A theory of the Zeeman effect and fine structure of the energy spectrum of electron-hole complexes in highly symmetric quantum dots grown along the [111] direction from materials with a zinc blende lattice has been presented. In the studied quantum dots with C3v point symmetry, the Zeeman effect for a heavy hole in a magnetic field B ‖ [111] has an unusual form: in addition to the diagonal component (gh1), the effective tensor of g-factors contains the off-diagonal element (gh2). For gh2 ≠ 0, there is a magnetically induced mixing of heavy-hole states, which explains two additional lines observed in experimental photoluminescence spectra of excitons and trions. A microscopic theory of the effective g-factors gh1 and gh2 within the Luttinger Hamiltonian in the spherical approximation has been discussed, as well as additional contributions to the off-diagonal element gh2 due to the warping of the spectrum of holes. The results of theoretical calculations of the g-factors gh1 and gh2 for quantum dots based on GaAs have been compared with the experimental data.
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