The energy funnel effect holds significant potential for enhancing light-emitting diode (LED) performance in the Quasi-two-dimensional (Quasi-2D) perovskite, which feature a unique multi-quantum well structure. However, random phase distribution and defects within Quasi-2D films pose challenges, leading to inefficient energy transfer and nonradiative recombination, thereby limiting device performance. Here, sodium 2-naphthalene sulfonate (b-NA) is introduced into the Quasi-2D perovskite film to enhance its the optical and electrical properties. The strong interaction between the S = O group and Na+ in b-NA with the perovskite matrix leads to reduced grain size, facilitating agglomeration and densification. This modification decreases the proportion of the low-n phase, enhances thermal stability, and passivates surface defects. Therefore, compared to the control device, the maximum brightness and external quantum efficiency of Quasi-2D perovskite LEDs with the optimal concentration (8b-NA) more than double, and the operational lifetime (T50) of the unpackaged device extends from 70.1 min to 168.5 min.