour in N2 with a sub-percent statistical uncertainty. The sensitivity of the spectrometer was carefully assessed, yielding a detection limit of about 2 nmol/mol.

Horizontal small-scale variability of water vapor in the atmosphere: implications for intercomparison of data from different measuring systems

Abstract. Water vapor concentration structures in the atmosphere are well approximated horizontally by Gaussian random fields at small scales (≲6 km). These Gaussian random fields have a spatial correlation in accordance with a structure function with a two-thirds slope, following the corresponding law from Kolmogorov's theory of turbulence. This is proven by showing that the horizontal structure functions measured by several satellite instruments and radiosonde measurements do indeed follow the two-thirds law. High-spatial-resolution retrievals of total column water vapor (TCWV) obtained from the Ocean and Land Color Instrument (OLCI) on board the Sentinel-3 series of satellites also qualitatively show a Gaussian random field structure. As a consequence, the atmosphere has an inherently stochastic component associated with the horizontal small-scale water vapor features, which, in turn, can make deterministic forecasting or nowcasting difficult. These results can be useful in areas where high-resolution modeling of water vapor is required, such as the estimation of the water vapor variance within a region or when searching for consistency between different water vapor measurements in neighboring locations. In terms of weather forecasting or nowcasting, the water vapor horizontal variability could be important in estimating the uncertainty of the atmospheric processes driving convection.

A novel mid-infrared hollow waveguide gas sensor for measuring water vapor isotope ratios in the atmosphere

A novel mid-infrared hollow waveguide gas sensor was developed to target H218O, H216O, H217O, and HDO absorption lines at 3662.9196, 3663.04522, 3663.32128, and 3663.84202 cm−1, respectively, based on wavelength modulation spectroscopy using a 2.73 µm distributed feedback diode laser. A hollow waveguide fiber with a 5-m length and 1-mm inner diameter was used for gas absorption. A dew point generator with liquid water with known water–isotope ratios was used to calibrate the sensor. Detection limits of 35.18 ppbv, 4.69 ppmv, 60.53 ppbv, and 3.88 ppbv were obtained for H218O, H216O, H217O, and HDO, respectively, in a 96-s integration time, which resulted in isotopic ratio measurement precision of 0.85‰, 0.57‰, and 10.48‰ for δ18O, δ17O, and δD, respectively. Field measurements of H218O, H216O, and H217O concentration were conducted on the Nanchang Hangkong University campus to evaluate sensor performance.

Measurements of Mesospheric Water Vapor From 1992 to 2021 at Three Stations From the Network for the Detection of Atmospheric Composition Change

AbstractWe present ground‐based microwave measurements of mesospheric water vapor made by the Water Vapor Millimeter‐wave Spectrometer (WVMS) instruments since the early 1990s from sites in California, Hawaii, and New Zealand. These measurements are compared with coincident measurements from the Halogen Occultation Experiment, the Aura Microwave Limb Sounder, and Sounding of the Atmosphere using Broadband Emission Radiometry; all of which combine to cover the entire time period of the ground‐based measurements. Comparisons are presented both on ∼weekly timescales in order to better identify discontinuities in the relative differences and on annual timescales in order to better study geophysical variations. The WVMS retrievals shown here are available on the Network for the Detection of Atmospheric Composition Change database. The range of WVMS trends and the differences from the satellite trends, with the latter varying over a range of ∼3%/decade, provide an estimate of how accurately it would be possible to determine multidecadal trends using ground‐based microwave instruments in a postsatellite era. This uncertainty is comparable to the trend in mesospheric water vapor that is expected to have occurred since the early 1990s.

An improved vertical correction method for the inter-comparison and inter-validation of integrated water vapour measurements

Abstract. Integrated water vapour (IWV) measurements from similar or different techniques are often inter-compared for calibration and validation purposes. Results are usually assessed in terms of bias (difference of the means), standard deviation of the differences, and linear fit slope and offset (intercept) estimates. When the instruments are located at different elevations, a correction must be applied to account for the vertical displacement between the sites. Empirical formulations are traditionally used for this correction. In this paper we show that the widely used correction model based on a standard, exponential, profile for water vapour cannot properly correct the bias, slope, and offset parameters simultaneously. Correcting the bias with this model degrades the slope and offset estimates and vice versa. This paper proposes an improved correction method that overcomes these limitations. It implements a multiple linear regression method where the slope and offset parameters are provided from a radiosonde climatology. It is able to predict monthly mean IWVs with a bias smaller than 0.1 kg m−2 and a root-mean-square error smaller than 0.5 kg m−2 for height differences up to 500 m. The method is applied to the inter-comparison of GPS IWV data in a tropical mountainous area and to the inter-validation of GPS and satellite microwave radiometer data. This paper also emphasizes the need for using a slope and offset regression method that accounts for errors in both variables and for correctly specifying these errors.

Clouds in the Vicinity of the Stratopause Observed with Lidars at Midlatitudes (40.5–41°N) in China

Based on long-term lidar (light detection and ranging) observations at Yanqing (40.5°N, 116°E) and Pingquan (41°N, 118.7°E), cloud events occurred in the vicinity of the stratopause above Beijing were reported for the first time. These events occurred with tenuous and sparse layers within the altitude range of 33–65 km, and the maximum VBSC value ranged from 1×10−10m−1sr−1 to 5.5×10−9m−1sr−1. Considering temperature and water vapor measurements from SABER/TIMED, the occurrence mechanism of these lidar-observed cloud events was examined. It was found that some cloud layers resulted from the nucleation of water vapor due to the local meteorological changes in the middle atmosphere, while other lidar-observed clouds could comprise floating clusters of cosmic dust, hydrate droplets, volcanic ash, space traffic exhaust, etc. These cloud events are rare cloud-like phenomena in the middle atmosphere observed by lidars at midlatitudes in China; they differ from NLCs and PSCs in terms of altitude distribution and seasonal variation, and the relevant microphysics processes behind their occurrence are likely meaningful to meteorology at midlatitudes.

Evaluation of encapsulation strategies for solution-processed flexible organic light-emitting diodes

Owing to the sensitivity of organic materials to ambient conditions, encapsulation of organic light-emitting diodes (OLEDs) is critical. In this work, Al2O3 film, deposited by atomic layer deposition (ALD) technique, on flexible polyethylene terephthalate (PET) substrate is used as a barrier film. Al2O3 is also deposited directly on OLED as thin-film encapsulation. Electrical Ca tests are used to measure water vapor transfer rate (WVTR) values, and an optimum WVTR value of 9 *10−4 g/m2/day using 43 nm Al2O3 film has been obtained. The related results on five different encapsulation structures for solution-processed OLEDs: (i) glass to glass encapsulation (G2G) as a reference, (ii) glass to barrier film encapsulation (G2B), (iii) glass to direct thin-film encapsulation (G2D), (iv) barrier to barrier film encapsulation (B2B), and (v) barrier to direct thin-film encapsulation (B2D), are evaluated. The operating half-lifetime values of OLEDs with G2B- and G2D-encapsulation are 54% and 82% of the half-lifetime with G2G encapsulation, respectively. The lifetime of flexible OLED devices with B2D encapsulation is also 34% more than that with B2B encapsulation. Based on the bending stress analysis, the estimated critical bending radius for B2B and B2D encapsulation of flexible OLEDs are 16.83 and 7.07 mm, respectively.

Extending water vapor measurement capability of photon-limited differential absorption lidars through simultaneous denoising and inversion

Abstract. The micropulse differential absorption lidar (MPD) was developed at Montana State University (MSU) and the National Center for Atmospheric Research (NCAR) to perform range-resolved water vapor (WV) measurements using low-power lasers and photon-counting detectors. The MPD has proven to produce accurate WV measurements up to 6 km altitude. However, the MPD's ability to produce accurate higher-altitude WV measurements is impeded by the current standard differential absorption lidar (DIAL) retrieval methods. These methods are built upon a fundamental methodology that algebraically solves for the WV using the MPD forward models and noisy observations, which exacerbates any random noise in the lidar observations. The work in this paper introduces the adapted Poisson total variation (PTV) specifically for the MPD instrument. PTV was originally developed for a ground-based high spectral resolution lidar, and this paper reports on the adaptations that were required in order to apply PTV on MPD WV observations. The adapted PTV method, coined PTV-MPD, extends the maximum altitude of the MPD from 6 to 8 km and substantially increases the accuracy of the WV retrievals starting above 2 km. PTV-MPD achieves the improvement by simultaneously denoising the MPD noisy observations and inferring the WV by separating the random noise from the non-random WV. An analysis with 130 radiosonde (RS) comparisons shows that the relative root-mean-square difference (RRMSE) of WV measurements between RS and PTV-MPD exceeds 100 % between 6 and 8 km, whereas the RRMSE between RS and the standard method exceeds 100 % near 3 km. In addition, we show that by employing PTV-MPD, the MPD is able to extend its useful range of WV estimates beyond that of the ARM Southern Great Plains Raman lidar (RRMSE exceeding 100 % between 3 and 4 km); the Raman lidar has a power-aperture product 500 times greater than that of the MPD.

Seasonal and interannual dynamics of water vapor flux at a fen in the Zoige peatlands on the Qinghai‐Tibetan Plateau: four‐year measurements

• The Riganqiao peatland was a net water source with emission (kg m −2 yr −1 ) of average 429.3 ± 51.5 from 2013 to 2017. • Impacts of interannual relative humidity (RH) and net radiation (Rn) on water vapor flux were different in each year. • Net CO 2 ecosystem exchange (NEE) was significantly negative related to water vapor flux, whatever in seasonal or interannual scale. Although carbon flux monitoring has been studied extensively in terrestrial ecosystems around the world, water vapor flux based on eddy covariance has received little attention. As a special type of terrestrial ecosystem, wetlands are transitions between land and water, material and energy, and therefore of great significance in times of global change. In wetlands, water vapor flux has a significant impact on micrometeorological environments, making it the main conduit for water vapor exchange between the wetland and the atmosphere. Using an eddy covariance tower, we measured water vapor flux (H 2 O) over four years at the Riganqiao fen in the Zoige peatlands on the eastern Qinghai‐Tibetan Plateau, China. Diurnal H 2 O peaks occurred around 14:00, and annual mean diurnal rate (mmol m −2 s −1 ) was 0.77 ± 0.02, 1.2 ± 0.02, 0.85 ± 0.02, and 0.93 ± 0.02, respectively over the 4 years. Daily H 2 O flux rate was substantially higher between June and August, with peak values of 8836 g m −2 d −1 on DOY (day of year) 161 in 2013. The Riganqiao peatland was a net water source, with an emission average of 429.3 ± 51.5 (kg m −2 yr −1 ). Hydrological and temperature were crucial to seasonal variation in water vapor fluxes in both growing and non-growing seasons, especially the latent heat flux (LE). However, interannual water vapor flux and relative humidity (RH) were significantly positively correlated to water vapor fluxes in 2016 and 2017 but not in 2013 and 2014. Net CO 2 ecosystem exchange (NEE) was significantly negatively related to water vapor flux at seasonal and interannual scales, suggesting that enhanced transpiration of alpine wetland plants will also promote CO 2 absorption over long time scales. Few previous studies have investigated these patterns based on such an interannual monitoring data with eddy covariance tower on the Qinghai‐Tibetan Plateau. Our results suggest that peatland water vapor flux affects not only the micrometeorological environment, but also NEE in wetland ecosystems over long-time scales.

Intercomparison of upper tropospheric and lower stratospheric water vapor measurements over the Asian Summer Monsoon during the StratoClim campaign

Abstract. In situ measurements in the climatically important upper troposphere–lower stratosphere (UTLS) are critical for understanding controls on cloud formation, the entry of water into the stratosphere, and hydration–dehydration of the tropical tropopause layer. Accurate in situ measurement of water vapor in the UTLS however is difficult because of low water vapor concentrations (<5 ppmv) and a challenging low temperature–pressure environment. The StratoClim campaign out of Kathmandu, Nepal, in July and August 2017, which made the first high-altitude aircraft measurements in the Asian Summer Monsoon (ASM), also provided an opportunity to intercompare three in situ hygrometers mounted on the M-55 Geophysica: ChiWIS (Chicago Water Isotope Spectrometer), FISH (Fast In situ Stratospheric Hygrometer), and FLASH (Fluorescent Lyman-α Stratospheric Hygrometer). Instrument agreement was very good, suggesting no intrinsic technique-dependent biases: ChiWIS measures by mid-infrared laser absorption spectroscopy and FISH and FLASH by Lyman-α induced fluorescence. In clear-sky UTLS conditions (H2O<10 ppmv), mean and standard deviations of differences in paired observations between ChiWIS and FLASH were only (-1.4±5.9) % and those between FISH and FLASH only (-1.5±8.0) %. Agreement between ChiWIS and FLASH for in-cloud conditions is even tighter, at (+0.7±7.6) %. Estimated realized instrumental precision in UTLS conditions was 0.05, 0.2, and 0.1 ppmv for ChiWIS, FLASH, and FISH, respectively. This level of accuracy and precision allows the confident detection of fine-scale spatial structures in UTLS water vapor required for understanding the role of convection and the ASM in the stratospheric water vapor budget.

The impact of aerosol fluorescence on long-term water vapor monitoring by Raman lidar and evaluation of a potential correction method

Abstract. The impact of aerosol fluorescence on the measurement of water vapor by UV (355 nm emission) Raman lidar in the upper troposphere and lower stratosphere (UTLS) is investigated using the long-term records of three high-performance Raman lidars contributing to the Network for the Detection of Atmospheric Composition Change (NDACC). Comparisons with co-located radiosondes and aerosol backscatter profiles indicate that laser-induced aerosol fluorescence in smoke layers injected into the stratosphere by pyrocumulus events can introduce very large and chronic wet biases above 15 km, thus impacting on the ability of these systems to accurately estimate long-term water vapor trends in the UTLS. In order to mitigate the fluorescence contamination, a correction method based on the addition of an aerosol fluorescence channel was developed and tested on the water vapor Raman lidar TMWAL located at the JPL Table Mountain Facility in California. The results of this experiment, conducted between 27 August and 4 November 2021 and involving 22 co-located lidar and radiosonde profiles, suggest that the proposed correction method is able to effectively reduce the fluorescence-induced wet bias. After correction, the average difference between the lidar and co-located radiosonde water vapor measurements was reduced to 5 %, consistent with the difference observed during periods of negligible aerosol fluorescence interference. The present results provide confidence that after a correction is applied, long-term water vapor trends can be reasonably well estimated in the upper troposphere, but they also call for further refinements or use of alternate Raman lidar approaches (e.g., 308 nm or 532 nm emission) to confidently detect long-term trends in the lower stratosphere. These findings may have important implications for NDACC's water vapor measurement strategy in the years to come.

Tunable laser spectroscopy for carbon dioxide capnography and water vapor sensing inside a breathing mask: application to pilot life support

Tunable laser spectroscopy (TLS) near 2683 nm was used to measure carbon dioxide and water vapor inside a pilot mask during jet fighter flights. Measurement frequency was 100 Hz in order to capture breathing profiles and other gas flow dynamics. Analysis of the full inhalation and exhalation breathing cycle allowed precise monitoring of breathing performance and interaction of the pilot with the life-support system. Measurements revealed dynamic phenomena pertaining to mechanical gas flow and pilot respiration that may be used to understand gas delivery stresses imposed upon the pilot and pilot physiology during flight. Typically, such measurements are made with non-dispersive infrared instrumentation for only carbon dioxide with intrinsic challenges regarding time and optical resolution. The TLS approach is a major advance because the sensor is placed directly into the mask improving its time response and enabling use of water vapor measurements that are less impacted from memory effects. This article presents the implementation of TLS and shows highly time-resolved pilot breathing data for high-performance aircraft tests.

Modeling of equilibrium water vapor adsorption isotherms on activated carbon, alumina and hopcalite

A static volumetric method measured the equilibrium adsorption isotherms of water vapor on commercial activated carbon, alumina and hopcalite adsorbents. A type II isotherm represents water vapor adsorption on alumina and hopcalite, whereas a type V isotherm characterizes activated carbon. A method based on the sensitivity analysis of parameters is used to evaluate the estimability of unknown parameters involved in the Toth-Aranovich–Donohue (type II) and Mahle (type V) adsorption isotherm equations. The estimable parameters are then identified using experimental water vapor measurements at three different temperatures, i.e., 293, 303 and 313 K and pressures up to the saturated concentration, simultaneously. The isotherm modeling methodology is implemented and solved within COMSOL Multiphysics®. The results of the isotherm model using the fitted parameters show excellent agreement with the experimental measurements. Thus, this is confirmed by the performance indices such as the Pearson correlation coefficient and the mean square error. In addition, the isosteric water vapor heat of adsorption is estimated using the Clausius-Clapeyron equation and the temperature-dependent models developed for each adsorbent.

Routine Measurement of Water Vapour Using GNSS in the Framework of the Map-Io Project

The “Marion Dufresne Atmospheric Program-Indian Ocean” (MAP-IO) project is a research program that aims to collect long-term atmospheric observations in the under-instrumented Indian and Austral Oceans. As part of this project, a Global Navigation Satellite System (GNSS) antenna was installed on the research vessel (R/V) Marion Dufresne in October 2020. GNSS raw data is intended to be used to retrieve Integrated Water Vapour (IWV) content along the Marion Dufresne route, which cruises more than 300 days per year in the tropical and austral Indian Ocean. This paper presents a first assessment of this GNSS-based IWV retrieval, based on the analysis of 9 months of GNSS raw data acquired along the route of the R/V Marion Dufresne in the Indian Ocean. A first investigation of GNSS raw data collected during the first 5 months of operation has highlighted the bad positioning of the antenna on the R/V that makes it prone to interference. Changing the location of the antenna has been shown to improve the quality of the raw data. Then, ship-borne GNSS-IWV are compared with IWV estimates deduced using more conventional techniques such as European Centre for Medium-range Weather Forecasts (ECMWF) fifth reanalysis (ERA5), ground-launched radiosondes and permanent ground GNSS stations operating close to the route of the R/V Marion Dufresne. The rms difference of 2.79 kg m−2 shows a good match with ERA5 and subsequently improved after the change in location of the GNSS antenna (2.49 kg m−2). The match with ground-based permanent GNSS stations fluctuates between 1.30 and 3.63 kg m−2, which is also shown to be improved after the change in location of the GNSS antenna. However, differences with ground-launched radiosondes still exhibit large biases (larger than 2 kg m−2). Finally, two operational daily routine analyses (at day+1 and day+3) are presented and assessed: the rms of the differences are shown to be quite low (1 kg m−2 for the day+1 analyses, 0.7 kg m−2 for the day+3 analysis), which confirms the quality of these routine analysis. These two routine analyses are intended to provide a continuous monitoring of water vapour above the Indian Ocean and deliver ship-borne IWV with a low latency for the entire scientific community.

From speed of sound to vapour pressure: an undergraduate school experiment as an example of systematic error research

This article presents an undergraduate project for measuring the speed of sound in the air as a function of air temperature. The measurement is implemented in two versions. The simplicity of the basic experiment in dry air is used for a detailed analysis of systematic errors: the measured values are corrected with an additive constant and optimized to match the expected parabolic dependence of the speed of sound on temperature. Such a time correction is correlated with the physical content, that is, by changing the phase of oscillation of the pressure difference at the reflection of the sound at the open end of the tube. The second part of the experiment involves measuring the speed of sound in saturated humid air as a function of air temperature and allows for a substantive connection of two areas of physics (waves and thermodynamics). The measured water vapour pressure, within the range of statistical errors, follows the theoretical course up to the upper limit of the measured temperature range (60 °C) surprisingly well.