ABSTRACTSecurity imaging systems working with crystalline silicon CCD or CMOS detectors are not able to distinguish colorimetrically between a large number of dangerous chemical substances, for example whitish powders [1]. In order to offer an alternative to expensive and destructive chemical methods of analysis, we developed optimized hydrogenated amorphous silicon (a-Si:H) multicolor photodiodes with different spectral response characteristics for a reliable, fast, cheap and non-destructive identification of potentially dangerous substances. Experimental optical, C-V and I-V studies were performed to explore the effect of combining linear graded a‑SiC:H-/a‑SiGe:H layers with low-reflective ZnO:Al back-contacts. Typically, a-Si:H with profiled energy gaps can be found in tandem solar cells to optimize the collection of incoming photons [2,3]. We determined the absorption coefficients of a group of a-SiC:H and a-SiGe:H graded and non-graded layers to calculate the penetration depth of photons at different energies into the device structure. Knowing the indices of absorption, refraction and extinction, it is possible to engineer diodes in such a way that accumulations of charge carriers are generated precisely at varying device depths. Common chromium back reflectors avoid a sharp falling edge of the sensitivity towards longer wavelengths and lead to interference fringes in the spectral response [4]. By combining linear graded absorption zones and ZnO:Al back contacts, we designed an optimized device with a highly precise adjustment of the spectral sensitivity reaching from 420 nm to 560 nm and reduced interference fringes at a very low reverse bias voltage of maximum -2.5 V. Similar three terminal devices allow a shift from 440 nm to 630 nm, however, at a much higher reverse bias of -11 V at 560 nm [4]. Present research efforts concentrate on the development of fast and high dynamic front illumination device structures which ensure a continuous narrow-band shift of the spectral photosensitivity and an optimum adaption to a predetermined light source-/sample measurement configuration.
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