Low Precipitation Rates Research Articles

Shaping the Huara Intrusive Complex in the Hyperarid Atacama Desert—Erosional Near‐Stasis Contrasting High Topographic Gradients

AbstractThe Atacama Desert is one of the driest and oldest deserts on Earth, with extremely low precipitation rates (<2 mm/yr). Mostly abiotic hyperarid environmental conditions prevail, and surface processes act at extremely low rates over the long‐term. To gain knowledge about the rate of surface processes and age of landscapes in desert environments, terrestrial cosmogenic nuclide derived erosion rate estimates can be used. Within the Huara Intrusive Complex, situated in the hyperarid core of the Atacama Desert, basin‐averaged bedrock erosion rates from channel sediments are extremely low, that is, less than 1 m/Myr. Such low rates indicate that fluvial processes operate very slowly or are almost absent. Bedrock erosion rates of channel knickpoints, however, reveal one to two orders of magnitude higher erosion rates (2–12 m/Myr). Erosion rates are remarkably low when compared to the steep surrounding topography. Tectonic uplift creates higher gravitational potentials for surface processes, controlling the overall erosion rate capacity. However, erosion itself is taking place by local precipitation capable of exceeding thresholds for surface activity. In the Atacama Desert, this happens only due to rare severe precipitation events, explaining the extremely low erosion rates. The efficiency of these events is modulated by local intrinsic processes and conditions, such as high infiltration capacities of Atacama soils and/or large channel boulder accumulations. Due to the virtual absence of these precipitation events capable of erosion, the landscape appears to be in hibernation.

Upwelling mechanisms of deep saline waters via Quaternary erosion windows considering varying hydrogeological boundary conditions

Abstract. Intrusion of deep saline waters into freshwater aquifers does not only endanger the regional drinking water supply, but also rivers and stagnant waters and their fauna are threatened by salinisation. The upwelling of highly mineralised saline waters in large parts of the North German Basin is favoured by the presence of Elsterian glacial erosion windows in the Lower Oligocene Rupelian Clay, the most important hydraulic confining unit in this region. Lower precipitation rates and decreasing groundwater levels as a consequence of global climate change, but also anthropogenic interventions, such as increasing extraction rates or the use of the deep geologic subsurface as a reservoir, decrease the pressure potential in the freshwater column and may possibly accelerate this primarily geogenic salinisation process in the coming years. Density-driven flow and transport modelling was performed in the scope of the present study to investigate the upwelling mechanisms of deep saline waters across Quaternary window sediments in the Rupelian. Simulation results show that the interactions between the groundwater recharge rate and anthropogenic interventions such as extraction rates of drinking water wells or the utilisation of the deep subsurface, have a significant influence on the groundwater pressure potential in the freshwater aquifer and associated saltwater upwelling. In all scenarios, salinisation is most severe in the sediments of the erosion windows. Hydraulically conductive faults also intensify salinisation if located nearside erosion windows or induce a more distributed or localised salinisation in aquifers with drinking water relevance in areas that do not intersect with erosion windows. A decline in groundwater recharge thereby significantly favours upward saltwater migration. The simulation scenarios further show that a decrease in groundwater recharge also results in freshwater salinisation occurring up to 10 years earlier, which underlines the need for waterworks to initiate effective countermeasures quickly and in time.

Precipitation process for combined impurity removal from a magnesium sulphate-based leachate of ionic rare earth ore

Impurity metal ions in ionic rare earth ores are similar to rare earth ions in terms of occurrences and similarities in properties. During the leaching operation, a large number of impurity ions enter the rare earth leaching solution, which makes the crystal form of the rare earth unstable or forms an amorphous flocculent precipitate. The commonly used ammonium bicarbonate (NH4HCO3) precipitation crystallization process has low rare earth precipitation rate, long precipitation crystallization period, and high ammonia nitrogen content in precipitation wastewater. In this paper, the leaching solution obtained by ionic rare earth ore magnesium salt leaching-combined impurity removal process was taken as the research object, and the effects of precipitants, such as NH4HCO3, calcium oxide, sodium carbonate, and oxalic acid, on the preparation of crystalline rare earth precipitation were investigated through comparison. On the premise of determining the best rare earth precipitant, the effects of dosage, stirring speed, stirring time, and aging time on the preparation of crystalline rare earth precipitate were investigated further. The precipitation effects of different precipitation processes were studied systematically combined with SEM-EDS, laser particle size analysis, and other means to characterize the morphology of crystalline products. Results showed that when calcium oxide was used as a precipitant, the molar ratio was 2.5. After stirring at a constant speed of 200 r/min for 4 h and aging for 4 h, precipitates with good crystal appearance, smooth crystal surface and easy filtration were obtained. This process promoted crystal growth of rare earth precipitates, and the crystal grain size, which was beneficial to the improvement of the quality of rare earth products, increases significantly.

Climatic Water Balance Comparison for Selected areas in The Middle of Iraq

The climate parameters annual rainfall and average mean temperature are investigated from 2000 to 2019 for Kut, Hilla and Iskandaryia. Evidence of climate change is noticed by decreasing the mean annual rainfall and relative humidity with an increase in the annual mean temperature. The climate water balance has been calculated. Due to high temperature, increased evaporation, and low precipitation rates, there was a large water deficit. The total water surplus in the Kut area is 32.86 mm from November to February, and in Hilla and Iskandaryia is 20.4 and 27.8 mm from December to February, respectively. The climate classification for the three stations was semi-dry to dry climates. The region has a significant water deficit of up to 79.6 % of the total rainfall values indicated in Hilla station. Climate change has affected the locations near meteorological stations such as Kut, Hilla and Alexandria. All the studied climatic variables imprint water surplus or water deficit with slight changes within each geographical area.

Plant Age and Soil Texture Rather Than the Presence of Root Hairs Cause Differences in Maize Resource Allocation and Root Gene Expression in the Field.

Understanding the biological roles of root hairs is key to projecting their contributions to plant growth and to assess their relevance for plant breeding. The objective of this study was to assess the importance of root hairs for maize nutrition, carbon allocation and root gene expression in a field experiment. Applying wild type and root hairless rth3 maize grown on loam and sand, we examined the period of growth including 4-leaf, 9-leaf and tassel emergence stages, accompanied with a low precipitation rate. rth3 maize had lower shoot growth and lower total amounts of mineral nutrients than wild type, but the concentrations of mineral elements, root gene expression, or carbon allocation were largely unchanged. For these parameters, growth stage accounted for the main differences, followed by substrate. Substrate-related changes were pronounced during tassel emergence, where the concentrations of several elements in leaves as well as cell wall formation-related root gene expression and C allocation decreased. In conclusion, the presence of root hairs stimulated maize shoot growth and total nutrient uptake, but other parameters were more impacted by growth stage and soil texture. Further research should relate root hair functioning to the observed losses in maize productivity and growth efficiency.

Using machine learning algorithms to predict groundwater levels in Indonesian tropical peatlands

Tropical peatlands play a vital role in the global carbon cycle as large carbon reservoirs and substantial carbon sinks. Indonesia possesses the largest share (65 %) of tropical peat carbon, equal to 57.4 Gt C. Human perturbations such as extensive logging, deforestation and canalization exacerbate water losses, especially during dry seasons, when low precipitation and high evapotranspiration rates combine with the increased drainage to lower groundwater levels. Drying and increasing temperatures of the surface peat exacerbate ignition and wildfire risks within the peat soils. As such, it is critically important to know how groundwater levels in peatlands are changing over space and time. In this study, a multilinear regression model as well as two machine learning algorithms, random forest and extreme gradient boosting, were used to model groundwater level over the study period (2010−12) within a peat dome impacted by drainage canals and multiple wildfires in Central Kalimantan, Indonesia. Although all three models performed well, based on overall fit, spatial modeling of groundwater level results revealed that extreme gradient boosting (R2 = 0.998, RMSE = 0.048 m) outperformed random forest (R2 = 0.997, RMSE = 0.054 m) and multilinear regression (R2 = 0.970, RMSE = 0.221 m) near drainage canals, which are key fire ignition risk locations in the peatlands. Our study also shows that, on average, elevation and precipitation are the most important parameters influencing groundwater level spatiotemporally.

Drought Severity and Frequency Analysis Aided by Spectral and Meteorological Indices in the Kurdistan Region of Iraq

In the past two decades, severe drought has been a recurrent problem in Iraq due in part to climate change. Additionally, the catastrophic drop in the discharge of the Tigris and Euphrates rivers and their tributaries has aggravated the drought situation in Iraq, which was formerly one of the most water-rich nations in the Middle East. The Kurdistan Region of Iraq (KRI) also has catastrophic drought conditions. This study analyzed a Landsat time-series dataset from 1998 to 2021 to determine the drought severity status in the KRI. The Modified Soil-Adjusted Vegetation Index (MSAVI2) and Normalized Difference Water Index (NDWI) were used as spectral-based drought indices to evaluate the severity of the drought and study the changes in vegetative cover, water bodies, and precipitation. The Standardized Precipitation Index (SPI) and the Spatial Coefficient of Variation (CV) were used as meteorologically based drought indices. According to this study, the study area had precipitation deficits and severe droughts in 2000, 2008, 2012, and 2021. The MSAVI2 results indicated that the vegetative cover decreased by 36.4%, 39.8%, and 46.3% in 2000, 2008, and 2012, respectively. The SPI’s results indicated that the KRI experienced droughts in 1999, 2000, 2008, 2009, 2012, and 2021, while the southeastern part of the KRI was most affected by drought in 2008. In 2012, the KRI’s western and southern parts were also considerably affected by drought. Furthermore, Lake Dukan (LD), which lost 63.9% of its surface area in 1999, experienced the most remarkable shrinkage among water bodies. Analysis of the geographic distribution of the CV of annual precipitation indicated that the northeastern parts, which get much more precipitation, had less spatial rainfall variability and more uniform distribution throughout the year than other areas. Moreover, the southwest parts exhibited a higher fluctuation in annual spatial variation. There was a statistically significant positive correlation between MSAVI2, SPI, NDWI, and agricultural yield-based vegetation cover. The results also revealed that low precipitation rates are always associated with declining crop yields and LD shrinkage. These findings may be concluded to provide policymakers in the KRI with a scientific foundation for agricultural preservation and drought mitigation.

Role of tectonics and climate on elevated arsenic in fluvial systems: Insights from surface water and sediments along regional transects of Chile

Globally, arsenic (As) contamination is widespread in hydrological systems and the link between As enrichment and regional tectonic and climatic factors is still not well understood in orogenic environments. This work provides new insights on the relationship between As, tectonics, and climate by assessing the hydrochemistry of Chile, an active subduction zone with highly diverse natural settings. Selected study sites include fluvial courses along four regional transects connecting the Chilean coast to the Andes Cordillera in the northern, central, and southern areas of the country.The results indicate that As concentrations in surface water and fluvial sediments show a general positive correlation to crustal thickness and they tend to decrease progressively from northern to southern Chile. In contrast, As concentrations are negatively correlated to average annual precipitation which shows a significant increase toward southern Chile. From a regional tectonic perspective, northern Chile presents greater Andes shortening and higher crustal thicknesses, which induces increased crustal contamination and As content at the surface. Extremely low precipitation rates are also tied to local As enrichment and a sediment-starved trench that might favor higher plate coupling and shortening. On the contrary, decreased shortening of the Andes in southern Chile and related lower crustal thickness induces lower crustal contamination, thus acting as an As-poor provenance for surficial sediments and surface water. High precipitation rates further induce dilution of surface water, potential mobilization from the solid phase, and a significant amount of trench sediments that could induce lower plate coupling and lower shortening.At the local scale, a low potential for As mobilization was found in northern Chile where a greater distribution of As-bearing minerals was observed in sediments, mostly as finer particles (<63 μm). The abundance of Fe-oxides potentially acts as a secondary surficial sink of As under the encountered physicochemical conditions.

Iron isotope fractionation in anoxygenic phototrophic Fe(II) oxidation by Rhodobacter ferrooxidans SW2

Microbially mediated Fe(II) oxidation is one of the most important pathways of Fe redox cycling on both present and early Earth. It was proposed to participate in iron formations (IFs) deposition under oxygen-depleted oceanic conditions before the Great Oxidation Event (GOE). Fe isotopic records in IFs provide important archives for the redox state of iron pool in paleo oceans. There have been a number of iron-oxidizing experiments which used bacteria with different metabolic pathways. However, it still needs further research on how and to what extent Fe isotopes are fractionated during Fe(II) oxidation mediated by the anoxygenic phototrophic Fe(II)-oxidizer, as well as its implications for the redox state of iron pool in paleo oceans. Here, we report Fe isotope fractionation between Fe(II)aq and Fe(III) (oxyhydr)oxides precipitates produced by the anoxygenic phototrophic Fe(II)-oxidizer Rhodobacter ferrooxidans SW2 at ambient temperature (20 °C). Mössbauer spectroscopy analyses indicated that the final mineral product was ferrihydrite. The corrected Fe isotope fractionation between Fe(II)aq and precipitates (Δ56Feprecipitate–Fe(II)aq) ranged from ca. −0.37 ± 0.04‰ (2se, N = 2) after 1 day of cultivation to 2.96 ± 0.17‰ (2se, N = 2) after 22 days of cultivation. The observed fractionation cannot be explained by neither a simple Rayleigh nor equilibrium process, but likely recorded a process from an isotopic disequilibrium reaching complete or near-complete equilibrium during 22 days of cultivation. The lower precipitation rate after 7 days, small size of oxidation products and dissolution-oxidation-reprecipitation processes probably promoted isotope exchange overwhelming the kinetic effect, resulting in a final isotope equilibrium between precipitates and Fe(II)aq. It revealed that the ferrihydrite produced by Fe(II) oxidation by anoxygenic photoferrotrophy could reach Fe isotope equilibrium relatively easily, thus IFs may record Fe isotope equilibrium with the fluids from which they precipitated, i.e. in some cases solely from seawater in Archean oceans.

Influence of Weather Conditions on the Spread of Fires in the Forest Fund of Zhytomyr Polesia

Fires are one of the critical factors in the weakening of forests. Given the high share of pine forests in the Zhytomyr Oblast, the conditions for fires are very favourable. Especially intense fires occurred in 2020, when rapid warming occurred in the spring, which in the absence of snow cover and the presence of intense winds in the February-March 2020 increased the fire danger in forests. The purpose of this study is to identify the features of the dynamics of the spread of fires in the forest stands of the Zhytomyr Oblast Department of Forestry and Hunting and assess the meteorological indicators that may affect their spread. Research methods: statistical – when analysing data on meteorological indicators and materials for accounting for forest fires. The study identified the specific features of the dynamics of fire spread in forest stands of Zhytomyr Oblast in 2014-2021. According to the analysis, there was a considerable increase in the number and area of fires in 2020 compared to the average figures for 2014-2019 and 2021 combined. During 2014-2021, 951 fires occurred on a forested area of 43,807.65 hectares. It was revealed that only 448 fires occurred in 2014-2019 and 2021, and 503 fires were recorded in 2020 on an area of 43,229 hectares. Among others, crown fires were recorded on an area of 6,389 hectares in the same 2020 year and on an area of 35.7 hectares in 2019 alone. The largest areas of crown fires were recorded on the territory of the State Enterprise “Ovrutske SF”, State Enterprise “Luhynske forestry”, State Enterprise “Ovrutske forestry” and State Enterprise “Slovechanske forestry”. The indicators of temperature, precipitation, and hydrothermal coefficient for 2014-2021 are analysed. The values of air temperature and precipitation were determined during the growing season, and the hydrothermal coefficient was calculated according to G.T. Selyaninov. The study established that the sum of air temperatures during the growing season was 3,127.6°C on average for 2014-2021. The highest temperature values were recorded during the growing season of 2018. According to the analysis of the amount of precipitation for the growing season 2014-2021, the indicators were set at 323.8 mm. The lowest precipitation rates were recorded in 2015. According to the ratio of temperature and precipitation indicators, the value of G.T. Selyaninov’s hydrothermal coefficient for the growing seasons of 2014-2021 was obtained, the average value of which was 1.04 units

New insights into Mn2+ and Mg2+ inhibition of calcite growth

Impurity ion and isotope partitioning into carbonate minerals provide a window into the molecular processes occurring at the fluid-mineral interface during crystal growth. Here, we employ calcium isotope fractionation together with process-based modeling to elucidate the mechanisms by which two divalent cations with starkly contrasting compatibility, magnesium and manganese, inhibit calcite growth and incorporate into the mineral lattice. Calcite growth inhibition by Mg2+ is log-linear and KMg is on the order of 0.02–0.03 throughout the range of {Mg2+}/{Ca2+} studied here (0.01–2.6). Mn2+ exhibits much stronger log-linear growth rate inhibition at low Mn2+ concentrations (fluid {Mn2+}/{Ca2+} = 0.001–0.02). Mn2+ is readily incorporated into the calcite lattice to form a calcite-rhodochrosite solid solution, with large partition coefficients (KMn 4.6–15.6) inversely correlated to growth rate. For both Mn2+ and Mg2+, calcium isotope fractionation is found to be invariant with {Me2+}/{Ca2+} despite more than an order of magnitude decline in growth rate. This invariant Δ44/40Ca suggests that the presence of Mn2+ or Mg2+ does not significantly change the relative rates of Ca2+ attachment and detachment at kink sites during growth, indicative of a dominantly kink blocking inhibition mechanism. Because the partitioning behavior dictates that Mn2+ must attach to the surface significantly faster than Ca2+, attachment of Mn2+ is likely to be as a non-monomer species such as an ion pair or possibly a larger polynuclear cluster. We propose that calcite growth rate inhibition by Mn is determined by the kinetics of carbonate attachment at Mn-occupied kink sites, potentially due to slow re-orientation kinetics of carbonate ions that have formed an inner-sphere complex with Mn2+ at the surface but must reorient to incorporate into the lattice. We demonstrate that patterns in Mg2+ partitioning and inhibition behavior are broadly consistent with growth inhibition driven by slow Mg2+-aquo complex dehydration relative to Ca2+ but argue that this mechanism likely represents one endmember scenario, seen in Mg-calcite growth at low supersaturations and net precipitation rates. During growth at faster net precipitation rates, some portion of Mg2+ is likely incorporated as a partially hydrated or otherwise complexed species, but calcite growth remains significantly inhibited by the kinetics of CO32− attachment at Mg2+ kink sites. These findings suggest a hybrid classical/nonclassical growth mechanism whereby Ca2+ incorporates largely as a free ion at kink sites while Mn2+ and some portion of Mg2+ are incorporated via non-monomer attachment. This pattern may be generalizable; trace constituent cations with aquo-complex desolvation rates significantly slower than the mineral growth rate preferentially incorporate as a non-monomer species during otherwise classical crystal growth.

Saline lakes as barriers against pollution: a multidisciplinary overview

Saline lakes are subject to numerous environmental impacts closely related to human activities, including mining, desiccation and pollution. These lakes are mostly located in arid and semi-arid regions located in endorheic basins, which combined with the low precipitation and high evaporation rates typical for these regions, may lead to the accumulation of pollutants. Saline lakes are polluted mainly through inputs of agricultural wastewater along with organic and inorganic wastes from domestic and industrial sources. The excessive anthropogenic loading of nutrients, especially nitrogen (N), can result in eutrophication of these ecosystems. Here, the importance of pollution in saline lakes was assessed, placing special emphasis on N pollution and its attenuation in aquatic interfaces. Two main interfaces are present in saline lakes: (1) the sediment-water interface; (2) the freshwater-saltwater interface. While the former is the most important one for microbial turnover, the latter plays also a key role in pollution attenuation based on solute transport by density-driven flows. The study of how saline lakes can attenuate N pollutants (e.g. nitrate) is a step forward in preserving the good ecological status of these ecosystems. This work highlights the need of integrating a wide range of techniques from different disciplines such as limnology, hydrogeology, geochemistry or microbial ecology for such studies. The effective application of conservation policies by managers will depend on the degree of knowledge of these systems.

Feasibility of Bridge Deicing Using Geothermal Energy Piles in Different U.S. Climates

Geothermal energy piles are an environmentally friendly energy source and an innovative approach to melt snow on the bridge surface and minimize or eliminate the use of deicing salt. However, the application potential of energy piles for bridge deicing or snow melting has not been fully explored for different climates. In this study, the feasibility of using energy piles for bridge deicing in eight cities of the United States was investigated. Temperature response function (G function) method was validated and used to estimate the extracted heat from energy piles installed in the soils with different thermal properties, which was used to heat the bridge deck during snowing. The results of numerical simulation and statistical analysis confirm that the performance of the geothermal deicing system depends on the weather conditions during snowing and thermal properties of soils. The coverage rate of the geothermal system (percentage of snowing time that the geothermal deicing system can keep the bridge surface above 0°C) increases with the increasing air temperature and thermal diffusivities of soils, and decreases with the increasing precipitation rate and wind speed. This deicing method is promising in cities with higher average air temperature and low precipitation rate during snowing.

Modeled Impacts of LULC and Climate Change Predictions on the Hydrologic Regime in Belize

Land use and land cover (LULC) change can have detrimental effects on water quality. In Belize, agricultural expansion creates the risk of increased sediment load and excess nutrients in runoff water, while deforestation removes potential infiltration sites for this outflow. Climate change and evolving precipitation rates can intensify the quantity of runoff, further enabling the flow of sediments and excess nutrients out to the lagoon surrounding the Belize Barrier Reef Reserve System (BBRRS). This study sought to estimate potential impacts on future water quality in Belize by first modeling LULC change through 2090 across Belize’s major watersheds based on observed trends from 2008 to 2018. Those LULC projections were subsequently combined with soil type data, elevation, and precipitation rates into a hydrologic model to produce runoff flow estimates as a proxy for water quality. The two Coupled Model Intercomparison Project phase 6 (CMIP-6) scenarios employed in the study represented bookend climate change scenarios, and both indicated generally lower precipitation rates in Belize over the next century due to climate change. The most extreme scenario predicted a 46% decrease in precipitation. When holding LULC change constant, these climate scenarios projected a decrease in runoff, suggesting a positive relationship between precipitation and runoff. In contrast with the northern watersheds, the southern watersheds are projected to experience greater decreases in annual rainfall and runoff by 2090. When holding climate constant, runoff increased by approximately 2.8% in the Conservation-focused LULC scenario by 2090, which was 28% lower than the Business as Usual scenario, and 42% lower than the Development scenario. The study’s integration of CMIP6 climate scenarios into LULC and hydrologic modeling provides a more holistic view of the future of Belize’s water quality and supports the long-term planning efforts of local decision-making agencies.

Driving Forces of Forest Expansion Dynamics across the Iberian Peninsula (1987–2017): A Spatio-Temporal Transect

This study analyzes the spatio-temporal dynamics of the drivers of forest expansion in the Iberian Peninsula for the periods 1987–2002–2017 through a 185 km-wide north–south Landsat scene transect. The analysis has considered a variety of biogeographical regions [0–3500 m.a.s.l, annual rainfalls 150–2200 mm] and 30 explanatory variables. A rigorous map production at 30 m resolution, including detailed filtering methods and uncertainty management at pixel scale, provided high-quality land cover maps. The main forest expansion trajectories were related to explanatory variables using boosted regression trees. Proximity to previous forests was a key common factor for forest encroachment in all forest types, with other factors being distance to the hydrographic network, temperature and precipitation for broadleaf deciduous forests (BDF), precipitation, temperature and solar radiation for broadleaf evergreen forests (BEF) and precipitation, distance to province capitals, and solar radiation for needleleaf evergreen forests (NEFs). Results also showed contrasting forest expansion trajectories and drivers per biogeographic region, with a high dynamism of grasslands towards new forest in the Eurosiberian and the mountainous Mediterranean regions, a high importance of croplands as land cover origin of new forest in the Mesomediterranean, and increasing importance over time of socioeconomic drivers (such as those employed in the industry sector and the utilized agricultural area) in the Supramediterranean region but the opposite pattern in the Southern Mesomediterranean. Lower precipitation rates favored new NEFs from shrublands in the Thermomediterraean region which, together with the Northern Mesomediterranean, exhibited the highest relative rates of new forests. These findings provide reliable insights to develop policies considering the ecological and social impacts of land abandonment and subsequent forest expansion.

Factors affecting precipitation formation and precipitation susceptibility of marine stratocumulus with variable above- and below-cloud aerosol concentrations over the Southeast Atlantic

Abstract. Aerosol–cloud–precipitation interactions (ACIs) provide the greatest source of uncertainties in predicting changes in Earth's energy budget due to poor representation of marine stratocumulus and the associated ACIs in climate models. Using in situ data from 329 cloud profiles across 24 research flights from the NASA ObseRvations of Aerosols above CLouds and their intEractionS (ORACLES) field campaign in September 2016, August 2017, and October 2018, it is shown that contact between above-cloud biomass burning aerosols and marine stratocumulus over the Southeast Atlantic Ocean was associated with precipitation suppression and a decrease in the precipitation susceptibility (So) to aerosols. The 173 “contact” profiles with aerosol concentration (Na) greater than 500 cm−3 within 100 m above cloud tops had a 50 % lower precipitation rate (Rp) and a 20 % lower So, on average, compared to 156 “separated” profiles with Na less than 500 cm−3 up to at least 100 m above cloud tops. Contact and separated profiles had statistically significant differences in droplet concentration (Nc) and effective radius (Re) (95 % confidence intervals from a two-sample t test are reported). Contact profiles had 84 to 90 cm−3 higher Nc and 1.4 to 1.6 µm lower Re compared to separated profiles. In clean boundary layers (below-cloud Na less than 350 cm−3), contact profiles had 25 to 31 cm−3 higher Nc and 0.2 to 0.5 µm lower Re. In polluted boundary layers (below-cloud Na exceeding 350 cm−3), contact profiles had 98 to 108 cm−3 higher Nc and 1.6 to 1.8 µm lower Re. On the other hand, contact and separated profiles had statistically insignificant differences between the average liquid water path, cloud thickness, and meteorological parameters like surface temperature, lower tropospheric stability, and estimated inversion strength. These results suggest the changes in cloud microphysical properties were driven by ACIs rather than meteorological effects, and adjustments to existing relationships between Rp and Nc in model parameterizations should be considered to account for the role of ACIs.

Seasonal and regional variability of wet and dry spell characteristics over Turkey

Understanding the variations and leading atmospheric mechanisms causing wet and dry episodes are very important for the water management strategies. For this purpose, this study investigates the spatiotemporal variation and background environmental conditions for wet and dry spell lengths in Turkey. With this aim, Mann-Kendall rank statistic test and fitted ordinary least squares regression method are implemented to the 92 meteorology stations, which are homogenously distributed over Turkey, for the period 1966–2018. In terms of atmospheric circulation mechanisms, synoptic composites of NCEP/NCAR Reanalysis data (sea level pressure, air temperature at 850-hPa level, geopotential height at 500-hPa level) and sea surface temperature from NOAA High Resolution data are applied to the five years of highest frequency long dry/wet spells. According to the results, both the increasing frequencies of wet spells and their highest contribution to the precipitation are mainly found in the eastern Black Sea Region (BSR) of Turkey during all seasons, especially in spring. In this sub-region, statistically significant increasing (decreasing) springtime wet (dry) spell lengths in the neighboring five stations (i.e. Ardahan, Artvin, Bayburt, Hopa, Rize) indicated that the majority of wet spells (almost 30%) appear to occur between 3 and 5 days and the maximum number of the wet spell days are shown in the last two decades of the eastern BSR. Local quasi-stationary surface high located over eastern Black Sea (1016-hPa core) and associated weak northerly winds transfer relatively warm moist air from the sea surface (11.8 °C in average). This air mass meets with cold- land and low level (6 °C at 850 hPa) air masses, developing instability conditions and resulting in low precipitation rates in wet spells for the eastern BSR. On the other hand, by the extension of the south-west Asian Monsoon to the inner parts of Turkey, relatively hot dry air is transferred to the eastern BSR via southerly winds. As a result of this long-staying Asiatic monsoon characteristics, more dry days are shown in the region due to insufficient moisture and associated lack of precipitation.

Thermodynamic and Kinetic Studies on the Conversion of Solvent-Shared to Contact Ion Pairs in Sparingly Soluble MF2 (M = Mg2+ and Ca2+) Aqueous Solutions: Implications for Understanding Supersaturated Behavior and Association Constant Determination.

The thermodynamic and kinetic behaviors of Mg2+-F- ion pairing in aqueous solution are investigated theoretically and experimentally and are contrasted to those of Ca2+-F-. Thermodynamically, similar to CaFx(H2O)142-x (x = 1 and 2), MgF(H2O)y+ (y = 14-20) contact ion pairs (CIPs) are more stable than their solvent-shared ion pairs (SSIPs), whereas the CIPs and SSIPs of MF2(H2O)y are almost isoenergetic. However, in kinetics, the conversion of SSIPs to CIPs for M2+-F- (M = Mg2+ and Ca2+) ion pairing must overcome a high energy barrier due to the strong hydration of Mg2+ and F-. The kinetics dominate after the thermodynamics and kinetics are balanced, which hinders the formation of M2+-F- CIPs in practical MF2 aqueous solutions (less than or equal to saturated concentrations). This result is also supported by the 19F nuclear magnetic resonance spectra of saturated MF2 solutions. Although the interaction between Mg2+ and F- is slightly stronger than that between Ca2+ and F- due to the smaller radius of Mg2+, the formation of Mg2+-F- CIPs needs to go through two rate-limiting steps, the dehydration and entrance of F- (i.e., via exchange mode) with a higher energy barrier, due to the ability of strongly bound water molecules and rigorous octahedral coordinated configuration of Mg2+, while the formation of Ca2+-F- CIPs only goes through a single rate-limiting step, the entrance of F- (i.e., via swinging mode) with a lower energy barrier, due to the flexible coordination configuration of Ca2+. This is responsible for precipitation in MgF2 aqueous solution requiring a larger supersaturation degree and a lower precipitation rate than in CaF2. These kinetic factors lead to the association constants previously reported for MF+ determined by a fluoride ion-selective electrode (ISE) combined with the titration method, where the MF2 solutions were always unsaturated at the titration end point, which actually corresponds to those of the ligand process going from completely free M2+ and F- to their SSIPs. A possible strategy to accurately determine the association constants of MF+ and MF2(aq) CIPs by fluoride ISEs is proposed. The present results suggest that judging the formation of M2+-F- CIPs in practical solutions from a theoretical calculation perspective requires significant consideration of the kinetic factors, except for the thermodynamic factors.

Precipitation Variability and Probabilities of Extreme Events in the Eastern Mediterranean Region (Latakia Governorate-Syria as a Case Study)

This study aimed at analysis of the general-index change for the mean annual and seasonal precipitation in six stations in Latakia Governorate (Syria). The data of precipitation were collected for 40 consecutive years (1970–2010) in order to figure out the extent of the changes and variability in precipitation rates and the impact of this change on changes in the potential density that might cause extremely high or low precipitation rates according to Gumbel distribution of the extreme precipitation rates. Results revealed a decrease of the annual precipitation rates in all stations, the reduction in precipitation ranged from 46 to 210 mm during the whole period of the study. Spring, however, recorded the highest and statistically significant reduction, which reached 46–210 mm, while winter precipitation increased by 21–82 mm. Spring also has witnessed a decrease of about 3–9% of the total annual precipitation as compared to winter precipitation which increased by 5–8% of the total. The potential density of extremely high winter precipitation rates increased in all stations as indicated from Gumbel distribution in winter, and a greater increase took place in the probabilities of occurrence of the extremely low spring precipitation rates. This shows significant probability of occurrence of drought during spring season. By contrast, probabilities of winter precipitation rates increased more, thus winter is relatively more humid than before and spring is relatively drier than before.

Effect of cutting speed and feed on surface roughness in dry turning of Inconel X-750

Dry turning is one of the sustainable way to achieve sustainability in machining but due to low heat precipitation rate of Inconel X 750, the excess temperature is generated during dry cutting which further causes built-up-edge formation and consequently creates poor surface finish. As a general practice, sharp edge of cutting tool reduces the vibration and enhances the surface roughness. Accordingly, the use of small nose radius is a better solution to smoothly cut the HRSA materials. Therefore, an attempt has made to study the effect of cutting speed and feed rate on surface roughness during turning of Inconel X-750 under dry environment by using PVD TiAlN coated negative inserts with small tool nose radius of 0.4 mm. The cutting speed and feed has been applied in three different ranges viz. 60,80 & 100 m/min and 0.05, 0.1 and 0.15 mm/rev respectively. Whereas, the depth of cut of 0.5 mm has kept constant for all experiments. In most of the cases it is noticed that with Ra value goes on increasing and found within acceptable range with increase in cutting speed and feed. However, at feed rate of 0.1 mm/rev with corresponding speed of 100 m/min, the continuous chips are produced which caused the rubbing action. Hence, excessive localized heat is generated at chip-tool interface and built up edge is formed. Consequently, the poor surface finish is produced due to the hard turning. The highest cutting speed and feed of 100 m/min and 0.15 mm/rev respectively found to be optimum cutting condition which imparted acceptable surface roughness value of 1.50 µm as per ANSI/ASME B46.1–2009 standards. The cutting speed and feed rate are found to be important parameters while studying surface roughness. However, In comparison to cutting speed, the feed rate havegreater impact on surface integrity.