Polarization Measurements Research Articles

Contribution of Induced Polarization to the Identification of Mineralization in the Agnibilékrou Department (Eastern Côte d’Ivoire)

The chargeability maps of the Siakakro, N’Guessankro, and Mossikro sites (Agnibilékrou Department, in the east of Côte d’Ivoire) are established from induced polarization (IP) measurements. These maps reveal both polarizable and weakly polarizable structures, with anomalies primarily oriented NE-SW. These orientations, influenced by geological faults, facilitate the migration of hydrothermal fluids and the potential formation of mineral deposits. The zones with high chargeability are mainly located in the center and east of the sites, suggesting the presence of sulfides and representing promising targets for mining exploration. The weakly polarizable areas are associated with sandy-clay formations and non-conductive materials, limiting their mining potential. However, their proximity to faults, especially at N’Guessankro, justifies further investigations to identify potential hidden mineralization. In summary, the zones with high chargeability, particularly at Siakakro, should be prioritized for exploratory drilling. Further exploration, particularly around geological contact zones, is necessary to assess the economic potential of these anomalies.

Effects of Thickness and Grain Size on Harmonic Generation in Thin AlN Films

High-harmonic generation from solid films is an attractive method for converting infrared laser pulses to ultraviolet and vacuum ultraviolet wavelengths and for examining the films using the generation process. In this work, AlN thin films grown on a sapphire substrate are studied. Below-band-gap third harmonics and above-band-gap fifth harmonics were generated using a Ti:sapphire oscillator running at 800 nm. A strong enhancement of the fifth-harmonic signal in the forward direction was observed from thicker 39 nm and 100 nm films compared to thinner 8 nm and 17 nm films. For the fifth harmonic generated in the backward direction, and also for the third harmonic in both the forward and backward directions, only a weak dependence of the harmonic signal on the film thickness was measured. Using both X-ray diffraction and dependence of the fifth harmonic on the laser polarization measurements, these behaviors are attributed to the crystallization and the grain size of the films, promising fifth-harmonic generation as a suitable tool to study AlN film properties.

Core excitation in 92Mo up to high-spin

Abstract An in-beam gamma-ray spectroscopy study of the even-even nucleus 92Mo
has been carried out using the 30Si + 65Cu, 18O + 80Se reactions at beam energies of
120 and 99 MeV, respectively. Angular distribution from oriented state ratio (RADO)
and linear polarization (Δasym) measurements have fixed most of the tentatively
assigned spin-parity of the high energy levels. A large-scale shell-model calculation
using the GWBXG interaction has been carried out to understand the configuration
and structure of both positive and negative parity states up to the highest observed
spin. The high-spin states primarily originate from the coupling of excited proton and
neutron-core structures in an almost stretched manner. The systematics of energy
required for forming a neutron particle-hole pair excitation, νg9/2→νd5/2, is discussed.
Lifetime of few high-spin states have been measured using DSAM. Additionally, a
qualitative argument is proposed to explain the comparatively strong E1 transition
feeding the 7310.9-keV level.

Magnetoelectric Coupling in a Mn4Na-Organic Complex under Pulsed Magnetic Fields up to 73 T.

Research on the magnetoelectric (ME) effect (or spin-electric coupling) in molecule-based magnetic materials is a relatively nascent but promising topic. Molecule-based magnetic materials have diverse magnetic functionalities that can be coupled to electrical properties. Here we investigate a realization of ME coupling that is fundamental but not heavily studied─the coupling of magnetic spin level crossings to changes in electric polarization. A mixed-valence Mn4Na complex with a total ground-state spin S = 5/2 under zero magnetic field and S = 17/2 under high magnetic field undergoes a cascade of ground-state level crossings of the Sz states with increasing magnetic field. Magnetization and electrical polarization measurements under pulsed magnetic fields up to 73 T show that each spin level crossing is accompanied by a significant change in electric polarization that is an even function of the applied magnetic field. A molecular Hamiltonian describing antiferromagnetic exchange in a distorted tetrahedron of three MnIII and one MnII ions matches the data well. We conclude that the ME coupling is caused by magnetostriction within the polar molecule as it distorts to lower its magnetic exchange energy.

Donor–Acceptor Type Solvatochromic Flavonoid Materials Fluorphores for Polarity Sensing and Real‐Time Temperature Monitoring

AbstractElectron donor–acceptor (D–A) molecules are emerging tools for designing sensitive luminogens, attracting significant research attention. However, due to poor quantum yields under certain conditions, current D–A fluorophores often suffer from fluorescence quenching in practical applications. Developing new D–A dyes and functional composites is crucial for expanding their applications. Here, a novel donor–acceptor type flavonoid dye molecule, namely “AFL”, exhibiting both polarity‐dependent fluorescence emission wavelength shift and viscosity‐dependent intensity change, for polarity measurement and temperature sensing is designed and synthesized. Because the intramolecular charge transfer (ICT) can be enhanced by a decrease of excited state energy caused in high‐polarity organic solvents, AFL undergoes fluorescence emission wavelength shift that shows fluorescence color response to solvents of different polarities and hence differentiates between them. Moreover, the actual temperature can be monitored by the as‐designed AFL@tetradecanoic acid (AFL@TA) sensor. By combining with TA, viscosity sensitively changes upon the temperature change of insoluble composites, thus realizing the fluorescence intensity response to temperature. Remarkable recyclable performance and satisfactory mechanical properties are integrated. This study provides a promising approach to developing a new D–A fluorescent probe and furnishes perspectives on the potential of such D–A type flavonoid material in stimuli‐responsive systems with a focus on visualization sensing technology.

Enhanced corrosion protection of copper in saline environments using bio-nanocomposite coatings based on chitosan and chitosan Schiff base

An in-depth study focuses on developing new environmentally friendly bio-nanocomposites, by incorporating SrTiO3 (STO) ceramic nanoparticles into matrices of chitosan and its derivatives, aiming to use them as protective coatings against corrosion. The various stages of this study include the cross-linking of chitosan, the synthesis of Schiff base chitosan, the cross-linking of Schiff base chitosan, and the preparation of nanocomposite coatings. The coatings' structure and composition were analyzed using different methods, including Fourier Transform Infrared Spectroscopy - Attenuated Total Reflectance (FTIR-ATR), X-ray Diffraction (XRD), Transmission Electron Microscopy coupled with Energy Dispersive X-ray Spectroscopy (TEM-EDX), and Scanning Electron Microscopy (SEM). In addition, Electrochemical Impedance Spectroscopy (EIS) and Potentiodynamic Polarization (PDP) measurements were carried out to assess the inhibitory efficacy of chitosan crosslinked with epichlorohydrin (Cs-Ep), epichlorohydrin-crosslinked chitosan-salicylaldehyde Schiff base (CS-S-Ep) and CS-Ep-STO and CS-S-Ep-STO nanocomposite coatings, as well as the long-term protection durability of CS-S-Ep-STO. These techniques revealed a significant reduction in corrosion current density after chemical modification of chitosan and incorporation of SrTiO3 (STO) nanoparticles into CS-Ep and CS-S-Ep matrices, confirming a notable improvement in the inhibitory efficiency of these coatings against copper corrosion in a saline environment. Computational modeling methods like Density Functional Theory (DFT), Molecular Dynamics (MD), and Monte Carlo (MC) simulations reinforced these results by demonstrating efficient adsorption of CS-S-Ep-STO nanocomposites on metal surfaces through the interaction with heteroatoms present in the functional groups (-C=N-, -C-O-, -OH) and STO nanoparticles. The present study's findings provide key information for developing innovative protective coatings, highlighting the potential of chitosan-based nanocomposites and derivatives, particularly with SrTiO3 incorporation, in mitigating metal surface corrosion in aggressive environments.

Wear and Corrosion Resistance of ZrN Coatings Deposited on Ti6Al4V Alloy for Biomedical Applications

Zirconium nitrides films were synthesized on Ti6Al4V substrates at a bias voltage of −50 V, −80 V, −110 V and −150 V by the direct current (DC) reactive magnetron sputtering technique. The as-deposited coatings were characterized by X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and atomic force microscopy (AFM). The wear and corrosion resistance of the obtained ZrN coatings were evaluated to determine the possibility for their implementation in modern biomedical applications. It was found that the intensity of the diffraction peak of the Zr-N phase corresponding to the (1 1 1) crystallographic plane rose as the bias voltage increased, while the ZrN coatings’ thickness reduced from 1.21 µm to 250 nm. The ZrN films’ surface roughness rose up to 75 nm at −150 V. Wear tests showed an increase in the wear rate and wear intensity as the bias voltage increased. Corrosion studies of the ZrN coatings were carried out by three electrochemical methods: open circuit potential (OCP), cyclic voltammetry (polarization measurements) and electrochemical impedance spectroscopy (EIS). All electrochemical measurements confirmed that the highest protection to corrosion is the ZrN coating, which was deposited on the Ti6Al4V substrate at a bias voltage of −150 V.

High Memory Window, Dual‐Gate Amorphous InGaZnO Thin‐Film Transistor with Ferroelectric Gate Insulator

Ferroelectric (FE) hafnium zirconium oxide (HZO) thin‐film transistors (TFTs) are of increasing interest for next‐generation memory and computing applications. However, these devices face challenges in achieving a substantial memory window (MW). This report presents amorphous InGaZnO (a‐IGZO) ferroelectric–dielectric (FD), dual‐gate thin‐film transistors (DG‐TFTs) with FE‐HZO as a bottom gate insulator (GI) and SiO2 as a top GI. The ferroelectricity in HZO is confirmed through the grazing incidence X‐ray diffraction (GI‐XRD), capacitance, and polarization measurements. The FD‐DG TFT can increase the MW by tuning the threshold voltage (VTH) due to electrostatic coupling between the top gate (TG) and bottom gate (BG). The increase of MW at the TG driving is related to the coupling factor which is equal to the ratio of the equivalent capacitance of top to bottom gated transistors. During the bottom sweep, the FD‐DG‐TFT demonstrates an anticlockwise hysteresis with a MW of 4.98 V, a high ION/IOFF ratio of ≈106, and a steep subthreshold swing (SS) of 90 mV dec−1. On the contrary, MW of 12 V and SS of 140 mV dec−1 are observed for the top sweep operation. A thinner ferroelectric GI at BG TFT induces sufficient electrostatic coupling to cause a large VTH shift at TG driving, resulting in a boosted MW.

Origin of charges in bulk Si:HfO2 FeFET probed by nanosecond polarization measurements

FeFET technology offers the potential for fast, energy-efficient, low-cost, and high-capacity non-volatile memory and neuromorphic devices. However, charge trapping significantly affects device operation, leading to issues like read-after-write delay and limited endurance. Therefore, a detailed understanding of charge trapping, charge origin and its role in polarization switching is crucial. In this study, we uncover the spectral energy origin of polarization charges in Si:HfO2 N-FeFET by probing electron (conduction band) and hole (valence band) currents separately during polarization-voltage (P–V) measurements. We utilize a fast (∼20 ns) and modified positive-up-negative-down (PUND) technique, where bulk, source, and drain currents of the FeFET are measured separately. The nanosecond timescale of the measurement results in measurable currents in FeFETs having dimensions of a few μm. This charge separation shows that program (PRG, VGS > 0) charge originates from the conduction band, whereas erase (ERS, VGS < 0) originates from the valence band of the Si. Moreover, the polarization curve (P–V) of a cycled device (following 5000 PRG/ERS pulses) shows measurable hysteresis even though the transfer curve of the same device shows that the memory window in the threshold voltage vanishes. Therefore, the FeFET polarization state can be read without delay after write operation by the fast PUND measurement, both for pristine and cycled FeFETs.

On the Reliability of Constraining Surface Conductivity using Induced Polarization Measurements in Sedimentary Rocks

Summary Recent advances in understanding the induced polarization (IP) method have led to improvements in interpreting hydraulic properties from electrical measurements. Distinguishing the effect of surface conduction from conduction through the electrolyte filling the interconnected pore spaces has been an ongoing challenge in interpreting field-scale electrical resistivity datasets. Previously proposed mechanistic models have suggested that this limitation can be overcome by utilizing the coefficient that describes the ratio between IP measurements and surface conductivity. In this study, we examine this proportionality coefficient ($\mathcal{l}$) through the relationship between IP parameters (imaginary conductivity and normalized chargeability) and surface conductivity for a sample group of 98 sedimentary rocks, composed of sandstones, carbonates, and mudstones. A strong linear relationship is observed between the IP parameters and surface conductivity. However, values of $\mathcal{l}$ vary significantly across each sample group such that low-salinity estimates of formation factor (F) using the single universal estimate of $\mathcal{l}$ are poor. Estimates of F for a single rock type (sandstone, carbonate, or mudstone) are improved using $\mathcal{l}$ values unique to that rock type, although F estimates for mudstones show high sensitivity to changes in $\mathcal{l}$. Using $\mathcal{l}$ coefficients calibrated on a sample group with similar lithological properties to the investigated group moderately improves the estimation of F. Consistent with theory, no relationship is observed between the proportionality coefficient and the measured petrophysical parameters of the porous medium. Our results suggest that, although IP measurements provide a valuable field-scale proxy for surface conductivity, improving petrophysical predictions (i.e. in this case, estimating F) remains a challenge.

Evaluation of thiocarbohydrazide derivative as corrosion inhibitor for C1018 carbon steel in 3.5% NaCl + 500ppm HAc solution: Electrochemical, SEM, FTIR and computational studies

N'-((E)-3-phenylallylidene)hydrazinethiocarbohydrazide (PHCT) was synthesized, purified, characterized and assessed for its inhibitive property against the sweet corrosion of C1018 carbon steel in CO2-saturated 3.5 % NaCl + 500 ppm HAc solution at 25 and 60 °C. At 50 ppm and 25 °C, electrochemical impedance spectroscopy (EIS) confirmed that the presence of PHCT in the electric double layer fortified the hydrophobicity of the region and mitigated rate of charge transfer. Potentiodynamic polarization (PP) measurements at 25 °C showed that PHCT is a mixed-type inhibitor, which could reduce corrosion rate from 24.32 mpy in blank to 0.67 mpy at 50 ppm dosage and deliver 97.24 % inhibition efficiency. PHCT adsorbs, principally, using its NH2, C = S and C = C functional groups, based on FTIR characterization. Computational modeling using the FMO and MEP analyses confirmed that PHCT exhibits higher electron donating than electron accepting power and interacts with the metal surface through nitrogen and sulfur atoms. Scanning electron microscopy (SEM) confirmed the ability of PHCT to protect the steel surface from localized pitting corrosion. Although increasing the temperature up to 60 °C diminished the efficiency of PHCT, the inhibitor was able to provide up to 92 % efficiency.

Investigation of phase transformation and mechanical properties of silicon addition on AlCrFeMnNi high entropy alloys

Abstract This paper examines the impact of silicon in the AlCrFeMnNi high-entropy alloy system, focusing on both its microstructural and mechanical properties. Alloys with varying silicon content (x = 0, 0.3, 0.6, 0.9 atomic ratio) were synthesized using vacuum arc melting. The phase formation of these high-entropy alloys was analyzed using X-ray diffraction to comprehend the alloying process behaviour. The findings revealed that the solidification of the AlCrFeMnNi alloy occurred in dendritically, with dendrite cores containing Cr, Fe, and Ni, while interdendritic regions were enriched in Al and Ni after adding Silicon. Increasing the silicon content from 0 to 0.9 led to significant improvements in microhardness and wear resistance. This improvement is attributed to the reinforcement of grain boundaries provided by silicon. The formation of an Al and Ni rich B2 phase is crucial in resisting dislocation motion and preventing further deformation. Additionally, the addition of silicon led to improved corrosion resistance, as demonstrated by potentiodynamic polarization measurements. However, a trade-off was observed between compressive strength and ductility: compressive strength increased with higher silicon concentrations, but at the expense of ductility.

Communication—Prediction of Area Specific Resistance of Solid Oxide Cell Stacks from Electrochemical Impedance Spectra

A support vector regression model was trained to predict the area specific resistance of solid oxide cell stacks from electrochemical impedance spectroscopy measurements. In particular, the minimum necessary frequency range required for accurate predictions was investigated. Therefore, 711 pairs of DC polarization and electrochemical impedance spectroscopy measurements, conducted at the same stage of stack degradation and under similar measurement conditions, were evaluated. Prediction accuracies of less than 8% mean absolute percentage error and coefficients of determination greater than 93% were achieved. The 101–102 Hz range is sufficient for accurate predictions, allowing an efficient and non-destructive etimation of DC polarization measurements.

Comparison between the Emission Torus and the Measured Toroidal Magnetic Field for the Crab and Vela Nebulae

Polarization measurements provide insight into the magnetic field, a critical aspect of the dynamics and emission properties around the compact object. In this paper, we present the polarized magnetic field of the Crab outer torus and the Vela arc utilizing Imaging X-ray Polarimetry Explorer observation data. The polarization angle (PA) measured for the Crab outer torus exhibits two monotonic evolutions along the azimuth angle, which are consistent with the normal line of the elliptical ring. There is a slight increase in PA along the azimuth angle for both the inner arc and the outer arc of the Vela Nebula. The polarized magnetic vector along the outer torus of the Crab Nebula shows the polarized magnetic field aligns with the Crab outer torus structure. The PA variation along the Crab outer torus suggests a bulk flow speed of 0.8c. Meanwhile, the Vela Nebula polarized magnetic field does not exactly align with the Vela arc structure. We noted that the Crab Nebula possesses a polarized toroidal magnetic field, whereas the Vela Nebula exhibits an incomplete toroidal magnetic field.

Effect of texture, grain boundary constitution, and molybdenum partitioning on corrosion and hydrogen permeation behavior of pulse electrodeposited Ni-Mo coatings

Microstructural evolution, electrochemical corrosion and hydrogen permeation in pulse electrodeposited Ni-Mo coatings (2, 4, 8, and 11wt% Mo) were investigated. Electrochemical impedance spectroscopy and potentiodynamic polarization measurements revealed improved corrosion resistance at an optimum Mo content. The corrosion current density icorr and polarization resistance Rp values obtained were 13.8 μA/cm2 and 1745 Ωcm2 respectively for pure Ni coating while the icorr and Rp values obtained were 1.7 μA/cm2 and 5406 Ωcm2 respectively for Ni-4wt% Mo coating. Further, increase in the Mo content beyond 4 wt% increased the corrosion rate. Nevertheless, corrosion resistance of Ni-Mo coatings was found to be higher than the pure Ni coating. Ni-Mo coatings contained relatively Mo-enriched clusters in a solid solution matrix. The highest corrosion resistance of Ni-4wt% Mo coating was due to lower energy (001) and (111) textures, lower energy grain boundary constitution, and low coating strain. In Ni-4wt% Mo coating, Mo-enriched Ni-Mo nanoclusters inhibited hydrogen passage by providing a torturous path. In contrast, a high fraction of high-angle grain boundaries (compared to pure Ni coating) facilitated hydrogen permeation leading to a similar extent of hydrogen permeation through pure Ni and Ni-4wt% Mo coatings.

Simultaneous X-Ray and Optical Polarization Observations of the Blazar Mrk 421

We present near-simultaneous X-ray and optical polarization measurements in the high synchrotron peaked (HSP) blazar Mrk 421. The X-ray polarimetric observations were carried out using Imaging X-ray Polarimetry Explorer (IXPE) on 2023 December 6. During IXPE observations, we also carried out optical polarimetric observations using 104 cm Sampurnanand telescope at Nainital and multiband optical imaging observations using 2 m Himalayan Chandra Telescope at Hanle. From model-independent analysis of IXPE data, we detected X-ray polarization with degree of polarization (ΠX) of 8.5% ± 0.5% and an electric vector position angle (ΨX) of 10.°6 ± 1.°7 in the 2−8 keV band. From optical polarimetry on 2023 December 6, in B, V, and R bands, we found values of Π B = 4.27% ± 0.32%, Π V = 3.57% ± 0.31%, and Π R = 3.13% ± 0.25%. The value of Π B is greater than that observed at longer optical wavelengths, with the degree of polarization suggesting an energy-dependent trend, gradually decreasing from higher to lower energies. This is consistent with that seen in other HSP blazars and favors a stratified emission region encompassing a shock front. The emission happening in the vicinity of the shock front will be more polarized due to the ordered magnetic field resulting from shock compression. The X-ray emission, involving high-energy electrons, originates closer to the shock front than the optical emission. The difference in the spatial extension could plausibly account for the observed variation in polarization between X-ray and optical wavelengths. This hypothesis is further supported by the broadband spectral energy distribution modeling of the X-ray and optical data.

Cross-community affinity: A polarization measure for multi-community networks

This article introduces a heterophily-based metric for assessing polarization in social networks when different opposing ideological communities coexist. The proposed metric measures polarization at the node level and is based on a node’s affinity for other communities. Node-level values can then be aggregated at the community, network, or any intermediate level, resulting in a more comprehensive map of polarization. We looked at our metric on the Polblogs network, the White Helmets Twitter interaction network with two communities, and the VoterFraud2020 domain network with five communities. Additionally, we evaluated our metric on different sets of synthetic graphs to confirm that it yields low polarization scores, as expected. We employed three ways to build synthetic networks: synthetic labeling, dK-series, and network models, in order to assess how the proposed measure behaves to various topologies and network features. Then, we compared our metric to two commonly used polarization metrics, Guerra’s boundary polarization and the random walk controversy score. We also examined how our suggested metric correlates with two network metrics: assortativity and modularity.

Synthesis of polyaniline tannate-modified carbon nanotubes by oxidative copolymerization as highly efficient corrosion inhibitors for mild steel in HCl solution

Corrosion is a prevalent issue in industrial production, directly impacting the production process and causing severe damages. To mitigate this problem, corrosion inhibitors are highly desired. Herein, a novel type of nano corrosion inhibitor, referred to as PTCNT, was synthesized through an oxidative copolymerization method utilizing aniline, ammonium persulfate (APS), and tannic acid (TA)-modified multiwalled carbon nanotubes (MWCNTs). The results demonstrated that the PTCNT effectively inhibited the corrosion of mild steel in 1 M HCl solution, achieving the corrosion inhibition efficiency of 90.6 % at the concentration of 75 mg/L. Characterization results implied that the PTCNT adsorbed onto the surface of the mild steel, forming a protective shielding layer. Potentiodynamic polarization measurements proved that the PTCNT functioned as the hybrid corrosion inhibitor. Furthermore, the adsorption of PTCNT on the mild steel surface was investigated using adsorption isotherm and adsorption kinetic modeling. Quantum chemical calculations were used to elucidate the adsorption mechanism of PTCNT. These findings raise new avenues for the development of highly efficient corrosion inhibitors for the mild steel in HCl solutions.

Regularized Regression Can Reintroduce Backdoor Confounding: The Case of Mass Polarization

Regularization can improve statistical estimates made with highly correlated data. However, any regularization procedure embeds assumptions about the data generating process that can have counterintuitive consequences when those assumptions are untenable. We show that rather than simply shrinking estimates, regularization can reopen backdoor causal paths, inflating the estimates of some effects, and in the wrong circumstances, even reversing their direction. Recently, Cavari and Freedman (2023), argued that declining cooperation rates in surveys have inflated measures of mass polarization. We show that this finding is driven by large penalty terms in their regularized regressions, which leads to the estimates being confounded with time. Alternative methods do not show a clear positive or negative effect of declining cooperation on estimated levels of mass polarization.

Synthesis and Electrochemical Properties of Oleylamine as a Sour Saline Corrosion Inhibitor Under Laminar Flow at 40 °C.

In this study, the synthesis of a long-chain aliphatic amino compound and its sour corrosion inhibition properties were reported. Oleylamine was obtained through the reaction of 4-(Aminomethyl) pyridine with 1-chloro-octadecane. The identification and characterization of reaction products were carried out through Fourier transform infrared spectroscopy (FTIR) and gas chromatography/mass spectroscopy (GC-MS). Oleylamine was tested as a sour corrosion inhibitor for steels. Different concentrations of oleylamine (0, 5, 10, 25, and 100 ppm) in a sour saline electrolyte were analyzed. The dynamic anticorrosive behavior of oleylamine on carbon mild steel (AISI 1018) surfaces was evaluated using a laminar flow of 100 rpm and tested with potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) measurements. After electrochemical testing, the surface of the steel specimens that were used was characterized with Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The electrochemical results of the anticorrosive efficiency of oleylamine for steel showed an exponential behavior as a function of inhibitor concentration. At a concentration of 20 ppm of the inhibitor, the anticorrosive efficiency did not show any significant changes. However, at 100 ppm of the inhibitor, an efficiency of over 95% was achieved. After the electrochemical tests, the surface of the steel samples with the inhibitor revealed the formation of an inhibitor layer that prevented the corrosion of the steel.