Lithium Polymer Research Articles

Enhanced Electrochemical Performance of Hybrid Solid Polymer Electrolytes Encompassing Viologen for All-Solid-State Lithium Polymer Batteries

Enhanced Electrochemical Performance of Hybrid Solid Polymer Electrolytes Encompassing Viologen for All-Solid-State Lithium Polymer Batteries

Design and implementation of sustainable solar energy harvesting for low-cost remote sensors equipped with real-time monitoring systems

Data acquisition systems, such as Wireless Smart Sensor Networks (WSSNs) can increase the resilience of infrastructure by providing real-time monitoring and data collection of environmental parameters. Yet, sustainable energy supplies for sensor networks established in remote and inaccessible areas still present a challenge. Previously, researchers have attempted to address this difficulty by proposing different energy systems including solar energy harvesting, however, significant prolonged experimental data for the operation of extensive networks powered by solar energy has not been reported. This paper presents an original design and implementation of an energy system for a large WSSN and provides the sensors' power status data over a significant duration. A network of low-cost flood monitoring sensors, including twenty-six water level sensors, twenty rain gauges, and eight communication nodes were deployed and tested on summer and fall 2022 at six remote locations at the northern New Mexico Pueblo, Ohkay Owingeh. A thermometer and a humidity sensor were added to each communication node to record temperature and air's moisture level. In addition, a networked voltage monitoring system was deployed to observe the sensors energy status in real-time. The items of the WSSN are composed of two differing energy circuits suited for their energy demands. The sensors' energy circuits contain a photovoltaic panel, a lithium-polymer battery, a control device, and a DC-to-DC converter. Whereas the communication nodes contain another photovoltaic panel, a lead-acid battery, and a solar charging controller. The findings provide a perspective on the long-term field deployment of WSSNs consisting of low-cost sensors.

Performance comparison of lithium polymer battery SOC estimation using GWO-BiLSTM and cutting-edge deep learning methods

Performance comparison of lithium polymer battery SOC estimation using GWO-BiLSTM and cutting-edge deep learning methods

Thermal explosion energy evaluation on LCO and NCM Li-ion polymer batteries using thermal analysis methodology

An advanced lithium-ion polymer battery (LIPB) has higher energy density, long-life cycle, and flexible configuration that can be arbitrarily shaped. It is the mainstream candidate for electronics products as energy storage device. However, an energetic LIPB will generate an abnormal electrochemistry reaction and will even cause spontaneous ignition to the battery pack in case cells fail, such as a short circuit or thermal runaway. Two commercial 603450 LIPBs, whose cathodes include lithium cobalt oxide (LiCoO₂, LCO) and lithium nickel cobalt manganese oxide (LiNixCoyMnzO2, NCM), were examined for their thermophysical data. Enhanced calorimetry methods are modified to analyse an LIPB’s heat capacity and enthalpy. In case thermal runaway the heat capacity and enthalpy are 0.99 kJ g–1 K–1 and 11.76 kJ for an LCO cell and 0.96 kJ g–1 K–1 and 10.68 kJ for an NCM cell, respectively. Furthermore, TNT equivalency mass is 7.62 g for an LCO and 7.01 g for an NCM cell. An LIPB is examined to identify the fire-explosion behaviour and thermokinetic data for enhancing battery thermal management.

Design and Development of Solar Drone

Abstract: The harnessing of solar energy during operations of unmanned aerial vehicle(UAV) provides potential solution to combat energy constraints. This Thesis examines the practicality of mini solar drone and provide experimental validation in regards to energy maximization through solar energy management and flight time optimization.The simulations results are consistent with real time measurements during flight test. This project deals with a quadcopter using solar energy as well as lithium polymer battery as power source combination to give maximum flight output. Using solar panels, it collects the energy during day time for immediate use and also store the remaining part for night as well. The objective is to identify , design and analyze such a reusable solar powered quadcopter for high altitude endurance and longer battery life.

Womens Safety Jacket by using Raspberry Pi-3 Module

Abstract: Now-a-days, the situation is become worst for women relating her safety. The government has provided security through rules and regulations to the society but the existing system needs advanced smart security for women safety. The purpose of our project is to design an easy and portable device for girl’s safety. Our project focuses on “women safety”. In our project we prepared safety jacket in which we provided different features like: Buzzer system. Video capturing of attacker. Location tracking by GPS. Msg sending to predefined numbers like: family, friend through Gmail. Video sending to selected family, friend numbers& police station. Msg sending to predefined numbers like: family, friend through Gmail. We used components such as Push Buttons, module raspberry pi 3, GPS NEO6MV2, GSM SIM900D, buzzer, and Lipo batteries etc.

Physico-Chemical Properties of Laponite®/Polyethylene-oxide Based Composites.

This review aims to provide a literature overview as well as the authors' personal account to the studies of Laponite® (Lap)/Polyethylene-oxide (PEO) based composite materials and their applications. These composites can be prepared over a wide range of their mutual concentrations, they are highly water soluble, and have many useful physico-chemical properties. To the readers' convenience, the contents are subdivided into different sections, related with consideration of PEO properties and its solubility in water, behavior of Lap systems(structure of Lap-platelets, properties of aqueous dispersions of Lap and aging effects in them), analyzing ofproperties LAP/PEO systems, Lap platelets-PEO interactions, adsorption mechanisms, aging effects, aggregation and electrokinetic properties. The different applications of Lap/PEO composites are reviewed. These applications include Lap/PEO based electrolytes for lithium polymer batteries, electrospun nanofibers, environmental, biomedical and biotechnology engineering. Both Lap and PEO are highly biocompatible with living systems and they are non-toxic, non-yellowing, and non-inflammable. Medical applications of Lap/PEO composites in bio-sensing, tissue engineering, drug delivery, cell proliferation, and wound dressings are also discussed.

Battery selection criteria for electric vehicles: techno-economic analysis

In this study, different battery types to be used in the conversion of a small and light (600-1000 kg) internal combustion engine vehicle into an electric vehicle were analyzed. The study was conducted to ensure that this vehicle is suitable for urban use and has a range of approximately 100 km. Each battery technology capacity is evaluated to be approximately 15 kWh. While performing the techno-economic analysis of different battery types, it was taken into account that they provide the necessary energy for about 10 years. Seven different battery technologies (lead-acid, gel, Ni-Cd, Li-Ion, LiFePo4, LiPo, Ni-MH) were used for comparison. In the analysis; price assessment in US Dollars ($), 10-year investment cost, weight and volume values, weight and volume values required to produce 1 kWh of energy were presented in tables. In addition to these, a review of battery life was made. Finally, the advantages and disadvantages of battery technologies compared to each other are given. As a result of the study, it was seen that the cheapest technology for a 10-year lifespan was lead-acid technology. It has been determined that lead-acid technology is 30% cheaper than the second cheapest gel technology and 82% cheaper than the most expensive technology, LiPo technology. In the study, it was revealed that the lightest technology was LiPo. It has been determined that this technology is 85% lighter than gel technology. Besides this information, data on cycle life, self-discharge, advantages and disadvantages are presented in tabular form.

Toward Practical Solid‐State Polymer Lithium Batteries by In Situ Polymerization Process: A Review

AbstractAlthough there are various strategies for solid‐state polymer lithium batteries (SSPLBs) manufacturing, the most promising is the in situ polymerization process. The in situ polymerization process inherits good liquid electrolyte/electrode interfacial contact and is compatible with existing lithium‐ion batteries manufacturing processes, making it easy to achieve scale‐up production. However, most of the current studies on the in situ polymerization process are based on lab‐level coin cells, while practical pouch cells are much less studied. There is a huge difference between lab‐level coin SSPLBs and practical pouch SSPLBs. Here, as a complement to the existing reports and reviews, a systematic review of the challenges and design principles of in situ polymerization process for fabricating practical pouch SSPLBs is provided to enable a comprehensive understanding and strategic guidance for practical SSPLBs applications. This review thoroughly discusses recent advances regarding the fabrication of SSPLBs using in situ polymerization process and presents the existing challenges and future outlook for the fabrication of practical SSPLBs by in situ polymerization processes. Furthermore, the critical issues of electrode materials for manufacturing practical SSPLBs are highlighted during the in situ polymerization process, and an attempt is made to call more attention to the performance of the practical pouch SSPLBs.

Room Temperature Resistive Hydrogen Sensor for Early Safety Warning of Li-Ion Batteries

Lithium-ion batteries (LIBs) have become one of the most competitive energy storage technologies. However, the “thermal runaway” of LIBs leads to serious safety issues. Early safety warning of LIBs is a prerequisite for the widely applications of power battery and large-scale energy storage systems. As reported, hydrogen (H2) could be generated due to the reaction of lithium metal and polymers inside the battery. The generation of H2 is some time earlier than the “thermal runaway”. Therefore, the rapid detection of trace hydrogen is the most effective method for early safety warning of LIBs. Resistive hydrogen sensors have attracted attention in recent years. In addition, they could be placed inside the LIB package for the initial hydrogen detection. Here, we overview the recent key advances of resistive room temperature (RT) H2 sensors, and explore possible applications inside LIB. We explored the underlying sensing mechanisms for each type of H2 sensor. Additionally, we highlight the approaches to develop the H2 sensors in large scale. Finally, the present review presents a brief conclusion and perspectives about the resistive RT H2 sensors for early safety warning of LIBs.

Preparation and properties of quinoxaline and pyrazine D (donor)–A (acceptor) conductive polymer lithium-ion battery anode materials

Preparation and properties of quinoxaline and pyrazine D (donor)–A (acceptor) conductive polymer lithium-ion battery anode materials

Takeoff of a 2.1 g Fully Untethered Tailless Flapping-Wing Micro Aerial Vehicle With Integrated Battery

Insect-scale micro-aerial vehicles (MAV) are becoming increasingly important for sensing and mapping spatially constrained environments. However, achieving untethered flight powered by a small and lightweight on-board energy source remains a challenge. In this study, we successfully demonstrated the untethered takeoff of a flapping-wing MAV powered by a commercially available LiPo battery for a short duration without stability control. By incorporating a high-efficiency direct-drive piezoelectric actuator, and an optimized control circuit for high-impedance-width modulation and charge recovery, this electronics configuration realizes over 5 min of practical operation with a thrust of 1.5 times its own weight, while offering wireless communication capability and sensors for attitude estimation. Our MAV has a total mass of 2.1 g, which is an eight-fold reduction compared to the lightest battery-powered tailless flapping-wing MAV currently available, making this the first report of a battery-powered tailless flapping-wing MAV with insect-scale weight.

A Systematic Study Aiming Toward Voltage Noise Elimination in Viscoelastic Poly(methyl methacrylate)–Poly(ethylene oxide) Polymer Blend Electrolytes in Li Metal Battery Cells

AbstractRandom appearance of micro short circuits and voltage noise is observed, until now, on initial cycles of solid polymer electrolyte high voltage cathode cells with lithium metal anodes. However, this phenomenon also takes place in lower operation voltages such as those in LiFePO4 cathode cells. Approaching the direct/indirect effect of the cathode, the polymer electrolyte, and the anode parts on this initial dendritic bridging between the electrodes separately, a systematic study is carried out toward determining potential causes of voltage noise and ways of prevention. Electrolytes based on the blend of PMMA–PEO show that relying only on the viscoelastic nature cannot prevent the appearance of voltage noise. Liquid polymers are used for the wetting of the cathode active material that lead to a complete pore infiltration. Having ensured the optimization of the interfacial area between the solid electrolyte and the cathode, studies along the directions of the lithium surface pretreatment and polymer ionic conductivity are examined as a means of dendrite growth suppression and cell cycling capabilities improvement, leading to the observation that methylated PEO chains work in favor of both of these directions.

Electric Rocket Launcher Aircraft—Drone-Launched Short Range Rocket System

This paper is concerned with the idea of a significant improvement of state-of-the-art short-range rockets by means of using rocket artillery systems. Such a system consists of a rocket launcher aircraft (RLA) and a drone-launched short range rocket (DLSRR). An RLA is a reusable first stage of a military rocket. A DLSRR is the expendable second stage, which flies to the target. RLA-DLSRR systems have not yet been built, but they have been described in previous works by the author. State-of-the-art rocket systems are completely expendable and, hence, extremely expensive. No rocket artillery system with a reusable first stage has been built so far. Civilian spaceships with reusable first stages have been successful since 2015. In an electrically pumped rocket engine, the fuel and oxidizer are pumped into a combustion chamber by an electric-motor-driven pump. The electric motor is powered by a battery bank. Electrically pumped rocket engines would further decrease the cost of RLA-DLSRR systems. These engines are less expensive and more reliable then conventional rocket engines. In the present paper, it is shown that commercially available lithium polymer battery banks, as well as high specific power electric motors, provide sufficient power for the rocket engines needed for RLA-DLSRR systems. In the example given, it is calculated that an ERLA–DLSRR system with a liftoff mass of 15 tons can deliver a 210 kg payload to a range of up to 567 km with an impact velocity of up to 2415 m/s.

In-Situ-Polymerized 1,3-Dioxolane Solid-State Electrolyte with Space-Confined Plasticizers for High-Voltage and Robust Li/LiCoO2 Batteries.

In-situ-polymerized solid-state electrolytes can significantly improve the interfacial compatibility of Li metal batteries. Typically, in-situ-polymerized 1,3-dioxolane electrolyte (PDOL) exhibits good compatibility with Li metal. However, it still suffers from the narrow electrochemical window (4.1 V), limiting the application of high-voltage cathodes. Herein, a novel modified PDOL (PDOL-F/S) electrolyte with an expanded electrochemical window of 4.43 V and a considerable ionic conductivity of 1.95 × 10-4 S cm-1 is developed by introducing high-voltage stable plasticizers (fluoroethylene carbonate and succinonitrile) to its polymer network. The space-confined plasticizers are beneficial to construct a high-quality cathode-electrolyte interphase, hindering the decomposition of lithium salts and polymers in electrolytes at high voltage. The as-assembled Li|PDOL-F/S|LiCoO2 battery delivers superior cycling stability (capacity retention of 80% after 400 cycles) at 4.3 V, superior to that of pristine PDOL (3% after 120 cycles). This work provides new insights into the design and application of high-voltage solid-state lithium metal batteries by in situ polymerization.

On the Usage of Battery Equivalent Series Resistance for Shuntless Coulomb Counting and SOC Estimation

In this paper, a feasibility study of a shuntless coulomb counting method for estimating the state of charge (SOC) of a battery is presented. Contrary to conventional coulomb counting, the proposed method does not require an external resistive shunt; it instead only requires voltage measurements performed on the battery under test while it is operating. The current is measured indirectly using the battery’s equivalent series resistance (ESR). The method consists of a preliminary calibration phase where the ESR and the open-circuit voltage of the battery are measured for different SOCs and stored in look-up tables (LUTs). Then, in the subsequent operational phase, the method uses these LUTs together with the measured voltage at the battery terminals to estimate the SOC. The performance of the proposed method is evaluated on a sample lithium polymer (LiPo) battery, using a realistic current profile derived from the Worldwide Harmonized Light-Duty Vehicles Test Procedure (WLTP). The results of this experimental evaluation demonstrate a SOC estimation root-mean-square error of 0.82% and a maximum SOC error of 1.45%. These results prove that the proposed method is feasible in a practical scenario.

Investigation on fin cooling for lithium-polymer batteries

PurposeLithium-polymer batteries have common usage in aviation industry especially unmanned aerial vehicles (UAV). Overheating is a serious problem in lithium-polymer batteries. Various cooling methods are performed to keep lithium-polymer batteries in the desired temperature range. The purpose of this paper is to examine pouch type lithium-polymer battery with plate fins by using particle image velocimetry (PIV) and computational fluid dynamics (CFD) for UAV.Design/methodology/approachBattery models were produced with a 3D printer. The upper surfaces of fabricated battery models were covered with plate fins with different fin heights and fin thicknesses. Velocities were obtained with PIV and CFD. Temperature dissipations were acquired with numerical simulations.FindingsAt the end of the study, the second battery model gave the lowest temperature values among the battery models. Temperature values of the seventh battery model were the highest temperatures. Fin cooling reduced the maximum cell temperatures noticeably. Numerical simulations agreed with PIV measurements well.Practical implicationsThis paper takes into account two essential tools such as PIV and CFD, for fluid mechanics, which are significant in the aviation industry and engineering life.Originality/valueThe originality of this paper depends on investigation of both PIV and CFD for UAV and developing a cooling method that can be feasible for landing and take-off phases for UAV.

FABRICATION OF QUADCOPTER FOR AGRICULTURAL SPRAYING

Unmanned aerial vehicles (UAVs) are being used more frequently for agricultural spraying as a result of their effectiveness and precision. This project involved building a quadcopter without sensors, cameras, or GPS for agricultural spraying. The quadcopter was created to rapidly and effectively cover a sizable amount of agricultural land, while also minimizing the usage of pesticides and the impact on the environment. The quadcopter's frame, which was made of lightweight materials to give strength and durability while minimizing the aircraft's overall weight, was used in its construction. The quadcopter's frame was made to accommodate four brushless motors, each of which had a propeller to give lift and movement. Four electronic speed controllers (ESCs) were used to control the motors' rotational speed and direction. The high-capacity lithium-polymer (LiPo) battery used by the quadcopter has sufficient power to run the motors and spraying system continuously. A tank, a pump that pressurized the liquid, and a nozzle that released the pressurized liquid over the crops as a fine mist made up the spraying system. A KK 2.1.5 circuit board served as the foundation for the flight control system, which was wired to the battery, four ESCs, and other components. The quadcopter's circuit board was configured to retain its position and altitude while flying steadily. Additionally, it provided buttons and an LCD panel for the user to use to change flying characteristics including the throttle, pitch, and roll. A handheld radio transmitter that interacted with a quadcopter receiver was used to control the aircraft.

An Unmanned Surface Vehicle (USV): Development of an Autonomous Boat with a Sensor Integration System for Bathymetric Surveys.

A reliable yet economical unmanned surface vehicle (USV) has been developed for the bathymetric surveying of lakes. The system combines an autonomous navigation framework, environmental sensors, and a multibeam echosounder to collect submerged topography, temperature, and wind speed and monitor the vehicle's status during prescribed path-planning missions. The main objective of this research is to provide a methodological framework to build an autonomous boat with independent decision-making, efficient control, and long-range navigation capabilities. Integration of sensors with navigation control enabled the automatization of position, orientation, and velocity. A solar power integration was also tested to control the duration of the autonomous missions. The results of the solar power compared favorably with those of the standard LiPO battery system. Extended and autonomous missions were achieved with the developed platform, which can also evaluate the danger level, weather circumstances, and energy consumption through real-time data analysis. With all the incorporated sensors and controls, this USV can make self-governing decisions and improve its safety. A technical evaluation of the proposed vehicle was conducted as a measurable metric of the reliability and robustness of the prototype. Overall, a reliable, economic, and self-powered autonomous system has been designed and built to retrieve bathymetric surveys as a first step to developing intelligent reconnaissance systems that combine field robotics with machine learning to make decisions and adapt to unknown environments.

The Design and Fabrication of Multiple-Transmitter Coils and Single-Receiver Coils for a Wireless Power Transfer System to Charge a 3s LiPo Drone’s Battery

Recent research has shown an increasing interest in wireless power transfer (WPT) technology for drone batteries. The inconvenience of wired charging, especially for drones, is a huge obstacle. In this research project, a WPT platform was proposed by applying four transmitting coils and a single receiving coil. To meet the industrial standards required for transmitter Tx and receiver Rx, a calculation of the parameters was implemented. An H-bridge MOSFET was used as a DC–AC inverter, a bridge diode was used as an AC–DC rectifier, and a Pi low pass filter was added to the receiver circuit design to filter the high-frequency noise. Experimental investigations were conducted to study the maximum power and power efficiency of the coil’s alignment. The focus of this article was to design and fabricate workable multiple-transmitter coils and a single-receiver coil for a wireless power transfer system, in order to charge a 3S LiPo drone’s battery. It not only covers an overview of wireless power transfer but also includes the method for charging a 3S LiPo drone’s battery, a misalignment study on the X and Y axes of the wireless charging system, and a stable charging of the battery that does not exceed the maximum current of 1.26 A for healthy charging. An efficiency of 58.29% was achieved at a power of 14.924 W and the minimum value was found to be 0.008 W. The efficiency of the typical coil design and the proposed coil design were 55.04% and 12.06%, respectively. The charging current obtained was 1.27 A, which gives an estimated charging time of 3.31 h based on the calculation. The actual charging time of the 3s 4200 mAh 11.1 V LiPo battery was 2 h.