Martensite-austenite Constituent Research Articles

Effect of Microstructural Constituents on Hydrogen Embrittlement Resistance of API X60, X70, and X80 Pipeline Steels

This study describes how microstructural constituents affected the hydrogen embrittlement resistance of high-strength pipeline steels. The American Petroleum Institute (API) X60, X70, and X80 pipeline steels demonstrated complicated microstructure comprising polygonal ferrite (PF), acicular ferrite, granular bainite (GB), bainitic ferrite (BF), and secondary phases, e.g., the martensite-austenite (MA) constituent, and the volume fraction of the microstructures was dependent on alloying elements and processing conditions. To evaluate the hydrogen embrittlement resistance, a slow strain rate test (SSRT) was performed after electrochemical hydrogen charging. The SSRT results indicated that the X80 steel with the highest volume fraction of the MA constituent demonstrated relatively high yield strength but exhibited the lowest hydrogen embrittlement resistance because the MA constituent acted as a reversible hydrogen trap site.

Effect of Wire Preheat and Feed Rate in X80 Steel Laser Root Welds: Part 1 — Microstructure

Laser welding with cold versus hot wire feed was employed as a root pass to weld X80 pipeline steel. The influences of wire feed rate and preheat on the fusion zone microstructure were investigated. Increasing the wire feed rate helped generate acicular ferrite in the weld metal, and preheating the wire further suppressed the formation of bainite. The acicular ferrite in the upper region of the fusion zone was finer than that in the lower region, which was due to an increase in nucleation sites available. Five fill and cap passes were applied by gas metal arc welding to fill the remaining top part of the groove. Compared to arc welding with a higher heat input, laser welding led to finer prior austenite grains and smaller bainite packet size in the coarse-grained heat-affected zone and limited the formation of martensite-austenite constituents in the intercritically reheated coarse-grained heat-affected zone.

해양구조물용 YS 420MPa 강재 Flux Cored Arc 용접금속의 기계적 성질에 미치는 용접 자세의 영향

This study investigated the mechanical properties of flux-cored arc weld metal of 420-MPa yield-strength (YS) steels for offshore structures based on welding position. Results showed that the recovery rate of alloying elements in the horizontal-position weld metal was higher than that in the vertical-up-position weld metal, and the fraction of low-temperature transformation phases with high dislocation density in the horizontal-position weld metal was high. Consequently, the YS, tensile strength, and impact toughness of the horizontal-position weld metal were higher than those of the vertical-up-position weld metal. In addition, the impact toughness of the weld metal was affected to a greater extent by the microstructure and fraction of the weld metal itself than by the fraction of the martensite-austenite constituents.

Microstructural and Mechanical Characterization of Low-Alloy Fire- and Seismic-Resistant H-Section Steel

This study investigates the microstructure and nano-hardness distribution across the thickness of an H-section steel beam, specifically designed for seismic and fire resistance and fabricated using a quenching and self-tempering process. The beam dimensions include a 24 mm thick flange, with flange and web lengths of 300 mm and 700 mm, respectively. Our findings indicate that the mechanical properties across the flange thickness meet the designed criteria, with yield strengths exceeding 420 MPa, tensile strengths of over 520 MPa, and a yield-to-tensile strength ratio below 0.75. Microstructurally, the central part of the flange predominantly consists of granular bainite with a small fraction of martensite–austenite (MA) constituents, while locations closer to the surface show increased acicular ferrite and decreased MA constituents due to faster cooling rates. Furthermore, thermal exposure at 600 °C reveals that while the matrix microstructure remains thermally stable, the MA phase undergoes tempering, leading to a decrease in nano-hardness. These insights underline the significant impact of MA constituents on the elongation properties and stress concentrations, contributing to the overall understanding of the material’s behavior under seismic and fire conditions. The study’s findings are crucial for enhancing the reliability and safety of construction materials in demanding environments.

Insights into microstructure evolution and fracture mechanisms of welded joints of high strength steel patchwork components

The hot roll bending patchwork components of B1500HS uncoated ultra-high strength steel processed at industrial scale were welded with filler wire. The microstructure, grain orientation, mechanical properties and fracture behavior of the joint were investigated. The results showed that the weld metal (WM) was mainly composed of lath martensite and lower bainite (LB). Various microstructure appeared in different positions of the HAZ, among which martensite-austenite (M-A) constituents in the incompletely quenched zone and tempered martensite (TM) in the tempered zone were the key factors determining the performance of the joint. The welded joint exhibited complex structure and anisotropic mechanical response due to the decarburization and rolling texture of the original base material (BM). In the tempered zone, lath merge and boundaries disappear lead to the annihilation of dislocations, carbide precipitation leads to reduction of mobile dislocations, and recrystallization and recovery eliminate work hardening. The reduction of the effect of dislocation strengthening results in the formation of a softening belt at 6 mm from the center of the weld, with a minimum hardness of 266 HV. The tensile strength of the joint in the rolling direction (RD) was 983 MPa, and the fracture occurred in the softening belt. Both brittle and ductile fracture features were observed. The reason why the fracture occurs in the high temperature tempered zone instead of the incompletely quenched zone was the difference in the effect of “constraint strengthening”. Fracture occurred through delamination cracking along the “weak interface” owing to precipitated high-hardness cementite particles and the unfavorably oriented ferrite cleavage planes.

Micro-Alloying Effect on the Inter-Critical Grain Coarsened Heat Affected Zone of a S355 Steel Welded Joint

The inter-critical heat affected zone (ICHAZ) appears to be one of the most brittle sections in the welding of high-strength micro-alloyed steels (HSLA). Following repeated heating cycles in in with temperature ranging Ac1 /Ac3, the ICHAZ will face with an evident toughness and fatigue behavior reduction especially due to martensite-austenite constituent (MA) formation. Microalloying in high strength steels causes the generation of some phases in the matrix able to increase the mechanical properties of the joint. In this paper we report an investigation related to 1000 ppm vanadium addition in the welded joint of a structural S355 steel. The inter-critical zone of ta double pass welded joint is here reproduced by dilatometer, with second peak temperature ranging 720°C-790°C. The residual austenite dependence on inter-critical temperature is analyzed and related to the hardness behavior.

Enhanced hydrogen induced stress corrosion cracking resistance of Ni-advanced weathering steel by Ni and Mn modification

The stress corrosion cracking (SCC) behavior of three kinds of Ni-advanced weathering steel and a common weathering steel are examined in a simulated harsh marine environment by X-ray diffraction, scanning electron microscopy, electron backscattered diffraction, transmission electron microscopy, electrochemical tests, and slow strain rate tensile tests under different applied potentials. The results show that the SCC susceptibility of all test steel is low at open circuit potential. However, the SCC sensitivity of the conventional weathering steel increases significantly at − 1200 mV, while the Ni-advanced weathering steel exhibits good resistance to hydrogen embrittlement, which is attributed to the improved stacking fault energy, decrease of martensite-austenite constituents and refined grain size caused by increase in Ni and Mn content.

Influence of initial microstructure on reaustenitization behavior in low alloy steel by in-situ high-temperature EBSD characterization

In-situ high-temperature EBSD characterization was carried out to directly observe reaustenitization in a low alloy steel with different initial microstructures. For lath bainite, globular austenite mainly nucleated at prior austenite grain boundaries, and grew gradually to form uniform small grains from 780 to 860˚C. For granular bainite, martensite-austenite constituents accelerated acicular austenite formation via martensitic reversion transformation. Then, acicular grains coalesced. Finally, recrystallization occurred due to high dislocation density in martensitic revered austenite.

Microstructural evolutions and impact toughness in simulated welding heat affected zones for a high-strength carbide-free bainitic rail steel

Systematic experimental investigations were conducted to study the microstructures and impact toughness of each heat affected zone (HAZ) formed during rail flash-butt welding. A high-strength carbide-free bainitic rail steel was subjected to different thermal simulation cycles to separately reproduce each HAZ subzone by tailoring the peak temperature (PT) with respect to 700, 850, 920, 1000 and 1350 °C, and hence to generate the corresponding microstructures by using Gleeble-3500 simulator. Results show that the HAZ subzones exhibit complicated microstructures depending on the PTs, and with increasing PT the dominant bainitic microstructure type evolves from polygonal bainitic ferrite (700 °C) to a mixture of fine bainitic ferrite and granular bainite (850–1000 °C), and finally to coarse bainitic ferrite and granular bainite (1350 °C). Impact tests demonstrate that the impact toughness initially increases significantly as the PT reaches 920 °C (i.e., fine-grained HAZ), beyond which the impact toughness starts to decrease. The fine-grained HAZ displays optimal impact toughness in HAZs, yet which is lower than the base metal. Moreover, the morphology and distribution of martensite-austenite (M-A) constituents is strongly dependent on the welding PT, and the high fraction blocky and coarse slender M-A constituents is considered to be detrimental for the impact toughness.

Microstructure-based cleavage modelling to study grain size refinement and simulated heat affected zones of S690 high strength steel

Study of the cleavage behavior of heat treated S690 steel by a microstructure-based approach combined with finite element analysis is present in this paper. Cleavage simulations of steels subjected to heat treatments that cause grain refinement or simulate heat affected zones are performed, and are compared with experiments. It is found that the experimental improvement of toughness from grain refinement is 80% of what would be expected based on the model. The 20% difference is due to the lower number fraction of high-angle misorientation boundaries. It is also found that the resistance to micro-crack propagation is more effective in heat affected zones, which can be explained by the residual compressive stress in martensite-austenite constituents. This research assesses the balance between microstructural parameters for controlling cleavage toughness.

Influence of Martensite–Austenite Constituents and Precipitates on Reheat Cracking Susceptibility of Coarse-Grained Heat-Affected Zone in T23 and Modified T23 Steels

Influence of Martensite–Austenite Constituents and Precipitates on Reheat Cracking Susceptibility of Coarse-Grained Heat-Affected Zone in T23 and Modified T23 Steels

Embrittlement mechanism of 460 MPa-Grade nuclear power steel deposited after heat treatment

The effects of post-welded heat treatment on microstructure evolution and embrittlement mechanism of 460 MPa-grade nuclear power steel deposited metal were studied using optical microscope, scanning electron microscope, transmission electron microscope and electron backscattered diffraction (EBSD). The results showed that there was no significant change in the type of deposited metal microstructure before and after heat treatment, except for some acicular ferrite turning into block ferrite. Further studies showed that the dispersive martensite-austenite (M-A) constituent did not worsen the toughness of the deposited metal. However, after heat treatment, the M-A constituent decomposed into ferrite and carbides, where the carbides were precipitated on the grain boundary, resulting in grain boundary embrittlement. The precipitated carbides also increased the dislocation tangle on the grain boundary, which was prone to causing stress concentration and induced crack initiation, resulting in the cleavage fracture. The analysis of the orientation characteristics of the impact fracture profile via EBSD showed that the ferrite laths were coarsened and the high-angle grain boundaries were reduced after heat treatment. Meanwhile, the plastic crack propagation was terminated earlier resulting in the early initiation of cleavage fracture. Moreover, the crack propagation path was smooth and secondary cracks formed during the propagation process. Finally, after heat treatment the inclusions easily fell off and formed micro-voids, which provided favorable channels for crack propagation and accelerated the deterioration of impact toughness. All of these were factors for the significant decline in the toughness of the heat-treated deposited metal.

Cleavage fracture micromechanisms in simulated heat affected zones of S690 high strength steels

High strength steels are widely used for structural applications, where a combination of excellent strength and ductile-to-brittle transition (DBT) properties are required. However, such a combination of high strength and toughness can be deteriorated in the heat affected zone (HAZ) after welding. This work aims to develop a relationship between microstructure and cleavage fracture in the most brittle areas of welded S690 high strength structures: coarse-grained and intercritically reheated coarse-grained HAZ (CGHAZ and ICCGHAZ). Gleeble thermal simulations were performed to generate three microstructures: CGHAZ and ICCGHAZ at 750 and 800 °C intercritical peak temperatures. Their microstructures were characterised, and the tensile and fracture properties were investigated at − 40 °C, where cleavage is dominant. Results show that despite the larger area fraction of martensite-austenite (M-A) constituents in ICCGHAZ 750 °C, the CGHAZ is the zone with the lowest fracture toughness. Although M-A constituents are responsible for triggering fracture, their small size (less than 1 μm) results in local stress that is insufficient for fracture. Crack propagation is found to be the crucial fracture step. Consequently, the harder auto-tempered matrix of CGHAZ leads to the lowest fracture toughness. The main crack propagates transgranularly, along {100} and {110} planes, and neither the necklace structure at prior austenite grain boundaries of ICCGHAZs nor M-A constituents are observed as preferential sites for crack growth. The fracture profile shows that prior austenite grain boundaries and other high-angle grain boundaries (e.g., packet and block) with different neighbouring Bain axes can effectively divert the cleavage crack. Moreover, M − A constituents with internal sub-structures, which have high kernel average misorientation and high-angle boundaries, are observed to deflect and arrest the secondary cracks. As a result, multiple pop-ins in load-displacement curves during bending tests are observed for the investigated HAZs.

Effect of microstructure on the mechanical properties and corrosion resistance of a welded joint of 620-grade marine steel

The relationship between the microstructure and the mechanical and corrosion properties of a welded joint of 620-grade marine steel was studied using metallographic microscopy, scanning electron microscopy, an energy dispersive spectrometer, transmission electron microscopy, and microhardness and tensile tests. The results showed that the strength and hardness of the weld center area (WMmid) were higher than those of the inner and outer welding surface region (WMin and WMout) because the volume fraction of the martensite-austenite (MA) constituents (21.6%) was higher than that in WMin and WMout (18.0% and 14.3%, respectively). There were numerous MnO-Al2O3-SiO2-TiO2-type inclusions located at the bottom of dimples in the fracture surface; however, the MA constituents took precedence over this kind of inclusion in inducing pitting corrosion. In contrast, pitting corrosion can be initiated by Al2O3-MgO-CaO-CaS inclusions in the heat-affected zone (HAZ) and base metal (BM). The corrosion resistance of the welded joint was in the order of weld metal > HAZ > BM. The WMmid with smaller dendrite spacing and a larger size of MA constituents had better corrosion resistance compared with the WMin and WMout. The corrosion resistance of the HAZ decreased in the sequence of coarse grain HAZ, fine grain HAZ, and intercritical HAZ.

Strain ageing embrittlement behaviour of X80 self-shielded flux-cored girth weld metal

ABSTRACT Strain ageing embrittlement behaviour of X80 self-shielded flux-cored arc welding (FCAW) girth weld metal at different strain ageing conditions (1% prestrain, and aged at 150°C/100°C for 1 –6 h, and 80°C for 1–30 days) was studied. Microstructure of FCAW girth weld generally consisted of coarse granular bainite and lath bainite. After strain ageing, toughness notably decreased, and higher ageing temperature or longer ageing induced lower toughness, until ageing is fully yielded. At initial stage of strain ageing, more dimples were found accompanying with cleavage facet. With the progress of strain ageing, the embrittlement was more obvious, while larger cleavage facet and less dimples were found. Meanwhile, the critical size for cleavage fracture initiation site became smaller. Martensite–austenite constituent (1–2 μm) was found to initiate cleavage fracture when partially strain aged, while submicron inclusions could initiate cleavage facet when fully strain aged.

Effect of Ce on inclusion, microstructure and mechanical properties of Al-killed high-strength steel

ABSTRACT The effect of Ce on inclusion evolution in the Al-killed high-strength steel is investigated through experimental observations and thermodynamic calculations. The microstructures are analysed by scanning electron microscope (SEM), optical microscope (OM) and electron backscattered diffraction (EBSD) analysis. Mechanical properties tests are carried out to study the effect of Ce on the tensile and impact properties. The results show that after Ce treatment, the typical inclusions are modified from Al2O3 inclusions and Al2O3+MnS complex inclusions to Ce-O-S inclusions, and the inclusions are refined. The area fraction, size and length/width ratio of martensite-austenite (M-A) constituents decrease with the addition of Ce. In the Ce-containing steel, the grains are finer, and the proportion of high angle grain boundaries and low-Σ coincidence site lattice boundaries is higher. Ce can improve the plasticity and impact toughness of the steel while maintaining high strength.

Microstructure characteristics and mechanical properties of deposited metals with different types of bainite

In this work, three types of bainite microstructure have been gained in the deposited metals by adjusting the Ni content (1 wt %, 2.5 wt %, and 4 wt %). The microstructure feature of different types of bainite has been characterized by optical microscope, scanning electron microscope, transmission electron microscope, and electron backscattering diffraction. Microstructure changed from granular bainite with different morphology to lath bainite with the increase of Ni content. The number of elongated Martensite-Austenite constituents in granular bainite increased with the increasing Ni content from 1 wt % to 2.5 wt % due to the increase in hardenability. The complex orientation in the deposited metal with 4 wt % Ni content attributed to the numerous autocatalytic nucleation occurrence during the bainite transformation. After crystallographic characterization, the bainite variant selection tendency decreased with the bainite type change from granular bainite to lath bainite with autocatalytic nucleation, and the density of high-angle grain boundaries increases obviously. The deposited metal with numerous autocatalytic nucleation has an outstanding match of high strength and excellent low-temperature toughness due to the effective grain-refinement strengthening. The large-sized elongated Martensite-Austenite constituents in the deposited metals with 1 wt % and 2.5 wt % Ni contents deteriorate low-temperature toughness in two aspects, promoting crack nucleation and reducing the crack propagation resistance. Interlaced bainite is the most optimized among different bainite types. This work guides the microstructure design in high-strength deposited metals.

Microstructure and mechanical behavior of AISI 4340 steel fabricated via spark plasma sintering and post-heat treatment

We investigated the evolution of microstructure and mechanical properties AISI 4340 steel during high-energy ball milling, spark plasma sintering (SPS), and post heat treatments. High-energy ball milling of the powder mixture led to the formation of a nanocrystalline (∼10 nm) bcc Fe matrix containing some segregation of alloying elements and oxide particles. As-sintered alloy consisted of martensite-austenite (MA) constituent and fine pearlite with an average grain size of 2.4 μm along with oxide particles and M23C6 particles. The quenching after austenitization formed a microstructure composed of martensite and MA constituent, thereby increasing the fraction of retained austenite and decreasing the average grain size (∼0.5 μm) compared to the as-sintered alloy. The M23C6 particles were fully dissolved at the high austenitization temperature, leading to the increase in retained austenite fraction after quenching. Tempering induced decomposition of retained austenite and precipitation of cementite particles, while it has negligible effects on the grain size, undissolved M23C6 particles, and oxide particles. As-sintered alloy exhibited a compressive yield strength of ∼2 GPa due to primary strengthening by dislocations and grain boundaries/cementite lamellae and secondary strengthening by oxide particles. Changes in dislocation strengthening played a dominant role in determining the yield strength of quenched and tempered steels.

Formation of a Martensite-Austenite Constituent in Х65 Low-Carbon Steel Under Thermomechanical Treatment and Welding

Formation of a Martensite-Austenite Constituent in Х65 Low-Carbon Steel Under Thermomechanical Treatment and Welding

VANADIUM ALLOYING IN S355 STRUCTURAL STEEL: EFFECT ON RESIDUAL AUSTENITE FORMATION IN WELDED JOINTS HEAT AFFECTED ZONE

The inter-critical heat affected zone (ICHAZ) appears to be one of the most brittle sections in the welding of high-strength micro-alloy steels (HSLA). Following multiple heating cycles in the temperature range between Ac1 and Ac3, the ICHAZ undergoes a strong loss of toughness and fatigue resistance, mainly caused by the formation of martensite-austenite constituent (MA). The presence of micro-alloying elements in HSLA steels induces variations in the formation of some microstructural constituents, more or less beneficial, which allow to improve the mechanical performance of a welded joint. The behavior in the inter-critical region of a S355 grade steel with 0.1wt% V addition is reported in this paper. Five double-pass welding thermal cycles were simulated using a dilatometer, with the maximum temperature of the secondary peak in the inter-critical area, in the range between 720 ° C and 790 ° C. The residual austenite dependence on inter-critical temperature is analyzed and related to the hardness behavior.