The present paper seeks to investigate the Machiavellianism in relation with Emotional Intelligence among Adolescents. It was hypothesized that Machiavellianism and Emotional Intelligence would be negatively correlated and Emotional Intelligence would be a significant contributor in predicting variance in Machiavellianism. In order to test the hypothesis 240 adolescents (120 females and 120 males) in the age range of 13 to 18 years were selected through random sampling. The measures used were Machiavellianism Scale (Mach IV Scale) and Modified Schutte Emotional Intelligence Scale (Schutte 1998). The correlation coefficient and regression analysis were used to assess the data. The results revealed significant and negative relationship between Machiavellianism and Emotional Intelligence .Emotional Intelligence emerged as a significant predictor of Machiavellianism. Thus, considering the possibility that individuals might have a dispositional tendency to emotionally manipulative behaviour immediately brings to mind the trait of Machiavellianism.