Maximum Hardness Value Research Articles

Effect of Micronised Pumice Powder Addition on Shore-D Hardness Values of Medium Density Fiber Epoxy Composite

The present study explores the effect of MDF powder-reinforced filled pumice powder epoxy composites on their Shore - D properties, produced by using different weight percentage. The composites samples containing 10, 20, 30, 40, and 50wt% of pumice powder were fabricated by using hand lay-up technique. The specimens prepared were tested for hardness as per the ASTMD2240 standards. The outcomes of the study revealed that pumice powder amount in the composite increasing with an increased in Shore-D hardness values. It is noted that the weight percentage of 50% of pumice powder and 50% of MDF powder composite was produce the maximum hardness values.

Potential plasma facing materials: A case study on CeB6 particulate reinforced W–1Ni matrix composites produced via different sintering techniques

Tungsten (W) is the most promising material for future plasma-facing materials. Its alloys or composites reinforced with various compounds have been studied to improve the irradiation resistance of W. This study aimed to investigate the effect of boron-containing reinforcement in the W matrix against He+ ion irradiation. Cerium hexaboride (CeB6) particulates, which have high neutron shielding properties, were incorporated into the W matrix pre-alloyed by 1 wt% Ni (W1Ni). CeB6 powders were home-made and prepared from CeO2/Mg/B2O3 powder blends via mechanochemical synthesis and purification steps. 1, 5, and 10 wt% CeB6 powders were added to pre-alloyed W1Ni by mechanical alloying, and then they were consolidated by using pressureless sintering (PS, 1400 °C, 1 h) and spark plasma sintering (SPS, 1410 °C, 1 min) techniques. CeB6 particle-reinforced W1Ni composites contained different amounts of reinforcements were prepared by two different sintering methods and were compared with respect to their compositional, microstructural, and microhardness properties and wear and irradiation behaviors. Based on the results, increasing the CeB6 reinforcement amount in the composite triggered the formation of the W2B phase, especially in the W1Ni–10CeB6 composite after both sintering methods. The mechanical and irradiation properties were enhanced more by increasing the CeB6 amount in the case of using the SPS method. When compared to other sintered samples, the SPS'ed W1Ni–10CeB6 composite has the lowest specific wear rate of ∼4 × 10−7 mm3/Nm and the maximum hardness value of ∼21 GPa. According to surface deformation, the W1Ni–5CeB6 composite exhibited comparatively higher resistance to He+ ion irradiation.

Microstructural evolution and mechanical properties of FeCrNiCuTix high entropy alloys

In this study, the microstructural evolution and mechanical properties of a series of FeCrNiCuTix (x = 0, 0.2, 0.4, 0.6, 0.8, and 1, in mole ratio) high entropy alloys (HEAs) were analyzed in detail to study the influence of Ti content on the HEAs. The microstructures of the alloys transformed from single-phase face-centered cubic (FCC) phase structure to FCC and body-centered cubic (BCC) diphase, finally to FCC, BCC and intermetallic compound (Fe2Ti) phase with the increase of Ti content. The addition of Ti element significantly refined the grain of the alloys. The hardness, strength and tribology tests of the alloys were also carried out. The results indicated that the Vickers hardness, yield strength, and fracture strength increased first and then decreased, the average friction coefficient variation law was just the opposite, and the plastic strain reduced monotonically, with the increase of x values for the alloys. At x = 0.4, the maximum yield strength and fracture strength of the alloy were 1646.89 MPa and 1947.09 MPa, respectively, and the average friction coefficient was a minimum of 0.47, with a hardness value of HV 489.68 and a plastic strain of 13.98%. The maximum hardness value of the alloy was HV 656.19 at x = 0.8. The fracture mechanism of the alloys was from ductile fracture to brittle fracture and the wear mechanism was form of abrasive wear. Accordingly, the FeCrNiCuTi0.4 alloy obtained the optimal mechanical properties overall. This research is of great significance for the development of engineering and structural materials with excellent mechanical properties.

Microstructure and mechanical properties of electroless Ni–P–Si3N4–TiN composite coatings

A high performance electroless Ni–P–Si3N4–TiN multi-nanocomposite coating was prepared on the surface of AZ31 Mg alloy. The results showed that the surface morphology of this multi-nanocomposite coating exhibits a uniform nodular structure, and the nodular size decreases clearly while increasing TiN nanoparticle concentrations to 2 g/L in the bath, resulting in the finest size of approximately 3 μm. Furthermore, the incorporation of TiN nanoparticles and Si3N4 nanowires into the Ni–P matrix can significantly enhance the microhardness and reduce the friction coefficient of the multi-nanocomposite coatings. The maximum hardness value of 921.4 HV200 and lowest friction coefficient of 0.54 as well as minimum wear weight loss of 0.7 mg can be also reached at a TiN nanoparticle concentration of 2 g/L.

Enhancing Dimensional Geometry Casting using Computer Modeling

Sand casting method is used to produce many useful products for many applications. The aim of the study is to manufacture a product with excellent dimensional geometry is achieved in sand casting process at low cost. We would expect manuscripts to show how design and/or manufacturing problems have been solved using computer modeling, simulation and analysis. In this work, the important mechanical properties of hardness and surface roughness are investigated on Aluminum 6063 cast material with and without incorporating the copper tubes as a vent hole in sand casting process. Since copper has high thermal conductivity when compared to other metals, the heat transfer rate will be varying from existing system. The copper tubes have made different diameters of holes on outer surfaces with selective distance of intervals. The specific number of copper tubes with various diameters are designed by CATIA modeling software and analyzed with Taguchi Design of Experiment. Taguchi L9 orthogonal array is used proficiently in the optimal value of hardness and surface roughness. The results are revealed that the maximum hardness value of 104 BHN is attained for 10mm distance of holes made on copper tube with an angle of 90o degree. The minimum surface roughness of 2.11 micron is achieved for 20mm distance of holes made on copper tube with 45o of angle as a vent hole in sand casting process.

Rapid processes for the production of nanocrystal yttria-stabilized tetragonal zirconia polycrystalline ceramics: ultrasonic spray pyrolysis synthesis and high-frequency induction sintering

In this study, nanocrystalline 3 mol % yttria-stabilized tetragonal zirconia polycrystalline (Y-TZP) ceramic was produced by sintering with a high-frequency induction heating (HFIH) system of granular powders obtained by ultrasonic spray pyrolysis (USP) at 600 °C. The granular nano-sized powders (10-30 nm) were micron in size (average size: 700 nm), spherical in shape and amorphous. The influences of the HFIH sintering temperature (1400-1600 °C), applied current time (60-300 sec.) and the mechanical pressure (10 MPa and 20 MPa) on the final density and grain size of the products were investigated. The amorphous granular Y-TZP powders compressed with the HFIH system allow very rapid condensation in the tetragonal phase at high density and avoid grain growth. High density (relative density over 95) nanocrystalline Y-TZP ceramic with ∼70 nm size could be obtained from the simultaneous application of 20 MPa pressure and an induced current within 300 sec. of sintering time at 1500 °C. In this condition, the sample’s maximum hardness and fracture toughness values were reached at 14.9 GPa and 3.8 MPa·m1/2, respectively. Y-TZP powders produced in nano-micro structure with the USP system were sintered with the HFIH system and rapid production was achieved by preventing grain growth.

Investigations on microstructure, hardness and tribological behaviour of AA7075-Al2O3 composites synthesized via stir casting route

Aluminium matrix composite (AMC) materials play an important role in the field of automobile and aerospace industries due to their excellent properties. In this research, aluminium alloy (AA7075) was reinforced with alumina (Al2O3) particles to improve their hardness and tribological behaviour of the base alloy. Four composites were prepared by varying the content (4, 8 and 12 wt.%) of Al2O3 particles through the stir casting technique. The surface morphology of the proposed composites ensured the uniform distribution of Al2O3 particles into the matrix alloy. The hardness of the composite was measured using a Brinell hardness tester and the maximum value of hardness was found in the AA7075 - 8 wt.% Al2O3 composite. Hence, a tribological investigation was carried out on this AA7075 - 8 wt.% Al2O3 composite. Load (P), sliding speed (V) and sliding velocity (D) were taken as the wear parameters for conducting the experiments. A Technique for Order Preference by Similarity to Ideal Preferred Solution (TOPSIS) approach has been applied to find out the optimal conditions of parameters to obtain the lowest wear rate (WR) and the co-efficient of friction (COF). The results showed that the lowest WR and COF was obtained at ‘P’ of 15 N, ‘V’ of 1 m•s-1 and ‘D’ of 1000 m•s-1. ANOVA results revealed that ‘P’ is the factor with the most significant contribution (38.36%), followed by ‘D’ (28.32%). The worn surface morphology of the confirmation experiment specimen was investigated by SEM and the wear mechanism was reported.

Effect of Nb and V doped elements on the mechanical and tribological properties of CrYN coatings

One of the most promising approaches to enhancing the tribological properties of engineering coatings is to add transition elements to the structure. In this study, Nb-doped CrYN and V-doped CrYN thin films were deposited by pulsed DC reactive sputtering in a closed-field unbalanced magnetron sputtering (CFUBMS) system. The deposition parameters examined were target current (1, 1.5 and 2 A), deposition pressure (0.15, 0.25 and 0.35 Pa), pulse frequency (100, 200 and 350 kHz) and duty cycle (85 %, 70 % and 50 %). A Taguchi L9 orthogonal design was used to define the deposition process parameters for each doped film. The Nb and V-doped CrYN thin films were characterized in terms of their microstructure, thickness, composition, hardness and tribological properties by X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), nanohardness and pin-on-disc testing, respectively. The bond strength between the substrate and the films (adhesion) was analyzed by scratch testing. For the Nb-doped thin films, a maximum hardness value of 21.4 GPa and the lowest friction coefficient of 0.36 were obtained. On the other hand, in the V-doped thin films, the maximum hardness value was 16.1 GPa, while the lowest friction coefficient obtained was 0.11. In addition, Nb-doped and V-doped CrYN thin films exhibited extraordinary adhesion properties. The effect of the selected deposition parameters (target current, pulse frequency, and duty cycle) in relation to the film thickness, hardness, and coefficient of friction properties of the Nb and V-doped CrYN thin films were investigated using the Taguchi approach and optimum operating conditions were identified and confirmed.

Stir Cast AA 6351/Graphene/TiB2/Rice Husk Ash composite: Fabrication and assessment of mechanical properties

Single composites are replaced by hybrid composites because of their highly efficient properties and easy processing ability. In this research work, the stir casting process has been used for the fabrication of an Aluminium 6351 metal matrix composite. The TiB2, Graphene and Rice Husk Ash (RHA) have been used as reinforcements. The various mechanical (hardness, impact, flexural, tensile) and surface (SEM, EDS, XRD) characterization have been carried out. The different samples with varying compositions of Graphene (0.0, 0.5, 1.0 and 1.5 wt.-%), the constant composition of Titanium boride (10 wt.-%) and Rice Husk Ash (2.0 wt.-%) have been fabricated. The maximum values of hardness and energy absorbed were 78.8 HV0.3 and 6 Joule respectively and minimum surface roughness of 0.308 µm have been obtained by doping 1.5 wt.-% Graphene in AA6351. Whereas, the maximum value of flexural and tensile strength was 418.73 and 154.81 MPa for AA6351 having 0.5 wt.-% of Graphene as reinforcement. Moreover, the presence of TiB2, Graphene, and RHA showed their uniform distribution in fabricated composites using surface characterization (such as SEM, EDS and XRD).

Effects of Frozen Storage Time, Thawing Treatments, and Their Interaction on the Rheological Properties of Non-Fermented Wheat Dough.

In this study, the effects of frozen storage time, thawing treatments, and their interaction on the rheological properties of non-fermented dough were evaluated. Texture profile analysis (TPA), rheological measurements, including strain/frequency sweep, and creep-recovery measurement were applied to the dough. Compared with unfrozen fresh dough, the frozen storage time (S) and thawing treatment (T) influenced almost all indicators significantly, and their mutual effects (S × T) mainly affected the hardness and springiness. Frozen time was the main factor resulting in the destruction of non-fermented dough during the thawing treatments. Moreover, refrigerator thawing (4 °C) produced a dough with minimal changes in the rheological properties, regardless of the frozen storage time. Meanwhile, microwave thawing resulted in lower G' and lower zero shear viscosity (η0) values, as well as higher maximum creep compliance (Jmax) and hardness values. Moreover, the difference between the three thawing treatments was exacerbated after 30 days of frozen storage. SEM images also showed that long-term frozen storage combined with microwave thawing seriously destroyed the rheological properties, structural stability, and inner microstructure of the dough.

Non-destructive evaluation of aging in welded pipeline X60 and X65 by thermoelectric power means

In this investigation, the sensibility of the thermoelectric power (TEP) to the aging condition of API X60 and API X65 steel pipeline welded joints was evaluated. Specimens of both API welded joints were artificially aged at 300 °C for 3, 7, 9, 18, 30 and 45 h, the microstructural evolution was assessed via optical microscopy (OM) and scanning electron microscopy (SEM). Image analysis revealed no significant changes in the microstructure with respect to the aging time. Vickers micro-hardness evaluation showed that both welded joints reach a maximum hardness value after 3 h of artificial aging followed by a reduction in its value in the next aging conditions. TEP was measured using the hot tip technique applying different hot tip temperatures (55, 60, 65, 70 °C), where higher temperature values showed to increase the sensibility of the technique to detect microstructural changes that affect micro-hardness and where not possible to observe via OM and SEM. TEP and micro-hardness exhibit an opposite correlation, which was confirmed calculating the Pearson's correlation coefficient (r). The correlation coefficient decreases when higher hot tip temperatures where employed to measure TEP. The good correlation between TEP values and micro-hardness allows to use TEP measurement as a prediction tool of material micro-hardness.

Corrosion resistance of nitrogenated high-carbon martensitic stainless steel designed and produced at nitrogen low pressures

A new martensitic stainless steel with high nitrogen and carbon content at low pressures was designed using the CALPHAD method. The chemical composition of the steel was checked by optical emission spectrometry, obtaining 0.17 wt%-N and 1.33 wt%-C. Scanning electron microscopy (SEM) analyses were carried out for microstructural characterization. The properties of the steel were assessed by Rockwell hardness and potentiodynamic polarization tests in 0.6M NaCl. The steel showed maximum hardness values of 60 HRC, regarded as a hard material. However, the passive film formation was prevented by the high carbon content promoting excessive Cr-rich carbides.

Study of ordered phase precipitation behaviour and hardening mechanism of Au-20Ag-10Cu alloy during deformation-aging treatment

With the rapid development of aerospace technology, the demand for a longer service life of Au-Ag-Cu alloy as conductive slip rings is increasing. Therefore, it is important to improve the hardness of the alloys in order to prolong their service life. Deformation-aging can improve the hardness of many alloys. The effect of the deformation-aging process of Au-20Ag-10Cu (wt%) alloy was investigated on the microstructure and properties, which characterized by DSC(Differential Scanning Calorimeter), XRD(X-ray Diffraction), EBSD(Electron Backscatter Diffraction), TEM(Transmission Electron Microscope) characterization techniques, microhardness and electrical conductivity testing methods. The results indicated that the microhardness increases and the conductivity decreases gradually with the increase of deformation rate. As the aging time increasing, the content of face-centered tetragonal AuCu I ordered phase increases, and thus the hardness increases gradually. The maximum hardness value of 307.44 HV was obtained after undergoing 70 % deformation and then aged at 300 ℃ for 16 h with the electrical conductivity values of 8.40 MS·m−1. This result indicated that both higher hardness and higher electrical conductivity of Au-20Ag-10Cu (wt%) alloy could be obtained, which ensures the requirements in the field of electrical contact materials.

Effect of nanoparticles adhesion and multipass friction stir processing on metallurgical properties of AZ91D magnesium alloy

In this work, the effect of SiC and Al2O3 nanoparticles and multipass friction stir processing (MPFSP) on the metallurgical properties of AZ91D was carefully investigated and observed a homogenous dispersion of nanoparticles and refined grain size in the processed zone. The presence of the Mg17Al12 intermetallic compound in the MPFSP of AZ91D with SiC and Al2O3 nanoparticles has significant implications for the material’s properties. Mg17Al12 is a typical intermetallic phase formed in magnesium alloys and can profoundly affect thermal, microstructural, and mechanical properties. The intermetallic phase can improve the processed region’s strength due to its inherent hardness and solid solution strengthening effect, resulting in enhanced tensile properties and hardness. As the FSP passes increased, the tendency for reinforcement agglomeration diminished. Before undergoing MPFSP/(SiC + Al2O3), the base metal AZ91D exhibited an ultimate tensile strength (UTS) of 208.36 MPa and a strain percentage 15.72. After implementing MPFSP/(SiC and Al2O3) on AZ91D, the UTS consistently increased with each FSP pass. This effect was evident at the fourth FSP pass, yielding a higher UTS of 284.35 MPa. In essence, this process facilitated a marked enhancement in the metallurgical properties of AZ91D, signifying the efficacy of the MPFSP approach when combined with reinforcement particles. The hardness value was higher when the indenter engaged with Mg17Al12 than α-Mg. The SZ of 4-pass FSP (Al2O3+SiC)/AZ91D reached a maximum hardness value of 69.37 HV, while single-pass FSP (Al2O3)/AZ91D exhibited a minimum value of 64.89 HV.

The Effect of Rotational Tool Speed on Dissimilar Joint Aluminum-Copper Plate Friction Stir Welded Joint

The study investigates the impact of rotational tool speed on the mechanical properties and microstructure of aluminum-cooper friction stir-welded joints. It found that higher rotational speed leads to increased grain size, possibly due to increased heat production. Higher hardness values in the stir zone result from uniform dispersion of smaller copper particles. The study found that 540 rpm yields the maximum hardness value in the stir zone, measuring 67 VHN. However, higher speed results in defects like voids, cracks, and intermetallic compounds (IMCs), which are linked to the formation of IMCs at elevated temperatures. The optimal welding conditions at 550 rpm balance grain refinement, hardness enhancement, and defect mitigation, contributing to the understanding of welding process parameters.

Applications of genetic algorithm in prediction of the best achievable combination of hardness and tensile strength for graphene reinforced magnesium alloy (AZ61) matrix composite

Due to lack of knowledge about role of process variables in the hot rolling of magnesium alloy composites, the most desirable wrought products of magnesium alloy-based composites could not be successfully produced till date. Moreover, use of wrought graphene reinforced magnesium alloy-based composite has emerged as a lucrative option for developing novel light alloy products in structural applications. The implicative need to obtain the best possible properties of the composite dictates to fix the optimized process variables in rolling operation. The present study envisages the development of data driven model that enables to derive desirable properties of the said composite; so, in order to secure the optimized subset of requirements (process parameters), a metaheuristic optimization tool is employed. We invoke the use of Genetic Algorithm (GA) optimizing tool in association with linear regression, so as to achieve the best combination of hardness and tensile strength of AZ-61-graphene nanoplate (GNP) composite.Modified magnesium AZ-61 alloy composites of varying GNP content (0, 1 and 2 wt.%) are produced by stir casting. The cast composites are homogenized at 450 °C for 12 h, followed by iced water quenching. The quenched materials are subjected to hot rolling and the process variables of hot rolling operation consist of rolling temperature, number of rolling passes as well as the initial stock thickness. The rolled materials are tested for hardness and tensile strength as the response variables. Instead of using artificial neural network to fix the objective function of GA, a mathematical model is developed by regression analysis; the derived equation is used as the objective function for multi-objective optimization task. The present paper explores the usefulness of implementing evolutionary algorithm (as in genetic algorithm) to correctly forecast the effect of rolling process variables onto the hardness and tensile strength of the stir cast AZ alloy-GNP nanocomposite.The experimental results show that the maximum achievable hardness value happens to be 106.6 VHN and is very close to that predicted by GA, ∼107.41VHN. Similarly, the maximum experimental tensile strength is found to be 266.82 MPa whereas, the corresponding GA predicted value is seen to be 253 MPa. A close fit can thus be noticed between the GA predicted and the experimentally obtained values. Barring a couple of exceptions, the difference between the experimental and GA predicted data lies within 1 % to 5 % (based on [Experimental value ∼ predicted value]/ [experimental value]). This entices to believe that the adopted muti-objective optimization strategy is quite useful in determining the optimum combination of rolling parameters that aids in achieving the most desirable property combination.

Isothermal oxidation behavior of W-based alloy coatings doped with Ta, Cr, Ti, V

Tungsten-based multi-alloy coatings with the addition of Ta, Cr, Ti, and V were prepared by double glow plasma surface alloying (DGPSA) technology. The alloyed specimens showed bulges and pits on the surface with an island growth mechanism. The coating exhibits a single BCC phase. The hardness shows an increasing trend with the increase of alloyed elements. The maximum hardness value of WTaCrTiV is 1748 HV100g. The oxidation behavior of coatings at 800 °C was investigated, with emphasis on the effect of elemental doping on the antioxidant properties. With the addition of Ta, Cr, Ti, and V elements, the antioxidant properties of multi-alloy coatings were effectively improved compared the tungsten matrix. The WTaCrTi coating shows the optimum antioxidant properties with a dense Cr2O3 layer. As the number of elements in multi-alloy increases, the mixing entropy increases, leading to a decrease in the Gibbs free energy, which results in a more stable alloy.

Study of Tl-based perovskite materials TlZX3 (Z = Ge, Sn, Be, Sr; X = Cl, Br, I) for application in scintillators: DFT and TD-DFT approach

Scintillators are designed significantly for utilization in a broad range of technology fields, notably nuclear physics, healthcare testing, and materials analysis. A number of applications involving scintillators, such as therapeutic image analysis, burglary prevention as well and nuclear investigation, have tempted scientists to establish novel and effective scintillators. In this report, thallium-based perovskite material TlZX3 (Z = Ge, Sn, Be, Sr; X = Cl, Br, I) has been examined by means of DFT and TD-DFT approaches. The structural, electronic, optical, and thermal properties of TlZX3 are calculated and discussed. The HOMO-LUMO energy gap of TlGeX3, TlSnX3, TlBeX3, and TlSrX3 are found in the range of 1.76 eV to 2.12 eV, 1.77 eV to 2.27 eV, 1.56 eV to 2.04 eV and 1.06 eV to 2.81 eV, respectively. Lattice constant, unit cell volume, formation energy, VEA, electrophilicity index, polarizability, refractive index, dielectric constant, entropy, and heat capacity of TlZX3 increase gradually from Cl to Br to I. However, HOMO-LUMO energy gap, tolerance factor, dipole moment, optical electronegativity, thermal energy, ZVPE, and Gibbs energy drop down from Cl to Br to I. Among the studied materials, TlGeI3 shows the maximum value of molecular hardness and electronegativity while TlSrCl3 exhibits the minimum value. The computed HOMO-LUMO energy gap and refractive index of the studied materials are in close agreement with the previously reported findings, it specifies their potential application in scintillator and solar cells.

Effect of Bi Content on the Microstructure, Mechanical and Tribological Properties of Cu-Sn Alloy.

To reduce the use of the toxic Pb element in the Cu-Sn alloy with high friction performance, Cu-xBi-10Sn alloys with different Bi contents were prepared by gravity casting, and the effect of Bi content on the microstructure, mechanical properties and wear property of Cu-Sn alloys were studied. The results showed that the Bi element was distributed in bands or long strips on the dendritic arms and did not form compounds with other elements. With the increase in Bi content, the hardness and tensile strength of Cu-xBi-10Sn alloys present a trend of increasing first and then decreasing. When the Bi content was 7 wt.%, the maximum hardness value was obtained, and the ultimate tensile strength was close to that of Cu-10Pb-10Sn alloy. Compared with Cu-10Pb-10Sn alloy, Cu-7Bi-10Sn alloy also possessed better friction reduction and wear resistance under the oil lubrication condition.

INVESTIGATION OF MECHANICAL PROPERTIES OF AL 7075 ALLOY SOLIDIFIED UNDER VIBRATION

Al 7075 alloy is a material with high mechanical properties and limited plastic formability at room temperature. In some special applications, it may need to be obtained by casting. In this study, it is aimed to increase the strength of the Al 7075 alloy by solidification which has a wide range of applications in sectors such as automotive, aircraft and space defense industry, under mechanical vibration applied at different frequencies after casting. Microstructure examination, compression test and hardness measurement tests are conducted to determine the changes in the mechanical properties of Al 7075 alloy in different frequencies by after solidification under mechanical vibration. Maximum hardness value is obtained at 30 Hz frequency in mechanical vibrations applied at frequencies between 10-50 Hz. This hardness value is lower than the hardness values that can be obtained by precipitation hardening, but considerably higher than the material without heat treatment.