Luminescence Characteristics Research Articles

Crystal structures and solid-state luminescent properties of Eu(III), Gd(III) and Tb(III) complexes with hexafluoroacetylacetone and 4′-substituted terpyridine ligands

Six mononuclear lanthanide complexes [Ln(hfac)3(ptpy)] (Ln(III) = Eu (1), Gd (2), Tb (3)) and [Ln(hfac)3(ftpy)] (Ln(III) = Eu (4), Gd (5), Tb (6)), synthesized with 1,1,1,5,5,5-hexafluoroacetylacetone (hfac) as a first ligand and 4′-phenyl-2,2′:6′,2″-terpyridine (ptpy) or 4′-furan-2,2′:6′,2″-terpyridine (ftpy) as a second ligand, were characterized by elemental analyses, infrared spectroscopy, single-crystal X-ray diffraction, and powder X-ray diffraction. Thermogravimetric analyses indicate that these ternary lanthanide complexes possess very good thermal stability. Solid-state samples of 1-Eu and 4-Eu exhibit characteristic red luminescence at CIE: 0.6721, 0.3276 and CIE: 0.6859, 0.3139, with absolute quantum yields of 59.95% and 83.14% and luminescence lifetimes of 0.819 and 0.727 ms, respectively. Solid-state samples of 3-Tb and 6-Tb display characteristic green luminescence at CIE: 0.2736, 0.7167 and CIE: 0.2674, 0.7219, with absolute quantum yields of 2.58% and 0.52% and luminescence lifetimes of 0.040 and 0.033 ms, respectively. The results suggest that terpyridine is a good sensitizer for Eu(III), while hfac is a good sensitizer for Tb(III). In solid-state, the synergistic sensitization effect of hfac and terpyridine is significant for Eu(III), but less for Tb(III). And the electron-donating substituent at the 4′-position make terpyridine more suitable for the sensitization of Eu(III), but unfavorable for Tb(III).

Microscopic and luminescence characteristics of Dy3+ doped KSrVO4 nanophosphors as energy efficient photoluminescent material with potential application in white light-emitting diodes.

Nanotechnology has drawn an enormous amount of attention by providing various measures to reduce energy consumption. Phosphor-converted white-light emitting diodes (pc-w-LEDs), which are used in lighting applications, are gaining popularity. These materials are affordable, effective, and safe for the environment. Therefore, the main objective of the current study is to synthesize an economical phosphor which consumes low energy and is less harmful to the environment. In this study, Dysprosium (Dy3+) doped Potassium Strontium Vanadate (KSrVO4) nanopowders synthesized via the combustion process and using X-ray diffraction, FESEM, EDAX, HRTEM, UV-Vis spectroscopy, and photoluminescence spectroscopy techniques, we have examined its various structural, spectroscopic, optical, and morphological characteristics. The crystallite size was estimated using the XRD patterns and was found to be 25.724 nm. The functional groups contained in synthesized phosphor were identified using FTIR spectrum measurements. Using HRTEM, a particle size of 36.33 nm was predicted, which is consistent with the XRD results. The Kubelka-Munk approximation is used to determine the band gap energy of the produced nanophosphors. Three major peaks that correspond to the transitions of 4F9/2 → 6HJ (J = 15/2, 13/2, and 11/2) were discovered at 476 nm, 578 nm, and 669 nm, respectively, under the excitation of 390 nm near UV light. We investigated the impact of Dy3+ doping, the enhancement of emission intensity and the mechanism of concentration quenching on the photoluminescence spectra of the KSrVO4 host. KSrVO4:Dy3+ also demonstrated a suitable CCT (3745 K), enhanced color purity and high quantum yield in this work, indicating that this phosphor has potential applications in w-LED devices.

Modeling and numerical simulation optimization for minimizing the gain spectrum of bismuth-doped broadband fiber amplifiers at 1200-1800 nm

Research on optical fiber amplifiers has gotten much more in-depth in recent years as a direct result of the emergence of the information age. The most effective of these materials are optical fibers that have been doped with rare earth elements. Lasers that have gain media composed of rare-earth doped optical fibers find widespread use in fields such as optical communication, medicine, and the processing of materials. For different rare earth ions, especially for bismuth-doped fiber amplifiers, bismuth-doped fiber has a good prospect in fiber amplifiers and lasers due to its unique luminescence characteristics and ultra-wideband near-infrared luminescence of bismuth. Therefore, for bismuth-doped fiber amplifiers, in this paper, the pump wavelength is designed for the signal wavelength range, energy level structure, and electron transition process. The corresponding rate equation and power equation are established. At the same time, the gain spectrum changes with the fiber length and doping concentration are calculated using Matlab programming, and the maximum and minimum gain differences are minimized using Matlab calculations.

Recent Advances in Lanthanide Metal–Organic Framework Thin Films Based on Eu, Tb, Gd: Preparation and Application as Luminescent Sensors and Light-Emitting Devices

Lanthanide Metal–Organic Frameworks (LnMOFs), in recent years, have developed into an interesting subclass of MOFs. While the number of published papers, in particular, were dedicated to their synthesis and functional properties, along with the application mechanisms of MOFs, only a few of them have been focused on LnMOFs thin films independently. LnMOFs have become interesting thanks to their outstanding properties, for example, excellent structural flexibility, tunable pore size, surface area, functionality, and good chemical stability. Significant progress over the past two decades in the preparation of MOF films has been achieved, especially towards the development of green, or at least greener, synthesis approaches. We begin with insight into various types of MOFs and summarize recent achievements in the production of LnMOF films, along with various film preparation approaches. Afterward, we briefly discuss the applications of luminescence features of lanthanide ions in films and their potential as white-light source materials. We also covered films based on Eu, Tb, and Gd with particular accents on different design approaches. Moreover, specifically, luminescent features applied for sensing temperature, a variety of ions, gases, and biomolecules are highlighted. The review ends with a comprehensive conclusion about the state-of-art-potential of LnMOFs together with an outlook on the future of LnMOF films in future technologies.

Nd3+ emission in the garnet structure of LiCa3ZnV3O12 phosphor

Nd3+ doped vanadate phosphors are well known, mainly for their suitability for solid-state laser applications. Garnet structures are also explored for such purposes. LiCa3ZnV3O12 is one of them. Luminescence in this host has not yet been investigated. The luminescence characteristics of LiCa3ZnV3O12:Nd3+ are reported here. Two types of emissions have been observed. The self-activated luminescence could be observed under UV excitation. The characteristic emission of Nd3+ is also observed. Apart from the f–f excitation, an efficient host sensitization of Nd3+ luminescence is observed. The LiCa3ZnV3O12:Nd3+ phosphor showed an intense Near Infrared emission at 1068 nm due to the transition of 4F3/2 → 4I9/2, for 350 nm excitation.

Regulating fluorescent properties and ESIPT behavior of novel flavone-based fluorophore by replacing oxygen atom in proton donor/acceptor with sulfur atom: A TD-DFT study

Recently, the fluorescent phenomena of a new excited state intramolecular proton transfer (ESIPT) based fluorophore 3-hydroxy-2-(naphthalen-2-yl)-4H-chromen-4-one (HFN) has been reported experimentally. However, the first-hand dynamic information of its ESIPT process is still lacking theoretically. Based on density functional theory (DFT) and time-dependent DFT (TD-DFT) methods, the luminescent features and ESIPT processes of HFN and its two derivatives were studied in detail. Two HFN derivatives, 3-mercapto-2-(naphthalen-2-yl)-4H-chromen-4-one (TFN1) and 3-hydroxy-2-(naphthalen-2-yl)-4H-chromene-4-thione (TFN2) were obtained by replacing the oxygen atom of proton donor and proton acceptor in HFN with sulfur atom, respectively. The changes and effects of fluorescent properties and ESIPT process generated by different proton donors and proton acceptors are demonstrated. The simulated maximum absorption and emission peaks of HFN are well consistent with the experimental data. After replacing the oxygen atoms in proton donor and proton acceptor with sulfur atoms, the absorption wavelength of HFN slightly blue-shifts and red-shifts, respectively. And the fluorescence wavelengths of HFN obviously red-shift. The S0→S1 transitions of HFN and TFN1 are dominated by ππ* charge transfer transition, whereas the S0→S1/S0→S2 transition of TFN2 is a mixed charge transfer transition of nπ* and ππ*. The substitution of oxygen atom by sulfur atom in the proton donor or proton acceptor of HFN obviously decreases or increases the ESIPT barrier, due to its stronger proton-donating ability of S–H group or weaker proton-accepting ability of sulfur atom, respectively.

Single Molecular Persistent Room-Temperature Phosphorescence and Circularly Polarized Luminescence from Binaphthol-Decorated Optically Innocent Cyclotriphosphazenes.

Circularly polarized luminescence (CPL) features of BINOL-decorated cyclotriphosphazenes (CPs) are reported for the first time. The luminescence dissymmetry factor (glum ) of these compounds in chloroform solutions and polymethyl methacrylate (PMMA) thin films with wt 1 % doping concentrations are found to be 1.0×10-3 , and 2.9×10-3 , respectively. However, no CPL signal is observed for the pristine solids. The enantiomers (CP-(R)/CP-(S)) show ultraviolet photoluminescence (~350-360 nm) in solution and the solid state. These compounds show ~10 times larger absolute photoluminescence quantum yield (PLQY) than the simple BINOLs in the solutions state. In the solid state, CP-(R) shows larger PLQY than binaphthol-(R); in contrast, the S enantiomer shows lower PLQY than binaphthol-(S); this indicates that the isomer-dependent solid-state packing of these compounds plays a crucial role in controlling the PL. Thin films with more than 1 % doping concentration and pristine solids of these compounds do not show persistent room-temperature phosphorescence (pRTP) due to concentration-caused quenching. However, thin films with wt 1 % of these chiral emitters exhibit pRTP characteristics with a ~159-343 ms lifetime under vacuum. Theoretical calculations reveal that the cyclophosphazene acts as an optically innocent dendritic core, and the optical features of these compounds are dictated by the pendent BINOL chromophore.

Multiresponsive Self-Healing Lanthanide Fluorescent Hydrogel for Smart Textiles.

Lanthanide organometallic complexes exhibit strong luminescence characteristics, owing to their antenna effects. The f-d energy level transition causes this phenomenon, which occurs when ligands and the external electrons of lanthanide metals coordinate. Based on this phenomenon, we used two lanthanide metals, europium (Eu) and terbium (Tb), in the present study as the metal center for iminodiacetic acid ligands. Further, we developed the resulting fluorescent organometallic complex as a smart material. The ligand-metal bond in the material functioned as a metal chelating agent and a cross-linking agent in a dynamically coordinated form, thereby prompting the material to self-heal. Temperature-sensitive poly-N-isopropylacrylamide was incorporated into the material as the polymer backbone. Afterward, we combined it with water-soluble poly(vinyl alcohol) and an additional ligand from poly(acrylic acid) to fabricate a high-performance hydrogel composite material. The shrinkage and expansion of the polymer form a grid between the materials. Because of the different coordination stabilities of Eu3+ and Tb3+, the corresponding material exhibits environmental responses toward excitation wavelength, temperature, and pH, thus generating different colors. When used in fabrics, the cross-linking mechanism of the material effectively looped the material between fabric fibers; furthermore, the temperature sensitivity of the polymer adjusted the size of pores between fabric fibers. At relatively higher temperatures (>32 °C), the polymer structure shrank, fiber pores expanded, and air permeability improved. Thus, this material appears to be promising for use in smart textiles.

Improving dispersibility of lanthanide-doped upconversion nanoparticles for luminescence applications in medium polarity solvents

The dispersibility of lanthanide-doped upconversion nanoparticles (UCNPs) is related to the polarity of solvents. Typically, the as-synthesized UCNPs are poorly dispersed in medium and high polarity solvents. Here, we investigated the dispersibility of oleate-capped UCNPs in different solvents and improved the dispersibility of the nanoparticles in medium polarity solvents by a ligand exchange process. 2-naphthoxyacetic acid and α-hydroxyhippuric acid were selected as ligands to improve the dispersion of UCNPs in long-chain alcohol and ester solvents, respectively. The improvement of dispersibility was confirmed by dynamic light scattering measurements and transmission electron microscope images. In parallel, the luminescence features of the UCNPs dispersed in different solvents were measured to understand the influence of solvents on the luminescence lifetime, red-green emission ratio and power dependent properties of UCNPs. Additionally, the ligand exchange rendered an improved dispersibility of UCNPs in medium polarity media, which prevented aggregation of UCNPs in polydimethylsiloxane (PDMS) matrix improving transmittance of UCNPs-polydimethylsiloxane (PDMS). This study provides an effective method to improve the dispersion of UCNPs in organic polymer media expanding the applicability of nanoparticles in displays and anticounterfeiting.

Recovery of cyanophycin granule polypeptide from activated sludge: carbon source dependence and aggregation-induced luminescence characteristics

Recovery of cyanophycin granule polypeptide from activated sludge: carbon source dependence and aggregation-induced luminescence characteristics

Study on the structural and photophysical properties of N-acyl amino acid europium complexes

In this paper, a series of acyl amino acid europium complexes (Eu[CH3(CH2CH2)nCONHCH(CH3)COO]3, n = 0 ∼ 5) were synthesized using N-acyl amido alanine as ligands, and their structures and photophysical properties were studied.The structural and functional group information of europium complexes was obtained by elemental analysis, as well as infrared and hydrogen nuclear magnetic spectral analysis (1H NMR). The theoretical structure of the complexes was obtained by density functional theory (DFT) calculations; the theoretical structure of the complex was shown to be reliable by the comparison of theoretical and experimental vibrational and 1H NMR spectra. Additionally, the photophysical properties of the solid complexes at room temperature were determined by analysis of Ultraviolet–visible spectroscopy(UV–vis) and luminescence spectra. From the test results, it can be seen that the complex had good light absorption capacity in the range of 200–––300 nm; By comparison of the luminescence intensities of the complexes and EuCl3 proved that acyl amino acid ligands played a role in sensitizing Eu3+ characteristic luminescence. In addition, the effect of solution concentration on fluorescence performance has been studied. It can be inferred that complexes with longer carbon chains are less prone to aggregation in solution (increasing repulsive forces with increasing hydrophobicity), and the concentration, where fluorescence quenching occurs, is higher. Moreover, the solvent effect on the luminescence performance of the complexes was investigated by testing the luminescence spectrum of the complexes with different carbon chain lengths in a methanol solution(0.01 mol/L). Finally, the variable temperature spectral analysis provided information on the temperature-dependent variation of the luminescence properties of the complexes. The fluorescence performance of complexes with different carbon chain lengths that having different changing trends with temperature, with long carbon chain complexes exhibiting better high-temperature fluorescence stability.

Luminescence characteristics of ultra-broadband near-infrared emission Li3Mg2SbO6:Cr3+ phosphors and their applications in light-emitting diodes

In this study, a Li3Mg2SbO6:Cr3+ phosphor was prepared by high-temperature solid-phase reaction. The phosphors doped with 0.03Cr3+ showed broadband emission at 805 nm, a wide spectral band of 200 nm at 435 nm excitation, an internal quantum efficiency of 80.8%, and the integrated emission intensity at 423 K of Li3Mg2SbO6:Cr3+ is about 50% of that at room temperature. The phosphors conversion (pc) - light-emitting diodes (LEDs) with broadband near-infrared (NIR) emission were prepared using the Li3Mg2SbO6:Cr3+ phosphor coating on blue LED chips. They achieved 10.4% photoelectric efficiency and 60.2 mW NIR output power at 210 mA. All results showed that the Li3Mg2SbO6:Cr3+ phosphors had considerable potential in NIR spectroscopy applications.

The bimetallic synthesis of TeO2–Sb2O4 thin films for optoelectronic applications

The current study aimed to synthesize the bimetallic oxide of TeO2–Sb2O4 thin films with different Te weights (0, 10, 20 and 50 wt %.). The chemical vapor deposition (CVD) technique is used for thin film deposition. Various analytical techniques are used for morphological, structural, optical and luminescent characterizations. Results of SEM and XRD indicated that Te contents changed the nucleation and growth rates, hence the regular-irregular morphology. The calculated crystallite size associated with the (222) peak achieved the maximum value of 41.2 nm when Te weight was 10 wt%, in opposite synchronization with both strain and dislocation density. The oxidation kinetics of TeO2–Sb2O4 are well explained. The optical analysis by spectrophotometer showed decrease in NIR transmittance (70 - 40%), direct (1.32–1.25 eV) and indirect band gaps (0.96–0.77 eV) with increasing Te weight. The PL spectra showed immutability and increase of the emission peaks of the mixed phase samples. The broad - intense luminescence peak of the bimetallic alloy encouraged their possible applications in light emitting devices. The mixed TeO2–Sb2O4 films have longer average life time than the unmixed films which might useable in various applications such as nanothermometers and in time-resolved fluorometry.

Rare Earth Ion Doped Luminescent Materials: A Review of Up/Down Conversion Luminescent Mechanism, Synthesis, and Anti-Counterfeiting Application

With the rapid development of modern technology and information systems, optical anti-counterfeiting and encryption have recently attracted considerable attention. The demand for optical materials is also constantly increasing, with new requirements proposed for performance and application fields. Currently, rare earth ion doped materials possess a unique electronic layer structure, underfilled 4f5d electronic configuration, rich electronic energy level, and long-life excited state, which can produce a variety of radiation absorption and emission. The distinctive properties of rare earth are beneficial for using in diverse optical output anti-counterfeiting. Design is essential for rare earth ion doped materials with multiple responsiveness and multi-channel optical information anti-counterfeiting in the field of information security. Therefore, this mini review summarizes the luminescent mechanisms, preparation methods, performance characteristics and anti-counterfeiting application of rare earth doped materials. In addition, we discuss some critical challenges in this field, and potential solutions that have been or are being developed to overcome these challenges.

Novel Fluoride Matrix for Dual-Range Optical Sensors and Visualization

Novel tetragonal matrix Ba0.5−xLn0.5NaxF2.5−x with x = 0.08, doped by Yb3+, Ho3+, Er3+, was synthesized by molten salt synthesis (MSS) from nitrate flux. XRD data show that the tetragonal phase with a = 4.122(1) Å, c = 17.672(1) Å is stable in an argon atmosphere up to 960 °C. Luminescence spectra recorded in 500–900 nm and 1050–1700 nm upon 974 nm pumping demonstrated the characteristic luminescence at 1550 nm (4I13/2 → 4I15/2) for Er3+ and 1150 nm (5I6 → 5I8) for Ho3+. The relative thermal sensitivity (Sr) at 296–316 K were 0.3%×K−1 and 5.5%×K−1 in shortwave infrared (SWIR) and visible range, respectively. Synthesized luminophores can be used as dual-range optical temperature sensors, which simultaneously operate in visible and SWIR ranges.

Al3+ doping enhanced photoluminescence properties of Ca2InNbO6: Mn4+ far-red phosphor for plant cultivation

The study focuses on the synthesis of far-red phosphors Ca2InNbO6: xMn4+ (0 ≤ x ≤ 0.006) and Ca2InNbO6: 0.003Mn4+, yAl3+ (0 ≤ y ≤ 0.024). First-principles calculations confirmed that the indirect bandgap of Ca2InNbO6 used to be 3.522 eV. Photoluminescence spectroscopy was used to examine the luminescence characteristics and energy transfer mechanism of CINO: xMn4+ and CINO: 0.003Mn4+, yAl3+ phosphors. When Mn4+ ions undergo the 2Eg → 4A2g transition under 380 nm excitation, brilliant red light with a central wavelength of 688 nm is released. In addition, the emission intensity reaches 2.6 times that of CINO: 0.003Mn4+, when Al3+ has a 1.2% optimal doping concentration. At the same time, the thermal stability of the material is improved. The reasons for the enhanced fluorescence and thermal stability were analysed by lattice distortion and blocking of energy transfer. Additionally, the prepared red LED lamps, which shown a bright red light even after long periods of operation at high temperatures, were used for the cultivation of plant seeds, and the germination rate as well as the stems and leaves thriving growth were significantly better than the cultivation without the red LED, suggesting that Al3+ doping Ca2InNbO6: Mn4+ has potential applications in the field of plant cultivation and growth LEDs, and is a guide for ion-doped modified phosphors.

A multi-mode self-referenced optical thermometer based on low-doped YVO4: Eu3+ phosphor

In recent years, the continued development of optical thermometry has become a hot topic of interest for researchers, due to its advantages of non-contact and non-invasive temperature measurement. The optical thermometry is based on the different photophysical properties or changes in luminescent parameters of luminescent materials to reflect temperature. Further, the development of multi-mode optical thermometers can effectively expand the practical application rang of the temperature measurements. Here, we monitored various temperature sensitive luminescence characteristics of YVO4: Eu3+ phosphor by testing its temperature-dependent photoluminescence (PL) spectra, photoluminescence excitation (PLE) spectra, and luminescence decay curves. We successfully realized a multi-mode optical thermometer based on the luminescence intensity ratio, absorption intensity ratio, the thermally induced behavior of the charge transfer band, and luminescent transition probability (A) of the host material. Different temperature measurement strategies were evaluated and compared in terms of relative sensitivity (Sr) and temperature uncertainty (ΔT). Notably, the Sr of the rarely used temperature measurement strategy based on the A of host luminescence was the optimal among the studied strategies with 2.03% K−1, corresponding to a ΔT of 0.5 K. The results suggest that YVO4: Eu3+ phosphor has potential applications in self-referential optical thermometry.

Synchrotron studies of Ag+ and Dy3+ ions in zinc lanthanum aluminum borate glasses synthesized using Novel Microwave melt-quenching technique

A novel microwave heating technique is used in the present work to synthesis the glasses. In this work, the stoichiometry ratio of (43-x) B2O3+ 45ZnO+ 5La2O3+ 5Al2O3+ 0.5SnO2+ 1.5AgNO3+ xDy2O3 were exposed to microwave energy, with 800-W power, holding time was 26 min to synthesize by novel melting in microwave and quenched suddenly. The study focused on borosilicate glasses such as physical, optical, and luminescent characteristics. The prepared glasses were subjected to evaluate density, molar volume, and refractive index. The optical absorption spectra of glasses were measured in the range of 200–2000 nm. The surface plasmon resonance of AgNPs peaks resonates with the radiative transitions of Dy2O3 ions at 429 nm. The emission spectra in the visible region showed three peaks in the range 450–700 nm, and the excitation spectra of developed glass samples in the range of 200–500 nm, most intense peak was observed at 351 nm. Asymmetry ratio enhancement was achieved by changing the excitation wavelength and silver nanoparticle concentration. The highest Y/B value of 1.532 was observed at 1.0 mol%. The non-exponential lifetime decay curves of 0.3, 0.5, and 1.0 mol%, show 0.337, 0.376, and 0.269 ms respectively. J-O parameter shows trend Ω2 > Ω6 > Ω4. Synchrotron studies were subjected to comprehend the coordination chemistry of silver nanoparticles, dysprosium ions, and correlated with the results obtained.

MnOx In Situ Growth-Induced Luminescence and Oxidase-Like Feature Bimodulation of CePO4:Tb Nanorods: Toward Ascorbic Acid-Related Bioanalysis in a "One-Stone-Two-Birds" Manner.

Nanozyme-based multimode detection is a useful means to improve the accuracy and stability of analytical methods. However, both multifunctional nanozymes and related multimodal sensing strategies are still very scarce. Besides, they require complex processes to fabricate and operate. To fill this gap, here we propose a spontaneous interfacial in situ growth strategy to prepare a new bifunctional material (CePO4:Tb@MnOx) featuring good oxidase-like activity and green photoluminescence for the dual-mode colorimetric/luminescence determination of ascorbic acid (AA)-related biomarkers specifically. CePO4:Tb@MnOx was gained through the controllable redox reaction between KMnO4 and CePO4:Tb nanorods. It was interestingly found that MnOx in situ growth not only significantly enhanced the enzyme-like activity but also could reversibly regulate the luminescence of CePO4:Tb via a dual quenching mechanism. More interestingly, CePO4:Tb@MnOx exhibited a distinctive response toward AA against other reducing species. A double-coordination regulation mechanism was further verified to clarify the catalytic activity and luminescence switching behaviors in CePO4:Tb@MnOx. Based on these findings, a dual-mode colorimetric/luminescence approach was established for AA sensing in a "one-stone-two-birds" manner, providing excellent selectivity, sensitivity, and practicability. Furthermore, the determination of AA-related biomarkers, including acid phosphatase activity and organophosphorus residue, was also validated by the sensing principle. Our work not only deepens the understanding of the coordinated regulation of the luminescence and enzyme-like features in lanthanide-based materials but also offers a novel way to design and develop multifunctional nanozymes for advanced bioanalytical applications.

Photoelectric and structural properties of super stable perovskite quantum dots glasses for contactless underwater electroluminescent LEDs

The photoelectric field has witnessed notable progress with the emergence of perovskite quantum dots. However, their practical utility is constrained by their susceptibility to degradation and malfunction when exposed to external environmental factors like light, heat, and humidity. To overcome these limitations, a potential solution lies in the growth of perovskite quantum dots within glasses, leveraging the dense network structure of inorganic glasses to achieve a seamless encapsulation of the quantum dots. This approach effectively addresses the challenges of quantum dot stability and the risk of lead contamination by isolating the quantum dots from the external environment. This study utilizes an in situ nanocrystallization approach to cultivate CsPbBr3 perovskite quantum dots within a matrix of glasses. The resulting CsPbBr3 perovskite quantum dots glasses (CsPbBr3 PQDs@glasses) demonstrate a vibrant green emission due to exciton recombination radiation. The investigation focused on the luminescent characteristics of CsPbBr3 PQDs@glasses subjected to pressures ranging from 0 to 7 GPa, which resulted in a significant red shift in the spectra, transitioning from 519 nm to 525 nm. Electronic structure, dispersion and vibrational properties of CsPbBr3 was investigated under varying pressure conditions through the utilization of first-principles methods. Furthermore, an examination of the pressure distribution within the diamond anvil cells was conducted from a macroscopic perspective employing the finite element method. Subsequently, contactless underwater electroluminescence devices incorporating CsPbBr3 PQDs@glasses were devised, employing the principle of electromagnetic induction. This study offers essential insights into the physics of perovskite materials subjected to high pressure, thereby establishing a groundwork for prospective applications.