Lower Moments Research Articles

Moment Curvature and P-M Interaction Analysis of Steel and GFRP Reinforced Concrete Column

This research explores the use of Glass Fiber Reinforced Polymer (GFRP) bars and GFRP circular sections as longitudinal reinforcement in Reinforced Concrete (RC) columns, specifically to mitigate corrosion issues in harsh coastal environments. Twelve concrete specimens were prepared and tested under various loading conditions to evaluate the performance of GFRP as a substitute for conventional steel reinforcement. The experimental findings indicated that GFRP-RC columns displayed slightly lower axial load and bending moment capacities compared to steel-RC columns, though the ductility of both types was found to be similar. The study also highlights the significance of considering the role of GFRP bars in compression, supported by experimental results. This research offers valuable insights into the behavior and performance of both steel and GFRP-reinforced concrete columns, particularly in environments vulnerable to corrosion, with assessments conducted at 28 and 60-day intervals. A comparison of the outcomes from these timeframes reveals the effectiveness of GFRP as a reinforcement option in corrosive conditions

Parallel dynamics of slow slips and fluid-induced seismic swarms

Earthquake swarms may be driven by fluids, through hydraulic injections or natural fluid circulation, but also by slow and aseismic slip transients. Understanding the driving factors for these prolific sequences and how they can potentially develop into larger ruptures remains a challenge. A notable and almost ubiquitous feature of swarms is their hypocenters migration, which occurrence is closely related to the processes driving the observed seismicity, in a similar way as seismicity accompanies slow-slip events at subduction zones. Here, we analyze global data on migrating sequences, and identify scaling laws for migration velocity, moment and duration measured on natural and injection-induced swarms, foreshock sequences, and slow slip events. We highlight two different behaviors among these sequences: one linked to slow slips, with elevated migration velocities and moments, and the other related to fluid-induced processes, featuring lower velocities and moments. These results provide metrics for distinguishing between the drivers of earthquake swarms, fluid or slow-slip related, and prompt a reevaluation of scaling laws of fault slip transients, especially for swarms.

Magnetic coupling through flux branching of adjacent type-I and -II superconductors in a neutron star

Abstract The inner and outer cores of neutron stars are believed to contain type-I and -II proton superconductors, respectively. The type-I superconductor exists in an intermediate state, comprising macroscopic flux-free and flux-containing regions, while the type-II superconductor is flux-free, except for microscopic, quantized flux tubes. Here, we show that the inner and outer cores are coupled magnetically, when the macroscopic flux tubes subdivide dendritically into quantized flux tubes, a phenomenon called flux branching. An important implication is that up to ∼1012(r1/106 cm) erg of energy are required to separate a quantized flux tube from its progenitor macroscopic flux tube, where r1 is the length of the macroscopic flux tube. Approximating the normal-superconducting boundary as sharp, we calculate the magnetic coupling energy between a quantized and macroscopic flux tube due to flux branching as a function of, f1, the radius of the type-I inner core divided by the radius of the type-II outer core. Strong coupling delays magnetic field decay in the type-II superconductor. For an idealised inner core containing only a type-I proton superconductor and poloidal flux, and in the absence of ambipolar diffusion and diamagnetic screening, the low magnetic moments (≲ 1027 G cm3) of recycled pulsars imply f1 ≲ 10−1.5.

Effect of Unanticipated Tasks on Side-Cutting Stability of Lower Extremity with Patellofemoral Pain Syndrome.

Patellofemoral pain syndrome (PFPS) is one of the most common causes of anterior knee pain encountered in the outpatient setting. The purpose of this study was to compare the lower limb biomechanical differences during anticipated and unanticipated side-cutting in athletes with PFPS. Fifteen male basketball players diagnosed with PFPS were enrolled in the study. Participants executed both anticipated and unanticipated 45-degree side-cutting tasks. Motion analysis systems, force plates, and electromyography (EMG) were used to assess the lower limb joint angles, joint moments, joint stiffness, and patellofemoral joint contact forces. Analyzed biomechanical data were used to compare the differences between the two circumstances. Unanticipated side-cutting resulted in significantly increased ankle plantarflexion and dorsiflexion angles, knee abduction and internal rotation angles, and hip abduction angles, as well as heightened knee adduction moments. Additionally, patellofemoral joint contact forces and stress increased, while contact area decreased during unanticipated tasks. Unanticipated movement raises the demands for joint stability and neuromuscular control, increasing injury risks in athletes with PFPS. These findings have practical implications for developing targeted rehabilitation programs and injury prevention strategies.

Dynamic analysis of a NiTi rotary file by using finite element analysis: Effect of cross-section and pitch length.

This study assessed stress distribution, maximum stress values and fatigue life of experimentally designed NiTi rotary files with different cross-sectional geometry and pitch length using finite element analysis (FEA). Four cross-sectional shapes (Convex triangle, S-shaped, Triple helix and Concave triangle) and two pitch lengths (2 mm and 3 mm) were tested in simulated root canals with curvatures of 30°, 45° and 60°. The FEA results indicated that convex triangle and triple helix geometries exhibited lower stress values compared to the S-shaped and concave triangle designs. Increasing the canal curvature angle resulted in higher stress values, with the S-shaped instrument showing the most significant increase (up to 12%). Instruments with shorter pitch lengths showed more even stress distribution enhancing fatigue life. The maximum stress was concentrated 5-8 mm from the tip, varying across cutting edges, with S-shaped sections experiencing the lowest forces but higher stress due to lower moments of inertia.

Age and initial position affect movement biomechanics in sit to walk Transitions: Lower limb muscle Activity and joint moments

Facilitating forward movement while maintaining dynamic stability during transitions like sit-to-walk (STW) requires coordination from many muscles. Age-related muscle, sensory, and neural decline can introduce compensatory biomechanics when completing STW, such as adjusting initial foot position or rising with arm support. Many previous STW studies restrict arm movement and prescribe symmetric foot positions, therefore the purpose of this study was to quantify lower limb muscle excitations and joint moments in STW transitions from four initial foot positions [symmetric, posterior offset, wide, narrow] and two arm placements [hands on knees, arms folded] in 15 younger and 15 older adults. Peak knee and ankle joint extension moments, as well as peak electromyography of five bilateral lower-limb muscles were analyzed. In all conditions, older adults had larger knee extension moments, whereas younger adults had larger ankle plantarflexion moments. Older adults generated larger peak excitation from the knee extensor muscles during rising compared to younger adults, consistent with the higher knee extension moments. Older adults had greater peak dorsiflexor and plantarflexor muscle excitation while rising compared to younger adults. Posterior offset and wide foot positions required the largest peak ankle plantarflexion and knee extension moments and plantarflexor muscle excitation. Arm-supported rising decreased peak knee extensor muscle excitation. In addition, there were interaction effects between age and initial foot position/arm placement for multiple quantities, indicating that the effects of foot and arm placement vary with age. These results inform assessments of movement performance and guidelines for rising given individual lower limb capability.

Joint reaction and simulated muscle forces during squatting and walking in persons with hemophilia

BackgroundPersons with hemophilia experience joint bleeding that can lead to debilitating arthropathy, most commonly seen in ankles, knees, and elbows. Arthropathy can hinder participation in daily and athletic activities. We explored how hemophilic arthropathy impacts movement patterns in walking and bilateral squatting tasks in persons with hemophilia compared to healthy controls. MethodsPersons with hemophilia and healthy controls completed walking and squatting tasks while kinematic and kinetic motion capture data were collected. The Hemophilia Joint Health Score exam was performed to measure hemophiliac arthropathy. OpenSim was used to model muscle and joint reaction forces and calculate moments and angles. Peak values were compared using Cohen's d to estimate effect sizes of hemophilia on movement parameters. FindingsNine persons with hemophilia and eight age-matched controls were analyzed. Temporal-spatial metrics were similar between hemophilia and control groups in both tasks. In walking, persons with hemophilia had higher peak ankle dorsiflexion angles, vertical ground reaction force weight acceptance peaks, and hip extension and flexion moments compared to controls. In squatting, persons with hemophilia had lower knee extension moments, ankle joint reaction force, and knee extensor forces, but had higher hip extension moments. InterpretationTemporal-spatial metric similarity between hemophilia and controls suggests that kinetic and kinematic analyses are needed to identify movement pattern differences. These data identify potential compensatory strategies at the hip that may be used by persons with hemophilia to mitigate impact on the knee and ankle. Future work will confirm these data in a larger sample size and be used to develop physical therapy strategies.

Comparing Sagittal-Plane Biomechanics of Drop Jump Landing in Athletes With and Without Knee Osteoarthritis 2-Year Post-Anterior Cruciate Ligament Reconstruction.

The study aimed to determine differences in sagittal-plane joint biomechanics between athletes with and without knee osteoarthritis (OA) during drop vertical jump 2years after anterior cruciate ligament reconstruction (ACLR). Forty-one athletes with ACLR completed motion analysis testing during drop vertical jump from 30cm. Sagittal-plane peak joint angles and moments and joint contributions to total support moment (TSM) were calculated during first landing. Medial compartment knee OA of the reconstructed knee was evaluated using Kellgren-Lawrencescores (ACLR group: Kellgren-Lawrence <2; ACLR-OA group: Kellgren-Lawrence ≥2). The ACLR-OA group (n = 13) had higher hip and lower knee contributions in the surgical limb than the ACLR group and their nonsurgical limb. Further, the ACLR-OA group had higher peak hip extension moment than the ACLR group (P = .024). The ACLR-OA group had significantly lower peak knee extension and ankle plantar flexion moments and TSM (P ≤ .032) than ACLR group. The ACLR-OA group landed with increased hip extension moment, decreased knee extension and ankle plantar flexion moments and TSM, and decreased knee and increased hip contributions to TSM compared with ACLR group. The ACLR-OA group may have adopted movement patterns to decrease knee load and compensated by shifting the load to the hip. Clinicians may incorporate tailored rehabilitation programs that mitigate the decreased knee load to minimize the risk of knee OA after ACLR.

Mechanisms of gait speed changes in middle-aged adults: Simultaneous analysis of magnitude and temporal effects

BackgroundMiddle-aged adults represent the transition between younger and older adults, where some of the characteristic gait differences due to aging begins to surface. However, the gait characteristics of middle-aged adults across the whole gait cycle remains an understudied topic. As speed is a sensitive indicator of health, characterizing the effects of speed on the gait of middle-aged adults and differentiating it from the response of young adults will provide insights into the effects of aging on gait speed modulation mechanisms. Research questionWhat are the mechanisms of gait speed changes that are employed by middle-aged adults, and how are they different from younger adults? MethodsA cohort of healthy young and middle-aged adults completed 60 second trials at three different speeds. Joint kinematics, kinetics, and surface electromyography data were analyzed and compared between the speed levels and age groups. Statistical Parametric Mapping along with a nonlinear curve registration algorithm was used to simultaneously assess the changes in both magnitude and timing of different metrics. ResultsWhen compared to the younger cohort, the middle-aged cohort had significantly lower ankle range of motion, dorsiflexion moment during loading response and plantarflexion moment during push-off. At the knee joint, the middle-aged adults had significantly lower knee flexion moment during stance. At the hip joint, the middle-aged adults had lower extension moment during terminal stance. SignificanceTime-continuous analysis showed that primary differences due to age were related to decreased joint range of motion and joint moment production capability in the middle-aged adults. Faster walking appears a safe method for middle-aged adults to increase joint range of motion and joint moment expression. However, targeted interventions that focus on improving capability are likely also needed. Suggested targets being improving ankle and knee joint moment capability, and increased range of motion at all joints.

A clinical investigation of force plate drift error on predicted joint kinetics during gait

Inverse dynamic analysis is a technique used during gait analysis to estimate intersegmental forces and net joint moments. Inverse dynamic calculations are susceptible to various forms of error. One such error is force plate drift, often produced by humidity condensing within the input connectors and electronics, causing an undesired change in output over time. This can be particularly concerning for movement laboratories where inverse dynamics are considered in clinical decision-making processes. Manufacturers will provide tolerance levels for drift. However, levels of acceptable drift are rarely considered from a clinical perspective. Therefore, this study aims to establish clinically acceptable limits of force plate drift error, induced by applying systematic errors to force plate channels, on predicted lower limb joint moments during gait. Gait data of 10 children with typical development were analysed and induced errors of 0.5 N, 1 N, 1.5 N, 3 N, 6 N and 12 N were incrementally applied to the horizontal and vertical force channels. Data were recalculated for each increment and mean profiles compared to an error free mean (±1SD) band. Error was deemed clinically significant when moments fell outside the mean (±1SD) band. Induced error at 6 N and above was sufficient to cause a clinically significant change. Sagittal and coronal plane moments at the hip were most affected, followed by the knee and then the ankle. While manufacturer guidelines for acceptable drift are usually well below 6 N, care is needed when using force plates over several minutes or more as drift may eventually exceed clinically acceptable limits.

ESG risk, economic policy uncertainty, and the downside risk: Evidence from US firms

This study investigates the relationship between risk factors of Environmental, Social, and Governance (ESG) and the downside risk of U.S. firms and tackles the role of economic policy uncertainty (EPU) in this relationship. Our results show that the downside risk of firms, as measured by value-at-risk and lower partial moment, is positively affected by ESG risk scores, and that this effect becomes more pronounced as EPU rises. These results are robust to two other alternative measures of ESG risk. We argue that enhancing ESG management and adaptability to economic uncertainty is crucial for aligning with sustainable development goals. Our findings provide valuable insights for U.S. firms, investors, and policymakers looking to navigate the evolving risk landscape.

Dissolved ammonia catalyzes proto-dolomite precipitation at Earth surface temperature

Marine carbonate rocks are the major reservoir of carbon through CaCO3 and CaMg(CO3)2 precipitation extracting CO2/HCO3- from the atmosphere/oceans; hence dolomite is one of the major sinks in the global carbon cycle. Most ancient dolomite has been considered as mainly precipitated under Earth surface conditions. Previous studies have demonstrated that microbes can mediate dolomite formation. However, the “microbial dolomite” model is not sufficient to explain the dolomite that shows no or little evidence of a microbial origin. Although attempted for decades, the synthesis of inorganically-produced dolomite at normal temperatures (<50 °C) has been relatively unsuccessful. Hence, this "dolomite enigma" has been one principal research focus this century. Here we demonstrate that NH3 catalyzes proto-dolomite precipitation inorganically with higher Mg/Ca molar ratios and CO32- activity at normal temperatures of 30 °C and 40 °C. NH3 dissolution increases the alkalinity of the solution and transformes into NH4+ ions, which prefer to bond with H2O on Mg[(H2O)6]2+ rather than free H2O, thus releasing Mg2+ to facilitate proto-dolomite nucleation. Furthermore, the low dielectric constant and low dipole moment allow NH4+ absorbed on crystal surfaces to lower the energy barrier of Mg[(H2O)6]2+ dehydration, promoting proto-dolomite nucleis growth. The system for proto-dolomite precipitation in our experiments closely simulates the natural aqueous environment. This study brings new insights to understanding the mechanisms of dolomite precipitation in natural waters.

Accuracy Validation of a Sensor-Based Inertial Measurement Unit and Motion Capture System for Assessment of Lower Limb Muscle Strength in Older Adults-A Novel and Convenient Measurement Approach.

(1) Background: The aim of this study was to assess lower limb muscle strength in older adults during the transfer from sitting to standing (STS) using an inertial measurement unit (IMU). Muscle weakness in this population can severely impact function and independence in daily living and increase the risk of falls. By using an IMU, we quantified lower limb joint moments in the STS test to support health management and individualized rehabilitation program development for older adults. (2) Methods: This study involved 28 healthy older adults (13 males and 15 females) aged 60-70 years. The lower limb joint angles and moments estimated using the IMU were compared with a motion capture system (Mocap) (pair t-test, ICC, Spearman correlations, Bland-Altman plots) to verify the accuracy of the IMU in estimating lower limb muscle strength in the elderly. (3) Results: There was no significant difference in the lower limb joint angles and moments calculated by the two systems. Joint angles and moments were not significantly different (p > 0.05), and the accuracy and consistency of the IMU system was comparable to that of the Mocap system. For the hip, knee, and ankle joints, the ICCs for joint angles were 0.990, 0.989, and 0.885, and the ICCs for joint moments were 0.94, 0.92, and 0.89, respectively. In addition, the results of the two systems were highly correlated with each other: the r-values for hip, knee, and ankle joint angles were 0.99, 0.99, and 0.96, and the r-values for joint moments were 0.92, 0.96, and 0.85. In the present study, there was no significant difference (p > 0.05) between the IMU system and the Mocap system in calculating lower limb joint angles and moments. (4) Conclusions: This study confirms the accuracy of the IMU in assessing lower limb muscle strength in the elderly. It provides a portable and accurate alternative for the assessment of lower limb muscle strength in the elderly.

Sex Differences in Ambulatory Biomechanics: A Meta-Analysis Providinga Mechanistic Insight into Knee Osteoarthritis.

Females typically present with a higher prevalence of knee osteoarthritis (KOA), and such a higher prevalence may be due to unique knee biomechanics during walking. However, the sex-dependent ambulatory mechanics has been yet to be clarified. To address this critical knowledge gap, this study implemented a series of computational approaches (1) to identify sex-related knee joint biomechanics during ambulation in persons with KOA and (2) to compare these biomechanical measures between individuals with vs. without KOA, stratified by sex. We searched five electronic databases for studies reporting sex-specific knee biomechanics in persons with and/or without KOA. Summary estimates were computed using random-effects meta-analysis and stratified by sex. The systematic review identified eighteen studies (308 males and 383 females with KOA; 740 males and 995 females without KOA). A series of meta-analyses identified female-specific knee biomechanics in a disease-dependent manner. Females with KOA had lower first peak knee adduction moment and peak knee adduction compared to male counterparts. On the other hand, healthy females had lower peak knee flexion moment than male counterparts. Effect estimate in each meta-analysis display poor quality of evidence according to the GRADE approach. The current study is the first to consider sex as a biological variable into ambulatory mechanics in the development of KOA. We discovered that sex-dependent alterations in knee biomechanics is a function of the presence of KOA, indicating that KOA disease may be a driver of the sex-dependent biomechanical alterations or vice versa. Although no strong conclusion can be drawn because of the low quality of evidence, these findings provide new insight into the sex differences in ambulatory knee biomechanics and progression of KOA.

When Heavy Tails Disrupt Statistical Inference

Heavy tails (HT) arise in many applications and their presence can disrupt statistical inference, yet the HT statistical literature requires a theoretical background most practicing statisticians lack. We provide an overview of the influence of HT on the performance of basic statistical methods and useful theorems aimed at the practitioner encountering HT in an applied setting. Higher or even lower product moments (i.e., variance, skewness, etc.) can be infinite for some HT populations, yet all L-moments are always finite, given that the mean exists, thus the theory of L-moments is uniquely suited to all HT distributions and data. We document how L-kurtosis, (a kurtosis measure based on the fourth L-moment) provides a general and practical heaviness index for contrasting tail heaviness across distributions and datasets and how a single L-moment diagram can document both the prevalence and impact of HT distributions and data across disciplines and datasets. Surprisingly, the theory of L-moments, an extension and evolution of probability weighted moments, has been largely overlooked by the literature on HT distributions that exhibit infinite moments. Experiments reveal L-kurtosis ranges under which various HT distributions result in mild to severe disruption to the bootstrap, the central limit theorem (CLT), and the law of large numbers, even for distributions which exhibit finite product moments.

Photocatalytic degradation of the remazol red ultra RGB dye using SrFe12O19-Fe3O4 magnetic oxides dispersed in silica: Effect of reduction temperature

Dyes are the most frequently discarded industrial wastes in aquatic ecosystems, among which Remazol Red ultra RGB stands out. In this context, magnetic iron-based catalyst dispersed in silica were prepared by Pechini route as an alternative for the photodegradation of Remazol Red Ultra RGB. The XRD and Mössbauer spectroscopy results indicated the formation of a magnetic material that, after reduction treatment with H2, forms a magnetite phase combined with Sr hexaferrite dispersed in amorphous silica. The TPR-H2 profiles indicated the reduction of Fe3+ to Fe2+ within the considered temperature range, the amount of Fe2+ increased with rising temperature. The SEM images showed sponge-like morphology for the samples. The EDS spectra and mapping confirmed a high uniformity in the distribution of active iron species in the silica. The magnetic measurements showed a lower magnetic signal for the sample reduced at 600 °C, due to the lower magnetic moment of Fe2+ formed after the reduction. The diffuse reflectance spectra showed a main absorption region between 500 and 200 nm and the estimated band-gap values were of 1.4 and 1.9 eV for the reduced sample and the fresh oxide, respectively. The surface charge was obtained via zeta potential, demonstrating good stability under pH changes and reaching a negative potential in the pH range from 2 to 6. The photocatalytic tests showed that the samples with higher content of Fe2+ demonstrated a greater photocatalytic degradation of the Remazol Red Ultra RGB dye, reaching 100 % degradation in 1 h for the solid reduced at 600 °C. A plausible mechanism for the photodegradation of Remazol Red Ultra RGB was proposed, considering the different elementary steps involving the participation of iron sites and the formation of oxidant radicals.

Waste biomass-derived activated carbons for selective oxygen adsorption

Activated carbons (ACs) derived from waste rice husk ash (RHA) exhibit remarkable potential for selective oxygen adsorption. The pore morphology of the prepared materials was characterized utilizing BET measurement, t-plot, and BJH-plot suggesting a linear relation between activation temperature and mesopore volume, whereas, micropore volume decreases at activation beyond 550 °C. FT-IR spectroscopy confirms their non-polar surface. Notably, AC-600 achieves an outstanding O2/N2 (0.21/0.78) of 152.7 at 0.01 bar at 25 °C, owing to the non-polar nature of the surface, favouring oxygen adsorption due to its low quadrupole moment. Additionally, the mixed micro and mesoporous structure of AC-600 significantly enhance the oxygen adsorption, showing an ∼18.4% (or 1.2-fold) increase compared to AC-500. However, a ∼32.3% decrease in oxygen uptake was observed for AC-800 due to excessive “burn-off”. Adsorption selectivity, assessed with Ideal Adsorption Solution Theory (IAST) and fitted to the Freundlich isotherm model, and adsorption kinetics, analysed using the pseudo-second-order Lagergren and Webber-Morris intraparticle diffusion models, highlighted the impact of activation temperature on the porosity of the material. Understanding the surface chemistry and pore morphology of activated carbon offers deeper insights to enhance oxygen uptake capacity, advancing the development of sustainable, industrially viable materials for oxygen production.

How Multifunctioning Joints Produce Highly Agile Limbs in Animals with Lessons for Robotics.

This paper reviews how multifunctioning joints produce highly agile limbs in animals with lessons for robotics. One of the key reasons why animals are so fast and agile is that they have multifunctioning joints in their limbs. The multifunctioning joints lead to a high degree of compactness which then leads to a host of benefits such as low mass, low moment of inertia and low drag. This paper presents three case studies of multifunctioning joints-the human wrist joint, knee joint and foot joints-in order to identify how multifunctioning is achieved and what lessons can be learned for robotics. It also reviews the multifunctioning nature of muscle which plays an important role in joint actuation. A key finding is that multifunctioning is achieved through various means: multiple degrees of freedom, multifunctioning parts, over-actuation and reconfiguration. In addition, multifunctioning is achieved through highly sophisticated layouts with high levels of integration and fine-tuning. Muscle also makes an important contribution to animal agility by performing multiple functions including providing shape, protection and heat. The paper reviews progress in achieving multifunctioning in robot joints particularly for the wrist, knee and foot. Whilst there has been some progress in creating multifunctioning robotic joints, there is still a large gap between the performance of animal and robotic joints. There is an opportunity to improve the agility of robots by using multifunctioning to reduce the size and mass of robotic joints.

Assessment the feasibility of an AI model predicting lower extremity joint moments during walking in patients with cerebral palsy

Assessment the feasibility of an AI model predicting lower extremity joint moments during walking in patients with cerebral palsy

Exploring Macroscopic Dipoles of Designed Cyclic Peptide Ordered Assemblies to Harvest Piezoelectric Properties

AbstractCrystalline materials exhibiting non‐centrosymmetry and possessing substantial surface dipole moments play a critical role in piezoelectricity. Designing biocompatible self‐assembled materials with these attributes is particularly challenging when compared to inorganic materials and ceramics. In this study, we elucidate the crystal conformations of novel cyclic peptides that exhibit self‐assembly into tubular structures characterized by unidirectional hydrogen bonding and piezoelectric properties. Unlike cyclic peptides derived from alternating L‐ and D‐amino acids, those derived from new δ‐amino acids demonstrate the formation of self‐assembled tubes with unidirectional hydrogen bonds. Further, the tightly packed tubular assemblies and higher macrodipole moments result in superior piezoelectric coefficients compared to peptides with lower macrodipole moments. Our findings underscore the potential for designing cyclic peptides with unidirectional hydrogen bonds, thereby paving the way for their application in design of biocompatible piezo‐ and ferroelectric materials.