Measurements of electron concentrations by the method of cyclotron resonance, and of non-thermal iron line intensities in emission, as a function of composition and dilution in the reaction zone of low-pressure acetylene-oxygen-argon mixtures, reveal a marked similarity in behaviour of these two quantities. On this and other circumstantial evidence, the possible causes of the anomalous line reversals can be narrowed down to two, neither of which can, however, be considered objection-free until further experimental evidence reveals in even more detail the nature of certain of the reaction steps proposed. One of these schemes involves postulating the bimolecular production of an excited species Y∗ by the mechanism also responsible for electron production. Species Y∗ must be sufficiently energetic, and be present in sufficient quantity, to produce excited metal atom M∗ by energy transfer with M. The other—a more specific scheme—involves reaction between M+ and e− to produce M∗ the emitted radiation being discrete. Although there is experimental evidence for all the important steps involved in this second scheme, this scheme, too, can fail if the cross sections for capture of e− by M+ prove to be too small. Schemes so far postulated involving termolecular reactions are eliminated as not satisfying the experimental observations presented.
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