Abstract Electromagnetic wave absorbing materials are particularly important in modern electronics, especially in the fields of stealth and communications. Carbon-based materials show great promise in the production and application of efficient wave-absorbing materials due to their rich structure, ultra-light weight, good corrosion resistance, and low cost. Among them, nitrogen-doped carbon-based two-dimensional materials have a stronger depletion effect on electromagnetic waves due to their higher specific surface area and abundant polarization states. In this article, nitrogen-doped carbon 2D flakes (NC) were successfully synthesized by a hydrothermal method. Furthermore, Fe single atoms were successfully loaded onto their surfaces, creating Fe@NC. The wave-absorbing properties of Fe@NC samples were significantly enhanced, with the minimum reflection loss (RLmin) reaching -69.22 dB at 11.48 GHz and the effective absorption bandwidth (EAB) extending to 5.79 GHz. The enhancement of electromagnetic wave absorption is attributed to the synergistic effects of magnetic loss, relaxation processes, dipole polarization, and electrical conduction loss. The successful preparation of Fe@NC offers new possibilities for the development of atomically dispersed wave-absorbing materials.
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