Vapor Mass Research Articles

Enhancing the sustainability of interfacial evaporation to mitigate solar intermittency via phase change thermal storage

Solar-driven interfacial water evaporation is a low-carbon footprint strategy for addressing global water scarcity. However, the operation of the evaporator requires continuity of solar radiation. Herein, the key to overcoming the intermittency of sunlight lies in utilizing the heat storage/release cycle of phase change materials. Additionally, the synergistic effect of high thermal conductivity materials and increased heat transfer area addresses the nonuniform spatial temperature within the heat storage device caused by the low thermal conductivity of molten paraffin. Although the heat transferred to the paraffin reduces the evaporation rate under illumination, the thermal storage/release capacity of paraffin increases the evaporation mass by 171.5% in darkness. Ultimately, after one light–dark cycle, the total evaporation mass over the entire period increased by 11.5%. Finally, although paraffin undergoes sensible and latent heat absorption and release across various temperature ranges during multiple light–dark cycles and prolonged operation, the phase change delays at different internal locations still ensure stable dark-state evaporation compensation for the evaporator, thereby enhancing the sustainability of the evaporation process.

Development of a Single Vial Mass Flow Rate Monitor to Assess Pharmaceutical Freeze Drying Heterogeneity.

During pharmaceutical lyophilization processes, inter-vial drying heterogeneity remains a significant obstacle. Due to differences in heat and mass transfer based on vial position within the freeze drier, edge vials freeze differently, are typically warmer and dry faster than center vials. This vial position-dependent heterogeneity within the freeze dryer leads to tradeoffs during process development. During primary drying, process developers must be careful to avoid shelf temperatures that would result in overheating of edge vials causing the product sublimation interface temperature to rise above the critical (collapse) temperature. However, at lower shelf temperatures, center vials require longer to complete primary drying, risking collapse or melt-back due to incomplete drying. Both situations may result in poor product quality affecting drug stability, activity, and reconstitution times. We present a new approach for monitoring vial location-specific water vapor mass flow based on Tunable Diode Laser Absorption Spectroscopy (TDLAS). The single vial monitor enables measurement of the gas flow velocity, water vapor temperature, and gas concentration from the sublimating ice, enabling the calculation of the mass flow rate which can be used in combination with a heat and mass transfer model to determine vial heat transfer coefficients and product resistance to drying. These parameters can in turn be used for robust and rapid process development and control.

Heat transfer performance and startup characteristics of separated gravity heat pipe

Separated gravity heat pipes, with distinct arrangements of evaporating and condensing sections, offer low thermal resistance, high heat transfer efficiency, and a simple structure, making them suitable for passive cooling of spent fuel pools through gravity-driven processes. In this study, a steady-state, one-dimensional, two-phase flow model is developed to analyze phase change heat transfer in a separated gravity heat pipe. The research investigates the impact of liquid filling rate and vacuum level on heat pipe operation. The findings reveal a notable increase in pressure drop inside the tube with higher liquid filling rates, which diminishes the adaptability of the heat pipe as pressure rises, resulting in a narrower range of effective liquid filling rates. Specifically, the liquid filling rate of the heat pipe ranges from 38 % to 72 % at P = 13.75 kPa and from 44 % to 68 % at P = 15.75 kPa. Additionally, a startup prediction model is formulated based on a thermal resistance network model using the ideal gas assumption. Two startup states—namely, the initial startup state and the subsequent startup state—are proposed for large-scale separated gravity heat pipe arrays. The heat pipe achieves the large-temperature-difference initial startup state at a 50 % liquid filling rate within 7 min before transitioning to the subsequent startup state. The vapor mass, heat transfer coefficient, and working fluid temperature initially increase and then decrease over time, with varying peak times. As the liquid filling rate increases, the maximum vapor mass also increases. The heat transfer coefficient peaks at a 60 % liquid filling rate before subsequently declining. The optimal liquid filling rate of 60 % is identified based on startup time, heat transfer coefficient, and overall heat transfer efficiency.

Heat and mass transfer performance of multi-solute electroplating wastewater in spray evaporation separation process

Electroplating wastewater is complex in composition and contains many harmful substances. Based on the single droplet heat and mass transfer method, a one-dimensional mathematical model for the evaporation separation heat and mass transfer process of multi-solute electroplating wastewater is established. In order to validate the model, the experimental system of evaporation separation tower is established, and Nusselt numbers corresponding to metal ion solutions are fitted, reliabilities of models are also verified. The maximum relative errors of mathematical models are within 10.0 %. In addition, effects of the type and concentration of metal ions and air inlet temperature on heat and mass transfer characteristics of spray separation tower are investigated. Experimental results show that when the wastewater inlet concentration is the same, the improvement effects of increasing air inlet temperature on evaporation and separation performance from high to low are ZnCl2, CuCl2, and NiCl2 solutions. When the air inlet temperature increases from 90 °C to 130 °C, the evaporation speed of ZnCl2, CuCl2 and NiCl2 solutions increase by 90.3 %, 84.3 % and 45.7 %, respectively. When the air inlet temperature is the same, with the increase of wastewater inlet concentration, the evaporation separation performance of electroplating wastewater in descending order is ZnCl2, CuCl2, and NiCl2 solutions.

Thin-film evaporation in microchannels: A combined analytical and computational fluid dynamics approach to assessing meniscus curvature impact

Computational fluid dynamics (CFD) is employed to investigate the effects of variation in bulk meniscus curvature on evaporative heat and mass transfer in microchannels. Evaporation in microchannels presents a classic multiscale problem, encompassing both microscopic and macroscopic length scales in the thin-film and bulk meniscus regions, respectively. Therefore, the liquid-vapor interface or meniscus shape is first determined through thin-film evaporation analysis using numerical approaches found in the literature. However, a new approach for establishing boundary conditions is also proposed, allowing for the representation of varying curvatures within the bulk meniscus region. Then, the obtained meniscus thickness profiles are exported to a two-dimensional CFD framework. The primary advantage of this developed CFD framework lies in its capability to simultaneously analyze evaporative heat and mass transfer from both microscopic and macroscopic regions, a feature that enhances research endeavors concerning micro and miniature heat pipes. The developed model is applied to various rectangular microchannel sizes, ranging from 10 to 100 μm in width, with wall superheats varying from 0.1 to 3.0 K. The aim is to quantify the effects of variations in bulk meniscus curvature on the evaporative characteristics of the extended meniscus (comprising both thin-film and bulk meniscus regions), using the concept of thermal resistance. Consequently, based on the CFD simulation results, multiple regression analysis is employed to formulate the total thermal resistance in terms of independent parameters, namely the microchannel width, wall superheat, and the radius of curvature (Rc). It is observed that the radius of curvature has a marginal impact on the total thermal resistance, allowing its influence to be expressed by a power-law function of (Rc/Rm)0.102, where Rm represents the minimum radius of curvature.

Acoustics of wet porous media with evaporation/condensation

This paper investigates acoustic wave propagation in wet rigid-frame porous media accounting for evaporation and condensation. At equilibrium, the solid walls are covered by a thin water film, and water vapor in the air is at its temperature-dependent saturation pressure. Small acoustic perturbations cause water to vaporize or condense, which together with the reversibility of the phase change, lead to a linear problem where the usual local poro-acoustics physics is enriched with the (i) Clapeyron relation linking liquid-wall temperature, vapor pressure, and latent heat of vaporization, (ii) latent heat transfer in the solid frame, (iii) diffusion equation for water vapor in air, and (iv) water vapor's equation of state. The equilibrium temperature highly influences the vapor concentration and the physical parameters of saturated moist air. Using the two-scale asymptotic homogenization method, it is shown that the dynamic permeability is determined similarly to classical porous media, while the effective compressibility is modified by evaporation/condensation and the equilibrium temperature. This modification is influenced by vapor mass and heat flows associated with phase changes through a local fully coupled heat transfer and water vapor diffusion problem, with specific boundary conditions at the gas–water interface. The analysis identifies dimensionless parameters and characteristic frequencies defining the upscaled model's features. Depending on equilibrium temperature, the theory qualitatively and quantitatively determines the characteristics of acoustic waves propagating through the media. The results are illustrated and discussed with analytically developed models.

Advancing thermohydraulic performance of micro-grooved flat heat pipes through a combined numerical-experimental approach

A combined numerical-experimental model has been developed to predict the thermohydraulic characteristics of micro-grooved flat heat pipes (FHPs). This model uses a limited number of experimental data for calibration with two parameters, βexp,1 and βexp,2, which account for uncertainties in the accommodation coefficients used to determine evaporation and condensation mass fluxes. This calibration, which is a key feature of the developed model, addresses the uncertainties and challenges in determining these coefficients. Moreover, the model incorporates the effects of interfacial shear stress, axial wall conduction, heat transfer in the liquid block region, and the contact angle of the liquid–vapor interface. Furthermore, the evaporation mass flux from the curved liquid–vapor interface is calculated using a separate multiscale approach developed in two recent works for analyzing evaporation from the extended meniscus in microchannels, considering thin-film evaporation. The model demonstrates high accuracy in predicting the maximum heat transport capacity (Qmax) and wall temperature distribution across various input heat powers, with a maximum error of less than 0.5 % in wall temperature predictions, as validated against experimental data. The validated model is then used to explore a new micro-grooved wick structure featuring converging/diverging microchannels. In this structure, the channel width is constant and equal to Wf2 in the first half of the heat pipe, from the condenser end to the midpoint, and then it decreases or increases to Wf1 by the end of the evaporator section. Results indicate that a flat heat pipe with a converging micro-grooved wick structure (Wf1 = 200 µm and Wf2 = 160 µm) can enhance Qmax from 53 to 70 W, 70.8 to 91.8 W, and 91.2 to 116.5 W at working temperatures of 60 °C, 70 °C, and 80 °C, respectively. This means the new converging micro-grooved wick structure can boost flat heat pipe performance by more than 25 % compared to a flat heat pipe with a straight micro-grooved wick (Wf1 = Wf2 = 200 µm) without increasing the occupied space.

Effect of pin fins on heat transfer during condensation in minichannel heat exchanger

In this study, condensation heat transfer of water vapor in a minichannel heat exchanger on smooth and pin fins surfaces was investigated experimentally. The experimental study was carried out to evaluate heat transfer coefficient, overall heat transfer coefficient, and Nusselt number over different ranges of vapor mass flux from 0.0064 to 0.0368 kg m−2 s−1 and cold-water flow rate range between 0.0013 kg s−1 to 0.0057 kg s−1. The minichannel has a rectangular shape with a hydraulic diameter of 1.3 mm. The experimental testing is carried out on aluminum surface with a channel that has a length of 270, width of 30 mm, and height of 1.3 mm. The pin fins surface is on the bottom of the condensing channel and the fins are circular and have diameter, height, and spacing of 1 mm, and are in-inline arrangement. It is found that condensation heat transfer coefficient on pin fins surface is about 15% higher than that on smooth surface. It is found that the condensation heat transfer coefficient increases significantly with increasing the vapor mass flux. In addition, the effect of increasing the cold fluid flow rate is lower than that of the hot vapor flow rate, but it becomes more significant for higher vapor flux.

On the influence of heat-induced evaporation over interfacial atomization driven by surface acoustic waves

In this work, the influence of evaporative flux over the atomization driven by surface acoustic waves (SAWs) of a Newtonian water drop is studied. The drop is placed on a heated substrate at constant temperature, higher than the saturation temperature at a given vapor pressure. In this manner, an interfacial temperature distribution arises along the drop free surface in terms evaporative mass flux and vapor recoil, which repercussion over aerosol size is studied by determining the asymptotic evolution equation governing the acoustically driven free surface. At such scenario, the connection between surface tension and temperature is also considered; thus, thermocapillary flow is incorporated into our drop model, described in terms of fundamental parameters, like the evaporation number, Marangoni number, and acoustic capillary number. Numerical solution of the evolution equation led us to obtain a simplified representation of the drop interfacial deformation mechanism, capable of predicting atomization and portraying the influence of evaporation over atomization. Subsequent analysis shows that the incorporation of evaporation at SAW atomization traduces in normal stresses counteracting the acoustic and thermocapillary effect, leading to the development of smaller drop aspect ratios with respect to the no-evaporative case. Being aware that the aerosol size is deeply related to the aspect ratio, we propose an analytical expression to estimate aerosol diameter under evaporative conditions. The results show that aspect ratio reduction leads to a decrement on aerosol size, up to two orders of magnitude, with respect to the no-evaporative case. Our study is a first approach providing insight about the importance of evaporation on aerosol regulation at SAW atomization.

A method to calculate the two-phase distribution in a microchannel heat exchanger

Maldistribution seriously impacts the heat transfer performance of the microchannel heat exchanger (MCHX). Fully understanding the two-phase distribution in the heat exchanger is important for advancing academic research and engineering applications. This study introduces a novel method for quantifying two-phase distribution in a microchannel heat exchanger. An experimental setup was developed to measure the local vapor mass fraction in the heat exchanger header. Capacitance signals were measured under inlet vapor mass fractions from 0 to 1, and inlet flow rates of 10, 15, and 25 g s−1 corresponding to a mass flux of 17.47, 26.2, and 43.66 kg m−2s−1, respectively. The local vapor mass fraction in the header was estimated using the capacitance measurements. The mass flow rate in the header, the microchannel tube, and the vapor mass fraction in the tube were calculated using the proposed model. The calculation model was validated against literature data, and the results were analyzed. The analysis reveals the characteristics of vapor mass fraction and mass flow rate distribution in the MCHX and further elaborates on the effects of phase separation, entrainment ratio, and pressure drop balance on the distribution. The proposed method can evaluate distribution in the header and tubes of microchannel heat exchangers, and it is also applicable to other types of two-phase flow devices.

The Evolution of the Hunga Hydration in a Moistening Stratosphere

AbstractThe 2022 Hunga eruption caused unprecedented stratospheric hydration. Aura Microwave Limb Sounder (MLS) measurements show that the stratospheric water vapor mass remains essentially unchanged as of early 2024 and that the Hunga hydration occurred atop a robust (possibly accelerating) moistening trend in the stratosphere. Enhanced by the excess Hunga water vapor, dehydration via polar stratospheric cloud sedimentation in the 2023 Antarctic vortex exceeded climatological values by 50%. Simple projections based on modeled exponential decay illustrate that the timing of the return to humidity levels that would have been expected absent the Hunga hydration depends on the ongoing stratospheric water vapor trend. With the Hunga hydration compounding an underlying moistening trend, the stratosphere could remain anomalously humid for an extended period.

High-Throughput Drug Stability Assessment via Biomimetic Metalloporphyrin-Catalyzed Reactions Using Laser-Assisted Rapid Evaporative Ionization Mass Spectrometry (LA-REIMS)

Background: Building extensive drug candidate libraries as early in the development pipeline as possible, with high-throughput in vitro absorption, distribution, metabolism, and excretion (ADME) profiling, is crucial for the selection of lead compounds to guide subsequent research and production phases. Traditionally, the analysis of metabolic stability assays heavily relies on high-throughput LC-MS/MS (liquid chromatography tandem mass spectrometry) techniques to meet with the lead profiling demands. Laser-assisted rapid evaporative ionization mass spectrometry (LA-REIMS) is a quick and efficient technique for characterizing complex biological samples without laborious sample preparation. Objective: In this study, using an automated LA-REIMS well plate reader, achieving an 8 s per sample measurement time, the oxidative metabolic stability of active drug agents was assessed using biomimetic metalloporphyrin-based oxidative model reactions. Results: The results obtained using the novel LA-REIMS-based protocol were compared to and corroborated by those obtained using conventional HPLC-UV-MS (high performance liquid chromatography with ultra-violet detection coupled with mass spectrometry) measurements. Conclusions: LA-REIMS emerges as a promising technique, demonstrating potential suitability for semi-quantitative high-throughput metabolic stability in an optimized solvent environment.

Experimental study of heat pipe start-up characteristics and development of an enhanced model considering gas diffusion effects

Heat pipe-based cooling reactors, offering passive heat transfer and modularity, are becoming the preferred type for micro-reactors. Alkali metals such as sodium, potassium and lithium are usually used as the working medium of the heat pipe, which is in a frozen state at normal atmospheric temperature. After heating the heat pipe, the working medium will melt and enter the gas chamber, and its flow state will undergo a transition from discontinuous flow to continuous flow. The start-up of the heat pipe affects the heat export and neutron physical characteristics of the heat pipe cooling reactor. Building a model of heat pipe can predict the start-up of heat pipe effectively, which can be helpful to study the start-up and safety analysis of heat pipe cooling reactor. In this paper, a heat pipe flat-front model considering the gas diffusion effect is established, and the gas temperature distribution characteristics in the non-continuous flow region are obtained through the start-up experiment of heat pipe. The calculated results of the flat-front model considering gas diffusion effect and the vertical flat-front model are compared with the experiment. The results show that the model in this paper can better describe the start-up of heat pipe. At the same time, the evaporation and condensation coefficient model based on temperature change is used to deal with the evaporation and condensation mass flow at the phase change interface of the heat pipe, which can better describe the temperature difference at the interface of the heat pipe.

Testing of rapid evaporative mass spectrometry for histological tissue classification and molecular diagnostics in a multi-site study

BackgroundWhile REIMS technology has successfully been demonstrated for the histological identification of ex-vivo breast tumor tissues, questions regarding the robustness of the approach and the possibility of tumor molecular diagnostics still remain unanswered. In the current study, we set out to determine whether it is possible to acquire cross-comparable REIMS datasets at multiple sites for the identification of breast tumors and subtypes.MethodsA consortium of four sites with three of them having access to fresh surgical tissue samples performed tissue analysis using identical REIMS setups and protocols. Overall, 21 breast cancer specimens containing pathology-validated tumor and adipose tissues were analyzed and results were compared using uni- and multivariate statistics on normal, WT and PIK3CA mutant ductal carcinomas.ResultsStatistical analysis of data from standards showed significant differences between sites and individual users. However, the multivariate classification models created from breast cancer data elicited 97.1% and 98.6% correct classification for leave-one-site-out and leave-one-patient-out cross validation. Molecular subtypes represented by PIK3CA mutation gave consistent results across sites.ConclusionsThe results clearly demonstrate the feasibility of creating and using global classification models for a REIMS-based margin assessment tool, supporting the clinical translatability of the approach.

Operational characteristics and performance optimizations of the organic Rankine cycle under different heat source/condensing environment conditions

The fluctuating heat sources and seasonal condensing environments are critical to the operation of Organic Rankine Cycle (ORC) under off-design conditions. This paper presents a comprehensive steady-state mathematical model developed using a newly built experimental platform. Focusing on the operational characteristics, including the evaporation pressure, condensation temperature, mass flow rate, and the performance of key equipment during the regulation of the expander, working fluid pump, and cooling water pump. Results show that the net efficiency initially increases before decreases, with both evaporation pressure and mass flow rate rising alongside the working fluid pump frequency. The quasi-two-stage single screw expander achieves an isentropic efficiency above 65 %. Additionally, flexible adjustments to the cooling water pump effectively regulate the cooling system, with timely cleaning of cooling pipelines enhancing net efficiency by up to 3.27 %. Optimization using the particle swarm algorithm improves system performance, achieving net efficiency enhancements of 1.8 % and 12.3 % under specific conditions. The novelty of this study lies in directly regulation of the expander, working fluid pump, and cooling water pump, significantly enhancing the off-design performance. This research provides valuable insights for researchers and designers, enabling flexible regulation of ORC operations to ensure efficient performance under varying conditions.

Rapid LA-REIMS-based metabolic fingerprinting of serum discriminates aflatoxin-exposed from non-exposed pregnant women: a prospective cohort from the Butajira Nutrition, Mental Health, and Pregnancy (BUNMAP) Study in rural Ethiopia

To date, the changes in maternal metabolic response associated with prenatal aflatoxin exposure remain largely unknown. This study investigated the effects of prenatal aflatoxin exposure on the maternal serum metabolome in rural Ethiopia. A total of 309 pregnant women were enrolled prospectively, and their serum aflatoxin concentrations were measured using targeted liquid chromatography coupled to tandem mass spectrometry (LC–MS/MS). Serum metabolic fingerprints were obtained using laser-assisted rapid evaporative ionization mass spectrometry (LA-REIMS), followed by combination of univariate and multivariate statistical modelling to evaluate changes in circulating metabolic features between aflatoxin-exposed and unexposed mothers and to select discriminatory metabolic features. The analysis revealed that 81.8% of women were exposed to aflatoxins, with a median concentration of 12.9 pg/mg albumin. The orthogonal partial least square discriminant analysis (OPLS-DA) regression model demonstrated significant disparities in the serum metabolome when comparing Ethiopian pregnant women with low vs high aflatoxin exposure. Thirty-two differentially expressed metabolic features were identified, affecting aminoacyl-tRNA biosynthesis pathway. Several discriminatory metabolites have been identified, including glutamine, tryptophan, tyrosine, carnosine, and 1-methylnicotinamide. In conclusion, our findings indicate that aflatoxin exposure during pregnancy have shown disparities in the maternal serum metabolome, primarily affecting protein synthesis. Further research is needed to identify specific metabolite biomarkers and elucidate the underlying mechanisms.

A Comparative Study of the Hydrogen Auto-Ignition Process in Oxygen–Nitrogen and Oxygen–Water Vapor Oxidizer: Numerical Investigations in Mixture Fraction Space and 3D Forced Homogeneous Isotropic Turbulent Flow Field

In this paper, we analyze the auto-ignition process of hydrogen in a hot oxidizer stream composed of oxygen–nitrogen and oxygen–water vapor with nitrogen/water vapor mass fractions in a range of 0.1–0.9. The temperature of the oxidizer varies from 1100 K to 1500 K and the temperature of hydrogen is assumed to be 300 K. The research is performed in 1D mixture fraction space and in a forced homogeneous isotropic turbulent (HIT) flow field. In the latter case, the Large Eddy Simulation (LES) method combined with the Eulerian Stochastic Field (ESF) combustion model is applied. The results obtained in mixture fraction space aim to determine the most reactive mixture fraction, maximum flame temperature, and dependence on the scalar dissipation rate. Among others, we found that the ignition in H2-O2-H2O mixtures occurs later than in H2-O2-N2 mixtures, especially at low oxidizer temperatures. On the other hand, for a high oxidizer temperature, the ignitability of H2-O2-H2O mixtures is extended, i.e., the ignition occurs for a larger content of H2O and takes place faster. The 3D LES-ESF results show that the ignition time is virtually independent of initial conditions, e.g., randomness of an initial flow field and turbulence intensity. The latter parameter, however, strongly affects the flame evolution. It is shown that the presence of water vapor decreases ignitability and makes flames more prone to extinction.

Performance enhancement of lab scale flash evaporation desalination system with sponge demisters: A practical approach

The current work focuses on mitigating the challenges associated with steam-carrying effects during flash desalination. Through experimental trials in a controlled laboratory setting, the impact of varying experimental parameters on the steam carrying ratio, flashing factor and separation efficiency is studied. Results suggested that the steam carrying ratio decreased with decreasing water pool height but increased with the degree of superheat and liquid entrainment. The value of the steam carrying ratio is reduced by 76.25 % by implementing a sponge inside the flash chamber at the same superheat. Liquid entrainment is significantly affected by the separation height and initial surge tank pressure. A high liquid entrainment results in a significant evaporated mass difference between experimental and theoretical results. The vapour mass transfer during the experiments without sponge arrangement is approximately two times the mass obtained from theoretical calculation. The results indicate that liquid entrainment is reduced by about 92% by incorporating the sponge at constant experimental conditions. The experimental data with sponge agree well with the theoretical results, with a maximum error of 18%. Finally, separation efficiency is proposed to compare the amount of liquid entrainment removed from total entrainment.

Explicitly defined empirical constant for phase-change simulation in a two-phase closed thermosyphon

Over several decades, the importance of energy recovery has grown because of the global shift from fossil fuels to renewable energy sources. Among various energy-recovery approaches, waste heat recovery has emerged as a prominent method owing to its ease of adoption in various fields such as power plants and commercial buildings and high amount of recovery by adopting in the heavy industry. A heat exchanger with a heat pipe offers superior waste heat recovery efficiency through its highly effective heat transfer in a two-phase closed thermosyphon (TPCT). Numerous investigations have explored the thermal hydraulic performance of TPCTs in various geometries and operation conditions, mostly relying on experimental methods owing to the challenges in accurately simulating phase change in TPCT systems. These challenges arise from using the mass-transfer intensity factor, r—an empirically selected constant in phase-change models—which lacks a robust basis in fundamental principles. This study introduces a novel approach to selecting the r value for simulating the phase-change process in TPCTs. By employing the volume-of-fluid model for multiphase interfaces along with the widely used Lee model for phase change, the proposed model establishes a correlation between evaporation and condensation mass fluxes to define the r value in condensation heat transfer within a TPCT. The utilisation of the proposed model in simulations yielded improved temperature predictions, deviating by 4–7 K from experimental results while offering a significant reduction in the number of r values to choose from, achieved by explicitly defining the r value for condensation heat transfer. The conventional approach was to set both empirical constants to re = rc = 0.1 s−1. However, this model, which provides a relationship between the two empirical constants based on mass balance, revealed that rc should be 9.8 s−1 rather than 0.1 s−1 corresponding to re = 0.1 s−1. Furthermore, the study examines the diverse thermal performance outcomes associated with varying r values for evaporation in a wide range of re (0.1–100 s−1). rc was in the range of 9.8–12.7 s−1, denoting an increase of only 30% as re increased 1000 times from 0.1 to 100 s−1. This research offers a comprehensive understanding of the computational modelling of TPCTs, providing valuable insights into their thermal characteristics based on the intricate phase-change phenomena occurring within them.

Extraction evolutionary features of continuous light-induced plasmonic nanobubbles by a dynamic spectral regression model

A comprehensive understanding of the nature of light-induced plasmonic nanobubbles (PNBs) generated around noble metal nanoparticles is essential for optimizing PNB-based applications, such as light-driven microfluidic control. To investigate the overall evolution pattern of plasmonic nanobubbles (PNBs) under continuous light illumination, a computational model based on the least-squares method is established. Meanwhile, the variations in nanofluid transmittance and vaporization mass under continuous light illumination are measured by an immersion fiber and an electronic balance, respectively. The effects of nanoparticle concentration on the nanofluid transmittance and vaporization mass are analyzed. Considering the variations in nanofluid concentration, the overall evolution pattern of PNBs is preliminarily analyzed by monitoring the real-time dynamic change in nanofluid transmittance. The experimental results indicate that the nanoparticle concentration has an important effect on the nanofluid vaporization process. During the illumination stage, an increased nanofluid concentration intensifies the synergistic effect of water vaporization and PNB growth on transmittance reduction. The change in nanofluid transmittance caused by PNB scattering greatly exceeds that caused by increasing nanoparticle concentration. The nanofluid concentration gradually increases and peaks at the end of the cooling stage, and the rate of change of the nanofluid concentration is proportional to the nanofluid concentration. The numerical calculations show that the average size and the range of the PNB size distribution continuously increase with increasing irradiation time, and decrease during the cooling stage. A higher nanofluid concentration corresponds to a wider range of PNB size distribution.