Long-term Performance Research Articles

Carbon bridge effects regulate TiO2-acrylate fluoroboron coatings for efficient marine antifouling

Synergy strategy of photocatalysts and polymer resins are promising technology for marine antifouling. However, it is still a main challenge to obtain a green, safe, and efficient antifouling coatings. Herein, carbon (graphene or CNT) modified TiO2 photocatalyst was synthesized via hydrothermal and annealing process and has successfully applied in acrylate fluoroboron polymer (ABFP) composite coating. Morphology and chemical composition were detailed characterized. The graphene or CNT acted as a bridge with supplemental spatial structures (petal gaps, entanglement) and new functional groups (C-O, C-Ti-O, etc.) on TiO2 particle. Carbon nanotube (CNT) modified TiO2-ABFP coatings (BTCP) achieved excellent antibacterial and anti-diatom adhesion rate of 89.33%-96.70% and 99.00%-99.50%, which was 1.84-4.94-fold more than that of the single ABFP. CNT or graphene served as electronic bridges was considered as the crucial mechanism, which significantly improved the light absorption range and capacity, conductivity, and photoelectric response of TiO2, and further accelerated the generation and transfer of free radicals to the surface of BTCP or FTGP. Moreover, the improvement of catalyst activity synergizes with the smooth surface, hydrophilicity, and slow hydrolysis of composite coatings, achieved long-term and efficient antifouling performance. This work provides a new insight into the modification of TiO2 and antifouling mechanism of polymer coating.

Role of Interface Strain and Chemo-Mechanical Effects during Electroplating in Sodium Metal Battery Anodes.

In this study, we demonstrate that elastic strain applied to a current collector can influence the overall thermodynamic and kinetic picture of sodium metal electrodeposition and hence the performance of a sodium metal battery. To controllably study the role of strain in electrochemical performance, we utilize NiTi foil as a stable current collector, nucleation interface, and superelastic material. Our findings demonstrate that a locked-in elastic tensile strain near 8% results in 40 mV lower onset potential for sodium electrodeposition, 19% decrease in charge transfer resistance, and 20% lower cumulative sodium loss, among other effects. These performance improvements are correlated primarily to the control of the irreversible behavior in the first few minutes of electroplating. Given the prevalence of strain buildup in commercial battery cell configurations, our work highlights that strained current collector interfaces can result in significant long-term chemo-mechanical performance outcomes broadly relevant to sodium and other metal battery design considerations.

Novel insights into intrinsic mechanisms of magnetic field on long-term performance of anaerobic ammonium oxidation process

The performance of an anaerobic ammonium oxidation (anammox) reactor with the magnetic field of 40 mT was systematically investigated. The total nitrogen removal rate was enhanced by 16% compared with that of the control group. The enhancing mechanism was elucidated from the improved mass transfer efficiency, the complicated symbiotic interspecific relationship and the improved levels of functional genes. The magnetic field promoted formation of the loose anammox granular sludge and the homogeneous and well-connected porous structure to enhance the mass transfer. Consequently, Candidatus Brocadia predominated in the sludge with an increase in abundance of 13%. Network analysis showed that the positive interactions between Candidatus Brocadia and heterotrophic bacteria were strengthened, which established a more complicated stable microbial community. Moreover, the magnetic field increased the levels of hdh by 26% and hzs by 35% to promote the nitrogen metabolic process. These results provided novel insights into the magnetic field-enhanced anammox process.

Effect of biochar on microplastics penetration treatment within soil porous medium under the wetting-drying cycles and optimisation of soil-biochar mixing format

Plant-based biochar was demonstrated promising capability in adsorbing microplastic particles (MPs) within soil porous mediums. However, biochar's function in mitigating MPs' vertical penetration during wetting-drying cycles, typical of seasonal precipitation and evaporation, remains uncertain. Furthermore, few studies have investigated the structures of how biochar combines with soil. This study conducted column tests to assess the MPs retention capabilities of soil-biochar porous media under saturated and wetting-drying conditions. The water retention and hydrophilic properties were investigated to elucidate the impact of wetting-drying cycles. Additionally, different biochar-soil structures were compared to optimise the structural design. Without biochar, wetting-drying cycles resulted in 8.74 % more MPs escaping from samples. However, incorporating 15 % biochar led to only around 2 % more MPs in effluent. Biochar significantly enhanced soil's MP absorption capacity and mitigated the negative effects of wetting-drying cycles. Biochar's alveolate morphology provides ample adsorption sites and creates complex flow paths. The hydrophilic groups of biochar and capillarity by micropores facilitated slower water release during drying, preventing crack propagation and flush on MP particles. This effect was more pronounced with higher biochar content and lower porosity. Moreover, layer structure was found to improve MPs removal, benefiting the long-term performance and management of the biochar functional layer.

Development and characterization of Al2O3/SrAl12O19 reinforced zirconia with high fracture toughness and low-temperature degradation-resistant for dental applications

The low fracture toughness and sensitivity to low-temperature degradation (LTD) are the primary reasons for the suboptimal long-term performance of dental zirconia. Composite ceramics of zirconia have gained popularity due to their ability to combine the benefits of various reinforcements. In this study, Al2O3-SrAl12O19-3Y/4Y/5Y-ZrO2 composite ceramics were fabricated using the Pechini method, and the optimal sintering temperature and time were investigated. The relative density, microstructure, grain size, mechanical properties, and LTD resistance of the samples were characterized. The results indicated that the composite achieved optimal performance when sintered at 1500°C for 3 hours. Al2O3 and SrAl12O19 primarily influence the properties of the zirconia composite ceramics by modulating their density and grain size. With an increase in the content of Al2O3 and SrAl12O19, the relative density first increases and then decreases, while the grain size exhibits an inverse trend, resulting in an initial increase followed by a decrease in fracture toughness. Additionally, the rate of increase in the m-phase fraction of the zirconia composite slowed down, but it reached a similar level after 64 hours of LTD. The incorporation of 8 vol.% Al2O3 and 8 vol.% SrAl12O19 into 3Y-ZrO2 resulted in a ceramic composite with the highest fracture toughness values and acceptable LTD sensitivity, measured at 5.23 ± 0.25 MPa·m1/2 and 48.35 ± 5.70% m-phase (LTD 64 hours), respectively. This composite also exhibited high bending strength (990.09 MPa) and hardness (16.52 GPa), making it a promising alternative to conventional 3Y-TZP ceramics commonly used in dentistry.

A practical approach to semi-automated supported liquid extraction and measurement of 18 steroids in plasma by targeted liquid chromatography tandem mass spectrometry

Chromatography combined with mass spectrometry is a gold standard technique for steroid measurement, however the type of sample preparation, the dynamic range and reliability of the calibration curve, the chromatographic separation and mass spectrometry settings ultimately determine the success of the method. The steroid biosynthetic pathway is conserved in higher mammals and literature demonstrates that the concentration ranges of different steroid groups are relatively comparable across species. We sought to develop a robust and reliable multi steroid targeted analysis method for blood that would have wide application across higher mammals. The method was developed following bioanalytical method validation guidelines to standards typically applied to human clinical studies, including isotopically labelled internal standards where at all possible. Here we describe the practical approach to a 96-well supported liquid extraction (SLE) method of extraction from plasma (200 μL) using an Extrahera liquid handling robot (Biotage, Sweden), including quality control samples, followed by a comprehensive separation and targeted LC-MS/MS analysis of 20 steroids. The method can measure 18 steroids in plasma (pregnenolone, progesterone, 17α-hydroxyprogesterone, 11-deoxycorticosterone, corticosterone, 11-dehydrocorticosterone, aldosterone, 11-deoxycortisol, 21-deoxycortisol, cortisol, cortisone, androstenedione, testosterone, 5α-dihydrotestosterone, dehydroepiandrosterone, estrone, 17β-estradiol and estriol). The workflow includes● SLE in a 96-well format of up to 74 biological plasma samples, enriched with multiple isotopically labelled internal standards, a 12-point aqueous calibration curve, and 6 serum quality controls, designed to monitor long-term performance of the method● Chromatographic separation of multiple steroids along the gradient, with ammonium fluoride mobile phase additive to improve sensitivity, followed by electrospray ionisation and constant polarity switching● Aqueous calibration standards that cover physiologically relevant ranges - high nanomolar glucocorticoids, low nanomolar androgens and picomolar ranges for estrogens and steroid intermediates.

Electrochemical evolution of size-controlled Pd nanocubes during long-term electrocatalytic hydrodechlorination reaction

Electrocatalytic hydrodechlorination (EHDC) emerges as a promising technology for remediating chlorinated organic pollutants, garnering considerable attention. However, the long-term performance evolution of EHDC, specifically its size-dependent aspect, remains relatively unexplored. This work aims to address this gap by examining Pd nanocubes with controlled sizes of 7.2 nm for Pd Cube-S, 10.6 nm for Pd Cube-M, and 14.7 nm for Pd Cube-L. The specific activity and electrochemical turnover frequency (TOF) of these Pd cubes increased with particle size, a pattern that is inverse to the trend of mass activity. Although Pd Cube-S initially demonstrated heightened EHDC efficiency, a long-term examination over multiple EHDC cycles revealed that Pd Cube-L exhibited escalating mass activity (from 2.10 to 3.11 min−1 g−1 after 5 cycles) and maintained stability over 180 h of continuous electrolysis. This phenomenon arose from structural reorganization of Pd cubes occurring during the EHDC cycles, leading to an expansion of the electrochemically specific surface area. Such structural reorganization brought about more enhancements in large-sized Pd cubes, whereas Pd Cube-S suffered more from particle agglomeration. Consequently, by fine-tuning the particle size, this work provided valuable insights into the long-term EHDC process, offering practical implications for enhancing the durability of Pd nanocatalysts.

Binary-Network structured PI@SiO2 nanofibrous composite aerogels with temperature invariant superelasticity for thermal insulation

The extreme temperatures encountered in aerospace pose formidable challenges to the performance of elastic materials in spacecraft and related apparatus. Traditional organic insulation materials face hindrance due to inadequate fire resistance, while inorganic insulation materials are often brittle. Herein, we designed binary-network composite aerogels with dual-crosslinked PI nanofibers as the scaffold and uniformly distributed silica nanoparticles within the anisotropic aerogel matrix. Owing to the dual-crosslinked PI nanofiber network, the resulting PI@SiO2 aerogel can withstand 1000 cycles of radial fatigue testing under 50 % compressive or buckling strains, maintaining structural stability across a wide angular frequency range of 0.1–100 rad/s. DMA testing shows that PI@SiO2 aerogel can endure 100,000 fatigue cycles from 25 to 300 °C, with storage modulus and loss modulus, and damping ratio, indicating robust long-term performance over a wide temperature spectrum. Even with liquid nitrogen (−196 °C) and butane torch flames (1100 °C), PI@SiO2 aerogel preserves its superelasticity through repeated compressions. Moreover, the composite aerogel exhibits excellent thermal insulation, with low thermal conductivity (27.2 mW m−1 K−1), and reachs the top flame-retardant level (UL94-V0). This work not only establishes a novel pathway for constructing polymer-based materials with temperature-invariant superelasticity but also holds great promise for extensive applications in ongoing and near-future aerospace exploration.

Minimum 15-Year Survival Of A Biconvex Inlay Patellar Component In Primary Total Knee Arthroplasty: An Analysis Of 2,530 TKA From A Single Institution

IntroductionRoutine patellar resurfacing during primary total knee arthroplasty (TKA) remains controversial. To our knowledge, there are no studies reporting the long-term performance of a cemented biconvex all-polyethylene inlay component implanted at the time of primary TKA. The purpose of this study was to examine the 15-year survivorship and long-term clinical outcomes of this biconvex inlay patella used at our institution. MethodsWe retrospectively reviewed our prospectively collected institutional database and identified 2,530 patients who underwent cemented TKA with a single prosthetic design (from 1996 to 2007) where the patella was resurfaced using this cemented biconvex inlay patellar. The mean age at surgery was 68 years (range, 29 to 93). The mean body mass index was 33.0 (range, 16.4 to 76.3), with 61.9% women. At the time of analysis, the mean time from surgery was 20.4 years (range, 15 to 26). We used Kaplan-Meier analysis to calculate survivorship at 15 years. We analyzed clinical outcomes using three patient-reported outcome measures collected prospectively. ResultsThe 15-year survivorship with revision surgery for all causes as the end point was 97.1 % (95% CI [confidence interval] 96.1 to 98.1%). The 15 year survivorship with revision surgery for a patella-related complication as the end point was 99.7% (95% CI 99.4 to 1.0). At a minimum of 13 years post-TKA, patients showed significant improvement in scores for the Knee Society Clinical Rating System (P < 0.001), Western Ontario and McMaster University Osteoarthritis Index (P < 0.001), and Veterans Rand 12 Item Health Survey physical component (P < 0.001). ConclusionRoutine patellar resurfacing using a biconvex inlay patellar component has excellent survivorship and a low rate of complications at 15 years post-TKA.

Synthesis, characterization and performance evaluation of different alkyl chain lengths flame-retardant plasticizers for poly(vinyl chloride) derived from sustainable vanillic acid

The current market for poly(vinyl chloride) (PVC) plasticizers is dominated by flammable petroleum-based compounds, accounting for over 80 % of the total share. Due to their high flammability, the search for novel approaches to enhance the fire resistance of flexible PVC has gained urgency. However, traditional flame-retardant schemes suffer from shortcomings such as poor compatibility, inferior long-term performance, and weak mechanical properties. Herein, we synthesized a novel biobased flame-retardant plasticizer (VAn-P) using vanillic acid as a skeleton. This plasticizer exhibits remarkable properties, including a substantially lower glass transition temperature compared to unplasticized PVC. The binding energy between VAn-P and PVC is calculated to be –33.30 kcal/mole, indicating a strong interaction. Furthermore, the maximum elongation at break of VAn-P plasticized PVC is 16 times higher than that of unmodified PVC. All PVC samples plasticized with VAn-P achieved a UL-94 VTM-0 rating. TGA-FTIR analysis revealed that the flame-retarding mechanism of VAn-P involves solid-phase action, significantly delaying the dehydrochlorination process of PVC. Moreover, VAn-P exhibits superior migration resistance compared to dioctyl phthalate (DOP). We also investigated the effects of alkyl chain lengths in VAn-P on various properties of PVC blends, including thermal stability, flame retardancy, mechanical properties, and optical performance. The toxicity of vanillic acid-based flame-retardant plasticizer has undergone an initial assessment. Overall, this green plasticizer is expected to endow polymers with high plasticizing performance and flame retardancy, providing a novel and sustainable approach for the synthesis of functional plasticizers.

Highly-durable plasma-sprayed Al2O3-YSZ/YSZ double ceramic layer TBCs against CMAS corrosion

The addition of Al2O3 inside thermal barrier coatings (TBCs) is highlighted effective on mitigating TBCs degradation induced by CMAS corrosion. In this study, the cost-effective 20wt.%Al2O3-7YSZ/7YSZ double ceramic layer (DCL) TBCs were fabricated and their long-term performance resisting CMAS corrosion was investigated. Significant bending and CMAS infiltration occurred readily for the single layer 7YSZ coatings just after 5h duration. The top sacrificial Al2O3-7YSZ layer of DCL coatings greatly constrained coating deflection and CMAS infiltration. This is due to the chemical reaction between alumina splats and CMAS, generating interconnected anorthites for effectively blocking CMAS infiltration and improving resistance to CMAS attack. However, it is highlighted that the role of alumina splats on mitigating CMAS degradation was found different between the short-term corrosion and long-term corrosion. In addition, interfacial delamination/cracking was not observed between the top Al2O3-7YSZ layer and bottom 7YSZ layer after 100h CMAS corrosion, demonstrating superior interface integrity and durability.

Does Regional Gambling Culture Affect Long-term Corporate Operational Risk? - Empirical Evidence from Lottery Sales

The findings of this paper indicate that regional gambling culture can increase the long-term performance volatility of enterprises. The results of heterogeneity tests show that the impact of regional gambling culture on the long-term performance volatility of enterprises is more pronounced in companies with higher information asymmetry and those in regions with lower levels of marketization. This discovery of variability offers targeted suggestions for enterprises to formulate cultural industry development strategies under different economic backgrounds and industry characteristics, providing practical guidance for policymakers and corporate managers.

Long-term properties evolution and life prediction of glass fiber reinforced thermoplastic bending bars exposed in concrete alkaline environment

Glass fiber reinforced polypropylene (GFRPP) bending bars have many advantages, such as high toughness, high durability, repeated molding and recycling, which can be used in concrete structures to replace steel stirrup for solving the problems of corrosion and service life. However, the changes in the properties of GFRPP bending bars during long-term use in alkaline concrete environments require further investigation. In the present study, GFRPP bending bars were immersed in alkaline solution at 20°C, 40°C, and 60°C for as long as 180 d. The water absorption, hydrolysis, mechanical properties, and microscopic properties of the bending bars were evaluated to understand the long-term performance and mechanism of degradation. The bending bars had a higher saturated water absorption percentage and time along with a lower diffusion rate than the straight bars due to the presence of pores and micro-cracks formed during the bending process. The dissolution of the glass fibers in alkaline solution led to the partial mass loss of the GFRPP bars. Compared to the control, the tensile strength retention of the bending bars was 20.6%–56.0%. The tensile failure mode changed from fiber bursting before immersion to shear fracture after immersion due to the decreased interfacial bonding strength and increased glass fiber brittleness. The primary degradation mechanisms were the etching of glass fibers, interface debonding, and increased void volume (∼23.7%). The bending bars were more seriously eroded than the straight bars due to the twisting of the fibers and imperfect interfaces. The predicted degradation times of the GFRPP bending bars ranged from 1.7 years (Haikou) to 3.9 years (Harbin), corresponding to a stable tensile strength retention of 22.13%. The results provide a basis for evaluating the durability and service life of GFRPP bending bars and promote the application of GFRPP composite stirrups in concrete structures.

Multi-scale analysis of satellite, reanalysis and muti-source precipitation estimates over the Tibetan Plateau

Due to the important hydrological and meteorological significance, the performance of different kinds of precipitation products for the Tibetan Plateau (TP) has been evaluated in previous studies. However, the performance of the products on a high spatial-temporal scale has not been clearly shown. Based on the Chinese Meteorological Administration (CMA) ground rain gauge observations during 2017–2018 over the TP, this paper analyzes the multi-scale performance of four satellite-based datasets (IMERG_Uncal, IMERG_Cal, GSMaP_MVK, and GSMaP_Gauge), two reanalysis datasets (ERA5 and ERA5-L), and one multi-source merged dataset (CMFD) for different precipitation intensities with a special attention to the characterization of spatiotemporal variability of heavy precipitation. Firstly, this study examines how the quality of precipitation products varies with time scale and precipitation intensity. CMFD generally shows the best quality and has the most stable quality at all temporal scales. Satellite products perform better in summer while reanalysis products show better results in cold seasons. Another significant issue is the impact of gauge-based calibration. GSMaP_Gauge with daily-scale gauge calibration is often considered to outperform other products. However, our study finds that GSMaP_Gauge is problematic at smaller spatiotemporal scales, especially in capturing heavy precipitation. The long-term performance of multi spatiotemporal scale comparison of different precipitation products is the focus of this study, which can help with their application and improvement.

Do CSR Firms Make Better Acquisitions? - The Case of Taiwan

This study examines the association between Corporate Social Responsibility (CSR) activities measured by two of Taiwan’s leading publishers, the Commonwealth Magazine and the Global View Magazine, and the acquirer’s short- and long-term performances after the merger announcement in Taiwan. We use CEO compensation and the firm’s free cash flow as the proxies for CEO self-confidence. We find that the acquirer’s CSR engagement is positively associated with its long-term performance but not with its short-term performance. CEO compensation is positively associated with the acquirer’s performance, especially after the mandatory establishment of the remuneration committee for publicly traded firms. However, the acquirer’s free cash flow is found negatively associated with its performance, supporting Jensen’s (Agency costs of free cash flow, corporate finance, and takeovers. American Economic Review, 76, 323–329) free cash flow hypothesis or CEO hubris. These findings indicate that the CSR measurements of Commonwealth Magazine and Global View Magazine do provide valuable information for CSR activities and that CSR activities do enhance firm value in the long run. Furthermore, the requirement for the establishment of the remuneration committee does improve the effectiveness of CEO compensation for firm performance in Taiwan.

Integrating Tensometer Measurements, Elastic Half-Space Modeling, and Long-Term Pavement Performance Data into a Mechanistic–Empirical Pavement Performance Model

Pavement performance models (PPMs) are utilized to predict pavement network conditions which is an essential part of any sustainable pavement management system (PMS). The reliability of a PMS and its outputs is proportional to the reliability of the PPM used. This article describes a mechanistic–empirical pavement performance model based on pavement response parameters—strains calculated in the pavement layers measured by tensometers embedded in the pavement surface and verified by calculations in the elastic half-space model and supplemented by empirical data from long-term pavement performance monitoring and accelerated pavement testing. Hence, the herein described PPM combines pavement serviceability evaluation, pavement bearing capacity, and the physico-mechanistic properties of paving materials. The analytical methods which were used to ascertain the physico-mechanistic characteristics, the material fatigue degradation model, and the surface degradation, unevenness in particular, are described. A comparison of the empirical PPM created in the last century used by the national road administrator to this day and the newly created PPM is presented. The comparison shows the difference in the calculated socio-economic benefits and subsequent cost–benefit analysis results. The comparison shows that the use of the old PPM may have produced false economic evaluation results that have led to poor decision making, partially explaining the unsustainable trend of road network management in our country.

Preventive Maintenance Decision-Making Optimization Method for Airport Runway Composite Pavements

Long-term preventive maintenance planning using finite annual budgets is vital for maintaining the service performance of airport runway composite pavements. Using the pavement condition index (PCI) to quantify composite pavement performance, this study investigated the PCI deterioration tendencies of middle runways, terminal runways, and taxiways and developed prediction models related to structural thickness and air traffic. Performance jump (PJ) and deterioration rate reduction (DRR) were used to measure maintenance benefits. Based on 112 composite pavement sections in the Long-term Pavement Performance Program, this study analyzed the influences of five typical preventive maintenance technologies on PJ, DRR, and PCI deterioration rates. The logarithmic regression relationship between PJ and PCI was obtained. For sections treated with crack sealing and crack filling, the DRR was nearly 0. For sections treated with fog seal, thin HMA overlay, and hot-mix recycled AC, the DRR was 0.2, 0.7, and 0.8, respectively. To solve the multi-objective maintenance problem, this study proposed a decision-making optimization method based on dynamic programming, and the solution algorithm was optimized, which was applied in a five-year maintenance plan. Considering different PCI deterioration tendencies of airport regions, as well as PJ, DRR, and costs of maintenance technologies, the preventive maintenance decision-making optimization method meets performance and financial requirements sufficiently.

Enhancing Thermal Insulation of Poly(β-Hydroxybutyrate) Composites with Charring-Foaming Agent-Coated Date Palm Wood

Date palm fiber (DPF) holds great potential for composite materials, but its flammability limits its practical applications. In this study, DPF was modified using a pad-drying method to impregnate it with a 5 wt.% solution of ammonium dihydrogen phosphate (ADP). These treated fibers were then utilized to fabricate poly(β-hydroxybutyrate)- (PHB-) based composites. The resulting thermal insulators were comprehensively evaluated for their flammability, physical, mechanical, and thermophysical properties, as well as morphological and thermal stability characteristics. The findings revealed a significant reduction in flame spread and smoke suppression; however, the concentration used is not sufficient to achieve the desired rating grades. The thermal insulation capacity of the modified fiber composites was substantially enhanced, particularly with the 40% PHB/DPF-ADP composite displaying the lowest thermal conductivity at 0.0564 W/m.K. Moreover, the presence of gaps and voids at the interface led to a reduction in tensile strength to 4-7 MPa. Additionally, the modified fiber composites exhibited significantly reduced water absorption (~0.76%), attributed to the formation of a highly water-resistant substance containing a furan compound. This work provides a simple and effective approach for achieving durable flame retardancy and long-term thermal insulation performance, offering promising opportunities for the practical application of biobased PHB composites.

Perceived Staff Motivation on the Adoption of Total Quality Management Practices in Nigeria

This study explores the relationship between employee motivation and the effective adoption of Total Quality Management (TQM) within modern organizational contexts in Nigeria. TQM, renowned for its all-encompassing strategy for continual enhancement, is widely recognized for its positive impact on product and service quality, employee involvement, and overall organizational effectiveness. Despite these well-documented benefits, the pivotal role of motivation in cultivating a TQM culture represents a critical yet insufficiently examined dimension. This study adopts a quantitative method using a closed-ended self-administered questionnaire to investigate the connections between motivation and TQM. The research focuses on assessing the levels of employee motivation within organizations practising TQM principles. It examines the resulting impact on various TQM dimensions, such as employee involvement and service quality. The findings revealed that staff motivation through intrinsic motivation and extrinsic motivation significantly affects the involvement of employees and the service quality of the selected deposit money banks in the Ilorin metropolis. The findings of this research highlight the importance of motivation in influencing TQM practices. Organizations should be mindful of the balance between intrinsic and extrinsic motivators to foster a work environment that promotes long-term commitment and performance. Practically, the results can guide organizations in developing and implementing strategies to motivate staff in a way that supports the successful implementation of TQM practices. The findings contributed significantly to the existing body of knowledge by elucidating the critical role motivation plays in shaping TQM practices.

Effects of thermoelasticity induced aperture variation on performances of Enhanced geothermal system

Geothermal energy, as one of the renewable energy types, has great potential to balance the variable energy supply from photovoltaic and wind energy types. This, however, requires the development of an Enhanced Geothermal System (EGS). Injecting cold water into deep geo-reservoirs induces thermoelastic deformation and changes the fracture apertures, which may significantly affect the EGS lifetime and energy performance. In this case, this study develops a fully coupled thermal–hydraulic-mechanical model to investigate the impacts of temperature, pressure, and aperture heterogeneity on the alterations of fracture aperture. Then, considering the reservoir lifespan, the research takes a further step into the influence of heterogeneous aperture variation on EGS production temperature and long-term energy performance. Results show that aperture significantly varies once a temperature breakthrough occurs in the production well for both homogeneous and heterogeneous aperture fields. The thermoelasticity-induced aperture variations enhance water flow rate, leading to a considerable increase in reservoir heat production rate, but a shorter EGS lifespan. Furthermore, temperature variation shows a more substantial influence on aperture alteration compared to pressure change. Additionally, a sensitivity analysis indicates that the 30-year total energy output is proportional to the injection/production pressures and injection temperatures. However, the fracture with either excessively large or small initial apertures leads to worse EGS energy performance.