The rapid growth of telecommunication technology calls for express evaluation and development for low dielectric constant (Dk) materials with higher performance requirements. At mean time, the extensive use of these dielectric materials generates increasing concerns over their crosslinking structures that cannot be readily recycled without causing environment pollution. Herein, a curing agent comprising dynamically exchangeable imine bonds was synthesized via the condensation of terephthalaldehyde (TPA) and isophorondiamine (IPDA). Epoxy vitrimers cured by this curing agent exhibited low Dk (2.75–2.79) and excellent wave transmission efficiency (>90.5 %) at high frequency range of 8.2–12.4 GHz. The cured resins can also be recycled through chemical degradation, producing reusable monomers. The cured resins demonstrate vitreous properties and its dielectric, thermal properties and wave transmission efficiency maintained unchanged after reprocessing. This work offers a strategy to prepare low Dk epoxy vitrimer used in communication field.