Marine Sediment Cores Research Articles

Cryptotephra from Lipari Volcano in the eastern Gulf of Taranto (Italy) as a time marker for paleoclimatic studies

AbstractWe present the first tephroanalysis based on geochemical fingerprinting of volcanic glass shards from eastern Apulian shelf sediments in the Gulf of Taranto (Italy). High sedimentation rates in the gulf are ideal for high-resolution paleoclimate studies, which rely on accurate age models. Cryptotephrostratigraphy is a novel tool for the age assessment of marine sediment cores in the absence of discrete tephra layers. High-resolution quantitative analysis of glass shard abundance in the uppermost 45 cm of a gravity core identified two cryptotephras. Microprobe analysis of glass shards supported by an accelerator mass spectrometry 14C–based age model identified the pronounced primary cryptotephra at 36 cm bsf (below sea floor) as the felsic AD 776 Monte Pilato Eruption on the island of Lipari, whereas the thinner, mafic tephra layer at 1.5 cm bsf is associated with the AD 1944 eruption of Somma-Vesuvius. Identifying these tephra layers provides an additional, 14C-independent, stratigraphic framework for further paleoclimatic studies allowing us to link Mediterranean climate and hydrology to orbital variation and large-scale atmospheric processes. Our results underline the importance of qualitative tephrostratigraphy in a highly geodynamic region, where solely quantitative approaches have demonstrated to bear a high potential for false correlations between tephra layers and eruptions.

Precession and atmospheric CO2 modulated variability of sea ice in the central Okhotsk Sea since 130,000 years ago

Recent reduction in high-latitude sea ice extent demonstrates that sea ice is highly sensitive to external and internal radiative forcings. In order to better understand sea ice system responses to external orbital forcing and internal oscillations on orbital timescales, here we reconstruct changes in sea ice extent and summer sea surface temperature (SSST) over the past 130,000 yrs in the central Okhotsk Sea. We applied novel organic geochemical proxies of sea ice (IP25), SSST (TEXL86) and open water marine productivity (a tri-unsaturated highly branched isoprenoid and biogenic opal) to marine sediment core MD01-2414 (53°11.77′N, 149°34.80′E, water depth 1123 m). To complement the proxy data, we also carried out transient Earth system model simulations and sensitivity tests to identify contributions of different climatic forcing factors. Our results show that the central Okhotsk Sea was ice-free during Marine Isotope Stage (MIS) 5e and the early-mid Holocene, but experienced variable sea ice cover during MIS 2–4, consistent with intervals of relatively high and low SSST, respectively. Our data also show that the sea ice extent was governed by precession-dominated insolation changes during intervals of atmospheric CO2 concentrations ranging from 190 to 260 ppm. However, the proxy record and the model simulation data show that the central Okhotsk Sea was near ice-free regardless of insolation forcing throughout the penultimate interglacial, and during the Holocene, when atmospheric CO2 was above ∼260 ppm. Past sea ice conditions in the central Okhotsk Sea were therefore strongly modulated by both orbital-driven insolation and CO2-induced radiative forcing during the past glacial/interglacial cycle.

First identification and characterization of Borrobol-type tephra in the Greenland ice cores: new deposits and improved age estimates.

ABSTRACTContiguous sampling of ice spanning key intervals of the deglaciation from the Greenland ice cores of NGRIP, GRIP and NEEM has revealed three new silicic cryptotephra deposits that are geochemically similar to the well‐known Borrobol Tephra (BT). The BT is complex and confounded by the younger closely timed and compositionally similar Penifiler Tephra (PT). Two of the deposits found in the ice are in Greenland Interstadial 1e (GI‐1e) and an older deposit is found in Greenland Stadial 2.1 (GS‐2.1). Until now, the BT was confined to GI‐1‐equivalent lacustrine sequences in the British Isles, Sweden and Germany, and our discovery in Greenland ice extends its distribution and geochemical composition. However, the two cryptotephras that fall within GI‐1e ice cannot be separated on the basis of geochemistry and are dated to 14358 ± 177 a b2k and 14252 ± 173 a b2k, just 106 ± 3 years apart. The older deposit is consistent with BT age estimates derived from Scottish sites, while the younger deposit overlaps with both BT and PT age estimates. We suggest that either the BT in Northern European terrestrial sequences represents an amalgamation of tephra from both of the GI‐1e events identified in the ice‐cores or that it relates to just one of the ice‐core events. A firm correlation cannot be established at present due to their strong geochemical similarities. The older tephra horizon, found within all three ice‐cores and dated to 17326 ± 319 a b2k, can be correlated to a known layer within marine sediment cores from the North Iceland Shelf (ca. 17179‐16754 cal a BP). Despite showing similarities to the BT, this deposit can be distinguished on the basis of lower CaO and TiO2 and is a valuable new tie‐point that could eventually be used in high‐resolution marine records to compare the climate signals from the ocean and atmosphere.

Late Quaternary environmental dynamics inferred from marine sediment core GeoB6211-2 off southern Brazil

Vegetation and climate changes in southern Brazil, as well as the dynamics of the adjacent South Atlantic were investigated through the analyses of pollen, spores and dinocysts from marine sediment core GeoB6211-2 that covers the last 19.3 kyr. The pollen record indicates the dominance of grassland (campos) in southeastern South America (SESA), reflecting cold and/or dry conditions during the Last Glacial Maximum. Forests, mainly gallery forests, expanded slightly during Heinrich Stadial 1, suggesting slightly wetter conditions. A stronger expansion of the Atlantic lowland rainforest is noticed in the record after ca. 5.5 cal kyr BP, likely due to wetter conditions. The relatively high amount of exotic Nothofagus pollen, transported by wind, rivers and then by oceanic currents northwards to the study site, as well as the dinocyst Brigantedinium spp., indicate a noticeable influence of the Brazilian Coastal Current from the south between 19.3 and 14.8 cal kyr BP. After that, the decrease in Nothofagus and Brigantedinium spp. together with the increase in dinocyst Operculodinium centrocarpum indicate that the Brazil Current from the north dominated the coring site. The abundance of freshwater algae between ca. 19.3 and 17.0 cal kyr BP suggests that the Rio de la Plata mouth was located close to the coring site during this period, and its discharge of nutrient-rich freshwaters strongly affected the upper water column. Sea level rise decreased this impact during the late glacial phase by moving the coastline further away from the core site. The presence of the Brazil Current at the core site became stronger after ca. 15 cal kyr BP and strongest after 9 cal kyr BP. In summary, the pollen, spores and dinocyst records from core GeoB6211-2 provide important climatic records to reconstruct the environmental changes in SESA.

An improved method for quantitatively measuring the sequences of total organic carbon and black carbon in marine sediment cores

Understanding global carbon cycle is critical to uncover the mechanisms of global warming and remediate its adverse effects on human activities. Organic carbon in marine sediments is an indispensable part of the global carbon reservoir in global carbon cycling. Evaluating such a reservoir calls for quantitative studies of marine carbon burial, which closely depend on quantifying total organic carbon and black carbon in marine sediment cores and subsequently on obtaining their high-resolution temporal sequences. However, the conventional methods for detecting the contents of total organic carbon or black carbon cannot resolve the following specific difficulties, i.e., (1) a very limited amount of each subsample versus the diverse analytical items, (2) a low and fluctuating recovery rate of total organic carbon or black carbon versus the reproducibility of carbon data, and (3) a large number of subsamples versus the rapid batch measurements. In this work, (i) adopting the customized disposable ceramic crucibles with the microporecontrolled ability, (ii) developing self-made or customized facilities for the procedures of acidification and chemothermal oxidization, and (iii) optimizing procedures and carbon-sulfur analyzer, we have built a novel Wang-Xu-Yuan method (the WXY method) for measuring the contents of total organic carbon or black carbon in marine sediment cores, which includes the procedures of pretreatment, weighing, acidification, chemothermal oxidation and quantification; and can fully meet the requirements of establishing their highresolution temporal sequences, whatever in the recovery, experimental efficiency, accuracy and reliability of the measurements, and homogeneity of samples. In particular, the usage of disposable ceramic crucibles leads to evidently simplify the experimental scenario, which further results in the very high recovery rates for total organic carbon and black carbon. This new technique may provide a significant support for revealing the mechanism of carbon burial and evaluating the capacity of marine carbon accumulation and sequestration.

Increased Amazon freshwater discharge during late Heinrich Stadial 1

The temporal succession of changes in Amazonian hydroclimate during Heinrich Stadial 1 (HS1) (ca. 18–14.7 cal ka BP) is currently poorly resolved. Here we present HS1 records based on isotope, inorganic and organic geochemistry from a marine sediment core influenced by the Amazon River discharge. Our records offer a detailed reconstruction of the changes in Amazonian hydroclimate during HS1, integrated over the basin. We reconstructed surface water hydrography using stable oxygen isotopes (δ18O) and Mg/Ca-derived paleotemperatures from the planktonic foraminifera Globigerinoides ruber, as well as salinity changes based on stable hydrogen isotope (δD) of palmitic acid. We also analyzed branched and isoprenoid tetraether concentrations, and compared them to existing bulk sediment ln(Fe/Ca) data and vegetation reconstruction based on stable carbon isotopes from n-alkanes, in order to understand the relationship between continental precipitation, vegetation and sediment production. Our results indicate a two-phased HS1 (HS1a and HS1b). During HS1a (18–16.9 cal ka BP), a first sudden increase of sea surface temperatures (SST) in the western equatorial Atlantic correlated with the slowdown of the Atlantic Meridional Overturning Circulation (AMOC) and the associated southern hemisphere warming phase of the bipolar seesaw. This phase was also characterized by an increased delivery of terrestrial material. During HS1b (16.9–14.8 cal ka BP), a decrease in terrestrial input was, however, associated with a marked decline of seawater δ18O and palmitic acid δD. Both isotopic proxies independently indicate a drop in sea surface salinity (SSS). A number of records under the influence of the North Brazil Current, in contrast, indicate increases in SST and SSS resulting from a weakened AMOC during HS1. Our records thus suggest that the expected increase in SSS due to the AMOC slowdown was overridden by a two-phased positive precipitation anomaly in Amazonian hydroclimate.

Diversity of Microbial Communities and Quantitative Chemodiversity in Layers of Marine Sediment Cores from a Causeway (Kaichu-Doro) in Okinawa Island, Japan.

Microbial community diversity and chemodiversity were investigated in marine sediments adjacent to the Okinawan “Kaichu-Doro” Causeway, which was constructed 46 years ago to connect a group of four islands (Henza-jima, Miyagi-jima, Ikei-jima, Hamahiga-jima) to the Okinawan main island. This causeway was not built on pilings, but by land reclamation; hence, it now acts as a long, thin peninsula. The construction of this causeway was previously shown to have influenced the surrounding marine ecosystem, causing ecosystem fragmentation and loss of water circulation. In this study, we collected sediment cores (n = 10) from five paired sites in 1 m water depths. Each pair of sites consisted of one site each on the immediate north and south sides of the causeway. Originally the members of each pair were much closer to each other (<150 m) than to other pairs, but now the members of each pair are isolated by the causeway. Each core was 60–80 cm long and was divided into 15-cm layers. We examined the vertical diversity of microbial communities and chemical compounds to determine the correlation between chemodiversity and microbial communities among marine sediment cores and layers. Principal coordinate analyses (PCoA) of detected compounds and of bacterial and archaeal operational taxonomic units (OTUs) revealed that the north and south sides of the causeway are relatively isolated, with each side having unique microbial OTUs. Additionally, some bacterial families (e.g., Acidaminobacteraceae, Rhizobiaceae, and Xanthomonadaceae) were found only on the south side of Kaichu-Doro. Interestingly, we found that the relative abundance of OTUs for some microbial families increased from top to bottom, but this was reversed in some other families. We conclude that the causeway has altered microbial community composition and metabolite profiles in marine sediments.

Late-Holocene dynamics of sea-surface temperature and terrestrial hydrology in southwestern Africa

Southwest Africa is an important region for paleo-climatic studies, being influenced by both tropical and temperate climate systems and thus reflecting the interplay of variable controls. The aim of this study was to unravel the interaction of sea-surface temperature (SST) changes in the southernmost Benguela upwelling system with precipitation changes in South Africa’s winter rainfall zone (WRZ) during the late Holocene. Therefore, a marine sediment core from the southernmost Benguela upwelling system was investigated to reconstruct climate changes in this region for the past ~2000 years. Grain size and geochemical analyses were conducted to reconstruct changes in fluvial sediment discharge and weathering intensity, while SST changes were estimated using alkenone paleo-thermometry. Results show that the southernmost Benguela behaves distinctly in comparison with the rest of the Benguela system reflecting amplified SST changes. Decreasing SSTs accompanied increasing river discharge during times of increased precipitation in the WRZ, reflecting northerly shifted westerly winds during austral winter. We infer a control of past SST changes by processes not analogous to modern processes driving seasonal SST changes by changes through upwelling intensity. The findings suggest that late-Holocene SST changes in the southernmost Benguela upwelling system and the precipitation in the WRZ were both driven by latitudinal shifts of the austral westerly wind belt and associated changes in advection of cold sub-Antarctic waters and/or changes in Agulhas leakage of warm Indian Ocean waters.

Assimilating the ICE‐6G_C Reconstruction of the Latest Quaternary Ice Age Cycle Into Numerical Simulations of the Laurentide and Fennoscandian Ice Sheets

We analyze the effects of nudging 100 kyr numerical simulations of the Laurentide and Fennoscandian ice sheets toward the glacial isostatic adjustment‐based (GIA‐based) ICE‐6G_C reconstruction of the most recent ice age cycle. Starting with the ice physics approximations of the PISM ice sheet model and the SeaRISE simulation protocols, we incorporate nudging at characteristic time scales, τf, through anomalous mass balance terms in the ice mass conservation equation. As should be expected, these mass balances exhibit physically unrealistic details arising from pure GIA‐based reconstruction geometry when nudging is very strong (τf=20 years for North America), while weakly nudged (τf=1,000 years) solutions deviate from ICE‐6G_C sufficiently to degrade its observational fit quality. For reasonable intermediate time scales (τf=100 years and 200 years), we perturbatively analyze nudged ice dynamics as a superposition of “leading‐order smoothing” that diffuses ICE‐6G_C in a physically and observationally consistent manner and “higher‐order” deviations arising, for instance, from biases in the time dependence of surface climate boundary conditions. Based upon the relative deviations between respective nudged simulations in which these biases follow surface temperature from ice cores and eustatic sea level from marine sediment cores, we compute “ice core climate adjustments” that suggest how local paleoclimate observations may be applied to the systematic refinement of ICE‐6G_C. Our results are consistent with a growing body of evidence suggesting that the geographical origins of Meltwater Pulse 1B (MWP1b) may lie primarily in North America as opposed to Antarctica (as reconstructed in ICE‐6G_C).

Lateglacial retreat chronology of the Scandinavian Ice Sheet in Finnmark, northern Norway, reconstructed from surface exposure dating of major end moraines

We report results from a comprehensive surface exposure dating campaign in eastern Finnmark, located in the northernmost part of Norway and close to the Norwegian-Russian border. This is a palaeo-glaciologically important region as it sits near the proposed border-zone between the former Scandinavian and Barents Sea Ice Sheets. However, until now the deglaciation history has few direct dates onshore and the chronology of ice front retreat is instead found by correlating ice-marginal deposits with isostatically raised shorelines and marine sediment cores. We measured the content of 10Be (N = 22) and 36Cl (N = 17) from boulders located at the crest of major moraine ridges at four localities; Kjæs, Kongsfjorden, Vardø and Kirkenes. These are key localities of existing regional reconstructions of ice recession in this area. Despite some spread in age results from each locality due to methodological challenges associated with surface exposure dating, the large numbers of samples from each site except Kjæs still allow for obtaining clusters of similar ages which are used for arriving at a likely chronology of ice front retreat. Our results show that the Kongsfjorden and Vardø moraines were deposited 14.3 ± 1.7 ka and 13.6 ± 1.4 ka, respectively, and thus point to a Older Dryas age of the proposed ‘Outer Porsanger’ deglaciation sub-stage. Moraine ridges belonging to the ‘Main’ sub-stage near Kirkenes were dated to 11.9 ± 1.2 ka, corresponding well with the ice retreat chronology farther west in northern Norway and suggesting that the maximum Younger Dryas ice sheet extent was attained in the late Younger Dryas along a more than 500 km long stretch in northernmost Scandinavia.

Identifying past petroleum exploration related drill cutting releases and influences on the marine environment and benthic foraminiferal communities, Goliat Field, SW Barents Sea, Norway

The present multiproxy investigation of marine sediment cores aims at: 1) Identifying dispersion of petroleum exploration related drill cutting releases within the Goliat Field, Barents Sea in 2006/07 and 2) Assessing past and present influence of drill cuttings on the marine environment. The cores were recovered 5, 30, 60, 125 and 250m from the drill site in the eastward downstream direction.Downstream dispersion of drill cuttings is evaluated by examining sediment grain size distribution and barium (Ba), heavy metal, total organic carbon and sulphur concentrations. Dispersion of drill cuttings was limited to <125m east from the drill site. Influence of drill cutting releases on the marine environment is assessed via microfaunal analysis of primarily calcareous benthic foraminifera. The findings suggest contemporaneous physical smothering at ≤30m from the drill site, with a natural fauna reestablishing after drilling cessation indicating no long-term effect of drill cutting releases.

Natural and artificial radionuclides in a marine core. First results of 236U in North Atlantic Ocean sediments

There are very few data available of 236U in marine sediment cores. In this study we present the results from the first oceanic depth profile of 236U in a sediment core sampled in the North Atlantic Ocean, at the PAP site (4500 m depth, Porcupine Abyssal Plain (PAP) site, 49°0′ N, 16°30′ W). Additionally, the sediment core was radiologically characterized through the measurement of anthropogenic 137Cs, 239Pu, 240Pu, 129I and 14C and natural 210Pb, 40K and 226Ra.The measured 236U concentrations decrease from about 90·106 at g−1 at the seafloor down to 0.5·106 at g−1 at 6 cm depth. They are several orders of magnitude lower than the reported values for soils from the Northern Hemisphere solely influenced by global fallout (i.e. from 2700·106 to 7500·106 at g−1). 236U/238U atom ratios measured are at least three orders of magnitude above the estimated level for the naturally occurring dissolved uranium. The obtained inventories are 1·1012 at m−2 for 236U, 80 Bq m−2 for 137Cs, 45 Bq m−2 for 239+240Pu and 2.6·1012 at m−2 for 129I. Atomic ratios for 236U/239Pu, 137Cs/236U and 129I/236U, obtained from the inventories are 0.036, 0.11 and 2.5 respectively. Concentration profiles show mobilization probably due to bioturbation from the abundant detritivore holothurian species living at the PAP site sea-floor. The range of 236U, 137Cs, 239+240Pu and 129I values, inventories and ratios of these anthropogenic radionuclides are more similar to the values due to fall-out than values from a contribution from the Nuclear Fuel Reprocessing Plants dispersed to the south-west of the North Atlantic Ocean. However, signs of an additional source are detected and might be associated to the nuclear wastes dumped on the Eastern North Atlantic Ocean.

Hydrographic variability in the northern South China Sea over the past 45,000 years: New insights based on temperature reconstructions by Uk’37 and TEXH86 proxies from a marine sediment core (MD972146)

Millennial-scale climate variability was persistent feature for Greenland ice core and North Atlantic marine records during the Marine Isotope Stage (MIS) 3. Studying high quality climatic archives outside of the Greenland and North Atlantic with precise constraint of absolute dating and high resolution sampling is a prerequisite to understand how the millennial-scale changes well expressed in North Hemisphere (NH) high latitudes had been propagated out to the other regions. Here, we generated the surface and subsurface hydrography (Uk’37 and TEXH86 temperatures) and terrestrial material input (n-alkanes) records with precise AMS 14C dated control for the 45 ka from a core (MD972146) retrieved from the northern South China Sea (SCS). Then, we compared our records to the oxygen isotope record from a Greenland NGRIP ice core, and the mean grain size record from a loess sequence at Gulang, China. We found that the millennial-scale oscillations of hydrolography and terrestrial material inputs records during the time since the last deglaciation and of ∼33–45 ka share similar patterns in timing and amplitude of the NH high latitude climate. However, we found that a non-NH pattern of millennial-scale oscillations for the late MIS 3, ∼20–33 ka of our hydrography and terrestrial material inputs records. Our studies imply that the changes of obliquity also may be important in determining the timing and amplitude of millennial-scale East Asian Monsoon (EAM) variability expressed in the northern SCS hydrography and terrestrial material inputs.

Late Holocene shift towards enhanced oceanic variability in a high-Arctic Svalbard fjord (79°N) at 2500 cal. yr BP

Paleoclimate records are crucial for understanding current changes taking place in the Arctic, e.g., the amplified warming and associated changes in sea-ice cover. However, paleoclimate and -oceanographic reconstructions, especially from the high Arctic, are scarce. Here, we present a reconstruction of sea surface and paleoenvironmental conditions from a Holocene marine sediment core collected from a high-Arctic fjord, Isvika Bay, Nordauslandet, Svalbard (79°N). Our proxies include qualitative diatom assemblage data [focusing on the Marginal Ice Zone (MIZ) taxa], a quantitative diatom-based August sea surface temperature (aSST) reconstruction, sediment grain-size distribution, and ice-rafted debris (IRD) spanning the period from 4200 cal. yr BP to the Little Ice Age (LIA) at ca. 200 cal. yr BP. The results reveal cold and stable, glacier-proximal conditions for the beginning of the late Holocene (from 4200 to 2500 cal. yr BP). Then, at 2500 cal. yr BP, the environment shifted into distinctly more fluctuating conditions, where colder and warmer aSSTs alternated in a glacier-distal environment. During the latter part of the late Holocene, sea-ice cover was extensive, yet variable, negatively co-varying with aSST. Based on our diatom data, we observe a clear increase in the influence of Atlantic water in Isvika Bay during the last ca. 600 years.

Response of the Amazon rainforest to late Pleistocene climate variability

Variations in Amazonian hydrology and forest cover have major consequences for the global carbon and hydrological cycles as well as for biodiversity. Yet, the climate and vegetation history of the lowland Amazon basin and its effect on biogeography remain debated due to the scarcity of suitable high-resolution paleoclimate records. Here, we use the isotopic composition (δD and δ13C) of plant-waxes from a high-resolution marine sediment core collected offshore the Amazon River to reconstruct the climate and vegetation history of the integrated lowland Amazon basin for the period from 50,000 to 12,800 yr before present. Our results show that δD values from the Last Glacial Maximum were more enriched than those from Marine Isotope Stage (MIS) 3 and the present-day. We interpret this trend to reflect long-term changes in precipitation and atmospheric circulation, with overall drier conditions during the Last Glacial Maximum. Our results thus suggest a dominant glacial forcing of the climate in lowland Amazonia. In addition to previously suggested thermodynamic mechanisms of precipitation change, which are directly related to temperature, we conclude that changes in atmospheric circulation are crucial to explain the temporal evolution of Amazonian rainfall variations, as demonstrated in climate model experiments. Our vegetation reconstruction based on δ13C values shows that the Amazon rainforest was affected by intrusions of savannah or more open vegetation types in its northern sector during Heinrich Stadials, while it was resilient to glacial drying. This suggests that biogeographic patterns in tropical South America were affected by Heinrich Stadials in addition to glacial–interglacial climate variability.

Influence of human activities and organic matters on occurrence of polybrominated diphenyl ethers in marine sediment core: A case study in the Southern Yellow Sea, China

The Southern Yellow Sea (SYS) is an important reservoir of anthropogenic organic contaminants, such as polybrominated diphenyl ethers (PBDEs). To reconstruct the historical records of PBDEs and examine their relationships with the human activities and organic matters, a210Pb-dated sediment core was collected from the central mud area in the SYS. The concentrations of tri-to hepta-BDEs (∑7PBDEs) and BDE-209 ranged from 9.8 to 99.8 pg g−1 d.w. and from 12.1 to 855.4 pg g−1 d.w., respectively, both displaying the increasing trends from the bottom to the surface. More importantly, there was a faster increase for PBDEs since the 1990s, especially for BDE-209, which responded well with the rapid economic growth, and the increases of urbanization and industrialization in the local areas of the SYS. The analogously vertical patterns and significant relationships between PBDEs and total organic carbon (TOC) implied the TOC-dependent deposition of PBDEs in the core. Furthermore, multiple biomarker-based proxies of terrestrial organic matter (TOM) and marine organic matter (MOM) were introduced to systematically investigate the different effects of TOM and MOM on PBDE deposition in the SYS. The similarly down-core profiles and significant correlations were found between PBDEs and the MOM proxies (sum of rassicasterol, dinosterol and C37 alkenones (∑A + B + D) and marine TOC) as well as the branched and isoprenoid tetraether (BIT), but not for TOM proxies (∑C27+C29+C31n-alkanes, terrestrial and marine biomarker ratio (TMBR) and terrestrial TOC), indicating that MOM was an important factor driving PBDE deposition in the sediment core from the SYS.

Automated counting of sand‐sized particles in marine records

AbstractContent and fluxes of ice‐transported sand‐sized and gravel‐sized, lithic particles in marine sediment cores are a common tool used to reconstruct glacial variability. Ice‐rafted debris data sets are currently acquired in several different and often time‐consuming ways, and within various grain‐size fractions. This article proposes a novel workflow using an automated method to count ice‐rafted debris to reduce analysis time and subjectivity. The described method is based on the instrument ‘Morphologi G3’ from Malvern Instruments Limited and includes all pre‐processing and post‐processing steps. This particle characterization tool is an automated microscope combined with a proprietary software package. In this study, the analysis was performed on the 150 to 1000 μm fraction. If desired, grain counts can be carried out on the entire sand and silt fractions. However, this would result in a considerably greater turnover time. A total of 350 sediment samples from core MD99‐2283, taken on the upper continental slope at the southern part of the north‐east Atlantic margin, were counted with this automated method. In addition, a total of 161 samples were counted manually as a control on the reliability of the scanning. The comparison of automated versus manually counted biogenic and lithic material shows a convincing correlation between the two methods. The turnover time per automatically counted sample is around 20 min, the method requiring less experience and skills than manual counting. The results yield a promising, time‐saving new technique to achieve high‐resolution ice‐rafted debris counting records with acceptable error margins.

Holocene glacial evolution of Mohnbukta in eastern Spitsbergen

Submarine geomorphology is one of the main tools for understanding past fluctuations of tidewater glaciers. In this study we investigate the glacial history of Mohnbukta, on the east coast of Spitsbergen, Svalbard, by combining multibeam‐bathymetric data, marine sediment cores and remote sensing data. Presently, three tidewater glaciers, Heuglinbreen, Königsbergbreen and Hayesbreen calve into Mohnbukta. Hayesbreen surged at the end of the Little Ice Age, between 1901 and 1910. The submarine landform assemblage in Mohnbukta contains two large transverse ridges, interpreted as terminal moraines, with debrisflow lobes on their distal slopes and sets of well‐preserved geometric networks of ridges, interpreted as crevasse‐squeeze ridges inshore of the moraines. The arrangement of crevasse‐squeeze ridges suggests that both landform sets were produced during surge‐type advances. The terminus position of the 1901–1910 Hayesbreen surge correlates with the inner (R.2) terminal moraine ridge suggesting that the R.1 ridge formed prior to 1901. Marine sediment cores display 14C ages between 5700–7700 cal. a BP derived from benthic foraminifera, from a clast‐rich mud unit. This unit represents pre‐surge unconsolidated Holocene sediments pushed in front of the glacier terminus and mixed up during the 1901 surge. An absence of retreat moraines in the deeper part of the inner basin and the observation of tabular icebergs calving off the glacier front during retreat suggest that the front of Hayesbreen was close to flotation, at least in the deeper parts of the basin. As the MOH15‐01 core does not penetrate into a subglacial till and the foraminifera in the samples were well preserved, the R.1 ridge is suggested to have formed prior to the deposition of the foraminifera. Based on these data we propose that a surge‐type advance occurred in Mohnbukta in the early Holocene, prior to 7700 cal. a BP, which in turn indicates that glaciers can switch to and from surge mode.

Long-term vegetation, climate and ocean dynamics inferred from a 73,500 years old marine sediment core (GeoB2107-3) off southern Brazil

Long-term changes in vegetation and climate of southern Brazil, as well as ocean dynamics of the adjacent South Atlantic, were studied by analyses of pollen, spores and organic-walled dinoflagellate cysts (dinocysts) in marine sediment core GeoB2107-3 collected offshore southern Brazil covering the last 73.5 cal kyr BP. The pollen record indicates that grasslands were much more frequent in the landscapes of southern Brazil during the last glacial period if compared to the late Holocene, reflecting relatively colder and/or less humid climatic conditions. Patches of forest occurred in the lowlands and probably also on the exposed continental shelf that was mainly covered by salt marshes. Interestingly, drought-susceptible Araucaria trees were frequent in the highlands (with a similar abundance as during the late Holocene) until 65 cal kyr BP, but were rare during the following glacial period. Atlantic rainforest was present in the northern lowlands of southern Brazil during the recorded last glacial period, but was strongly reduced from 38.5 until 13.0 cal kyr BP. The reduction was probably controlled by colder and/or less humid climatic conditions. Atlantic rainforest expanded to the south since the Lateglacial period, while Araucaria forests advanced in the highlands only during the late Holocene. Dinocysts data indicate that the Brazil Current (BC) with its warm, salty and nutrient-poor waters influenced the study area throughout the investigated period. However, variations in the proportion of dinocyst taxa indicating an eutrophic environment reflect the input of nutrients transported mainly by the Brazilian Coastal Current (BCC) and partly discharged by the Rio Itajaí (the major river closest to the core site). This was strongly related to changes in sea level. A stronger influence of the BCC with nutrient rich waters occurred during Marine Isotope Stage (MIS) 4 and in particular during the late MIS 3 and MIS 2 under low sea level. Evidence of Nothofagus pollen grains from the southern Andes during late MIS 3 and MIS 2 suggests an efficient transport by the southern westerlies and Argentinean rivers, then by the Malvinas Current and finally by the BCC to the study site. Major changes in the pollen/spore and dinocyst assemblages occur with similar pacing, indicating strongly interlinked continental and marine environmental changes. Proxy comparisons suggest that the changes were driven by similar overarching factors, of which the most important was orbital obliquity.

SedCT: MATLAB™ tools for standardized and quantitative processing of sediment core computed tomography (CT) data collected using a medical CT scanner

AbstractComputed tomography (CT) of sediment cores allows for high‐resolution images, three‐dimensional volumes, and down core profiles. These quantitative data are generated through the attenuation of X‐rays, which are sensitive to sediment density and atomic number, and are stored in pixels as relative gray scale values or Hounsfield units (HU). We present a suite of MATLAB™ tools specifically designed for routine sediment core analysis as a means to standardize and better quantify the products of CT data collected on medical CT scanners. SedCT uses a graphical interface to process Digital Imaging and Communications in Medicine (DICOM) files, stitch overlapping scanned intervals, and create down core HU profiles in a manner robust to normal coring imperfections. Utilizing a random sampling technique, SedCT reduces data size and allows for quick processing on typical laptop computers. SedCTimage uses a graphical interface to create quality tiff files of CT slices that are scaled to a user‐defined HU range, preserving the quantitative nature of CT images and easily allowing for comparison between sediment cores with different HU means and variance. These tools are presented along with examples from lacustrine and marine sediment cores to highlight the robustness and quantitative nature of this method.