In poor sanitary conditions, people need to wear masks to protect the health of their respiratory system. Meanwhile, it is necessary for patients with respiratory diseases to have real-time measurement on respiratory rate when wearing masks. Thermoelectric generation provides a new approach and method for powering and sensing small low-power devices, and has good application prospects in smart masks. In view of this, a novel sensible smart mask using micro thermal-electric energy conversion elements (TECE) is proposed in this paper, which can detect and display the respiratory rate in real time. First, the temperature conversion characteristic of micro TECE represented by the thermoelectric generator module is analyzed. Second, the respiratory characteristics of the human body are studied, and the respiratory rate sensing effect based on micro TECEs is analyzed and verified. Then, a sensible smart mask, which can show respiratory rate in real time, is developed by integrating MCU and OLED module. Finally, human respiratory rate experiments are conducted, the experimental results verified the effectiveness and accuracy of the proposed sensible smart mask.