Hierarchical Nano/Micro-Array Structured CuMgAl-LDH/rGO Hybrids for Remarkably Improved Flame Retardancy and Smoke Suppression Performance of Flexible Polyvinyl Chloride.

Abstract

In this study, we explored the rational integration of layered double hydroxides (LDHs) with reduced graphene oxide (rGO) to create a hierarchical nano/microarray structured CuMgAl-LDH/rGO hybrid aimed at enhancing the flame retardancy and smoke suppression properties of polymer nanocomposites. The results indicated that the limiting oxygen index (LOI) value of the G-CuMgAl/polyvinyl chloride (PVC) composite reached 35.8%, reflecting a 6.4% increase compared to pristine PVC (29.4%), and achieved a UL-94 V-0 rating. Furthermore, in comparison to pristine PVC, the peak heat release rate (PHRR) of the G-CuMgAl/PVC composite was significantly reduced by 40.2%; the total heat release rate (THR) decreased by 24.3%; the maximum average heat release rate (MARHE) diminished by 41.6%; the peak smoke production (PSPR) decreased by 37.8%; the total smoke production (TSP) was reduced by 31.3%; and the average effective heat of combustion (av-EHC) decreased by 15.2%. The enhanced flame retardancy and reduced smoke production can primarily be attributed to the multiple synergistic interactions among the highly dispersed constituents and the nano/microstructures, which effectively impede the transfer of heat, mass, and O2 from various directions while preventing further combustion of the underlying matrix by creating a tortuous path in the condensed phase. Additionally, this study provides a novel perspective on the design and synthesis of structured LDHs/rGO hybrids, with the potential to enhance flame retardancy and smoke suppression properties across a broad spectrum of polymer materials.