Low Aspect Ratio Research Articles

Radiation Impedance of Rectangular CMUTs.

Recently, capacitive micromachined ultrasound transducers (CMUTs) with long rectangular membranes have demonstrated performance advantages over conventional piezoelectric transducers; however, modeling these CMUT geometries has been limited to computationally burdensome numerical methods. Improved fast modeling methods, such as equivalent circuit models, could help achieve designs with even better performance. The primary obstacle in developing such methods is the lack of tractable methods for computing the radiation impedance of clamped rectangular radiators. This paper presents a method that approximates the velocity profile using a polynomial shape model to rapidly and accurately estimate radiation impedance. The validity of the approximate velocity profile and corresponding radiation impedance calculation was assessed using finite element simulations for a variety of membrane aspect ratios and bias voltages. Our method was evaluated for rectangular radiators with width:length ratios from 1:1 up to 1:25. At all aspect ratios, the radiation resistance was closely modeled. However, when calculating the radiation reactance, our initial approach was only accurate for low aspect ratios. This motivated us to consider an alternative shape model for high aspect ratios, which was more accurate when compared with FEM. To facilitate the development of future rectangular CMUTs, we provide a MATLAB script that quickly calculates radiation impedance using both methods.

Design of a Thomson scattering diagnostic for the SMall Aspect Ratio Tokamak (SMART).

We describe the design of a Thomson scattering (TS) diagnostic to be used on the SMall Aspect Ratio Tokamak (SMART). SMART is a spherical tokamak being commissioned in Spain that aims to explore positive triangularity and negative triangularity plasma scenarios at a low aspect ratio. The SMART TS diagnostic is designed to operate at high spatial resolution, 6mm scattering length in the low-field side and 9mm in the high-field side regions, and a wide dynamic range, electron temperature from 1eV to 1keV and density from 5×1018m-3 to 1×1020m-3, to resolve large gradients formed at the plasma edge and in the scrape-off layer (SOL) under different triangularities and low aspect ratios. A 2J @1064 nm laser will be used that is capable of operating in the burst mode at 1, 2, and 4kHz to investigate fast phenomena and at 30Hz to study 1s (or more) long discharges. The scattered light will be collected over an angular range of 60° - 120° from 28 spatial points in the midplane covering the entire plasma width and the outer midplane SOL. Each scattering signal will be spectrally resolved on five wavelength channels of a polychromator to obtain the electron temperature measurement. We will also present a method to monitor in situ laser alignment in the core during calibrations and plasma operations.

Multipeak ultraviolet lasing based on F-P mode from in-situ ZnO nanowire

Abstract High-quality ultraviolet singlemode and multimode lasing from zinc oxide nanowires are highly desirable. In this paper, we achieve high-Q lasing oscillation in vertically grown Zinc oxide (ZnO) microwires. The broad gain range reaches 13 lasing modes under high-energy excitation. We observe multiple peak emissions from the Fabry-Perot (F-P) lasing mode. In contrast, nanorod arrays with low aspect ratios exhibit amplified spontaneous emission (ASE) due to significant diffraction losses. Our work demonstrates that high-quality ZnO nanowires with an appropriate aspect ratio realize high-Q ultraviolet multipeak lasing based on F-P mode. These findings will benefit the design and fabrication of nanolasers based on nanowires.

Experimental and numerical study on the performance index of mixing for low aspect ratio serpentine microchannels

In this work, the effect of a range of Dean numbers (De) varying from 0.01–70 on low aspect ratio (AR = 0.05–0.2) serpentine microfluidic devices was studied experimentally and numerically. It was observed that the AR, the number of circular bumps, and the angular positions of bumps transverse to the flow have a significant influence on the pressure drop and flow features (i.e., the position and shape of flow separation zones). Mixing was exclusively driven by diffusive mechanisms at low De values and at high De values, it was primarily induced by Dean vortices. The lowest mixing index (MI) was observed for De = 1 in all channel types, highlighting the transition region between the diffusion and Dean vortices-dominant mixing regimes. The MI was generally increased by increasing the AR of the channels. However, at high De, Dean vortices became strong enough to induce rapid mixing that was largely independent of the AR and bump placement. A dimensional performance index (PI) was defined as a function of the MI and the pressure drop per unit length. Distinct flow patterns arising from various positioning of bumps resulted in significant variations in the MI and PI values, with different dependencies on De. This underscored the importance of bump positioning based on the operational De range to optimize the mixing performance. Despite minor deviations between the designed and fabricated channels, the use of 3D-printed molds proved effective even at scales close to the resolution of the printer, resulting in mixing patterns consistent with the designed channels. These findings provide valuable insights into optimizing serpentine microchannels for efficient mixing while considering the trade-offs between enhanced mixing and increased pressure drop.

Unruptured intracranial aneurysm volume change patterns and association with age, sex, location in vascular tree, and common risk factors: a single-centre retrospective study.

Unruptured intracranial aneurysms pose a significant clinical and decision-making dilemma. Increase in dome size is one of the crucial indications for treatment. Almost no data exists as to how aneurysms change in size over time. 102 patients (76 women) who had a total of 501 CT examinations were included in the study. Inclusion criteria were: at least three CT angiography studies, an observation period of at least three years, or bleeding during the follow-up period. In each study, the volume of each aneurysm was measured at least four times by two experienced neuroradiologists with the use of dedicated tools. Collected data was used to obtain numerical volume change models for each aneurysm. 149 aneurysms were analysed in the study (118 in women) No significant differences in location, size or age of observation were detected between men and women. Median follow-up was 5.64 years (IQR 4.17-7.71) and total aneurysm observation time amounted to 964.59 years. There were 57 branching zone aneurysms (women 46), 44 sidewall aneurysms (women 36), 20 anterior communicating artery aneurysms (women 16), 20 posterior communicating artery aneurysms (women 13), and eight posterior circulation aneurysms (women 7). 78 (52%) aneurysms remained stable (women 59), 24 (16.6%) increased their volume (women 20), and five (3.4%) decreased (women 4). In 42 (28%) cases, we observed non-uniform routes of volume changes over surveillance (women 35). In the last group, analysing the whole period of follow-up, 29 (69%) did not change volume (women 24), 11 (26%) grew (women 10), and two decreased in size (4.8%, women 1). Bifurcation zone aneurysms, lower aspect ratio, lower patient age, and higher initial volume were associated with an increased risk of aneurysm growth. Posterior circulation aneurysms presented the lowest rate of volume increase. A substantial amount of followed up aneurysms could change volume in a non-uniform way, and an increase in volume may not lead to aneurysm rupture.

Enhancing the pull-out behavior of ribbed steel bars in CNT-modified UHPFRC using recycled steel fibers from waste tires: a multiscale finite element study

In the current investigation, the effect of recycled steel fibers recovered from waste tires on the pull-out response of ribbed steel bars from carbon nanotube (CNT)-modified ultrahigh performance fiber reinforced concrete (UHPFRC) was considered using the multiscale finite element method (MSFEM). The MSFEM is based on three phases to simulate CNT-modified UHPC, recycled steel fibers (RSFs), and ribbed steel bars. For the first time, a bar ribbed has been simulated to make more realistic assumptions, and RSFs have been distributed in the form of curved cylinders of different lengths and with a random distribution within a concrete matrix. The interaction of the steel bar and the RSFs with the concrete is applied by the cohesive zone model (CZM). After confirming the simulation outcomes with the experimental results, the steel bar pull-out response is investigated using load-slip curves. The impact of the CNT content, RSFs and their aspect ratio on the bond strength of steel bars and CNT-modified UHPFRC was assessed. The results show that using RSFs with a lower aspect ratio (steel microfibers) significantly improves the pull-out characteristics of steel bars from concrete. Accordingly, the proposed MSFEM is considered for simulating the effects of different parameters on the pull-out response of ribbed steel bars from concrete without causing complex, time-consuming, or costly experiments. The results indicated that waste fiber or RSF can be used as a toughening component in CNT-modified ultrahigh-performance concrete and as a replacement for industrial steel fibers.

Crystal Resorption as a Driver for Mush Maturation: an Experimental Investigation

Abstract The thermal state of a magma reservoir controls its physical and rheological properties: at storage temperatures close to the liquidus, magmas are dominated by melt and therefore mobile, while at lower temperatures, magmas are stored as a rheologically locked crystal network with interstitial melt (crystal mush). Throughout the lifetime of a magmatic system, temperature fluctuations drive transitions between mush-dominated and melt-dominated conditions. For example, magma underplating or magma recharge into a crystal mush supplies heat, leading to mush disaggregation and an increase in melt fraction via crystal resorption, before subsequent cooling reinstates a crystal mush via crystal accumulation and recrystallisation. Here, we examine the textural effects of such temperature-driven mush reprocessing cycles on the crystal cargo. We conducted high-P-T resorption experiments during which we nucleated, grew, resorbed, and recrystallised plagioclase crystals in a rhyolitic melt, imposing temperature fluctuations typical for plumbing systems in intermediate arc volcanoes (20–40 °C). The experiments reproduce common resorption textures and show that plagioclase dissolution irreversibly reduces 3D crystal aspect ratios, leading to more equant shapes. Comparison of our experimental results with morphologies of resorbed and unresorbed plagioclase crystals from Mount St. Helens (MSH) (USA) reveals a consistent trend in natural rocks: unresorbed plagioclase crystals (found in MSH dacite, basalt and quenched magmatic inclusions [QMIs]) have tabular shapes, while plagioclase crystals with one or more resorption horizons (found in MSH dacite, QMIs, and mush inclusions) show more equant shapes. Plagioclase crystals showing pervasive resorption (found in the dacite and mush inclusions) have even lower aspect ratios. We therefore suggest that crystal mush maturation results in progressively more equant crystal shapes: the shapes of plagioclase crystals in a magma reservoir will become less tabular every time they are remobilised and resorbed. This has implications for magma rheology and, ultimately, eruptibility, as crystal shape controls the maximum packing fraction and permeability of a crystal mush. We hypothesise that a mature mush with more equant crystals due to multiple resorption–recrystallisation events will be more readily remobilised than an immature mush comprising unresorbed, tabular crystals. This implies that volcanic behaviour and pre-eruptive magmatic timescales may vary systematically during thermal maturation of a crustal magmatic system, with large eruptions due to rapid wholesale remobilisation of mushy reservoirs being more likely in thermally mature systems.

Bifurcation analysis of wing rock and routes to chaos of a low aspect ratio flying wing

Bifurcation analysis of wing rock and routes to chaos of a low aspect ratio flying wing

Direct numerical simulation of 45° oblique flow past surface-mounted square cylinder

Comprehensive coherent structures around a surface-mounted low aspect ratio square cylinder in uniform flow with an oblique angle of $45^{\circ }$ were investigated for cylinder-width-based Reynolds numbers of 3000 and 10 000 by direct numerical simulation based on a topology-confined mesh refinement framework. High-resolution simulations and the critical-point concept were scrutinized to reveal for the first time the reasonable and compatible topologies of flow separation and complete near-wall structures, due to their extensive impact on various engineering applications. Large-scale horseshoe vortices are observed at two notable foci in the viscous sublayer. Within this layer, a wall-parallel jet is formed by downflow intruding into the bottom surface at the half-saddle point, then deflecting in the upstream direction and finally penetrating the bottom surface until the half-saddle point. A pair of conical vortices on the cylinder's top surface switch themselves on two sides of the square cylinder, where the switching frequency is identical with that of the sway of the side shear layer. The undulation of the Kelvin–Helmholtz instability is identified in the instantaneous development of a conical vortex and side shear layer, where the scaling of the ratio of the Kelvin–Helmholtz and von Kármán frequencies follows the power-law relation obtained by Lander et al. (J. Fluid Mech., vol. 849, 2018, pp. 1096–1119). Large-scale arch-shaped vortex is often detected in the intermediate wake region of a square cylinder, involving two interconnected portions, such as the leg portion separated from leeward surfaces and head portion rolled up from the top surface. The leg portion of the arch-shaped vortex was rooted by two foci near the bottom-surface plane.

Carbon-Monoxide Assisted Synthesis of Cobalt-Nickel Phosphides for Hydrogen Evolution Reaction

Alkaline water electrolysis is a method for production of hydrogen as an alternative source for renewable energy. This method can be completely free of greenhouse gas emissions if it is paired with another alternative energy source, such as solar energy or wind power, to provide the necessary electricity to drive the reaction. Water electrolysis requires catalysts to make that necessary amount of electricity low enough for competitive hydrogen production in the current market. Vast numbers of studies have been performed in an attempt to fill this need for cost-effective catalysts for water electrolysis. This work focuses on the development of synthesis methods for cobalt-nickel phosphide catalysts for the hydrogen evolution reaction (HER) for water electrolysis in alkaline media. The methods for preparation of the catalysts are explored for cobalt, nickel, and cobalt-nickel alloy phosphides in the presence of carbon monoxide as a shape-controlling capping agent. Depending on the condition of carbon monoxide addition, the reaction results in high vs. low-aspect ratio nanorods or nanospheres for mono- or bimetallic cobalt-nickel phosphide nanostructures. These phosphides are then subjected to evaluation for HER via cyclic voltammetry and linear sweep voltammetry to study the effects of morphology on their HER activity. Materials characterization such as XRD, TEM, and ICP-MS are performed before the HER electrochemical evaluation for better understanding of the structure-activity relationship. The catalytic activities of these phosphides are also compared to the noble metal benchmark HER catalyst Pt/C in the same environment at their equal mass loadings. The best-performing phosphide is further tested for HER at increased mass loadings to study the effects of catalyst loadings on the mass transport and thus the activity. Further TEM characterization is performed on the most active catalyst after HER to evaluate morphological stability. It is found that in order to achieve an overpotential at the current density of 100 mA/cm2 comparable to Pt/C for 50 μg/cm2, the necessary loading for the phosphide is 250 µg/cm2.

Investigation of wake dynamics near the cylinder with the variation of length-to-diameter ratio

The study investigates the impact of drag forces on underwater pipeline structures at junctions where diameter changes occur, utilizing three-dimensional numerical simulations to analyze flow patterns around dual-step cylinders at a Reynolds number of 5000. The numerical model is validated against benchmark studies for a plain circular cylinder at heating condition, demonstrating strong agreement. Subsequently, cylinder temperatures were varied to assess their influence on drag force. The study further explores the effect of varying the aspect ratio L/D from 1 to 3 on drag reduction. Analysis of the flow structures is conducted, focusing on vortex patterns, velocity fields, and force coefficients surrounding the cylinders. Additionally, streamwise and crosswise velocities are analyzed at different sectional planes of the step cylinder. Results indicate that the drag force diminishes with increasing aspect ratio, correlating with formation length (Lf). At lower aspect ratios, step-induced vortices migrate toward the wall, while at higher aspect ratios, they drift midway. This research provides insights for designing stepped diameter cylinder systems in the subcritical regime, contributing to optimized underwater pipeline structures.

Excavation Method Comparison and Optimization for a Super Large Cross-Section Tunnel

Characterized by long spans, low aspect ratios, and intricate construction sequences, super-large cross-section tunnels present substantial construction risks. Therefore, the selection of the optimal excavation method and construction sequence is crucial for ensuring the safety of tunnel construction and minimizing project costs. This paper takes a super large transverse-section highway tunnel as a case study, employing field monitoring data combined with ABAQUS software to analyze the stress and deformation of surrounding rock and support structures under different excavation methods. The findings reveal that the deformation of surrounding rock and support structures excavated by the Double-Side Drift Method is smaller than those caused by the three-benching seven-step method and the CRD excavation method. Nevertheless, the significant stresses of surrounding rock and support structures are released by the Double-Side Drift Method, leading to potential stress concentrations. Thus, it is necessary to ensure the rapid completion of early support and quick sealing of the tunnel. Furthermore, the sixth process achieves smaller deformation (including arch displacement and surface settlement) of the tunnel, a shorter construction period, and lower economic costs when compared to other construction processes. Consequently, it can obviously be concluded that both the Double-Side Drift Method and the sixth construction process stand out as the most appropriate choices for excavating super large cross-section tunnels. The insights obtained from this study provide theoretical guidance for the design and construction of similar tunnel projects.

The effects of brick wall and RC tie variables on the seismic performance of low-rise confined masonry buildings

An extensive parametric investigation is carried out to determine the effects of different RC tie system and brick wall variables on the performance of confined masonry walls and buildings. The variables considered include: the number of storeys and adjacent walls, the walls aspect ratio, thickness and compressive strength of masonry walls, presence of openings, the RC tie system dimensions, compressive strength and detailing of the longitudinal and transverse reinforcements. The main aim of the investigation is to verify the efficiency of some of the prescriptive code recommendations and to provide a basis for further descriptive guidelines for low-rise confined masonry buildings. Among the major conclusions, it is found that the main affecting parameters are those of the masonry walls themselves. When the walls have sufficient shear capacities, due to lower aspect ratio, higher compressive strength and wall thickness and lack of, or small openings, the flexural demand on the tie system is small and its elements act mainly as axially-loaded tie elements. Therefore, the least affecting parameters are those of the tie system's reinforcement detailing. However, when the masonry walls are weak in shear (low masonry strength and large openings), the demand on the tie system increases, to the point that instead of acting as an integral part of the wall, it acts similar to a weak, moment-resisting frame having infill masonry walls, for which it has not been designed. The scenarios that this will happen include: the wall aspect ratios AR > 2, the masonry compressive strength, f′m < 5.0 MPa and the ratio of length of opening to the length of the wall, Ol/Wl > 0.5. To avoid such behaviour, it is also suggested that the tensile stresses in the longitudinal bars of the RC tie elements be limited to 0.6fy.

Exploring the Impact of Steam Explosion Pretreatment on the Binding Characteristics of Coal-Biomass Briquettes: A Study on Lignocellulose Type and Fibre Morphology

AbstractThe urgency to shift from coal to renewable energy sources drives the need for innovative solutions. Steam exploded lignocellulose acting as both binder and fuel in coal-briquetting presents a pathway for this transition whilst utilizing waste coal-fines. However, the applicability of different industrially relevant feedstocks and their specific binding mechanism is unknown. In this study we assess the impact of treatment severity and explosion pressure on fibre properties and briquette tensile compressive strength (TCS) across four feedstocks (sugarcane bagasse (SCB), corn stover (CS), black wattle (BW), and pine). Lignocellulose was steam exploded at severities ranging from 3.53 to 4.71 and physical modifications due to explosion pressure was isolated by conducting explosive decompressions at pressures ranging from 3 to 22.5 bar. Briquettes, prepared using 18% by mass steam exploded lignocellulose as a binder, were quantified for TCS and results showed that as particle aspect ratio increased, so did TCS, regardless of lignocellulose type. For SCB, CS, and BW, high explosion pressure and low to moderate severity (3.5–3.8) produced the highest aspect ratios and, consequently, highest TCS (1288, 1181, 905 kPa respectively). However, at high severity and pressure, a reduction in aspect ratio was observed and, subsequently, TCS. Pine required high severity and pressure to produce barely acceptable briquette TCS (364 kPa), due to its low aspect ratio. Physical modification of fibre aspect ratio during steam explosion therefore played a crucial role in its binding performance in coal-briquettes and the relative success of SCB, CS and BW indicate that there are significant resources of lignocellulose available for this technology and allow for widespread industrial application. Graphical Abstract

Computational approach towards shear strength prediction of squat RC walls implementing ensemble and hybrid SVR paradigms

Squat-reinforced concrete (RC) walls are shear walls with a low aspect ratio and are vital structural components for nuclear structures and conventional buildings owing to their considerable strength in resisting lateral seismic load. Existing empirical equations and design codes carry substantial discrepancies in terms of accuracy in estimating the shear strength (Vn) of squat RC walls. This work employs a hybrid paradigm of support vector regressor (SVR) and Harris hawk optimisation (HHO) algorithm, i.e., SVR-HHO, to predict the Vn of squat RC walls. The outcomes of the SVR-HHO framework were compared with some of the widely used soft computing paradigms, namely the generalised linear model, decision tree, random forest, gradient boosting tree, and standard SVR. Overall outcomes indicate that the developed SVR-HHO paradigm attained the most precise estimation of Vn of squat RC walls with 98 % (in terms of R-index) accuracy in the testing phase. Moreover, the SVR-HHO framework was validated based on parametric and sensitivity analyses. The outcomes were also compared with the present codes and empirical models previously available in the literature. Compared to the developed models, SVR-HHO demonstrated robust predictions. The minimum coefficient of variation (COV in %) was observed to be 23. 02 % for SVR-HHO, followed by ACSE (41.2 %) and ACI (45.3 %). To facilitate a quick estimation of the results, the developed model is also attached as supplementary materials.

Fabrication of low aspect ratio solid-state pores from sub-micron to microscales utilizing crossing blades

This article introduces a novel method for fabricating low aspect ratio pores in various sizes, from sub-micron to microscales. This technique utilizes the intersection of two collided blades as a soft lithography mold. The theoretical details of the fabrication method, including the pore’s shape and geometrical parameters, were inspected, modeled, and discussed. Multiple mechanical and electrochemical measurements were performed to characterize the fabricated pores. Pore fabrication results showed that a wide range of pore sizes, from 350 nanometers to more than 30 micrometers, can be constructed by employing this method. Electrochemical impedance spectroscopy (EIS) implied that the blades-intrusion pores have the same electrochemical behavior as the ones on 2D materials. Meanwhile, the durability of the fabricated pores against the pressure of two bars ensures great mechanical stability of these pores. Fabricated pores with sizes of 2.3 µm and 20 µm were successfully employed as sensing gates in resistive pulse sensing (RPS) for detecting polystyrene beads of 600 nm, 1 µm, and 2 µm in diameter and downsized yeast cells, respectively. A distinct scatter of pulses of different particle sizes in the pulse amplitude-width plane verified the blades-intrusion pore’s capability as a sensing gate.

Linearly polarized GaN micro-LED with adjustable directional emission integrated with a continuous metasurface

Traditional LEDs emit light that exhibits incoherence and displays a Lambertian distribution. To achieve linearly polarized (LP) light and control the emission direction, a variety of optical components are required to be stacked, which is unsuitable for compact applications and results in low deflection efficiency. Here, we propose and and numerically simulate a novel single-chip micro-resonant cavity LED (micro-RCLED) device that generates directional LP light by integrating a continuous metasurface. This device includes a bilayer grating at the GaN layer's bottom, providing high transverse electric (TE) reflectivity above 89.5% and an extinction ratio exceeds 57 dB at 500 nm. The top distributed Bragg reflector (DBR) and the bilayer grating together constitute a TE mode Fabry–Pérot resonant cavity. This not only promotes the emission of the TE wave, but also guarantees its collimation with the appropriate phase, thereby enhancing its spatial coherence. A functional metasurface above the DBR layer precisely controls the TE wave's deflection angle. It maintains a low aspect ratio while enabling efficient, large-angle deflection. The simulation results demonstrate that this device provides an effective solution for generating highly spatially coherent directional LP light, with broad potential applications in fields such as polarized light imaging and advanced 3D micro-LED display systems.

Cutout effects on the vibration of sandwich auxetic cylindrical shells with an experimental validation

This study investigates the influence of auxetic core layers on the vibrational characteristics of sandwich cylindrical shells with cut-outs. The analysis utilizes the First-order Shear Deformation Theory (FSDT) and analytical techniques. The irregular behavior of auxetic re-entrante honeycomb cells necessitates the exploration of their effects on various systems. Additionally, the proposed method offers advantages over Finite Element Method (FEM). FEM modeling suffers from increased computational time and reduced accuracy with a large number of elements or high aspect ratio elements. These challenges are particularly significant for shells with geometric features of disparate scales, such as large cylinders with tiny cutouts or cutouts with low aspect ratios. However, the present research addresses these challenges by employing a method that integrates five panels with varying dimensions. Consequently, each section can utilize specific Two-Dimensional Generalized Differential Quadrature (2D-GDQ) grid points, tailored to the size of each side, enabling rapid and accurate prediction of displacement and stress parameters, particularly for shorter sides. The proposed method excels at precisely modeling cutouts while preserving their realistic properties. This is achieved by avoiding geometric and material simplifications and by assigning distinct boundary conditions to each region, including critical areas like corners, internal, and external sides. Moreover, Frequency Response Functions (FRFs) obtained from accelerometer and laser signals, alongside vibration-induced sound wave signals captured by electroacoustic microphones, validate the precision of the numerical calculations.

Mechanical behavior of MXene-Polymer layered nanocomposite using computational finite element analysis

The structural integrity of MXene and MXene-based materials is important across applications from sensors to energy storage. While MXene processing has received significant attention, its structural integrity for real-world applications remains challenging due to its flake-like structure. Here the mechanical response of layered MXene-polymer nanocomposites (MPC) with high MXene concentration (>70 %) and bioinspired nacre-like brick-and-mortar architecture is investigated to offer insights for MPC design and processing. An automated finite element analysis (FEA) framework is developed to analyze MPC models with randomized geometries and multiple combinations of the parameter space. Specifically, the influence of concentration, aspect ratio (AR), flake thickness, flake distribution, and interfacial strength is investigated. The results reveal property trends such as increasing elastic modulus, strength, and toughness with increasing cohesive strength and concentration for lower AR (=40, 60) but a decreasing trend at higher AR of 75. Local structural features like flake distribution, overlapping MXene lengths, and interconnected polymers in adjacent layers was found a critical determinant of performance. For example, stronger cohesive interaction showed 6X high toughness (291 ± 226 KJ/m3) compared to weaker case (50 ± 24 KJ/m3), but the large scatter highlighted the impact of microstructural features. The results are compared and validated with theoretical, computational, and experimental work. The findings provide valuable guidance for optimizing MPC design and their processing. Finally, the automation of the framework allows the design to be extended beyond the current system and chosen material combinations.

Functional Noncentrosymmetric Nanoparticle-Nanofiber Hybrids via Selective Fragmentation.

Noncentrosymmetric nanostructures are an attractive synthetic target as they can exhibit complex interparticle interactions useful for numerous applications. However, generating uniform, colloidally stable, noncentrosymmetric nanoparticles with low aspect ratios is a significant challenge using solution self-assembly approaches. Herein, we outline the synthesis of noncentrosymmetric multiblock co-nanofibers by subsequent living crystallization-driven self-assembly of block co-polymers, spatially confined attachment of nanoparticles, and localized nanofiber fragmentation. Using this strategy, we have fabricated uniform diblock and triblock noncentrosymmetric π-conjugated nanofiber-nanoparticle hybrid structures. Additionally, in contrast to Brownian motion typical of centrosymmetric nanoparticles, we demonstrated that these noncentrosymmetric nanofibers undergo ballistic motion in the presence of H2O2 and thus could be employed as nanomotors in various applications, including drug delivery and environmental remediation.