Maximum Heat Release Rate Research Articles

Flame Retardation of Polyamide 6 by Electro-Sprayed Phosphorus–Copper Complex Supported by Layered Silicate

Abstract The primary objective of this study was to demonstrate the effect of a phosphorus–copper complex on the flammability of polyamide 6 (PA6) materials, including organoclay-reinforced nanocomposites. The secondary objective was to compare the effectiveness of the deposition methods of the three-layer copper complex. Our previous work successfully revealed the effectiveness of reducing the flammability of polyamide composites by depositing phosphorus and copper compounds using a Layer-by-Layer technique. In the current work, we turned our attention to modifying the PA6 surface by electro-spray (ES) using the same flame retardants as before, and we investigated the effectiveness of the resulting surface protection against high temperatures during combustion. Surface roughness analysis revealed that the use of the ES method favors the formation of surface unevenness. The UL-94 test results showed that composite materials having 5-15 triple layers were among the best flammability classes compared to the others. Both types of materials tested also showed a tendency to reduce the heat release rate (HRR) by increasing the degree of surface coverage when using the electro-spray technique. Remarkably, deposition of 15 triple layers on the surface of the nanocomposite reduced the maximum HRR point by 20%. Graphical abstract

Experimental analysis of glass failure criteria under different thermal conditions

The initiation of the first crack mainly determines the criteria for glass failure. However, the extended consequences of cracking, with the formation of multiple cracks merging, result in fallout conditions under varying thermal loads that become more critical. Point-supported glass arrangements are globally used in high-rise and energy-efficient buildings for architectural ingenuity aimed at a low budget. However, the formation of cracks due to thermal load resulting in glass breakage could infuriate the overall fire dynamics of the enclosed area. Therefore, experimental study and prediction of glass failure become very crucial. The present experimental study focuses on finding the most critical parameter that may quantify the cause of glass failure and further breakage in fallout conditions under varying thermal loads. 45 experiments were carried out on float glass of 300 × 300 mm2 with 4 mm, 6 mm, 8 mm, 10 mm, and 12 mm with continuous fuel supply arrangements. Critical parameters analysed were the time of crack initiation, glass temperature at the time of cracking, maximum temperature difference at glass failure, and thermal strain caused by the temperature difference on the glass surface. The range of minimum and maximum temperature difference recorded on the glass surface for the present study was between 30–35°C and 55–60°C at the breakage time for all the experiments. The Maximum temperature difference measured was 56.99°C on the 12 mm glass surface, and the corresponding maximum thermal strain found was 482 × 10−6 mm/mm. The maximum heat release rate was found to be approximately 200 kW. Maximum heat flux was found in the range of 10.33 kW/m2 to 21.14 kW/m2. A correlation was also developed using the least square method for all the thicknesses, which is well correlated with the glass thickness per unit length.

Comparative Study on the Characteristics of Compartment Fire and Travelling Fire for Large-Space Fire Analysis

Fire models typically include standard and parametric types. These models assume that the gases produced by the fire within the compartment are fully mixed, resulting in a uniform temperature distribution. However, in real fires, significant non-uniformity is observed, and some large-compartment fires exhibit localized combustion and move across the floor of the burning room over time. This scenario is known as a “travelling fire”. In this study, the characteristics of the traditional compartment and travelling fires were compared. Combustion experiments were conducted in a medium-sized compartment with a single opening using heptane pools. Throughout these experiments, the heat-release rate and temperature changes were measured to analyze the simultaneous and delayed ignition of the flames. The experimental results showed an approximately 19% difference in the maximum heat-release rate and 50% difference in the time required to reach it. Consequently, the temperature changes within the internal compartment were also delayed and reduced.

Hierarchical Nano/Micro-Array Structured CuMgAl-LDH/rGO Hybrids for Remarkably Improved Flame Retardancy and Smoke Suppression Performance of Flexible Polyvinyl Chloride.

In this study, we explored the rational integration of layered double hydroxides (LDHs) with reduced graphene oxide (rGO) to create a hierarchical nano/microarray structured CuMgAl-LDH/rGO hybrid aimed at enhancing the flame retardancy and smoke suppression properties of polymer nanocomposites. The results indicated that the limiting oxygen index (LOI) value of the G-CuMgAl/polyvinyl chloride (PVC) composite reached 35.8%, reflecting a 6.4% increase compared to pristine PVC (29.4%), and achieved a UL-94 V-0 rating. Furthermore, in comparison to pristine PVC, the peak heat release rate (PHRR) of the G-CuMgAl/PVC composite was significantly reduced by 40.2%; the total heat release rate (THR) decreased by 24.3%; the maximum average heat release rate (MARHE) diminished by 41.6%; the peak smoke production (PSPR) decreased by 37.8%; the total smoke production (TSP) was reduced by 31.3%; and the average effective heat of combustion (av-EHC) decreased by 15.2%. The enhanced flame retardancy and reduced smoke production can primarily be attributed to the multiple synergistic interactions among the highly dispersed constituents and the nano/microstructures, which effectively impede the transfer of heat, mass, and O2 from various directions while preventing further combustion of the underlying matrix by creating a tortuous path in the condensed phase. Additionally, this study provides a novel perspective on the design and synthesis of structured LDHs/rGO hybrids, with the potential to enhance flame retardancy and smoke suppression properties across a broad spectrum of polymer materials.

Defining a maximum heat release rate probability distribution function for design fires in sprinkler‐protected residential buildings

AbstractIn fire safety engineering analysis of sprinkler‐protected residential buildings, the maximum heat release rate is a key parameter requiring consideration. Several documents provide advice for estimating the heat release rate of a sprinkler‐controlled fire, with a prevailing suggestion that it is fixed upon activation of the first sprinkler. When carrying out deterministic analysis, this requires the engineer to assume fixed fire parameters and consider that sprinklers limit fire growth. To explore these assumptions, the study uses three deterministic models to estimate a sprinkler‐controlled maximum heat release rate for a representative apartment layout. The models include Alpert's correlation, a B‐RISK zone model and a computational fluid dynamics model in the Fire Dynamics Simulator. These deterministic models are compared to a probabilistic model in B‐RISK, where Monte Carlo simulations are used to generate a range of maximum heat release rates from distribution functions for fire and sprinkler properties. An output distribution function is generated with a mean of 296.6 kW and a standard deviation of 503.8 kW, with a lognormal distribution (μ = 5.014, σ = 1.165) estimated as a best‐fit. The deterministic models are estimated to sit in the 92–98 percentile range of this function, indicating that common deterministic assumptions are reasonably conservative. The article concludes with suggesting that, for deterministic analysis, a percentile between the 80th and 99th (340–2640 kW) could be qualitatively selected based on the design objectives, building situation and relative consequence of a fire. Further research is needed to establish guidelines for selecting appropriate percentiles across various building scenarios.

Autoignition of premixed hydrogen/air mixtures with uniformly dispersed carbon particles

The autoignition of a stoichiometric hydrogen/air mixture laden with uniformly distributed coal char particles is simulated with the Eulerian-Lagrangian approach under isochoric conditions. A zero-dimensional model is adopted to assess the effects of gas temperature, pressure, particle diameter, and concentration on ignition dynamics. Increasing the initial temperature reduces the ignition time and maximum heat release rate of the homogeneous reactions, while the parameters for particle reactions stabilize after reaching a critical temperature. Initial pressure exhibits a non-monotonic influence on gas phase ignition, with higher pressures promoting particle autoignition. An increase in particle diameter decreases the ignition time for the homogeneous reaction, approaching that of particle-free conditions. Meanwhile, particle ignition time first decreases and then linearly increases. Increasing particle concentration reduces the interphase disparities of ignition times, while the two-phase ignition times rapidly rise after exceeding the critical concentration. Moreover, pre-ignition temperature equilibrium (PTE) significantly impacts the ignition parameters and processes. PTE results in a minimal ignition time disparity between the gas and particles, with coal char particles markedly influencing hydrogen ignition. Failure to reach PTE leads to significant two-phase ignition time differences, with negligible impact from the solid phase on gas phase ignition. The particle effect ratio, δ, is introduced to evaluate these effects. Notably, the evolution variations in ignition time and heat release rate are determined by the existence of the PTE under corresponding initial conditions. The findings of this study are crucial for developing strategies to mitigate explosion hazards and enhance the performance of detonation propulsion systems using hybrid fuels.

Study on the Thermal Safety of 3,7‐Dinitro‐1,3,5,7‐Tetraazabicyclo[3.3.1]nonane Synthesized by Nitrolysis of Hexamine

AbstractThe thermal flow curves of the nitrolysis for the synthesis of 3,7‐dinitro‐1,3,5,7‐tetraazabicyclo[3.3.1]nonane (DPT) from hexamine in the presence of different amounts of acetic anhydride were obtained using reaction calorimetry. The maximum heat release rates during the feeding process, the corresponding maximum adiabatic temperature rises, and the Maximum Temperature of the Synthesis Reaction (MTSR) were determined, respectively. The thermal stability of the reaction product DPT and the reaction mixture was analyzed, and data on their thermal decomposition characteristics were obtained. The thermal decomposition kinetic model was utilized to simulate the stability under adiabatic conditions. TD24 (The temperature corresponding to the time required to reach the maximum reaction rate under adiabatic conditions for 24 hours) of the reaction mixture was calculated as 69.65°C. According to the thermal hazard parameters of the reaction, the process's hazard level under various acetic anhydride addition conditions was determined to be level 5 using the cooling failure scenario method.

Comparison of different geometry trees in fire simulation

AbstractWildfire simulations can help to better understand the dynamics and effects of forest fires. The basis of wildfire simulation is the tree-burning simulation. In this paper, the fire simulation of 7 different geometry Hungarian trees in the case of arson is presented. It was observed that the trees were burned down fast. The maximum mass loss rate and maximum heat release rate were larger as the tree was larger. The largest intensity fire could be observed in the case of the smallest tree. The maximum temperature was higher in the case of a large crown diameter. The maximum aerosol reached high pollutant concentrations. In the case of large crown height, the maximum CO2 concentration was higher. The results presented in this paper can be the basis of the following forest fire simulations.

Urchin-like NiCo-based bimetallic hydroxide decorated with DOPO as highly hydrophobic flame retardant for remarkably reducing fire hazard of poly (L-lactic acid)

Designing high-performance flame retardants for poly (L-lactic acid) (PLA) materials and exploring a simple and scalable strategy have been hot topics in research. In this work, a novel and highly efficient flame retardant, that is, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) decorated urchin-like NiCo-based bimetallic hydroxide (NiCo-BH@DOPO), was synthesized and incorporated into PLA to prepare PLA and NiCo-BH@DOPO (PLA/NiCo-BH@DOPO) composite. Benefiting from the DOPO organic modification, NiCo-BH@DOPO had superb hydrophobicity and presented excellent dispersion in the PLA matrix. When 20 wt% NiCo-BH@DOPO was added, the LOI value of PLA/NiCo-BH@DOPO composites reached 33.2 %, passed the V-0 level of UL-94 grade, and its maximum peak heat release rate (PHRR) and total heat release (THR) were reduced by 13.2 % and 17.3 %, respectively, compared with PLA/NiCo-BH composites. Furthermore, the residue of PLA/NiCo-BH@DOPO at 800 °C reached 19.8 wt% and the T10% (temperature at 10 % weight loss) increased by 33 °C. More importantly, the residual PLA/NiCo-BH@DOPO char exhibits a significantly reduced presence of large cracks compared to PLA/NiCo-BH, indicating a more compact formation of residual char. NiCo-BH@DOPO endowed PLA with outstanding flame retardancy, thermal stability and carbonization properties, which were owing to the multi-coordinating effect transition metal (NiCo-BH) catalyzed the char formation to form a char layer barrier and DOPO free radicals captured to inhibit the combustion reaction chain. This investigation provided a facile strategy for the novel multi-function NiCo-based bimetallic hydroxide flame retardant, expanding NiCo-BH potential applications in PLA.

Construction and application of B/P/N durable flame retardant crosslinking system on cotton fabric

The inherent flammability of cotton fabrics necessitates the implementation of flame retardancy to prevent fires. In this study, a B/P/N cross-linking flame retardant system was developed using phosphoric acid, boric acid, and glycerol. The cross-linking system was ammoniated and catalyzed by urea and dicyandiamide to enhance water solubility and fiber bonding strength. Following treatment, the limiting oxygen index of the cotton fabric increased from 18.0 % to 40.5 %, while the damage length in vertical flammability testing decreased from 30.0 cm to 4.8 cm. Thermogravimetric testing revealed an increase in residual char content at 750 °C in a nitrogen atmosphere from 9.7 % to 31.9 %, proving improved thermal stability. Furthermore, the maximum heat release rate and total heat release of the treated samples decreased by 86.7 % and 36.5 %, respectively, compared with pure cotton fabrics. Finally, possible flame retardant mechanisms were inferred from XPS and TG-IR data, demonstrating efficacy in both solid phase and gas phase.

Investigation on NOx control of a CI engine through the collective effect of hydrogen and biodiesel blend at modified compression ratio

The main challenges with using biodiesel in CI engines are higher NOx emissions and reduced brake thermal efficiency. These biodiesel-related issues can be handled by concurrently introducing gaseous fuels along with primary fuel into CI engines. This study examines the effects of hydrogen in a dual fuel mode operation with diesel and Calophyllum inophyllum biodiesel blend (B20) at different compression ratios on the engine's performance, combustion, and emission characteristics. A single-cylinder, 4-stroke, variable compression ratio engine operating at 1500 rpm was used for the research. A standard compression ratio (SCR) of 17.5 and a modified compression ratio (MCR) of 15.5 at a constant hydrogen flow rate of 6 L per minute (lpm) were used with diesel and B 20. The addition of hydrogen with diesel and B20 resulted in higher cylinder pressure and heat release rate when compared to pure diesel and B20 operation. This resulted in a shorter delay period (by an average of 9.4 % and 7.1 %) with lower peak pressure than pure diesel and B20 operation. During the dual fuel mode of H2 with B 20 at a modified compression ratio, the maximum heat release rate was decreased and its occurrence was retarded. NOx, UBHC, and CO emissions of the engine were decreased significantly by an average of 20.8% 43.7, %, and 22 % respectively with 37.7 % increase in smoke opacity. The increase in NOx emission with the use of H2 with diesel was reduced by operating H2 with B20 and at a reduced compression ratio. This lower emission was achieved with a compromise of a marginal decrease in engine brake thermal efficiency.

Experimental investigation of aging effects on thermal behavior of lithium-ion batteries during charging process

Thermal runaway generated by lithium-ion batteries is considered as one of the major hazards that exhibits great thermal risk during operation. The aging behavior, as an inevitable phenomenon after long-term cycling, largely contributes to the deterioration of thermal characteristics. In this paper, comparative experiments were conducted to investigate the aging cell thermal performance during the charging process. The results indicate that the aging cell with a high charging rate presents a higher thermal risk. With the decrease of SOH, the anode structure was destroyed and side reactions reduced the thermal stability. The thermal runaway onset temperature decreased from 274.8 ± 9.1 °C for fresh to 238 ± 1.2 °C for aging cells, and the corresponding critical time shortened by approximately 1 min. In addition, the maximum heat release rate increased by 37.5 %–45.5 % for aging cells under high charging conditions, manifesting that aging cells are more prone to trigger fire accidents. Finally, a modified risk assessment method was established. This study contributes to comprehending the coupling effects of aging behavior and charging rate thermal runaway mechanisms, and provides valuable guidance for thermal runaway detection during the whole life.

CNG impact on combustion quality of a diesel engine fueled in diesel-gas mode

The main objective of the paper is to reveal a few aspects related to combustion quality of a diesel engine fueled in diesel-gas mode with diesel fuel and compressed natural gas. The total amount of heat released per cycle will be higher when the engine is fueled in dual-fuel mode due to higher LHV and because of the gaseous state of CNG. For low and medium loads the total quality of heat released per cycle will increase with 10 % and for higher loads it will reach levels with 25 % higher. The heat release rate of the preformed mixture will double its value for low and medium loads and will reach thresholds up to 3.5 times higher (interval −15; −5°CA); admitting CNG into cylinder will help the preformed mixture to reach stoichiometric values and thus improving the fast combustion phase. Fueling the engine in dual fuel mode with diesel fuel and CNG will have a negative effect on the maximum heat release rate; there will be a 10 % drop in maximum HRR for low loads when the energetic substitution coefficient reaches 36 % and 14 % at high loads when the xc is 26 %. The gaseous state and a higher LHV of CNG will have a good impact on indicated mean effective pressure for all studied regimes when the engine is fueled in DG mode: for low and medium loads 30 % and for high loads 20 % increase will be recorded. Gaseous state of CNG will lead to a higher percentage of preformed mixture and thus the fast combustion phase will extend for longer periods for all studied regimes when the engine is fueled in DG mode (20 % longer for low and medium loads and 30 % for high loads). The diffusive combustion phase will become shorter due to a lower quantity of the main dose when CNG is injected into the intake manifold (10–15 % shorter for low loads and 7 % at high loads).

Analysis of stage parameters of low-temperature oxidation of water-soaked coal based on kinetic principles

Mine fires caused by spontaneous coal combustion are major disasters in coal mines. The staged oxidation kinetic parameters of various coal samples at oxygen concentrations of 21 %, 15 %, 10 %, 5 %, and 3 % were analyzed using a programmed temperature testing system. Herein, the temperature increase rate of coal, the temperature difference between the furnace and coal, and the oxygen consumption characteristics were obtained. Based on the amount of CO produced and the temperature sensitivity coefficient, three characteristic temperatures and four stages of low-temperature oxidation (LTO) were identified. The results showed that at a critical temperature (TC), the amount of CO gas released from the coal samples increased with increasing oxygen concentration, and the difference in the oxygen consumption rate increased. After the limit temperature (Tu), the amount of CO gas increased steadily, and the increase in the oxygen consumption rate stagnated. CO production, the maximum heating rate, and the maximum heat release rate were positively correlated with the oxygen concentration. As the oxygen concentration increased, the activation energy during the oxygen absorption stage gradually decreased. The average reaction enthalpy (ΔH) of pre-oxidized water-immersed coal was 19.37 kJ/kg greater than that of raw coal. The equation for the conservation of energy of the coal oxidation warming process was normalized. The theoretical values of the awakening stage and the stable stage were τν and τν (1-B), respectively. When B was >1, pre-oxidized water-immersed coal at a low oxygen concentration was prone to crossover points during the oxygen absorption stage, which increased the risk of coal spontaneous combustion (CSC). The research results could provide a theoretical basis for the staged control of the spontaneous combustion of water-immersed coal in goaf areas.

Large eddy simulation investigation of the effect of radiative heat transfer on the ignition progress in a model combustor

Radiation significantly influences turbulent combustion. This paper investigates the impact of radiative heat transfer on the ignition process in a multi-staged model combustor. The ignition process is simulated both without and with consideration of radiation. Large Eddy Simulations based on the Euler-Lagrange description of the liquid spray and the Dynamic Thickened Flame model coupled with a skeletal chemical reaction mechanism are employed. The Weighted Sum of Gray Gases method are employed to solve the spectral properties and the Discrete Ordinates method is employed to solve the radiative transfer equation. The results indicate that radiative heat transfer influences the flame structure during the ignition process. In the flame propagation phase, both the total heat transfer and the exit average temperature are higher, with the radiative heat transfer during ignition being less than 15% of the total heat transfer. During the kernel generation phase, radiative heat transfer leads to a 7.24% increase in the maximum temperature of the flame kernel, a 7.74% expansion of the flame surface area, and outward movement of the position of the maximum heat release rate. Additionally, the ignition delay time extends by 14.91%. In the flame propagation phase, the flame transfers heat to the mixed gas and droplets near the flame surface through radiation, promoting flame spread.

Simulation Study on Temperature Control Performance of Lithium-Ion Battery Fires by Fine Water Mist in Energy Storage Stations.

The combustion of lithium-ion batteries is characterized by fast ignition, prolonged duration, high combustion temperature, release of significant energy, and generation of a large number of toxic gases. Fine water mist has characteristics such as a high fire extinguishing efficiency and environmental friendliness. In order to thoroughly investigate the temperature control effect of fine water mist on lithium-ion battery fires. This study employs numerical simulation methods, utilizing PyroSim software to simulate the fire process in lithium-ion battery energy storage compartments. First, we focus on the variation patterns of flame, changes in combustion temperature, and heat release rate over time at environmental temperatures of 10, 25, and 35 °C. Subsequently, the suppression of flame, reduction in temperature, and changes in heat release rate are simulated for water mist in lithium-ion battery fires. The simulation results indicate that the environmental temperature has a considerable impact on the flame but a lesser effect on the heat release rate. Fine water mist effectively impedes the spread of thermal runaway between internal battery core cells, leading to a reduction in the flame size and a significant decrease in the maximum temperature and heat release rate. The numerical simulation results can provide scientific guidance for the prevention and control of fires in lithium-ion battery energy storage compartments.

Enhancing Combustion Efficiency: Utilizing Graphene Oxide Nanofluids as Fuel Additives with Tomato Oil Methyl Ester in CI Engines

The research aims to conduct a thorough examination of the combustion, injection, performance, and emission characteristics of a diesel engine below different engine loads, as well as the synthesis of graphene oxide (GO) nano fuels and their utilization in combination with Tomato Oil methyl ester (TOME) and diesel fuel blend. The (GO), plays a vital role in the pre-mixed combustion phase of diesel engines. Addition of GO nano fuels enhances the high-pressure combustion stage, resulting in increased maximum pressure and heat release rate (HRR). TOME (B20GO75) and TOME (B20GO100) exhibit comparable HRR to diesel due to improved fuel characteristics and quicker ignition delay duration. While TOME (B20) shows a slight decrease in (BTE) compared to diesel, the addition of GO improves BTE, with TOME (B20GO50) displaying the highest BTE at full load, indicating enhanced combustion efficiency. Moreover, GO addition leads to a reduction in carbon monoxide (CO) and hydrocarbon (HC) emissions, with emissions decreasing as the dosage of GO increases. However, NOx emissions initially decrease with TOME (B20) compared to diesel but increase with higher GO dosages. Smoke emissions increase with TOME (B20) but decrease with higher GO dosages. Overall, the incorporation of GO nano fuels into TOME biodiesel fuel blends demonstrates potential for improving engine performance and reducing emissions.

Synergistic effect of hydrogen induction on the performance, combustion and emission phenomenon of dual-fuel CI engine with Chlorella vulgaris algae oil and its methyl ester

The present work aims to investigate the cumulative effect of hydrogen enrichment with the fuels of diesel, Neat chlorella vulgaris oil (NCVO), and Chlorella vulgaris methyl ester (CVME) in a mono-cylinder CI engine. The performance, combustion, and emission parameters of diesel, NCVO, and CVME are analyzed and compared to the findings obtained with hydrogen induction in the intake manifold under dual fuel configuration. With the effect of hydrogen infusion, the metrics of performance, combustion and emission parameters are improved. Under maximum load condition, the induction of hydrogen escalates the BTE from 32.74%, 28.01%, and 23.02%–35.39%, 31.40%, and 28.12% with diesel, CVME, and NCVO at maximal hydrogen share energy of 14.38%, 11.50% and 9.61% respectively. Alongside, the enrichment of hydrogen declines the carbon monoxide (CO) from 4.13, 10.38, and 19.24 g/kWh to 3.16, 8.02, and 15.26 g/kWh, unburned hydrocarbons (UHC) from 0.51, 0.71, and 2.02 g/kWh to 0.36, 0.50, and 1.64 g/kWh, smoke opacity from 55%, 75%, and 85%–43%, 67%, and 71% with diesel, CVME, and NCVO respectively. However, the hydrogen's significant flame velocity and immense calorific value confect to an elevated combustion temperature and subsequent rise in heat release rate (HRR) to, cylinder pressure, and emission of nitrogen oxide (NO). Among the tested fuels, diesel posses maximum HRR and cylinder pressure of 80.46 J/0CA and 88.67 bar respectively. Maximum specific NO emission was observed with CVME having 10.80 g/kWh, whereas diesel and NCVO has 9.49 g/kWh and 4.93 g/kWh respectively.

Evaluation of heterogeneous core sandwich panels for energy efficiency and fire safety in warehouse buildings

Sandwich panels are extensively used in the construction industry because of their superior thermal insulation performance and ease of installation. However, panels with combustible cores are prone to fire, whereas those with mineral-based cores exhibit lower thermal insulation capabilities. Therefore, to address these limitations, this study proposed a composite core approach to enhance both fire resistance and thermal insulation performance. A surface layer incorporated phenolic foam (PF), which fulfilled the fire resistance requirements and delivered excellent thermal insulation properties, and 30–40 mm of glass wool (GW) and mineral wool (MW) with exceptional fire resistance were applied. The heterogeneous core sandwich panels exhibited excellent flame-retardant performance, with a maximum peak heat release rate of 0.712 kW/m2 and a total heat release of 0.18 MJ/m2. This satisfied the semi-non-combustible flame retardancy level and ensured sufficient time for residents to evacuate safely. Moreover, based on its low thermal transmittance of 0.114–0.125 W/m2·K, when applied to warehouse-type buildings, heating energy consumption was reduced by approximately 10 % compared to sandwich panels based on inorganic core GW and MW. Heterogeneous core sandwich panels can exhibit excellent flame retardancy and thermal performance owing to the use of inorganic materials and PF, respectively.

Combustion characteristics of RP-3 aviation kerosene/n-butanol blended fuel in a compression ignition engine

In order to meet the requirements of Sustainable Aviation Fuel (SAF) to achieve the imperatives of energy conservation and emission reduction. This paper compares the combustion characteristics of diesel, RP-3/n-butanol blends in terms of heat release rate, in-cylinder pressure, temperature and fuel economy in a compression ignition engine, taking into account the advantages of lightweight structure, low fuel consumption and wide range of applications of aviation piston engines. The results certified the viability of applying RP-3 and RP-3/n-butanol blends in diesel engines. Adding n-butanol prolonged the ignition delay and shorten the combustion duration. Moreover, the peak of the pressure, temperature and apparent heat release rate (AHRR) increased. In addition, the blended fuel showed obvious diffusion combustion characteristics at high load. With the n-butanol increased, the combustion instability of the blended fuels decreased significantly, at low load. At n = 2400r/min, pme = 0.53 MPa, compared with diesel, the maximum heat release rate (MHRR) of R70B30 increased by 76.6 %, improving the combustion characteristics of the blended fuel. Moreover, the equivalent specific fuel consumption (ESFC) of RP-3 is 5.56–14.83 % lower than that of diesel, and the effective thermal efficiency (ETE) of RP-3 is 2.8–13.46 % higher than that of diesel under most working conditions.