Magmatic Research Articles

Multiple mantle metasomatism recorded by Triassic post-collisional ultrapotassic and tholeiitic magmatism in West Qinling, NW China

Mantle properties and metasomatic processes, together with interlayer interactions at orogenic belts are still under debate. The post-collisional magmatic rocks could provide secondhand constraints on these issues. Hereby, an integrated geochronologic, geochemical, and isotopic study was conducted on post-collisional Zhanwa dolerites, Dashui granodiorite–monzonite-monzogabbro complex, and Jiuzigou pyroxenite–syenite complex at West Qinling. The Zhanwa dolerites, being tholeiitic with flat trace elemental pattern, were mixtures of melts from asthenospheric and oceanic slab-fluid-metasomatized lithospheric mantles. The Dashui monzonite-monzogabbro suite is ultrapotassic with strongly right-inclined trace elemental pattern and evolved isotopic composition (( 87 Sr/ 86 Sr) i = 0.7066–0.7068, ε Nd ( t ) = -4.56 to -4.35, ε Hf ( t ) = -3.14 to -2.35, and ( 206 Pb/ 204 Pb) i = 17.99–18.12)). It derived from melting of continent-crustal materials-metasomatized mantle. In contrast, the Dashui granodiorites are shoshonitic–calc-alkaline with more evolved isotopic compositions with ( 87 Sr/ 86 Sr) i , ε Nd ( t ), ε Hf ( t ), and ( 206 Pb/2 04 Pb) i of 0.7074–0.7091, -7.56 to -5.51, -5.61 to -3.53, and 18.18–18.46, respectively. They represent hybrids of mantle-derived K-rich and crustal-derived felsic melts. The Jiuzigou complex holds extremely high trace elemental contents. Its mantle source was metasomatized by both oceanic crustal fluids and sedimentary melts. Generation of these rocks (ca. 235–223 Ma) not only recorded multiple mantle metasomatism, but also captured collective asthenospheric and lithospheric magmatic responses at a post-collisional setting.

Relative paleointensity of geomagnetic field during the last 9000 years estimated by the pseudo Thellier method from the bottom sediments of Lake Shira, Northern Khakassia

The results of rock magnetic studies and determination of relative paleointensity from sediments of Lake Shira, Khakassia, are presented. The NRMcarrier minerals were determined from the hysteresis parameters, thermomagnetic and X-ray diffraction (XRD) analyses. The age of the sediments was determined by radiocarbon dating. According to these measurements, the column spans about 9100 years. The qualitative determinations of relative paleointensity were obtained from linear segments of the pseudo-Arai–Nagata diagrams. The quality of the determinations was evaluated by the following criteria: number of points used to calculate the slope; quality criterion (q), fraction ofNRMdestroyed in the paleointensity determination interval, and relative paleointensity determination error (σ). According to rock magnetic studies and XRD analysis, the magnetization carriers are represented mainly by single-domain and pseudo-single-domain magnetite and hematite. The comparison of the obtained series of relative paleointensity data with both the model paleointensity values calculated for Shira coordinates from various models (CALS10K.1b [Korte et al., 2011], PFM9k.1 [Nilsson et al., 2014], HFM.OL1.AL1, CALS10k.2 ARCH10k.1 [Constable et al., 2016]) and with absolute paleointensity, as well as the aggregate results of the studies on sedimentary and igneous rocks and on archaeomagnetic objects has shown that these data are in good agreement with each other and have common trends. This provides a rationale for using this methodology to determine paleointensity from sediments of modern lakes using the pseudo-Thellier method.

The Mesozoic Subduction Zone over the Dongsha Waters of the South China Sea and Its Significance in Gas Hydrate Accumulation

The Mesozoic subduction zone over the Dongsha Waters (DSWs) of the South China Sea (SCS) is a part of the westward subduction of the ancient Pacific plate. Based on the comprehensive interpretation of deep reflection seismic profile data and polar magnetic anomaly data, and the zircon dating results of igneous rocks drilled from well LF35-1-1, the Mesozoic subduction zone in the northeast SCS is accurately identified, and a Mesozoic subduction model is proposed. The accretion wedges, trenches, and igneous rock zones together form the Mesozoic subduction zone. The evolution of the Mesozoic subduction zone can be divided into two stages: continental subduction during the Late Jurassic and continental collision during the late Cretaceous. The Mesozoic subduction zone controlled the structural pattern and evolution of the Chaoshan depression (CSD) during the Mesozoic and Neogene eras. The gas source of the hydrate comes from thermogenic gas, which is accompanied by mud diapir activity and migrates along the fault. The gas accumulates to form gas hydrates at the bottom of the stable domain; BSR can be seen above the mud diapir structure; that is, hydrate deposits are formed under the influence of mud diapir structures, belonging to a typical leakage type genesis model.

Crystal Resorption as a Driver for Mush Maturation: an Experimental Investigation

Abstract The thermal state of a magma reservoir controls its physical and rheological properties: at storage temperatures close to the liquidus, magmas are dominated by melt and therefore mobile, while at lower temperatures, magmas are stored as a rheologically locked crystal network with interstitial melt (crystal mush). Throughout the lifetime of a magmatic system, temperature fluctuations drive transitions between mush-dominated and melt-dominated conditions. For example, magma underplating or magma recharge into a crystal mush supplies heat, leading to mush disaggregation and an increase in melt fraction via crystal resorption, before subsequent cooling reinstates a crystal mush via crystal accumulation and recrystallisation. Here, we examine the textural effects of such temperature-driven mush reprocessing cycles on the crystal cargo. We conducted high-P-T resorption experiments during which we nucleated, grew, resorbed, and recrystallised plagioclase crystals in a rhyolitic melt, imposing temperature fluctuations typical for plumbing systems in intermediate arc volcanoes (20–40 °C). The experiments reproduce common resorption textures and show that plagioclase dissolution irreversibly reduces 3D crystal aspect ratios, leading to more equant shapes. Comparison of our experimental results with morphologies of resorbed and unresorbed plagioclase crystals from Mount St. Helens (MSH) (USA) reveals a consistent trend in natural rocks: unresorbed plagioclase crystals (found in MSH dacite, basalt and quenched magmatic inclusions [QMIs]) have tabular shapes, while plagioclase crystals with one or more resorption horizons (found in MSH dacite, QMIs, and mush inclusions) show more equant shapes. Plagioclase crystals showing pervasive resorption (found in the dacite and mush inclusions) have even lower aspect ratios. We therefore suggest that crystal mush maturation results in progressively more equant crystal shapes: the shapes of plagioclase crystals in a magma reservoir will become less tabular every time they are remobilised and resorbed. This has implications for magma rheology and, ultimately, eruptibility, as crystal shape controls the maximum packing fraction and permeability of a crystal mush. We hypothesise that a mature mush with more equant crystals due to multiple resorption–recrystallisation events will be more readily remobilised than an immature mush comprising unresorbed, tabular crystals. This implies that volcanic behaviour and pre-eruptive magmatic timescales may vary systematically during thermal maturation of a crustal magmatic system, with large eruptions due to rapid wholesale remobilisation of mushy reservoirs being more likely in thermally mature systems.

In situ geochemistry of apatite: Petrogenetic and tectonic interpretations of Jurassic felsic magmatism in the Yanbian area, NE China

Geochemical analyses of individual minerals provide more detailed insights into the petrogenesis of igneous rocks than whole-rock analyses. This study conducted in situ geochemical and Nd isotope analyses of apatites from 10 Jurassic granitic plutons in the Yanbian area, NE China, to establish the petrogenesis and regional tectonic evolution. The results indicate that the apatite geochemistry of Jurassic granitoids in the Yanbian area was controlled primarily by the composition of parental melt. Post-magmatic alteration may lead to geochemical decoupling between apatite and parental melt, while Nd isotopes exhibit some resilience to such alterations. Apatites from Early Jurassic granitoids display characteristics that are consistent with an I-type origin, whereas those from Middle and Late Jurassic granitoids exhibit an adakitic affinity. Variations in apatite compositions indicate the fractional crystallization of other rare earth element (REE)-bearing minerals during magma evolution. The early crystallization of plagioclase and allanite led to decreases in Sr and Th contents in apatite, respectively, resulting in a negative Eu anomaly and light REE depletion. The fractional crystallization of titanite and hornblende resulted in the depletion of middle REE in apatite. Hornblende is regarded as the main residual phase in the magma source of Middle and Late Jurassic adakitic granitoids in the Yanbian area. Apatite Nd isotopic compositions suggest that the Jurassic granitoids in the Yanbian area originated from two crustal sources: the Central Asian Orogenic Belt and the North China Craton. Additionally, increasing trends in apatite Sr/Y and (La/Yb)N ratios from the Early to Late Jurassic suggest a gradual thickening of the regional crust, which is likely driven by the continentward migration of the subduction zone associated with the Paleo-Pacific Plate.

Low paleomagnetic field in the proterozoic: new 1.72–1.76 ga paleointensity data obtained on the proterozoic volcanics from the Ukrainian shield

A collection of igneous rocks from the Ukrainian Shield sampled from the Korsun-Novomyrhorod pluton (age interval 1760–1735 Ma, Ingul Domain) and from the Korosten pluton (age 1760–1750 Ma, North-Western Domain) is studied. To obtain reliable determinations of paleointensity (Banc), the magnetic and thermomagnetic properties of samples were studied and X-ray diffraction analyses were carried out. It is shown that the carriers of the characteristic component of natural remanent magnetization are single- and small pseudo-single-domain magnetite grains. To determine Banc, two methods were used: the Thellier‒Coe procedure with the pTRM-checks and the Wilson method. Paleointensity determinations are obtained from five sites and are shown to meet quality criteria. For all five sites, the values of the Banc and the virtual dipole moment (VDM) are extremely low, varying within the range of 3.6–9.76 μT and (0.92–2.43)×1022 Am2, respectively. The analysis of the data from the paleointensity world database (WDB) has shown that the operating mode of the geodynamo in the Proterozoic can be characterized by a succession of strong and weak dipole regimes, but the reality of this conclusion entirely depends on the reliability of the data reported in the literature and presented in the WDB.

Earth's longest lava flows erupted from its largest igneous province: The submarine Ontong Java Plateau

We use high-precision analyses of fresh basalt glasses from the submarine, Cretaceous Ontong Java Plateau (OJP) recovered by the Ocean Drilling Programs (ODP) to test for long submarine lava flows. Major elements and Cl show that glasses from ODP Holes 1185B and 1186A, which are 200 km apart, are compositionally identical and must have erupted simultaneously from the same well-mixed magma chamber. Identical CO2 contents show they erupted at the same water depth, but 1185B is directly downslope from 1186A and has a corrected basement depth that is >700 m deeper. Remarkably, <2 °C cooling took place over 200 km, requiring a cooling rate <0.01 °C/km.Further evidence of long flows is the lack of vesicles in OJP's glasses, in contrast to mid-ocean ridge basalt glasses that almost always contain vesicles and are often oversaturated in dissolved CO2. We propose that OJP's lavas degassed to saturation levels of dissolved CO2 +H2O and lost all bubbles because they remained liquid for much longer periods during long distance flow. Dissolved CO2+H2O are used to estimate paleoeruption depths which are compared to current corrected basement depths. Using a fixed value of plateau subsidence (500 m) we reconstruct flow distances of 0 to 900 km for eight lava groups from six drill sites. Eruption depths in Hole 807 C are 3040 m for Kwaimbaita-type lavas but 1110 m for Singgalo-type lavas that directly overlie them suggesting that the Singgalo lavas erupted 900 km away (near Site 1183).Paleoeruption depths for Cretaceous glasses from the Jurassic East Mariana and Nauru Basins adjacent to OJP are shallower than most glasses recovered from OJP even though their reconstructed basement depths are 1500–3800 m deeper. It is very likely that the basins’ lavas were erupted on OJP and flowed up to 1600 km: longer than any lava flow known on Earth. Flow distances are shorter (≤1000 km) if a plateau subsidence of 1500 m is used in the calculations. Extremely high Cl in Nauru Basin glasses also supports eruption from OJP. Long distance flow with minimal cooling was facilitated on OJP by favorable slopes, lack of barriers, insulation of rapidly forming glass, and possibly by flow within lava tubes. Lava effusion rates were probably >100 m/sec and flow rapid: >1 m/sec.

Graben systems and geological history of Mbokomu Mons region, Parga Chasmata, Venus

The relationship between chasmata (rift zones) and spatially associated volcanism (mons and coronae) on Venus has been extensively discussed but remains enigmatic. One region where these features are prominently displayed is along the 10,000 km long, WNW trending, Parga Chasmata, which connects Atla Regio with Themis Regio. The Mbokomu Mons area (located about 2200 km SE of Atla Regio) was selected for detailed study to provide insight into these relationships. More than 39,000 extensional lineaments (grabens, fissures and fractures) were mapped at 1:500,000 scale using full resolution Magellan Synthetic Aperture Radar (SAR) images and grouped into radiating, circumferential and linear systems. They are (except where noted) interpreted to represent the surface expression of underlying mafic dyke swarms, on the basis of associated volcanic features and terrestrial analogues. Radiating and/or circumferential swarms are associated with Mbokomu Mons and the four coronae in the surrounding area, Among Corona (AC), Repa Corona (RC) and two unnamed coronae (UC1 and UC2). Mbokomu Mons is unique among the tectono-magmatic features in this region of Parga Chasmata, in having both corona and mons characteristics. The initial Corona Phase consists of radiating and circumferential systems mainly preserved in an unflooded annular uplift, while the Mons Phase includes a second radiating swarm associated with a central edifice, and smaller circumferential fracture pattern near the summit that could overlie a magma reservoir. The plume or diapir that is interpreted to have been responsible for the initial Corona Phase is estimated to have had a radius of ∼150 km. Cross-cutting relationships indicate that Mbokomu Mons is younger than nearby Among, Oduduwa and Onenhtse coronae. All four centres are aligned along a WNW-trend parallel to the Parga Chasmata (rift system). Mbokomu Mons is located at, and its emplacement may be linked to, the intersection of this WNW-trending zone of weakness and the orthogonal Jokwa Linea rift system. Mbokumo Mons is also younger than the nearby parallel Penthesilia Fossa (PF) (part of the Great Dyke of Atla Regio).

Petrophysical and petrographic data correlation and the discrimination of magmatic environments and processes in Santos Basin, offshore SE Brazil

The igneous rocks in the context of oil & gas exploratory sedimentary basins have been a paradigm and challenge for industry and academia due to the difficulty of reconnaissance and interpretation using indirect methods, e.g. geophysical data. We presented the combination of the petrographic and well log data of distinct magmatic sections from wells of Santos Basin, SE Brazil. Effusive and explosive felsic rocks, mafic volcanic subaerial and subaqueous and plutonic mafic rocks were recognized by petrography and petrophysics proprieties data, as radioactive (GR), electric resistivity (R), acoustic property (Δt), porosity (Φ) and density (ρ), showed different patterns along sections. This enables the division on magmatic subsections and allowed the recognition of rock types and igneous setting. The compositional influences are clearly distinguished by GR, as felsic and mafic rocks, presence of amygdales in mafic effusive rocks and inter-pillow intervals in subaqueous environments, can interfere with GR patterns. In plutonic environment, GR can show evidence of magmatic differentiation. Δt and Φ are directly proportional with similar pattern and both are inversely proportional to R and ρ. Felsic rocks, effusive or explosive, and inter-pillow intervals makes Φ and ρ curves closer. Less dense and more porous rocks, as explosive, tend to imprint the Φ and ρ pattern to the left of the log. Welding processes are distinguished by gradual decrease of Φ and increase of ρ. Otherwise, denser mafic rocks, volcanic or plutonic, tend to show separate Φ and ρ curves on the right of the log, while amygdaloidal portions are lighter and more porous than the massive one, showing the separate pattern on the left. The subaqueous mafic volcanic rocks imprint GR, ρ and Φ intermediate patterns between mafic massive and amygdaloidal. The recognition of the type of magmatic rock, the environment and the physical properties can aid to improve not only the decisions of exploration and production but also the elaboration of a geodynamic context for offshore sedimentary basins.

Groundwater–rock interactions and mixing in fault–controlled karstic aquifers: A structural, hydrogeochemical and multi-isotopic review of the Pontina Plain (Central Italy)

Karstic aquifers represent crucial water resources and are categorized as either stratigraphically or fault–controlled. This study investigates groundwater–rock interactions and mixing processes within one of the largest fault–controlled karstic aquifers in Central Italy, adjacent to the Pontina plain, which is a highly populated area where agricultural activities and climate change challenge the groundwater assessment of a complex aquifer. We conducted structural, hydrogeochemical, and multi-isotopic screening of ten selected springs with different degrees of mineralization (ranging from Ca–HCO3 to Na–Cl hydrofacies), incorporating new analyses and modeling of δ34S(SO4), δ18O(SO4), 87Sr/86Sr, and δ11B. Additionally, the reinterpretation of a seismic section provides a more detailed framework extending to depths of approximately 5–7 km that allows the identification of the geometry of normal faults, which act as pathways for upwelling fluids. Our findings reveal that hydrogeochemical compositions result from multiple interactions between karstic water and deeper fluids that have interacted with different rocks. Concentration (Na/Li) and isotope (SO4–H2O) geothermometers, coupled with geochemical modeling and trace element analysis, enabled the estimation of a water temperature equilibrium of approximately 95.5 °C, with Triassic evaporites generally corresponding to a depth of approximately 3 km and a temperature of 40 °C with magmatic rocks at approximately 1 km depth, which is likely associated with ongoing tectonics and the Quaternary tectonically controlled Volsci Volcanic Field. To obtain the latter estimate, we used a new geothermometer activity based on the equilibrium between analcime and pollucite. Furthermore, this multidisciplinary approach enhances the understanding of groundwater behavior in fault–controlled karstic aquifers, where mantle-derived CO2 dissolved in groundwater is the driving force behind water–rock interactions. Given the potential for further variations in mixing, which may worsen water quality and increase aquifer vulnerability, periodic monitoring of these processes is essential in a human-impacted environment amidst ongoing climate change.

Configuration of the early-mid Cenozoic extensional arc volcanism of the North Patagonian and the Southern Central Andes (33–44°S)

The late Eocene to earliest Miocene volcanic arc of the Southern Central Andes (33–40°S) and North Patagonian Andes (40–44°S) exhibits distinctive features that shed light on the dynamics of subduction-related volcanic activity in extensional tectonic settings. This period is particularly significant in the Andes, as it records the opening of forearc, intra-arc, and retroarc extensional basins, accompanied by high-volume volcanism, preceding the middle-late Miocene final major uplift phase of the Andes. This extensional event occurred in two phases, associated with changes in the geometry and dynamics of the subduction system: from oblique convergence at low rates during the late Eocene-early Oligocene to an orthogonal convergence at high rates during the late Oligocene-early Miocene. This study presents a compilation of field, petrographic, geochemical, and isotopic data from volcanic sequences in the North Patagonian Andes and the Southern Central Andes, aiming to analyze petrogenetic processes at different stages of arc evolution.During the late Eocene to early Oligocene, subduction-related volcanism occurred in a wide area from 100 to 300 km from the trench. In this period, magmatic arc rocks exhibit intermediate composition and a relatively homogeneous geochemical signature, transitional between tholeiitic and calc-alkaline series, with a marked subduction-related signature. These magmas originated from depleted mantle sources with high slab-derived fluid and sediment contributions and limited crustal interactions. In contrast, the late Oligocene to earliest Miocene volcanic activity, at the peak of the extensional regime, displays significant geochemical differences along the Andes. In the Southern Central Andes (33–40°S), volcanism displays compositions similar to those of the previous stage with varying influence from the subducting slab. In some sectors, magmas register the climax of the extensional conditions, whereas the youngest volcanic rocks towards the north (33–34°S) present evidence of the onset of contractional tectonics, demonstrated by the increased interaction of the magmas with a progressively thickened crust. In the North Patagonian Andes (40–44°S), subaerial and subaqueous arc-related lava flows are interbedded with marine deposits, indicating a rapid subsidence regime. These rocks exhibit geochemical features transitional from arc to E-MORB and even OIB compositions, which suggest a genesis primarily dominated by decompression melting of a heterogeneous mantle source. Above all, the contrasting nature of late Eocene-early Miocene arc products in the Southern Central and Patagonian Andes highlights that no single process can explain the changes in composition, distribution, and evolution of arc magmatism; rather, it is a combination of factors, including variations in subduction zone configuration and mantle dynamics and composition.

Grain textural bias in detrital single-mineral provenance studies

Detrital single-mineral geochemistry and geochronology are strong tools in provenance studies and indicate great potentials in addressing issues in earth sciences. Various biases (both natural and artificial) exist objectively and may mislead provenance interpretations. Both the sedimentary sorting process and hand-picking in-laboratory processing may lead to analyzed grain textural (e.g., size and shape) variability and thus may introduce biases in single-mineral provenance analysis. Here, we take the Mesozoic–Cenozoic Qaidam basin, northeastern Tibet, as an example to investigate the relationship between single-mineral grain texture and detrital zircon geochronological and detrital tourmaline, rutile and garnet geochemical data and to explain how grain texture affects detrital single-mineral provenance interpretations. Results indicate that Precambrian zircons take less proportions in coarse (>125 μm), subrounded and high aspect ratio (>2) fractions than Phanerozoic zircons. Parent rock lithology discrimination results of detrital tourmaline and garnet in different grain size fractions show significant differences. Zr-temperature values of detrital rutile have an increasing trend with increasing grain size. The geochemistry of detrital tourmaline, rutile and garnet shows no dependence with grain aspect ratio and roundness. We suggest that inheritance of grain texture features from parent rocks is the major reason. Detrital zircons from recycled (meta)sedimentary rocks tend to be smaller and more rounded than those from igneous rocks. Detrital tourmaline, rutile and garnet grains from different parent rock types vary in size. Grain textural bias may cause the underestimated contributions of the Qilian Shan to the Cenozoic Qaidam basin if small detrital zircons were not involved in the analysis. Quantitative description of the source-to-sink system of the Cenozoic Qaidam is also influenced by grain textural bias. This study highlights the underestimated grain textural bias in single-mineral provenance studies. We suggest that a comprehensive understanding of potential sedimentary sources, depositional processes, sample petrographic features and laboratory analysis procedures is important to reliable provenance interpretations and to related implications in earth sciences.

New Geochemical and Geochronological Constraints on the Genesis of the Imourkhssen Cu±Mo±Au±Ag Porphyry Deposit (Ouzellagh-Siroua Salient, Anti-Atlas, Morocco): Geodynamic and Metallogenic Implications

The Imourkhssen porphyry Cu±Mo±Au±Ag deposit is located at the Ouzellagh-Siroua Salient (OSS) straddling the boundary between the central Anti-Atlas and the central High Atlas. It is characterized by a typical porphyry-style mineralization. The volcanic rocks are intruded by numerous magmatic rocks of the Ouarzazate Group (580–539 Ma), referred to as the Late Ediacaran magmatic suites (LEMS). Of these, the Askaoun, Imourkhssen, and Imourgane granites are the most significant as they are related to the porphyry mineralization. The entire set is intruded by the Zaghar mafic dyke swarms. Zircon U-Pb dating of the Imourkhssen granite and the ore-bearing granite porphyry shows that these intrusive rocks were emplaced at 558 ± 1 and 550 ± 2 Ma, respectively. Moreover, the whole-rock major and trace element geochemistry reveal a high-K calc-alkaline I-type composition, consistent with an emplacement in a post-collisional setting under a trans-tensional tectonic regime. Ore bodies are hosted by the Askaoun granodiorite as well as the Imourgane granite. The mineralization occurs as fine-grained dissemination and infills of hydrothermally altered NNE–SSW to N–S trending veins and veinlets. Ore-related hydrothermal alteration consists of potassic, chlorite-sericite, serecitic, and propylitic mineral assemblages along with pervasive silicification and pyritization, providing a porphyry-style alteration pattern. The ore periods comprise supergene and magmatic-hydrothermal periods. The latter includes primary dissemination and secondary NNE–SSW to N–S ore-bearing system stages. The occurrence of molybdenite is either restricted to the potassic and chlorite-sericite alteration zones of the ore-bearing granite as fine disseminations or alternatively as veinlet infills within the propylitic halos. The molybdenite occurrences along with pyrite, chalcopyrite, galena, and tennantite dissemination are assigned to the primary ore stage, while the NNE–SSW to N–S ore-bearing system is related to the secondary ore stage. It consists of pyrite, chalcopyrite, bornite, covellite, diagenite, sphalerite, hematite, galena, gold, and chenguodaite. The predominance of cockade and crack-and-seal textures suggest multiple episodes of ore-forming fluid circulations under epithermal conditions. The supergene stage is achieved by subordinate malachite, azurite, barite, hematite, epsomite, and chrysocolla. From the descriptions above, we argue that the Imourkhssen Cu±Mo±Au±Ag mineralization shares many mineralogical and paragenetic attributes of porphyry-copper deposits.

Geochemical Characteristics and Paleo Weathering in Sediments of Noyyal River Basin, Tamilnadu – India

A geochemical study of surface sediment samples distributed in the Noyyal River basin in western Tamil Nadu was studied for major oxides, parent rock source, and the extent of weathering. The Al2O3/TiO2 ratio of the samples ranged from (4.5-18) during monsoon and (3.94-32.14) during summer and fell in the category of mafic and intermediate igneous rocks during both seasons. The samples exhibited PIA with an average value of 64.80 during monsoon and 66.36 during summer. CIA values of the samples averaged 61.48 during monsoon and 62.35 during summer. The CIA vs. PIA, CIA vs. K/Na, and CIA vs. Al/Na for the studied samples for both seasons show low to intermediate silicate weathering in almost all locations. ICV values of samples averaged 49 during monsoon and 47 during summer suggesting that rock-forming minerals like plagioclase and alkali-feldspar are more prevalent and fewer clay minerals are present. The Al2O3/TiO2 ratio of the sample locations ranged from (4.5-18) during monsoon with an average of 10.06 and (3.94-32.14) during summer with an average of 9.94. Most of the samples fell in the category of mafic and intermediate igneous rocks during both seasons. The A-CN-K plot shows the weathering tendency towards muscovite and illite, and the A-C-N plot shows the parent rocks' plagioclases are low to intermediately weathered and the sediments gradually reduce albite and are enriched in weathering of anorthite parent material. The A-CNK-FM shows all the sediment samples lying below the feldspar region, indicating garnet and biotite presence.

U–Pb–Hf and morphological evolution of zircon from granites associated with world-class tungsten skarn deposits in the northern Canadian Cordillera

The northern Canadian Cordillera is the most significant tungsten district in North America. Here, high-grade tungsten skarn deposits are associated with small, reduced, high-K calc-alkaline, S-type biotite granite plutons belonging to the 102–96 Ma Tungsten plutonic suite (TPS). A detailed U–Pb–Hf and morphological study of magmatic zircon from plutons in the southern half of the TPS belt was undertaken to better understand magmatic processes leading to the generation of the associated tungsten deposits. Antecrystic zircon from the TPS plutons began crystallizing during a transpressional regime ca. 117 Ma, suggesting the TPS magmas were active for up to 21 Myr prior to their upper crustal emplacement and final crystallization. This prolonged magmatic activity necessitates a magma origin in long-lived, deep crustal magma chambers. Hafnium isotopic compositions in zircon for the southern TPS as a whole form a non-radiogenic, univariate, and relatively wide ranging population (εHfi = −17.6 ± 4.5), but U–Pb–Hf trends become apparent when the data are sub-divided into sample groups with similar age, zircon morphology, and geographic location. These evolutionary trends in magmatic zircon are most simply explained by interactions between the parent melt and dissolving inherited zircon grains. This, along with changing zircon morphology, is consistent with gradual cooling and crystallization pathways exhibited by S-type magmas. Differing evolutionary trends in the U–Pb–Hf isotopic data between sample groups, however, suggest there were multiple magma batches that evolved independently, possibly in separate pockets within large, deep magma chambers. Zircon morphologies also suggest some grains in all sample groups were equilibrated with hotter and more alkaline magmas, although there is no textural or compositional evidence in the zircon for mixing of magmas with widely different compositions. An unconstrained inversion of local aeromagnetic data indicates reduced batholiths could be present 4–6+ km below the surface and that the plutons are apophysies to (or, higher level injections from) these deeper bodies. Although these batholiths can only be short-term holding chambers for magmas ascending from deep crustal levels, they may have been important for the segregation of mineralizing fluids. Since no single magmatic evolutionary pattern in the unaltered TPS plutons can be definitively linked to tungsten mineralization, pulses of mineralizing fluid may have been derived instead from the underlying batholiths. The 20+ Myr duration of deep magmatic activity exhibited by the TPS is similar to timeframes suggested for magmas associated with tungsten deposits in southern China, and may have allowed extended fractionation of a large volume of crustally derived magma to concentrate tungsten into late-stage melts. The emplacement of upper crustal batholiths and plutons in both regions during or following a transition to an extensional tectonic regime suggests the relaxed geodynamic regime may have been important in the ascension of metal-rich magmas and (or) fluids, ultimately resulting globally important tungsten deposits.

Extension settings favour initial REE enrichment in the parent granites of ion-adsorption REE deposits: implication from Late-Permian to Triassic granites in South China

The mechanism of rare earth elements (REE) enrichment in granites is important to understand generation of ion-adsorption REE deposits. We investigated Late Permian to Triassic granites from South China to investigate these issues. The ore-related granites with high REE contents (192-467 ppm) intruded in Late Permian have high K 2 O and Zr+Ce+Nb+Y contents, high Ga/Al and K/Na ratios, and low CaO contents, which belong to aluminous A-type granite derived from melting of felsic igneous rocks at a high-temperature extensional setting. The ore-unrelated Triassic Pingtian granite with relatively low REE contents (81.7-127 ppm) is peraluminous with occurrence of muscovite, indicating a S-type affinity. Its high Rb/Sr and low CaO/Na 2 O ratios indicate magma origin from a metapelitic source related to the compressional setting due to the continental collision. In the extensional settings in South China, the high temperature condition promoting melting of REE-rich accessory minerals and F-rich conditions improving the solubility of REE in the melts could be the reasons for the initial REE enrichment in these granites. Given that parent rocks for ion-adsorption REE deposits are all generated in extensional settings, multiple tectonic stages and long-term extensional setting in South China contributed to generation of the specific ion-adsorption REE deposits in South China.

The Early Neoproterozoic Andean-Type Orogenic and Within-Plate Magmatic Events in the Northern Margin of the Yangtze Craton during the Convergence of the Rodinia Supercontinent

Although considered a crucial component of the Rodinia supercontinent, it remains uncertain how the Yangtze craton relates to the accretion and breakup of Rodinia. Here, the Huanglingmiao granitic complex (HGC), an intermediate-acid rock series that intruded on the southern Kongling terrane of the northern Yangtze craton margin, is investigated to help resolve this conundrum. Our analysis indicates that these rocks consist of tonalite, trondhjemite, granodiorite, oligoporphyritic granodiorite, porphyric biotite granodiorite, and fine- to medium-grained granodiorite dyke compositions. Collectively, this assemblage is further subdivided into two categories by their temporal, spatial, and geochemical features into early TTG-like and later granitic–dioritic units, which are composed of tonalite, trondhjemite, granodiorite, porphyritic granodiorite, and the fine- to medium-grained granodiorite dykes, respectively. Zircon U-Pb dating yields ages of 865~850 Ma for the TTG-like rocks, 844~825 Ma for the porphyritic granodiorites, and ~800 Ma for the granodiorite dykes. Combined with geochemical evidence, the data suggest that the early- and late-series rocks were formed by a partial melting of Mesoproterozoic and Paleoproterozoic crustal materials, respectively, suggesting that the vertical layering of the crust controlled the composition of the independent units. In addition, isotopic evidence points to different sources for the various rocks in the Kongling terrane and that mantle-derived materials influenced the early-series lithologies. Combined with previous studies on the northern margin of the Yangtze craton, it is inferred that the early-series rocks formed in an active continental margin environment, while the late-series rocks display within-plate boundary formation characteristics. The multiple magmatic activities revealed by this study record sequential partial melting with tectonic transition characteristics from an Andean-type to within-plate magmatism in the northern margin of the Yangtze craton. Taken together, these observations point to a strong association between these rocks, convergence, and incorporation of the northern Yangtze craton margin into the Rodinia supercontinent during the Tonian Period.

The structure of a continental intraplate volcanic system and controls from shear zones: Insights into the central Hoggar Cenozoic volcanic province, Northwest Africa, from electrical resistivity images

Continental intraplate volcanic systems, with their locations far from plate tectonic boundaries, are not well understood: the crustal and lithospheric mantle structure of these systems remain enigmatic and there is no consensus on the mechanisms that cause melt generation and ascent. The Cenozoic saw the development of numerous volcanic provinces on the African plate, including within the Central Hoggar, located in Northwest Africa, part of the Tuareg shield. The magmatic activity began at approximately 34 Ma and continued throughout the Quaternary. In order to understand the origins and potential mechanisms that generated the intraplate volcanic activity in the Central Hoggar we aim to image the subsurface architecture, in terms of electrical resistivity, from the surface to the lithospheric mantle. To do so we use magnetotelluric measurements from 40 locations to generate a 3-D electrical resistivity model, over an area of about 100 km by 160 km. Low-resistivity features (i.e., conductors) are observed in the crust that are narrow, linear structures congruent with the boundaries of terranes and prominent fault zones (e.g., Azrou N’Fad). They likely reflect the Pan-African mega-shear zones, which were reactivated throughout the tectonic evolution of the region. The model reveals that these faults are lithospheric-scale. The low-resistivity features likely represent the signatures of past fluid pathways and mineralization. A deeper low-resistivity feature is observed in the upper lithospheric mantle directly beneath the Manzaz and Atakor volcanic districts. It may represent local, small-scale metasomatism of the sub-continental lithospheric mantle, and low-percent partial melting, that sits above a regional, large-scale asthenospheric upwelling associated with the Hoggar swell. It is likely the origin point of the fluids responsible for the overlying anomalies. The results highlight the control of the lithospheric-scale, mega-shear zones on the spatial distribution of the recent Cenozoic volcanic activity, which was influenced by the location of pre-existing structural weaknesses.

Hidden magma reservoirs: Insights from helium and carbon isotopic compositions in shallow groundwater beneath the Wudalianchi volcanic field, Northeastern China

The lack of strong geothermal manifestations and limited fumarolic activity has sparked widespread debate about the presence of active magma reservoirs beneath the Wudalianchi volcanic field (WVF). Helium (He) in hydrological systems is sensitive and responsive to the mixture of mantle-derived He, making it an excellent tool for deciphering mantle-derived magmatic processes. Through investigating dissolved He and inorganic carbon (DIC) in shallow groundwater of the WVF, we found that He captures mantle characteristics with R/Ra ratios (R equals to 3He/4He ratios, Ra is atmospheric 3He/4He ratio of 1.39 × 10−6) ranging from 0.07 to 2.27 and the highest proportion of mantle-derived He is 30.38 %. In contrast, DIC shows minimal mantle influence, with low concentrations (1.91–7.39 mmol/L) and depleted δ13C-DIC values ranging from −17.9 ‰ to −13.6 ‰. The calculated mantle 4He fluxes in groundwater are 2–3 orders of magnitude higher than that in stable continents and show the signature of volcanic degassing. The high mantle He fluxes and high upward flow rates suggest the efficient release and transfer of mantle-derived He into shallow groundwater through magma degassing. Magma-aging model effectively constraints the period of magmatic activity to within the last 47 ka. These findings, consistent with seismic noise imaging results, support the presence of magma reservoirs in the upper–middle crust. The absence of magmatic carbon signature in groundwater suggests the decoupling of magmatic He and magmatic CO2. Magmatic CO2 may be removed during ascent, possibly being trapped through dissolution or precipitation processes within the low-resistivity bodies identified at ∼2.5 km depth by magnetotelluric imaging. These findings not only contribute to resolving the controversy surrounding the existence of magma reservoirs beneath the WVF but also have broader implications in guiding the exploration and validation of hidden magmatic systems.

Кварц-кианит-мусковитовый магматический слюдит Борисовских сопок на Южном Урале

The article describes the simulation of ontogenesis of rock mineral aggregate with debatable genesis. Lenses or stokes of weakly deformed rocks are found in the South Urals in the block of kyanite-bearing stratified rocks of the Borisovskiye Sopki, the structure of which corresponds to the structures of igneous rocks. Induced surfaces of joint simultaneous growth are observed in all minerals — muscovite, kyanite, quartz, rutile, pyrite, monazite, xenotime and zircon. This is a paragenesis (eutectics). An interesting fact is that large quartz individuals are saturated with muscovite inclusions, while kyanite, synchronous with them, is free from muscovite inclusions, which is explained by repulsion in the melt-solution of minerals with equally charged surface. The mineral aggregate of the studied rocks lacks morphological signs of metasomatism (metacrystals, pseudomorphs, shadows of previous solid bodies) and recrystallization. This indicates magmatic genesis of the studied quartz-kyanite-muscovite rocks.