Studies with regard to how to obtain superhydrophobic properties by directly coating emulsified silicone oil onto the surface of cotton fabric have always been a hot topic in the field of textiles. In this paper, an amphoteric microgel with thermo- and pH-responsive ability was synthesized. Subsequently, a series of Poly(methylhydrosiloxane) (PMHS) /water emulsions were prepared by using these amphoteric microgels as a Pickering emulsifier. When the PMHS/water system's mass ratio was 5/5 and the microgel content was kept at 2.0 wt%, this emulsion showed good stability allowing the PMHS parts to be dispersed uniformly in aqueous solution. The optical microscopy showed the emulsion's particle size was in a range from 5 to 20 μm and the stability test confirmed that no stratification occurred when this emulsion was subjected to 3000 rpm for 30 min. By using this emulsion as a post-treatment reagent, cotton fabrics with different yarn counts can obtain a water contact angle as high as 150o, which is about 25 % higher than commercial emulsifiers. Furthermore, this cotton fabric can hold superhydrophobicity after 50 rubbing cycles and 10 peel-off cycles. The development of this work provides a new direction for the study of the application of microgels.
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