Magnesium Zinc Research Articles

Biological Applications of Ore Materials: Chili Absorption of Natural MG and ZN Ions Released from Modified Serpentinite Powders

Introduction: This study investigated the characteristics of the powder, the concentration of the ions, and the growth characteristics of Chili that were irrigated with the natural magnesium– zinc ionised water. The findings revealed that the ion dissolution rate was higher for greater water temperatures. Methods: Extended sintering of the zinc-modified natural serpentinite powder at 400°C reduced the number of dissolved magnesium ions and increased the number of dissolved zinc ions. The Chili planting experiment was performed with two groups: 1) Chili irrigated with natural magnesium– zinc ionised water (natural magnesium–zinc Chili) and 2) Chili irrigated with distilled water (distilled-water Chili). Results: The natural magnesium–zinc Chilis were discovered to have higher concentrations of magnesium and zinc ions in various parts. Furthermore, during the later stages of growth, the natural magnesium–zinc Chili had a larger body and did not easily turn yellow, resulting in better freshness. This study used modified serpentine powder to cultivate natural magnesium–zinc Chili. Appropriate powder roasting conditions and the rates of magnesium and zinc dissolution were established, and the growth characteristics of natural magnesium–zinc Chili were determined. Conclusion: The Chilis can help humans ensure healthy lives and promote well-being for all at all ages by sufficient zinc and magnesium intake.

Dy3+ doped Zn0.66Mg0.3Al2O4 nanophosphor for high dose radiation thermoluminescence dosimetric applications

Zinc Magnesium Aluminate doped with Dysprosium (Zn (1-x-y) Mg(y)Al2O4:x Dy (x=0.04 and y=0.3 mol%)) was prepared using the solution combustion synthesis method. The prepared phosphor was characterized using energy-dispersive X-ray spectroscopy, scanning electron microscopy, X-ray diffraction, transmission electron microscopy, and Fourier transform infrared, respectively, to study crystal structure, surface morphology, and vibrational properties. The thermoluminescence peak temperatures were 250°C, 248°C, and 246°C at irradiating doses of 600–1000 Gy, respectively. Through the computation of the activation energy (E), order of kinetics (b), and frequency factor (s−1), the kinetic parameters were assessed using the TL glow curve. It is observed from the TL dose-response curve that the intensity rises nearly linearly for all doses between 600 and 1000 Gy. Nanophosphor Zn0.66Mg0.3Al2O4:0.04Dy shows almost linear dose-response for a dose range of 600–1000 Gy and an optimum activation energy (E) of 0.93–0.97 eV, which makes it suitable for high-dose radiation thermoluminescence dosimetric applications.

Role of cerium dopant in tuning the semiconductor-to-metal transition properties of magnesium zinc ferrite nanomaterials

In this research work, Magnesium zinc ferrite (CexMgZn1-xFe2O4) nanomaterials have been synthesized with various cerium concentrations (x = 0, 0.05, 0.1, 0.15) using the coprecipitation method. With no deformation as per structural analysis, cerium ions are doped in the spinel lattice of MgZnFe2O4 nanomaterials. The undoped MgZnFe2O4 with initial flake-like morphology is changed to cube-like shapes upon Ce (x = 0.15) addition. The DC resistivity exhibits a varying pattern in both ferromagnetic and paramagnetic regions as temperature increases. Furthermore, the samples with x = 0.15 exhibit a high resistivity on the order of 1.09∗1010 Ω cm, and an activation energy of 0.909 eV. The dielectric properties, such as dielectric constant, dielectric losses, and impedance, exhibit a progressive drop as the frequency increases from 1 MHz to 2 MHz. Furthermore, dielectric parameters reach their lowest value in the dopant x = 0.1. The highest Q values for x = 0.05 and 0.15 indicate that the mentioned materials are most suitable for use in high-frequency devices, likewise multi-layer chip inductors and resonant circuits. Growth inhibition of two types of bacterial extracts (E.Coli and S. aureus) has been studied. Results revealed MgZnFe2O4 enhanced growth inhibition against S. aureus bacteria with increasing Ce concentration, however, inhibition of E. Coli is hampered (50 % at maximum) by Ce incorporation into ferrite lattice.

Exploring the influence of Zn impurities on the structural, optical, and H2 sensor properties of ultrasonic spray pyrolysis-grown MgO thin films

Magnesium oxide (MgO) thin films, both pure and zinc (Zn) doped, were fabricated on soda lime glass substrates using ultrasonic spray pyrolysis. Zn was introduced at concentrations of 0.5 %, 1 %, 2 %, 4 %, and 8 %. The effects of these doping levels on the films' structural, morphological, optical, and H2 gas sensing properties were studied using XRD, SEM, EDAX, UV–vis spectroscopy, PL spectroscopy, gas sensing measurements, and XPS. The films showed a cubic crystal structure without secondary phases, and grain sizes generally decreased with doping. Morphological changes in nanocrystal shapes were noted due to impurities. Optimal doping enhanced MgO's absorbance, with a slight increase in bandgap. The PL spectra showed increased luminescent emissions with higher doping, due to defects from Zn ions. Pure films were responsive to H2 gas, while Zn-doped samples showed weaker responses. The XPS confirmed the expected chemical compositions.

Studies on InZnMgO amorphous buffer layer for Cu(In,Ga)(S,Se)2 solar cell

This study explores the effectiveness of an amorphous buffer layer, specifically Indium Zinc Magnesium Oxide (IZMO), as an alternative buffer in Copper Indium Gallium Sulfide Selenide (CIGSSe) solar cells. The findings reveal a significant impact on efficiency through precise adjustment of the Mg/(In+Zn+Mg) ratio (MIZM) from 0 to 0.23. The bandgap exhibits a consistent increase with an ascending Mg/(In+Zn+Mg) ratio, transitioning from 3.42 eV to 3.63 eV for IZMO prepared with Ar and from 3.18 eV to 3.53 eV for IZMO prepared with an Ar+O2 gas mixture, respectively. This rise is attributed to the augmentation of the conduction band minimum (EC) of IZMO resulting from the addition of MgO. Moreover, an increase in the Mg/(In+Zn+Mg) ratio correlates with improved conversion efficiency, escalating from 6.31 % to 9.19 %. Notably, the open-circuit voltage experiences a rise from 0.430 V to 0.520 V. This is attributed to the heightened EC of IZMO due to MgO addition, which mitigates recombination between the light-absorbing layer and the buffer layer, consequently elevating the open circuit voltage. The addition of MgO also enhances the resistance of the buffer layer, contributing to an increase in shunt resistance and a subsequent decrease in leakage current. Conversely, IZMO introduced with O2 exhibits inferior performance akin to IZO, attributable to substantial sputter damage induced by O2 introduction.

Multifunctional Bionic Periosteum with Ion Sustained-Release for Bone Regeneration.

In this study, a novel bionic periosteum (BP)-bioactive glass fiber membrane (BGFM) is designed. The introduction of magnesium ion (Mg2+) and zinc ion (Zn2+) change the phase separation during the electrospinning (ES) jet stretching process. The fiber's pore structure transitions from connected to closed pores, resulting in a decrease in the rapid release of metal ions while also improving degradation via reducing filling quality. Additionally, the introduction of magnesium (Mg) and zinc (Zn) lead to the formation of negative charged tetrahedral units (MgO4 2- and ZnO4 2-) in the glass network. These units effectively trap positive charged metal ions, further inhibiting ion release. In vitro experiments reveal that the deigned bionic periosteum regulates the polarization of macrophages toward M2 type, thereby establishing a conducive immune environment for osteogenic differentiation. Bioinformatics analysis indicate that BP enhanced bone repair via the JAK-STAT signaling pathway. The slow release of metal ions from the bionic periosteum can directly enhance osteogenic differentiation and vascularization, thereby accelerating bone regeneration. Finally, the bionic periosteum exhibits remarkable capabilities in angiogenesis and osteogenesis, demonstrating its potential for bone repair in a rat calvarial defect model.

Chemically deposited nanocrystalline ZnMgS thin film: The impact of deposition time on its structural and optical properties

This work reports the growth and characterization of nanocrystalline Zinc magnesium sulphide thin films fabricated on glass substrates using the chemical bath deposition technique. X-ray diffraction studies revealed that the as-prepared films are nanocrystalline in nature and possess a cubic phase with a preferred orientation along the (111) plane. The crystallite size increases from 18.3 to 29 nm with deposition time. The field emission scanning electron microscope micrographs showed uniform nanostructures on the film surface. The grain sizes increased from 215 to 310 nm with deposition time. EDX spectra displayed the presence of elements Zn, Mg, and S. The absorbance peak increased with deposition time and all the films had a transmittance of over 80 %. From the absorption measurements, the band gap showed an increase from 3.848 eV to 3.945 eV with deposition time. The fabricated ZnMgS thin films exhibit crucial characteristics suitable for optoelectronic devices.

Time-Resolved Mechanism of Positive Aging in InP Quantum-Dot Light-Emitting Diodes.

Positive aging has been reported to be effective for enhancing electroluminescence characteristics of quantum dot (QD) based optoelectrical devices. This study investigated the intricate mechanisms underlying the positive aging effect in quantum-dot light-emitting diodes (QLEDs) influenced by encapsulation with ultraviolet-curable resin. A 120-h analysis assessed the impact of the resin on the electron transport layer and emission layer, utilizing a strategically positioned perfluorinated ionomer (PFI) interlayer. The PFI layer effectively delayed the Al2O3 formation at the zinc magnesium oxide (ZMO)/Al interface and further reduced the interactions within the QD/ZMO interface, thereby curtailing exciton quenching at the interfaces. The time-sequential effect of positive aging demonstrated that resin encapsulation effectively passivates the ZMO surfaces after 12 h. The positive aging facilitated the reaction between aluminum and oxygen from ZMO, contributing to Al2O3 formation within 48 h of aging. Furthermore, positive aging passivated the defect states of the QD surface and the QD/ZMO interface, reducing exciton quenching at the QD or QD/ZMO interface. The enhanced electron injection and reduced exciton quenching resulted in aged InP QLEDs, exhibiting an external quantum efficiency of 12.04%. This is a significant increase from the 3.16% observed in the control device. Finally, a sequential mechanism of positive aging in InP QLEDs was devised, providing new insights into the time-related operation of aging agents. This study elucidates an advanced time-resolved mechanism of positive aging, thereby offering valuable insights into the intricate dynamics of excitons within the domain of QLED physics.

SYNTHESIS STRUCTURAL AND MAGNETIC PROPERTIES OF TITANIUM DOPED MAGNESIUM ZINC FERRITE

Magnetic ceramics or ferrites are very well established group of magnetic materials which exhibits ferrimagnetism. It possess high electrical resistivity, low eddy current and dielectric loss which makes it superior than the other ordinary magnetic oxides that contain the ferric oxide (Fe₂O₃) as their basic magnetic compounds. The ceramic magnets are widely used in high frequency transformer application. [(Mg, Mn, F12o4)] spinels are used in square-loop application. Ceramic materials found application in nuclear physics. In nuclear reactors ceramics are used as core components. The studies include the preparation and analysis of Titanium doped Magnesium zinc ferrite. Here, Titanium doped magnesium zinc ferrite nanoparticles (NPS) were synthesized using solid state reaction method. Titanium doping can enhance the magnetic properties of magnesium zinc ferrite in several ways these can contribute to improved magnetic properties , such as increased magnetic moment, saturation magnetization, and magnetic ordering , making titanium – doped magnesium zinc ferrite a promising material for various applications including magnetic storage, sensors, and spintronics. According to the stoichiometric equation [Mg0.9Zn 0.1TixFe2-xO4] at different values of x, (x=0.1, 0.3) are synthesised. Calcination and sintering of the samples is made by high temperature PID controlled muffle furnace which can go up to 1000°C. The structural and magnetic properties are examined using XRD, FTIR and Curie temperature analysis. From the XRD analysis it revels the phase structure and lattice parameters of the samples. XRD analysis gives maximum intensity of (h k l) values as (3 1 1) in both cases. It also reveals that no secondary phases are produced during growth. That means the specimens FCC stacking. FTIR analysis of the samples done using Fourier transformer infrared spectroscopy. From this analysis it revels the detailed atomic structure and bonding of the samples. The bands obtained reveal spinal ferrite structure. Curie temperature of the specimens is determined by Curie temperature apparatus for the study of magnetic properties of the specimens.

Investigation of the Thermal Effects of MgO and ZnO Nanoparticles in a Pressurized Water Reactor Coolant with Computational Fluid Dynamics Model

When nanofluids are used as reactor coolants, they provide more effective heat transfer with their increase in thermal conduction properties. This plays an important role in energy production by increasing the efficiency of nuclear reactors. The present study delves into the thermal-hydraulic ramifications of utilizing nanofluids as coolants in the VVER-1000 nuclear reactor. Specifically, the thermal-hydraulic characteristics, encompassing parameters such as coolant temperature and departure from nucleate boiling ratio, were scrutinized in light of the incorporation of magnesium oxide (MgO) and zinc oxide nanoparticles. While performing these analyses, not only uranium but also thorium was used in the core as reactor fuel. Considering the emergence of thorium as a potential fuel material in nuclear technology, its inclusion in the fuel composition contributed to the originality of the research. With the addition of 0.2% MgO nanoparticles to a VVER nuclear reactor using 5% thorium dioxide (ThO2) fuel, the coolant temperature as a result of the channel flow was determined as 617.4 K (while 613.7 K for the light water). When employing thorium fuel (with an equivalent nanoparticle concentration), the maximum temperature exhibited an approximate increase of 3 deg compared to uranium fuel. With the addition of 0.2% MgO nanoparticles, the enthalpy value at the end of the channel was 1303.6 kJ/kg when using 5% ThO2 fuel, while the enthalpy value was determined as 1295 kJ/kg in 3.7% enriched UO2 fuel. As one of the most important results of the analysis, it was observed that the temperature value of the coolant increased when nanoparticles were used.

Biodegradable magnesium and zinc composite microspheres with synergistic osteogenic effect for enhanced bone regeneration

Biodegradable polymer microspheres in bone tissue engineering have become appealing as their non-invasive advantages in irregular damage bone repair. However, current microspheres used in BTE still lack sufficient osteogenic capacity to induce effective bone regeneration. In this study, we developed osteogenic composite microspheres concurrently loaded with magnesium oxide (MgO) and zinc oxide (ZnO), both of which are osteogenic active substances, using a facile and scalable emulsification method. The osteogenic composite microspheres exhibited a sequential yet complementary release profile characterized by a rapid release of Mg2+ and a gradual release of Zn2+ in a physiological environment, thereby maintaining the concentration of bioactive ions at a sustained high level. As a result, the combination of Mg2+ and Zn2+ in the composite microspheres led to a synergistic enhancement in biomimetic mineralization and the upregulation in the expression of osteogenic-related genes and proteins at the cellular level. Through a critical-sized calvarial rate defect model, the osteogenic composite microspheres were demonstrated to have strong osteogenic ability to promote new bone formation via ultrasonic imaging, histological and immunohistochemical evaluations. In sum, these osteogenic composite microspheres as microcarriers of Mg2+ and Zn2+ have great potential in the delivery of therapeutic ions for treating bone defects.

A Study of MgZnO Thin Film for Hydrogen Sensing Application.

This research introduces a hydrogen sensor made from a thin film of magnesium zinc oxide (MgZnO) deposited using a technique called radiofrequency co-sputtering (RF co-sputtering). Separate magnesium oxide (MgO) and zinc oxide (ZnO) targets were used to deposit the MgZnO film, experimenting with different deposition times and power levels. The sensor performed best (reaching a sensing response of 2.46) when exposed to hydrogen at a concentration of 1000 parts per million (ppm). This peak performance occurred with a MgZnO film thickness of 432 nanometers (nm) at a temperature of 300 °C. Initially, the sensor's responsiveness increased as the film thickness grew. This is because thicker films tend to have more oxygen vacancies, which are imperfections that play a role in the sensor's function. However, further increases in film thickness beyond the optimal point harmed performance. This is attributed to the growth of grains within the film, which hindered its effectiveness. X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) were employed to thoroughly characterize the quality of the MgZnO thin film. These techniques provided valuable insights into the film's crystal structure and morphology, crucial factors influencing its performance as a hydrogen sensor.

Novel three-dimensional architectured ZnMgAl ternary layered double hydroxide@reduced graphene oxide nanocomposites as electrode material for high-performance supercapacitor

Ternary layered double hydroxides (LDH) have recently attracted immense attention owing to their stupendous features, such as fine compositional tuning, multiple valence states, and superior electrochemical activity. Moreover, their intriguing structures and distinctive physiochemical properties delineate them as an exemplary material to serve as electrodes for high-performance supercapacitors (SCs). The present work reports the in-situ synthesis of Zinc Magnesium Aluminium LDH (ZMA) integrated with reduced graphene oxide (rGO) through a single-step hydrothermal approach. The resulting novel ternary ZMA@rGO nanocomposite (ZMAG) possesses a unique architecture incorporating hierarchical 3D nanoflowers of ZMA embedded on graphene nanosheets. The porous morphology of LDH improves interfacial charge transport, which results in more faradaic reactions at the electrochemically active sites. In addition, the conductive graphene nanosheets render a high specific surface area, endowing excellent capacitive behavior. The amalgamated electrochemical properties of ZMA and rGO develop a competent electrode material (ZMAG) for SCs. The ZMAG2 nanocomposite having ZMA and rGO in 1:1, evinces a specific capacitance (Cs) of 656.7 F/g at a current density (Id) of 1 A/g. Furthermore, the asymmetric supercapacitor (ASC) features admirable cycle stability (retains 89% of initial capacitance after 15,000 charge/discharge cycles). Herein, the real-time application of ZMA@rGO//AC ASC has also been demonstrated. Therefore, hierarchical porous nanostructure proclaims new prospects for fabricating proficient electrode materials for energy storage devices.

Biosafety and osteogenic properties of a new type of absorbable magnesium-based amorphous alloy

The treatment of bone defects has always been a difficult problem in orthopedic clinical practice, and research on new materials is currently a hot topic. In this study, the biological safety and bone induction ability of a new magnesium-based amorphous alloy (Mg66Zn30Ca3Sr1) and zinc–magnesium powder were verified and compared in animal experiments. Thirty Sprague–Dawley rats were randomly divided into three groups, and a bone defect was made in the lateral condyle of the femur of the left hind limb. The blank group closed the wound after establishing the bone defect model, the control group added zinc–magnesium powder and chondroitin sulfate gel, and the experimental group added magnesium–zinc–calcium–strontium alloy and chondroitin sulfate gel with the same volume. Peripheral venous blood of rats was collected at 4, 8, and 12 weeks postoperatively, and alanine aminotransferase (ALT), aspartate transferase, creatinine, blood urea nitrogen, magnesium ion, and zinc ion levels were evaluated. The expression levels of bone morphogenetic protein 2 (BMP-2), osteoprotegerin (OPG), osteopontin (OPN), core binding factor α1 (RUNX2), and alkaline phosphatase (ALP) were detected using enzyme-linked immunosorbent assay (ELISA). After the rats were euthanized, samples were taken. X-rays and micro-computed tomography (CT) images of the bone defect were obtained, and hematoxylin and eosin and Masson staining were performed. This study shows that amorphous magnesium–zinc–calcium–strontium alloy is a biodegradable metal with good biocompatibility and bone induction and has good application prospects in treating bone defects.

In Males with Adequate Dietary Needs Who Present No Sleep Disturbances, Is an Acute Intake of Zinc Magnesium Aspartate, Following Either Two Consecutive Nights of 8 or 4 h of Sleep Deprivation, Beneficial for Sleep and Morning Stroop Interference Performance?

Purpose: We examined whether supplementation of zinc magnesium aspartate (ZMA) in two groups of males, either partially sleep-restricted (4 h) or with habitual sleep (8 h) for 2 nights, was beneficial for sleep and subsequent morning Stroop performance. Participants were randomly allocated to two independent groups who either had 4 h (33 males) or 8 h (36 males) sleep for two nights. Using a double-blinded, randomised counterbalanced design, they then completed five sessions, (i) two familiarisation sessions including 7 days of sleep and dietary intake, (ii) three conditions with 4 h or 8 h sleep and either NoPill control (NoPill), placebo (PLAC) or ZMA (ZMA). Sleep was assessed by actimetry and sleep questionnaires, and cognitive performance was assessed by the Stroop test. The data were analysed using a general linear model with repeated measures. A main effect for "sleep" (4 or 8 h) was found, where more opportunity to sleep resulted in better "sleep" metrics (both objective and subjective) as well as better Stroop scores (lower colour-interference and word-interference scores and lower error in words). No main effect for "Pill" was found other than the mood state depression, where subjective ratings for the PLAC group were lower than the other two conditions. Interactions were found in anger, ease to sleep and waking time. Having 8 h opportunity to sleep resulted in better "sleep" metrics as well as better Stroop scores compared to 4 h. Supplementation of ZMA for 4 or 8 h for 2 nights had no effect on subsequent morning cognitive performance but reduced sleep or total sleep time by ~0.46 h compared to the other conditions. An interaction was found where sleep time was reduced by ~0.94 h in the ZMA group in the 8 h condition compared to NoPill or PLAC.

Harnessing halides: Comparative study of oxide fullerene modifications for sodium ion secondary battery efficiency

The quest for secondary batteries drives ongoing research aimed at developing cost-effective and high-performance nanomaterials. While lithium-ion batteries initially offered high efficiency, however escalating demand has led to increased costs prompting exploration of other alternatives such as sodium (Na) ion batteries. Na resources are much more abundant and widely distributed globally compared to lithium. This study explores the potential of sodium ion battery by adopting a novel approach of incorporating endohedral halides into oxides fullerenes to enhance the voltage. We investigated the thermodynamic and electronic stabilities of Na/Na+ ions with both bare and halide-doped magnesium oxides (Mg12O12) and zinc oxides (Zn12O12) fullerenes to understand how encapsulated halide affects the structural and electrochemical properties. The bare oxide fullerenes exhibit cell voltages of 0.29 and −0.50 V in the presence of toluene solvent. Upon incorporation of various halide ions into oxides fullerenes, we obtained cell voltage in acceptable range for anode materials. Specifically, the variation in free energy experiences a remarkable improvement where the Cl−@Zn12O12 in toluene has the most appropriate cell voltage of 1.09 V in the presence of toluene solvent, among all halides adsorbed oxides nanocages. These findings provide valuable insights for the design of novel low-cost nanomaterials having better cell voltage. The endeavor additionally catalyzes further research work into the design of halide-encapsulated oxide-fullerene-based secondary batteries, intended for widespread applications in electrochemical energy storage devices. This comprehensive work serves as a detailed blueprint for experimentalists, facilitating the synthesis of such systems to address the future challenges posed by energy scarcity.

Mineral Quantitation of Irish Potato (Solanum tuberusom) Treated with Maca (Lepidium meyenii) During Storage

Irish potato (Solanum tuberusom) has contributed to human diet for thousands of years, first in the Andes of South America and then in the rest of the world. Potato is rich in potassium which reduces the risk of cardiovascular disease. Maca (Lepidium meyenii) contains macamides which are thought to have antioxidant effects. Prolonged storage of Irish potatoes is the stage at which good quality tubers are most difficult to maintain because of the transformations occurring at that time lead to quantitative changes in the composition of tubers. This work was designed to quantify potassium along aside with some minerals in Irish potato during storage with aqueous solution of maca flour. In the storage process, potatoes are affected by two negative factors, i.e., high (room) temperature, light and physiological activities in the tuber. The values obtained for Irish potato treated with aqueous maca 1:10 mL distilled water (MA1) and untreated potato as control (CTRL) respectively are potassium (173.85 and 93.67 mg/100 g), sodium (99.74 and 39.59 mg/100 g), magnesium (14.20 and 12.37 mg/100 g), phosphorus (56.00 and 39.00 mg/100 g), zinc (0.34 and 0.30 mg/100 g), manganese (0.39 and 0.33 mg/100 g) and copper (0.01and 0.01 mg/100 g). MA1 differs significantly (p < 0.05) from CTRL for potassium, sodium and magnesium phosphorus and zinc while there was no significant difference for manganese and copper. These results indicate that treating potato with low concentration of aqueous maca helps to retain minerals composition during storage.

Microwave absorption properties of spinel-structured magnesium zinc aluminate nanocomposites through Mn doping: characterization and performance analysis of (Mg–Zn)1−xMnxAl2O4 (x = 0.05, 0.1, 0.15, and 0.2)

Microwave absorption properties of spinel-structured magnesium zinc aluminate nanocomposites through Mn doping: characterization and performance analysis of (Mg–Zn)1−xMnxAl2O4 (x = 0.05, 0.1, 0.15, and 0.2)

Peripheral vascular bioresorbable scaffolds: Past, present, and future

As peripheral vascular disease affects more and more people in the world, interventional treatment of peripheral blood vessels evolves from percutaneous transluminal angioplasty to bioresorbable vascular scaffolds (BVS). At present, the materials of peripheral vascular bioresorbable scaffolds mainly include polymers and metal materials, and have achieved certain clinical application effects. Examples of these BVS are provided, and their advantages and defects are discussed. Poly-L-lactic acid is most commonly used in polymer BVS. There have been some polymer BVS entering clinical research for peripheral blood vessels since the 10 s, and have various outcomes. Metal materials for BVS mainly include magnesium alloy, iron alloy, and zinc alloy. The improved magnesium alloy BVS show excellent antiplatelet adhesion ability and can reduce the formation of acute stent thrombosis in clinical research. The iron alloy BVS and zinc alloy BVS also show excellent performance in animal experiments. The drug coating of BVS is expected to be improved. Finally, prospects of future development are highlighted. With the continuous improvement of manufacturing and drug-coating process, their therapeutic effect is expected to continue to improve.

Microstructure evolution and ductility improvement of additively manufactured biodegradable zinc–magnesium alloys via annealing

Zinc–magnesium (Zn–Mg) alloys, fabricated by laser powder bed fusion (LPBF) additive manufacturing techniques, have emerged as promising candidates for biomedical implants due to their biodegradation capability, superior mechanical strength, and excellent biocompatibility. However, LPBF-fabricated Zn–Mg alloys still face challenges related to extremely low ductility and limited exploration of degradation characteristics. In this study, the impact of Mg incorporation on the printability, degradation properties, microstructure, and mechanical properties of LPBF-fabricated Zn–Mg alloys was primarily investigated. Furthermore, we proposed a viable annealing post-processing route for the first time to tailor the microstructural characteristics of the fabricated Zn–Mg alloy and enhanced its limited ductility. The results demonstrated that by applying a laser power of 80 W and a scanning speed of 600 mm/s, the relative density of LPBF-fabricated Zn–Mg alloy reached 98.62%. Increasing the Mg amount from 1 to 5 wt% refined the grain size while promoting an increase in Mg2Zn11 and MgZn2 phases. Among these compositions, the Zn–1Mg alloy exhibited the greatest degradation rate at 0.126 mm/year. The annealing treatment facilitated the microstructure evolution of the Zn–1Mg alloy, resulting in equiaxed grains, increased average grain size, high-angle grain boundaries, and enrichment of Mg at grain boundaries. After annealing at 300°C for 0.5 h, the tensile strength of Zn– 1Mg alloy decreased from 254.92 to 170.93 MPa, while the elongation significantly increased by a factor of 14.3 from 0.55% to 8.43%. These findings provide valuable insights into an effective post-processing approach for tailoring the microstructure and resultant mechanical properties of LPBF-fabricated Zn and its alloys.