The description of the topic and problems of the object. The factors of environmental danger that can lead to emergency situations in areas of technogenic impact of mining enterprises in the Lviv-Volyn coal basin are analyzed.
 The purpose of the article is to justify the feasibility of the measures to minimize the spread of pollutants from mine dumps by the arrangement of geochemical barriers.
 The results of the research. The microelement composition of the dumps rocks of some mines in the coal basin have been examined. The rocks of mine waste heaps Chervonograd in compareness with the clark for clays and mudstone rocks of waste heaps concentrate Cobalt, Lead, Magnesium, Yitrium, Cuprum, Itterbium and Beryllium; Nadiia – Gallium, Manhan, Plumbum, Stanum, Itterbium, Cuprum; Stepova – Titanium and Tsirconium; Mezhyrichanska – Molybdenum and Plumbum. By the principal component methodparagenetic associations of trace elements and environmental parameters, which gave the opportunity to predict the ways and forms the main components of migration of trace element contamination are dedicated. In particular, for the rocks of mine waste heaps at Stepova such paragenetic associations are allocated: 1) the thickness of the bulk layer, the swiftness of slope, the ash content of rocks, the concentration of Sn, Cr, Zn and mudstones; thecontent of coal, pyrite, siderite, siltstone, Co, Ni, Mo, Cu, geomorphological characteristics, radioactivity of rocks; 2) the concentration of Pb, Ti, Cu, Sr, mudstone and rocks; 3) the contents of Mn and P. For the rocks of mine Mezhyrichanska are shown the association: 1) content of V, Y, Yb, Co, Ti, P, Cr, Ni, Be, Mn, Cu, Ba, Sn, Sc, Zn, Ga, Sr, Zr, ash content of rocks 2) the content of Mo, distribution of coal, not burnt rocks and pyrite. For the environment protection from pollution the most optimal methods are based on acceleration of the natural transformation of pollutants in the secure or their targeted concentrations in some limited areas with an area of the lithosphere, which are declared. To reduce the level of environmental risk and minimize the occurrence of emergency, on the territory of the Lviv-Volyn coal basin, the arrangement of artificial geochemical barriers on the way of pollutants from coal mine waste dumps to water have been proved for the first time.
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