Luminescence Of Phosphors Research Articles

Enabling efficient persistent luminescence in CdSiO3 phosphors through In3+ doping for optical information storage and dynamic encryption

CdSiO3, with its distinctive crystal structure, has become a subject of considerable interest as a potential silicate host for long persistent luminescence (LPL) phosphors. However, in most cases, impurity phases in the host adversely affect the persistent luminescence (PersL) performance. Furthermore, there is still a lack of insightful understanding regarding the role of non-rare-earth (non-RE) In3+ ions in the enhanced blue PersL of CdSiO3. Here, pure-phase monoclinic CdSiO3 phosphor is synthesized through a solid-state reaction method and the intense blue PersL is achieved by aliovalent doping of In3+. Combining experimental results with theoretical calculation, we reveal that the intrinsic defects of O and Cd vacancies in CdSiO3 are the trap centers for excited electrons and holes, respectively. In3+ doping adjusts the distribution and increases the density of intrinsic defect-related traps, thus producing the intense blue PersL in CdSiO3:In3+. Moreover, the generality of In3+ in enhancing the PersL properties is validated in CdSiO3:Mn2+,In3+ and CdSiO3:RE3+,In3+ (RE = Tb, Dy, Pr, Sm, Eu) phosphors, enriching the spectrum of PersL emission colors. Encouraged by the outstanding optical properties of CdSiO3:Mn2+,In3+, we demonstrate dual-mode information storage-reading and dynamic information encryption applications. This advancement opens new avenues for the application of optical information security. This work emphasizes the key role of In3+ in adjusting the distribution and increasing the density of intrinsic defect-related traps. Consequently, it reveals a clear mechanism for enhancing PersL through In3+ doping and expands the range of LPL phosphors with broad spectral selectivity.

Luminescent phosphor glasses with Sm2O3 for photodynamic therapy application

Photodynamic therapy is a modern and non-invasive therapy used for the treatment of non-cancerous diseases as well as cancers of various types. Because of good therapeutic results and the possibility of parallel application of photodynamic therapy (PDT) with other therapeutic protocols, this treatment is widely used in many fields of medicine and biomedical applications. This paper is devoted to the preparation of new luminescent phosphate glasses, suitable for the application in photodynamic therapy. Phosphor glasses with different composition were prepared in this study. Transmittance spectra, excitation spectra and luminescence of the prepared samples were measured. Furthermore, the photosensitivity of rhodamine b to light generated by the prepared N4 glass was described. By measuring all samples, it was found that the most optimal from all prepared glasses is sample N4. This sample, containing oxides in molar percentages, is well-suited for use in photodynamic therapy applications: Na2O – 12.75 %; CaO – 2.31 %; ZnO – 34.20 %; SiO2 – 40.08 %; P2O5 – 9.11 %; Sm2O3 – 1.55 %.

Upconversion luminescence and thermosensitive properties of NaGd(PO3)4:Yb3+/Er3+

High-sensitivity optical temperature measurement has attracted extensive attention in both fundamental studies and practical applications. In this study, a series of upconversion (UC) luminescence phosphors composed of NaGd(PO3)4 (NGP) doped with 20 at% Yb3+ and various concentrations of Er3+ (0.5 at% as the optimal concentration) was synthesized by high-temperature solid-state method. And their crystal structure and the distribution of lanthanide dopants were analyzed using X-ray diffraction with Rietveld refinement verifies. Under 980 nm laser excitation, the obtained phosphors show the characteristic Er3+ upconversion green and red emission bands through two-photon processes. The fluorescence intensity ratio (FIR) based on the thermal coupled states demonstrates the thermal sensing ability in a wide temperature range of 200–573 K. The thermal sensitivity is relatively high with the maximum absolute thermal sensitivity Sa of 0.53 % K−1 (523 K) and the maximum relative thermal sensitivity Sr of 2.60 % K−1. The phosphor NGP:Yb/Er also exhibits high repeatability as the thermal sensors reach 97 %. These findings postulate the potential of NGP:Yb/Er as a promising candidate in optical thermal sensing applications.

Spectral characteristics and luminescence applications of Eu3+-activated fluorosilicate Na2MgGd2[SiO3]4F2

This work reports the luminescence spectra and application of novel Eu3+-doped Na2MgGd2[SiO3]4F2 phosphor. The X-ray powder diffraction confirmed the pure phase formation of the samples with the monoclinic space group P21/c (No:14). The phosphors demonstrated efficient red emission at 613 nm from the electric dipole transitions 5D0→7F2. The optimal doping concentration was found to be approximately 25 mol%. Na2MgGd2[SiO3]4F2:0.25Eu3+ exhibits a high quantum efficiency (QE) of 57 % with excellent thermal stability and pure chromaticity. Red- and the white light-emitting diode devices were packaged using InGaN chips and Na2MgGd2[SiO3]4F2:0.25Eu3+. The fabricated WLED has CIE coordinates of (x = 0.33, y = 0.34), which are very close to the white point in the National Television System Committee (x = 0.33, y = 0.33). The color rendering index (CRI, Ra) and correlated color temperature (CCT) of the WLED are 91 and 4400 K, respectively. The results show that as a red luminescent phosphor, it is a potential candidate for the preparation of near-UV/blue InGaN-based WLEDs.

Temperature dependent upconversion luminescence of GdScO3 phosphors with low phonon energy for optical thermometry

Temperature dependent upconversion luminescence of GdScO3 phosphors with low phonon energy for optical thermometry

Highly thermally stable CaLaMgSbO6: Sm3+ double perovskite phosphors for optical thermometer and plant growth

A series of CaLaMgSbO6: Sm3+ orange-red phosphors were synthesized using a high-temperature solid-state method. These phosphors' phase, luminescence properties, and thermal stability were thoroughly investigated. Under 405 nm excitation, the CaLaMgSbO6: Sm3+ phosphor exhibit a broadband orange-red emission with the maximum emission peak positioned at 598 nm. The optimal CaLaMgSbO6: 0.025Sm3+ phosphor features CIE chromaticity coordinates of (0.5902, 0.4085) with an orange-red hue. Impressively, the emission intensity at 423 K remains at 78.7 % of its room temperature intensity, which shows its outstanding thermal stability. The emission spectra of light-emitting diodes (LEDs) fabricated with CaLaMgSbO6: 0.025Sm3+ phosphor possess a large overlap with the absorption band of phytochromes. Meanwhile, the temperature-sensing properties of CaLaMgSbO6: Sm3+ phosphors were studied across various wavelength bands using the fluorescence intensity ratio (FIR) technique. The relative sensitivity of FIR (I598/I563) was found to be highest at 298 K, measuring 0.15 % K−1. The above research results suggest that CaLaMgSbO6: Sm3+ phosphors have potential applications in plant growth and optical temperature sensing.

X-ray/γ-ray/Ultrasound-Activated Persistent Luminescence Phosphors for Deep Tissue Bioimaging and Therapy.

Persistent luminescence phosphors (PLPs) can remain luminescent after excitation ceases and have been widely explored in bioimaging and therapy since 2007. In bioimaging, PLPs can efficiently avoid tissue autofluorescence and light scattering interference by collecting persistent luminescence signals after the end of excitation. Outstanding signal-to-background ratios, high sensitivity, and resolution have been achieved in bioimaging with PLPs. In therapy, PLPs can continuously produce therapeutic molecules such as reactive oxygen species after removing excitation sources, which realizes sustained therapeutic activity after a single dose of light stimulation. However, most PLPs are activated by ultraviolet or visible light, which makes it difficult to reactivate the PLPs in vivo, particularly in deep tissues. In recent years, excitation sources with deep tissue penetration have been explored to activate PLPs, including X-ray, γ-ray, and ultrasound. Researchers found that various inorganic and organic PLPs can be activated by X-ray, γ-ray, and ultrasound, making these PLPs valuable in the imaging and therapy of deep-seated tumors. These X-ray/γ-ray/ultrasound-activated PLPs have not been systematically introduced in previous reviews. In this review, we summarize the recently developed inorganic and organic PLPs that can be activated by X-ray, γ-ray, and ultrasound to produce persistent luminescence. The biomedical applications of these PLPs in deep-tissue bioimaging and therapy are also discussed. This review can provide instructions for the design of PLPs with deep-tissue-renewable persistent luminescence and further promote the applications of PLPs in phototheranostics, noninvasive biosensing devices, and energy harvesting.

X‐ray–induced multicolor long afterglow and photostimulated luminescence from Pr3+‐doped Sr3(PO4)2

AbstractIn this paper, X‐ray–induced multicolor long afterglow and photostimulated luminescence from Sr3(PO4)2: Pr3+ was reported. The Rietveld refinement results have confirmed the as‐prepared sample was pure Sr3(PO4)2 phase with hexagonal crystal system. And Sr3(PO4)2: Pr3+ showed an excellent X‐ray–induced long afterglow luminescent performance. Under the excitation of X‐ray, the sample showed multicolor long afterglow luminescence from UVC to red region located at 268, 359, 466, 548, 604.3 and 685 nm, which can be ascribed to 4f5d‐3H4, 4f5d‐ 1D2, 4f5d‐3P0, 3P0→3H5 and 1D2→3H4, respectively. And the strongest afterglow emission intensity appeared at 468 nm. Furthermore, only 30 s X‐ray irradiation can induce 12 h afterglow emission, which afterglow emission intensity of 468 nm still reached 3.71 × 104 cps and was about 37.1 times stronger than the background intensity. In particular, the relation between 268 nm afterglow emission intensity and 468 nm afterglow emission intensity showed good linearity. And the UVC afterglow emission can be easily “observed” via the visible afterglow light. Furthermore, Sr3(PO4)2: Pr3+ possessed an excellent photostimulated luminescence (PSL) under the excitation of 980 nm NIR laser and the PSL intensity of the 12 circle still arrived at 1.26 × 105 cps, which was about 37.1 times stronger than the afterglow emission intensity after 5 h decay. All these results showed that the as‐prepared Sr3(PO4)2: Pr3+ phosphor was an excellent X‐ray–induced long afterglow luminescence phosphor, which possessed large potential applications in the medical field.

Realizing Tunable Long Persistent Luminescent in Novel Cu2+‐Doped NaGaO2 for Multi‐Level Information Storage and Encryption

AbstractAnti‐counterfeiting and encryption are key technologies for information transmission in modern society. However, most optical materials offer only a single fixed response mode, limiting their security level in advanced anti‐counterfeiting applications. Exploring efficient and tunable long persistent luminescent (LPL) phosphors is urgently demanded and highly meaningful. In this work, a dual‐site occupancy strategy is innovatively reported via Li+ doped NaGaO2: Cu2+ (NGO: Cu2+/Li+) phosphors for enhancing LPL properties. To be specific, Cu2+ initially occupies both Na and Ga sites in NaGaO2, producing orange–yellow LPL at 585 nm and near‐infrared (NIR) emission at 712 nm, respectively. Furthermore, the introduction of Li+ will occupy the Na+ sites, attenuating the NIR emission and increasing the defect density of the oxygen‐deficient states, which results in enhanced LPL intensity and prolonged afterglow time. Significantly, the obtained NGO:Cu2+/Li+ exhibits multi‐emission modes with dynamic change of LPL time (10–20 min). More importantly, the NGO: Cu2+/Li+ has great potential applications in multi‐level information storage and encryption.

Nuanced synthesis strategies and comprehensive analysis of intricate multifarious luminescent phosphor hosts

AbstractThis paper primarily addresses various methodologies for synthesizing novel phosphors, with our focus mainly on the mixed alkaline tungstate phosphor Ca2MgWO6. In the initial synthesis phase, we used precisely weighed CaCO3, MgO, and WO3 for the synthesis. The XRD patterns indicated the presence of an impure phase, specifically CaWO4, in the resulting product. We adeptly tackled the formation of CaWO4 and mitigated it by employing a multifaceted approach. These included adding an excess amount of MgO, opting for an alternative chemical route, and the incorporation of flux during synthesis. It was observed that the product obtained through the addition of flux exhibited a purity level of approximately 99.75% with a margin of error of ± 0.02%. Ultimately, we have carried out structural, morphological, optical, and thermal characterizations, along with density functional theory (DFT) simulations, to assess the fundamental parameters of the pure sample.

Degree of Crystal Structure Distortion-Induced Tunable LiGaO2 Long Persistent Luminescence for Optical Information Encryption.

Tunable long persistent luminescence (LPL) phosphor materials have great potential for optoelectronic cryptographic applications. However, the mainstream techniques of modulating LPL generally have the characteristics of complex preparation processes, demanding crystal field environments, or expensive dopant ions, which restrict large-scale commercial application. Herein, we develop a simple, high-efficiency, and low-cost strategy to optimize the LPL of LiGaO2(LGO):Cu2+ by changing the sintering time to regulate the degree of crystal structure distortion. The Cu2+ as charge compensation will substantially enhance the emission intensity of LGO by a factor of 11.02 originating from the appropriate ionic size and coordination mode. Besides, the LPL time of LGO:Cu2+ can be extended effectively to 2 h by adjusting the sintering temperature and time (900 °C@24 h). The extension mechanism is that Li and Ga can be substituted for each other more easily and induce crystal structure distortion due to the special crystal structure of LGO, resulting in an optimal trap concentration in LGO:Cu2+. Thus, our findings provide a simple way to modulate long persistent luminescence and further consider their potential impact on optical information encryption.

A Cr3+-Yb3+ co-doped high-efficiency near-infrared luminescent phosphor for NIR-II light source applications

Phosphor conversion light-emitting diode (PC-LED) technology has become a focal point of research for portable near-infrared light sources in recent years. One of the crucial aspects is to develop phosphor materials that can be effectively stimulated by commercial available blue light. Unfortunately, efficient phosphors in the NIR-II that can be excited by commercial blue light are particularly scarce. In this study, Mg4Ta2O9:0.04Cr3+,0.03Yb3+,0.07Li+ (MTO:0.04Cr3+,0.03Yb3+,0.07Li+) phosphor was synthesized using the high temperature solid phase method, and its emission spectrum covered the first and second near-infrared windows (700–1200 nm). The internal quantum efficiency (IQE) and external quantum efficiency (EQE) are 88.7 % and 45.6 %, respectively, due to the synergistic effect of energy transfer and Li-ion modification. Additionally, the doping of Yb3+ ions and Li+ ions enhances the thermal stability of luminescence. The thermal stability of MTO:0.04Cr3+,0.03Yb3+,0.07Li+ and MTO:0.04Cr3+,0.03Yb3+ is 9.81 % and 14.43 % higher, respectively, than that of MTO:0.04Cr3+,0.03Yb3+ and MTO:0.04Cr3+. To evaluate its potential applications, we developed a prototype PC-LED utilizing MTO:0.04Cr3+,0.03Yb3+,0.07Li+ phosphor as an emission emitter which demonstrated advantages in biomedical imaging, night vision, and non-destructive testing.

Simultaneously enhanced photoluminescence and persistent luminescence in SrLaAlO4: Tb type layered perovskite via Gd3+ codoping

Gd3+ co-doping is effective to enhance the photoluminescence of rare earth activators in various host due to energy transfer, however, it is rarely reported via such strategy to regulate persistent luminescence properties. In this work, Gd3+ was co-doped into the SrLaAlO4: Tb persistent luminescence phosphors, and it is found that the photoluminescence and persistent luminescence of the products can be simultaneously improved. The results indicate that as the doping concentration of Gd3+ increases, the particle diameters increase which contributes the increased luminescence. Additionally, an energy transfer process from Gd3+ to Tb3+ ions was observed, which enhances the emission of Tb3+ ions. Furthermore, the persistent luminescence properties of the synthesized phosphors were improved. When the UV light source is turned off, the persistent luminescence of SrLaAlO4: 0.03Tb3+, xGd3+ (x = 0.00–0.97) can last for more than 2 h, which is 100 % enhanced compared to SrLaAlO4: 0.03Tb3+. The trap distribution of SrLaAlO4: 0.03Tb3+, xGd3+ (x = 0.00–0.97) phosphors was analyzed by thermoluminescence. It is found that after the substitution of La3+ with Gd3+, the trap position shifted towards higher temperatures and the trap concentration increased. The initial intensity of the persistent luminescence was also enhanced after Gd3+ co-doping. Based on the experimental findings, the luminescence and persistent luminescence mechanism of SrLaAlO4: 0.03Tb3+, xGd3+ (x = 0.00–0.97) phosphors were described and discussed.

Boosted sensitive optical thermometers utilizing synergistic effects of thermal enhancement and quenching in Er/Yb/Nd triply-doped Bi4Ti3O12 nanosheets

Rare earth-doped nanomaterials can achieve diverse upconversion luminescence by changing doping ions, presenting them as promising candidates for rapid temperature measurement. However, most upconversion luminescent phosphors have a thermal quenching effect, which greatly weakens the luminous intensity of the material and impairs thermometry performances. Here, we studied the synthesis of Bi4Ti3O12 nanosheets tridoped with Er3+, Yb3+, and Nd3+ ions using molten salt method. Notably, this luminescent material demonstrates both thermal quenching and thermal enhancement effects. The unusual phenomenon results in a high sensitivity of the optical temperature sensor based on the inter-ion energy level between Er3+ and Nd3+. At 523 K, this sensitivity reaches 5.94×10−2 K−1, surpassing that of sensors relying on the thermal coupling of only Er3+ ions by nearly ninefold. Our findings suggest a promising strategy to augment the temperature sensing sensitivity of luminescent materials, paving the way for potential applications in precise temperature monitoring.

Broadband Near-Infrared Light Excitation Generates Long-Lived Near-Infrared Luminescence in Gallates.

Persistent luminescence describes the phenomenon whereby luminescence remains after the stoppage of excitation. Recently, upconversion persistent luminescence (UCPL) phosphors that can be directly charged by near-infrared (NIR) light have gained considerable attention due to their promising applications ranging from photonics to biomedicine. However, current lanthanide-based UCPL phosphors show small absorption cross sections and low upconversion charging efficiency. The development of UCPL phosphors faces challenges due to the lack of flexible upconversion charging pathways and poor design flexibility. Herein, we discovered a lattice defect-mediated broadband photon upconversion process and the accompanying NIR-to-NIR UCPL in Cr-doped zinc gallate nanoparticles. The zinc gallate nanoparticles can be directly activated by broadband NIR light in the 700-1000 nm range to produce persistent luminescence at about 700 nm, which is also readily enhanced by rationally tailoring the lattice defects in the phosphors. This proposed UCPL phosphor achieved a signal-to-background ratio of over 200 in bioimaging by efficiently avoiding interference from autofluorescence and light scattering. Our work reported a lattice defect-mediated photon upconversion phenomenon, which significantly expands the horizons for the flexible design of UCPL phosphors toward broad applications ranging from bioimaging to photocatalysis.

Strong red upconversion luminescence of Yb3+/Er3+ co-doped Sc6WO12 phosphor for optical thermometry

Herein, a strong red upconversion phosphor of Yb3+/Er3+ co-doped Sc6WO12 was prepared by employing an equivalent substitution approach. When irradiated by 980 nm near-infrared laser, the phosphor emits strong 660 nm red light. The main excitation mechanism for its red upconversion luminescence emission is the energy transfer process, through which the Er3+ ions is promoted from the 4I13/2 energy level to the 4F9/2 energy level. In addition, it is noteworthy that the multimode upconversion luminescence phosphor exhibits three different trends upon temperature change, and its upconversion emission integral intensity ratio exhibits a linear relationship with temperature in the range of 298 K–623 K. This special property makes the phosphor promising for applications in optical temperature measurement.

Structural characterization and luminescence characteristics of Dy3+ doped Sr9Y2W4O24 phosphor for application in white-LEDs

In this research, a series of Dy3+ ions doped Sr9Y2W4O24 (SYWO) phosphors was prepared for the application in white-LEDs and display devices. The structure, surface, and photo-luminescent (PL) behaviour of the samples were studied. X-ray diffraction (XRD) and Fourier Transform Infra-Red (FT-IR) spectroscopy indicated the formation of single phase particles with no contaminants with various vibrational bands present in the host lattice. The synthesised powders showed agglomeration with the average crystallite size to be in the range of 22–27 nm. The optical band gaps were estimated using diffuse reflectance spectral (DRS) data. The emission spectra of SYWO: xDy3+ (1.0, 2.0, 3.0, 4.0, & 5.0 mol%) have been obtained at different excitation wavelengths of 354, 367, and 391 nm. The SYWO phosphors emit intense blue and yellow colors at 491 nm (4F9/2 → 6H15/2), 576 nm (4F9/2 → 6H13/2) & 679 nm (4F9/2 → 6H11/2), respectively. Furthermore, from the CIE 1931 diagram, it is evident that the emission from these Dy3+ doped phosphors lies in the white region. The lifetime of excited Dy3+ ions decreased with increasing Dy3+ concentration as seen in the luminescence decay graphs. Finally, to determine the phosphor's luminescence thermal stability, temperature dependent photoluminescence (TD-PL) was recorded and the activation energy calculated from this study was found to be 0.231 eV. In the light of aforementioned results, we can conclude that Dy3+ doped Sr9Y2W4O24 phosphors could be used in construction of w-LEDs or as white-emitting luminescent materials in various photonic devices and other photonic applications.

Study on structural luminescence characteristics of a new Dy3+ activated white luminescent phosphor

A series of Y1-xGa1.5Al1.5(BO3)4: xDy3+ were prepared by a high-temperature solid-phase method. Rietveld refinement characterized the phase purity of the samples obtained, suggesting that the prepared phosphors were high-purity material phases. After synthesizing high purity phase, the luminescence mechanism is revealed, under 348 nm excitation in Y0.97Ga1.5Al1.5(BO3)4: 0.03Dy3+ phosphor, the samples have two characteristic peaks at 480 nm and 572 nm and the burst mechanism is dipole-dipole mechanism. The mechanism of luminescence and quenching is analyzed by analyzing the band structure, and the relationship between the band gap and thermal stability is explained. The prepared phosphor has a quantum efficiency of 51.22 % and exhibits intense white light emission. The thermal stability of the samples was characterized, and the phosphor could still achieve 88.20 % thermal stability at 423 K. Finally, the chromaticity coordinates of the Y1-xGa1.5Al1.5(BO3)4: xDy3+ phosphors all fall in the white-light region, with the color coordinates around (0.33, 0.33). By combining with the 365 nm chip and Y0.97Ga1.5Al1.5(BO3)4: 0.03Dy3+ phosphor, the W-led device with Ra = 68.3 and CCT = 6670 K was synthesized. Therefore, the Y0.97Ga1.5Al1.5(BO3)4: 0.03Dy3+ phosphor prepared in this experiment has some application value in the field of solid-state lighting.

Bi3+/Eu3+ Co‐Activated Multimode Anti‐Counterfeiting Material with White Light Emission and Orange‐Yellow Persistent Luminescence

AbstractTraditional anti‐counterfeiting luminescent phosphors are usually composed of single‐mode photoluminescence materials, which greatly limits the security of encryption by its static fluorescent pattern. Herein, multi‐mode luminescence properties are achieved including fluorescence and persistent luminescence (PersL) within single host by co‐doping Bi3+ and Eu3+ in CaNaSb2O6F (CNSOF). A tunable emission is observed from blue (Bi3+, 3P1→1S0) to white and then to orange‐yellow (Eu3+, 5D1→7F2 and 5D0→7F0, 1, 2, 3, 4) as the excitation schemes, environment temperatures and doping level are modulated. Impressively, the blue emission attributed to the Bi3+ rapidly disappears after stopping the excitation light irradiation, and only the intense orange‐yellow PersL produced by Eu3+ can be observed. And a possible model for the energy transfer and PersL mechanism is proposed by the investigation crystal structure and photoluminescence/PersL. A schematic of security logo and digital information encryption is demonstrated using the prepared samples, which shows the dynamic evolution of the emission color and PersL brightness. The excellent property of multiple color outputs, different decay processes, and external field stimulation modes (including low energy light, thermal, and mechanical stimuli) present in CNSOF:Bi3+, Eu3+ provides a fast, low‐cost, and effective method for advanced anti‐counterfeiting and information encryption applications.

Luminescent boron carbon oxynitride phosphors: a cost-efficient strategy to boost solar cell spectral responsiveness

The incorporation of a Luminescent down-shifting (LDS) layer has emerged as a compelling approach for augmenting the light absorption sensitivity and power conversion efficiency of solar cells, particularly in the short-wavelength light spectrum. In this investigation, we propose the utilization of low-cost, environmentally benign Boron carbon oxynitride (BCNO) phosphors as a viable material for the enhancement of solar radiation absorption in the ultraviolet-blue range. We synthesized BCNO phosphors through a combustion method and conducted a comprehensive analysis of the structural and spectral attributes concerning the impact of temperature. The synthesized boron carbon oxynitride phosphors exhibit a hexagonal boron nitride structure, with an irregular shape and an average particle size of 2447.9 nm. The analysis of photoluminescence spectra reveals that BCNO phosphors effectively capture photons within the 300–500 nm wavelength range and subsequently re-emit them at longer wavelengths. This phenomenon aligns with the overarching goal of optimizing solar cell performance, as it is in the longer wavelength range that solar cells exhibit enhanced efficiency. These findings support the promising potential of BCNO phosphors as a compelling choice for deployment as an LDS layer material on the periphery of solar cells. By facilitating increased photon absorption in the short-wavelength region, BCNO phosphors have the capacity to significantly enhance device performance.