Low-density Water Research Articles

Recent Trends in Polymer Matrix Solid Buoyancy Materials: A Review.

Polymer matrix solid buoyancy materials (PSBMs) have the advantages of low density, high strength, low cost, and low water absorption, and they are widely used in marine engineering fields. How to improve the performance of PSBMs further and adapt them to harsh marine environments has become a hot topic in current research. This paper provides a comprehensive summary of PSBM, detailing both the preparation methodologies and properties of single-component and multi-component PSBM. In this paper, relevant research is systematically summarized from two dimensions of matrix and filler, and the application of thermosetting resin and thermoplastic resin as a matrix in PSBM is introduced in detail, and the corresponding research on fillers such as hollow glass microspheres, fly ash, hollow ceramic spheres and hollow polymer microspheres are expounded. This paper aims to summarize the latest advancements in PSBM research, thereby providing insights into the current state of the field and guiding future investigations.

Evidence of ferroelectric features in low-density supercooled water from ab initio deep neural-network simulations

Over the last decade, an increasing body of evidence has emerged, supporting the existence of a metastable liquid-liquid critical point in supercooled water whereby two distinct liquid phases of different densities coexist. Analyzing long molecular dynamics simulations performed using deep neural-network force fields trained to accurate quantum mechanical data, we demonstrate that the low-density liquid phase displays a strong propensity toward spontaneous polarization, as witnessed by large and long-lived collective dipole fluctuations. Our findings suggest that the dynamical stability of the low-density phase, and hence the transition from high-density to low-density liquid, is triggered by a collective process involving an accumulation of rotational angular jumps, which could ignite large dipole fluctuations. This dynamical transition involves subtle changes in the electronic polarizability of water molecules which affects their rotational mobility within the two phases. These findings hold the potential for catalyzing activity in the search for dielectric-based probes of the putative second critical point.

Unveiling a common phase transition pathway of high-density amorphous ices through time-resolved x-ray scattering.

Here, we investigate the hypothesis that despite the existence of at least two high-density amorphous ices, only one high-density liquid state exists in water. We prepared a very-high-density amorphous ice (VHDA) sample and rapidly increased its temperature to around 205 ± 10K using laser-induced isochoric heating. This temperature falls within the so-called "no-man's land" well above the glass-liquid transition, wherein the IR laser pulse creates a metastable liquid state. Subsequently, this high-density liquid (HDL) state of water decompresses over time, and we examined the time-dependent structural changes using short x-ray pulses from a free electron laser. We observed a liquid-liquid transition to low-density liquid water (LDL) over time scales ranging from 20ns to 3 μs, consistent with previous experimental results using expanded high-density amorphous ice (eHDA) as the initial state. In addition, the resulting LDL derived both from VHDA and eHDA displays similar density and degree of inhomogeneity. Our observation supports the idea that regardless of the initial annealing states of the high-density amorphous ices, the same HDL and final LDL states are reached at temperatures around 205K.

Intelligent Devices Harnessing Underwater Superoleophobic and Underoil Superhydrophobic Quartz Sands for the Separation of Diverse Stratified and Emulsified Water-Oil Mixtures.

To achieve the green, sustainable, and controllable recovery of oil-water resources and to address the limited functionality of single superwet materials in oil-water separation, this study reports a multifunctional oil-water separation strategy by compositing the underwater superoleophobic and underoil superhydrophobic materials (HS). The underwater superoleophobic quartz sands with an oil contact angle of 152.68° were prepared by adjusting the particle size. This material demonstrated a water flux of 4688 L m-2 h-1 and a low-density oil and water mixture separation efficiency of 98.6%, which remained above 97.9% over 50 cycles. It was effective in separating oil-in-water emulsions with a separation efficiency of >99%. For HS, quartz sands were modified with dodecyltrimethoxysilane. The optimized HS-4 exhibited superhydrophobic properties with a water contact angle of 157.06°. It achieved an oil flux of 5775 L m-2 h-1 and a water and dichloromethane mixture separation efficiency of 98.4%. Additionally, they exhibited significant potential in the separation of water-in-oil emulsions. Furthermore, by placing the underwater superoleophobic and underoil superhydrophobic units at the bottom of the filter, we achieved cyclic separation of high-density oil and water mixtures, low-density oil and water mixtures, water-in-oil emulsions, and oil-in-water emulsions. The separation efficiency consistently exceeded 96.5% over 10 cycles. In addition, the oil-water separation mechanism of underwater oleophobic and underoil hydrophobic materials was demonstrated by the relative concentration distribution of water and oil with molecular dynamics simulations. This intelligent oil-water separation method marks a significant advancement in the sustainable separation of diverse oil-water mixtures.

The MD study of water short-range order during liquid-liquid transition: Toward the second critical point

Full-scale thermodynamic experimental investigations of the liquid-liquid transition and different water phases remain challenging due to spontaneous crystallization and the complexity of studies on the nanosecond time scale. Moreover, the specific position of the second critical point in water is still unclear. This study used molecular dynamics to reproduce the structural properties of both low- and high-density waters and to characterize changes in the order parameters, average number of hydrogen bonds, and ordering of neighboring molecules during liquid-liquid transitions and in regimes of supercooled waters. A rapid change in calculated parameters under increased pressure could be attributed to a first-order phase transition. In addition, we provided evidence that low-density water becomes dissolved in high-density water inclusions as the temperature or pressure increases. The presumed location of the second critical point has been identified as TC ≈ 220 K, PC ≈ 1.5 kbar, and ρC ≈ 1.02 g/cm3.

Prediction of water anomalous properties by introducing the two-state theory in SAFT.

Water is one of the most abundant substances on earth, but it is still not entirely understood. It shows unusual behavior, and its properties present characteristic extrema unlike any other fluid. This unusual behavior has been linked to the two-state theory of water, which proposes that water forms different clusters, one with a high density and one with a low density, which may even form two distinct phases at low temperatures. Models incorporating the two-state theory manage to capture the unusual extrema of water, unlike traditional equations of state, which fail. In this work, we have derived the framework to incorporate the two-state theory of water into the Statistical-Associating-Fluid-Theory (SAFT). More specifically, we have assumed that water is an ideal solution of high density water molecules and low density water molecules that are in chemical equilibrium. Using this assumption, we have generalized the association term SAFT to allow for the simultaneous existence of the two water types, which have the same physical parameters but different association properties. We have incorporated the newly derived association term in the context of the Perturbed Chain-SAFT (PC-SAFT). The new model is referred to as PC-SAFT-Two-State (PC-SAFT-TS). Using PC-SAFT-TS, we have succeeded in predicting the characteristic extrema of water, such as its density and speed of sound maximum, etc., without loss of accuracy compared to the original PC-SAFT. This new framework is readily extended to mixtures, and PC-SAFT-TS manages to capture the solubility minimum of hydrocarbons in water in a straightforward manner.

Deciphering Density Fluctuations in the Hydration Water of Brownian Nanoparticles via Upconversion Thermometry.

We investigate the intricate relationship among temperature, pH, and Brownian velocity in a range of differently sized upconversion nanoparticles (UCNPs) dispersed in water. These UCNPs, acting as nanorulers, offer insights into assessing the relative proportion of high-density and low-density liquid in the surrounding hydration water. The study reveals a size-dependent reduction in the onset temperature of liquid-water fluctuations, indicating an augmented presence of high-density liquid domains at the nanoparticle surfaces. The observed upper-temperature threshold is consistent with a hypothetical phase diagram of water, validating the two-state model. Moreover, an increase in pH disrupts the organization of water molecules, similar to external pressure effects, allowing simulation of the effects of temperature and pressure on hydrogen bonding networks. The findings underscore the significance of the surface of suspended nanoparticles for understanding high- to low-density liquid fluctuations and water behavior at charged interfaces.

Weakened Interfacial Hydrogen Bond Connectivity Drives Selective Photocatalytic Water Oxidation toward H2O2 at Water/Brookite-TiO2 Interface.

The formation of H2O2 through the two-electron photocatalytic water oxidation reaction (WOR) is significant but encounters the competition with the four-electron O2 evolution reaction. Recent studies showed a crystal-phase dependence in H2O2 selectivity, where high purity brookite TiO2 (b-TiO2) exhibits remarkable H2O2 selectivity in contrast to the common rutile phase TiO2 (r-TiO2). However, the origin of such a structure-induced selectivity preference remains elusive, primarily due to the complexities associated with the solid-liquid interface system and excited-state chemistry. Herein, we conducted a comprehensive investigation into the selectivity mechanism of WOR at the water/b-TiO2(210) and water/r-TiO2(110) interfaces, employing first-principles molecular dynamics simulations and microkinetic analyses. Intriguingly, our results reveal that the intrinsic catalytic ability of the b-TiO2(210) itself does not enhance H2O2 selectivity compared to r-TiO2(110). Instead, it is the weakened interfacial hydrogen bond connectivity, modulated by the herringbone-like local atomic structure of the b-TiO2(210) surface, that determines the selectivity. Specifically, this weakened H-bond connectivity (i.e., local low water density) at the interface, owing to the strong water adsorption and distinct adsorption orientation, can stabilize the OH• radical and inhibit its deprotonation, leading to an improved H2O2 selectivity. By contrast, the relatively strong interface H-bond connectivity established over r-TiO2(110) accelerates the deprotonation of OH•, with the OH• coverage being 3 orders of magnitude lower than at the water/b-TiO2(210) interface. This study quantitatively demonstrates that the local H-bond structure (water density) at the liquid/solid interface significantly influences photocatalytic selectivity, and this insight may offer a rational approach to enhance the H2O2 selectivity.

The effect of flow stratification on ship performance: a numerical study

ABSTRACT If a layer of low-density water settles on top of higher density water, such as fresh water melting from a glacier and settling on top of colder seawater, a body of water can stratify into stable, distinct layers. A vessel advancing in such a stratified fluid can generate internal waves between these layers. The generation of internal waves requires energy and thus increases the resistance experienced by the vessel, a phenomenon known as the dead water effect which can result in a severe reduction in speed and loss of steering power. This study uses Computational Fluid Dynamics (CFD) to investigate the increase in ship resistance caused by the dead water effect. The results show that the presence of a stratified flow can increase total resistance approximately sixfold in extreme conditions. At standard operating conditions, total resistance may increase by approximately 6% as a result of flow stratification.

A close look at the hydration layer and at the premelting layer of K-feldspar

In this work, we perform molecular dynamics simulations to investigate the structural properties of water at the interface with K-feldspar. We aim at understanding the modifications induced on water structure by the presence of this mineral. We analysed both the hydration layer of K-feldspar in supercooled water and the premelting layer at the interface between K-feldspar and hexagonal ice. We studied the density profile, the orientational tetrahedral order parameter, the distribution of the cos ⁡ ( γ ) function, the hydrogen bond distribution, the number of water molecules belonging to different phases close to the surface of the feldspar. We focused on the interplay between high-density water and low-density water to inquire on local modifications of water structure with respect to the bulk phase. We investigated four different pressures where the structure of bulk water spans from high-density liquid (locally more disordered) to low-density liquid (locally more ordered). The investigation showed that both the hydration and the premelting layers present a low-density liquid water component and similarities as a function of pressure with the corresponding bulk. We also find that the premelting layer shows structural features intermediate between the liquid and the crystalline state acting as a matching layer.

An entropy trap model of thermodynamic anomalies for dual-amorphous water undergoing liquid-liquid phase transition

Water displays numerous anomalously thermodynamic behaviors. However, the working principles behind these anomalies are not well understood, and the liquid-liquid phase transition (LLPT) is often regarded as the potential reason. In this study, we developed an entropy trap model to characterize the thermodynamic LLPT in dual-amorphous water, i.e. having both low-density and high-density liquid water. From the Adam-Gibbs model and free-volume theory, thermodynamic behaviors of water have been described using the proposed model, in which the constitutive relationships among density, heat capacity, thermal expansivity and glass transition temperature have been formulated. Moreover, the glass transition and its connection to thermodynamic behaviors were also investigated for dual-amorphous water. Finally, experimental data reported in the literature were used to verify effectiveness of the proposed model. This study is expected to provide a physical insight into the anomalous thermodynamics of dual-amorphous water undergoing the LLPT.

What Causes the Subsurface Velocity Maximum of the East Australian Current?

Abstract The East Australian Current (EAC) system includes a poleward jet that flows adjacent to the continental shelf, a southward and eastward extension, and a complex eddy field. The EAC jet is often observed to be subsurface intensified. Here, we explain that there are two factors that cause the EAC to develop a subsurface maximum. First, the EAC flows as a narrow current, carrying low-density water from the Coral Sea into the denser waters of the Tasman Sea. This results in horizontal density gradients with a different sign on either side of the jet, negative onshore and positive offshore. According to the thermal wind relation, this produces vertical gradients in southward current that are surface intensified onshore and subsurface intensified offshore. Second, we show that the winds over the shelf are mostly downwelling favorable, drawing the surface EAC waters onshore. This aligns the region of positive horizontal density gradients with the EAC core, producing a subsurface velocity maximum. The presence of a subsurface maximum may produce baroclinic instabilities that play a role in eddy formation and EAC separation from the coast. Significance Statement Observations of the East Australian Current (EAC) show that the strongest currents are often below the surface at about 100-m depth. Two factors cause this subsurface maximum. First, because the EAC is a narrow jet, carrying warm water southward from the Coral Sea, the density gradient across the jet changes sign, causing surface-intensified currents onshore and subsurface-intensified currents offshore. Second, the wind field over the shelf often pulls the shallow waters shoreward, shifting the waters that cause subsurface intensification to align with the center of the jet, resulting in a subsurface maximum of the EAC. This process may be responsible for the generation of eddies in the Tasman Sea.

Enhanced fluidity of water in superhydrophobic nanotubes: estimating viscosity using jump-corrected confined Stokes-Einstein approach.

Accurately predicting the viscosity of water confined within nanotubes is vital for various technological applications. Traditional methods have failed in this regard, necessitating a novel approach. We introduced the jump-corrected confined Stokes-Einstein (JCSE) method and now employ the same to estimate the viscosity and diffusion in superhydrophobic nanotubes. Our study covers a temperature range of 230-300 K and considers three nanotube diameters. Results show that water inside superhydrophobic nanotubes exhibits a significantly lower viscosity and higher diffusion than those inside hydrophobic nanotubes. Narrower nanotubes and lower temperatures accentuate these effects. Furthermore, water inside superhydrophobic nanotubes display a lower viscosity than bulk water, with the difference increasing at lower temperatures. This reduction is attributed to weaker water-water interactions caused by a lower water density in the interfacial region. These findings highlight the importance of interfacial water density and its influence on nanotube viscosity, shedding light on nanoscale fluid dynamics and opening avenues for diverse applications.

Potential of Coffee and Cocoa Shell Waste as An Energy Source: Analysis of Characteristics of Briquettes From Coffee and Cocoa Shell Waste Through The Carbonization Process

This research aims to compare the characteristics of briquettes as an energy source produced from coffee shell waste and cocoa waste. The briquette-making process involves carbonization to produce charcoal as the primary raw material for briquettes. Carbonization time varies, influenced by the type of waste and size of the material. After that, the charcoal is reduced and sifted into fine and coarse powder. Briquette molding uses pressure using a pipe as a mold. The characteristics of briquettes are analyzed through water content, density, burning rate, and ash content. The research results show differences in characteristics between coffee and cocoa waste. The carbonization process affects the time and mass difference of raw materials. Cocoa pod shells require the longest (±35 minutes), while cocoa bean shells require the shortest (±17 minutes). Next, making briquettes involves molding and pressing using a pipe as a mold. The results showed that waste cocoa pod shells and cocoa bean shells produced more briquettes than waste coffee pod shells and coffee bean shells. The moisture content of briquettes from all types of waste meets the standards, but the density of the raw material for coffee husk waste is low, while the briquettes have a high density. The burning rate of briquettes varies, with cocoa bean shell briquettes having the fastest burning rate and producing much smoke. The ash content of cocoa pod husk briquettes exceeds the standard, while cocoa bean husk briquettes have low ash content. The density of the raw material is correlated with the moisture content of the briquettes. The highest burning rate occurs in cocoa bean shell briquettes, influenced by low density and high water content. The ash content of the briquettes meets standards, except for cocoa shell briquettes. This research proves that cocoa and coffee shell waste can be processed into briquettes with different characteristics.

Diesel fuel properties of renewable polyoxymethylene ethers with structural diversity

Polyoxymethylene ethers (POMEs) are a class of low-soot and high-cetane oxygenate oligomers of structure RO-(CH2O–)n-R, with different chain lengths (n) and end-groups (R) that determine their diesel-like fuel properties. Commercial POMEs with methyl end-groups (MM-POME3-6) exhibit undesirably low energy density and high water solubility. A previous computational assessment indicated that the lower heating value (LHV) and water solubility for MM-POME3-6 both improve upon end-group exchange with larger butyl, iso-butyl and iso-pentyl end-groups. Here, we expanded upon our initial trans-acetalization reaction that employed 1-butanol to install butyl end-groups to also include branched, higher carbon-number end-groups using iso-butanol and fusel oil as reagents. These new products are termed iB*POME1-6, and FOil*POME1-5, respectively, and collectively referred to as R*POMEs. They possess the advantaged properties of the parent MM-POME3-6 while exhibiting higher LHV (31 MJ kg−1 and 28 MJ kg−1 for iB*POME1-6, and FOil*POME1-5, respectively) and much reduced water solubility (2.7 g L−1 and 1 g L−1 for iB*POME1-6, and FOil*POME1-5, respectively). Additional fuel property analyses were performed using 20 vol% blends of the R*POMEs with a base diesel fuel. Overall, the greater energy density and decreased water solubility of the R*POMEs, as well as their synergistic blending with diesel at moderate blend levels, provide the greatest benefits to consumers and position this group of products as an environmentally friendlier blendstock alternative to the commercially-available MM-POME3-6.

Surface premelting of ice far below the triple point

Premelting of ice, a quasi-liquid layer (QLL) at the surface below the melting temperature, was first postulated by Michael Faraday 160 y ago. Since then, it has been extensively studied theoretically and experimentally through many techniques. Existing work has been performed predominantly on hexagonal ice, at conditions close to the triple point. Whether the same phenomenon can persist at much lower pressure and temperature, where stacking disordered ice sublimates directly into water vapor, remains unclear. Herein, we report direct observations of surface premelting on ice nanocrystals below the sublimation temperature using transmission electron microscopy (TEM). Similar to what has been reported on hexagonal ice, a QLL is found at the solid-vapor interface. It preferentially decorates certain facets, and its thickness increases as the phase transition temperature is approached. In situ TEM reveals strong diffusion of the QLL, while electron energy loss spectroscopy confirms its amorphous nature. More significantly, the premelting observed in this work is thought to be related to the metastable low-density ultraviscous water, instead of ambient liquid water as in the case of hexagonal ice. This opens a route to understand premelting and grassy liquid state, far away from the normal water triple point.

The interplay of drought and hurricanes on tree recovery: insights from dynamic and weak functional responses.

Identifying the functional traits that enable recovery after extreme events is necessary for assessing forest persistence and functioning. However, the variability of traits mediating responses to disturbances presents a significant limitation, as these relationships may be contingent on the type of disturbance and change over time. This study investigates the effects of traits on tree growth-for short and longer terms-in response to two vastly different extreme climatic events (droughts and hurricanes) in a Puerto Rican forest. I found that trees display a dynamic functional response to extreme climatic events. Leaf traits associated with efficient photosynthesis mediated faster tree growth after hurricanes, while trees with low wood density and high water use efficiency displayed faster growth after drought. In the longer term, over both drought and hurricanes, tree size was the only significant predictor of growth, with faster growth for smaller trees. However, despite finding significant trait-growth relationships, the predictive power of traits was overall low. As the frequency of extreme events increases due to climate change, understanding the dynamic relationships between traits and tree growth is necessary for identifying strategies for recovery.

Extensive Analysis of a Reinvigorated Solar Water Heating System Using Low-Density Polyethylene Glazing

Solar energy is one of the most promising forms of alternative energy because it has no adverse effects on the environment and is entirely free. Converting solar energy into thermal energy is the most common and straightforward method; the efficiency of solar thermal conversion is approximately 70 percent. The intermittent nature of solar energy availability affects the performance of solar water heaters (SWH), which lowers the usefulness of solar energy in residential and commercial settings, particularly for water heating. Even at low temperatures, the performance of a collector can be improved by using low-density polyethylene (LDPE) glazing instead of traditional glass because it is less expensive and lighter than glass. Using a comprehensive experimental-simulative study, the Glass Solar water heater (glass SWH) and the low-density polyethylene solar water heater (LDPE SWH) are analyzed, examined, and compared in this work. These solar water heaters have galvanized iron (GI) as their absorber material. The SWHs were operated in a closed loop at a constant mass flow rate of 0.013 kg/s, and a 4E analysis (which stands for energy, exergy, economics, and efficiency recovery ratio) was carried out. This analysis included a look at the dynamic time, uncertainty, weight reduction, carbon footprint, and series connection. An LDPE SWH has an energy efficiency that is 5.57% and an exergy efficiency that is 3.2% higher than a glass SWH. The weight of the LDPE SWH is 32.56% lower than that of the glass SWH. Compared to the price of a conventional geyser, installing our SWH results in a cost savings of 40.9%, and monthly energy costs are reduced by an average of 25.5%. Compared to October, September has the quickest dynamic time to reach the desired temperature, while October has the most significant dynamic time. The efficiency recovery ratio (ERR) of a glass SWH is 0.0239% lower than that of an LDPE SWH. LDPE SWHs had a carbon credit worth INR 294.44 more than glass SWHs. The findings of these tests demonstrate that the LDPE SWH is a practical replacement for traditional means of heating water, such as SWHs and geysers.

Evaluation method for reservoir damage of cementing slurry

The damage of cement slurry to the reservoir is directly related to the production of oil and gas wells, and is a problem that must be solved for the efficient and economic development of oil and gas reservoirs. According to the characteristics and field conditions of reservoir damage caused by cement slurry, this paper analyzes the main factors affecting the degree of reservoir damage, puts forward the technical index requirements of the evaluation device, and establishes the evaluation method of reservoir damage caused by cement slurry in case of loss of injection. The results show that the influence of temperature on the damage of the cement slurry layer is small, and the influence of pressure difference on the damage to the cement slurry layer is large; When the pressure difference is 22 Mpa, the penetration damage rate caused by cement slurry to the pore center without mud cake attachment is about 43%. After a day of core maintenance, the permeability damage rate will reach 61.2%; The damage of cement slurry to the pore micro-fractured core is very serious. After 1 day of maintenance, the damage to the core permeability after cement slurry solidification is as high as 83%, with an average of 76.5%; When the risk of leakage is low, the cement slurry system with low density and low water loss can be used for cementing operation. The filtrate of cement slurry should be better matched with the formation clay minerals, formation water, and drilling fluid filtrate. When the risk of leakage is high, high-density cement slurry, balanced pressure cementing, pressure control cementing, and other technologies to avoid leakage can be used for cementing operations. When the cementing conditions are more difficult, the cementing slurry system can be used to dissolve the cementing slurry system at a later stage. The research results provide theoretical data support for the study of reducing the damage of cement slurry to the reservoir.

An assessment of the zooplankton biomass in Campeche Canyon (southern Gulf of Mexico) during the "Nortes" storm season of 2011

Biomass is a valuable indicator of biological production in any ecosystem and represents a proxy of secondary production in the case of zooplankton. This short communication aims to report zooplankton biomass values in the waters of the Campeche Canyon, southern Gulf of Mexico, during the "Nortes" storm season of 2011 and to explore their relationship with the hydrography and the circulation pattern. The results showed the presence of cyclonic and anticyclonic eddies associated with high and low water density at the base of the pycnocline. The highest values of zooplankton biomass (>40 g 100 m-3) were observed in regions that presented higher water density values (~26.1 kg m-3). In comparison, the lowest zooplankton biomass values (<5 g 100 m-3) were associated with low water densities (<25.6 kg m-3). The results presented here contribute to elucidating the role that physical forcing plays on the zooplankton biomass of the region, particularly during a season in which the passage of extreme storms is widespread.