This study examines the behavior of ethanol or water films on the surface of a NACA 0012 airfoil placed in a high-speed air flow. New water film results complement previous measurements of time averaged ligament lengths and droplet sizes generated with the same airfoil. In addition, new data are obtained for ethanol. Air velocities up to 175 m/s are used with liquid flow rates between 1.4 cm2/s and 2.6 cm2/s. The liquid was introduced onto one side of the airfoil via 26 holes, each measuring 0.5 mm in diameter and spaced 1 mm apart. These holes are positioned 35 mm downstream from the leading edge and 65 mm upstream from the trailing edge. Film behavior on the vane is captured with front-lit high-speed video. The accumulation of liquid and breakup of ligaments are captured with backlit highspeed video. Phase Doppler interferometry is used to measure droplet size and simultaneous axial and pitch wise velocity 70 mm downstream of the trailing edge. Finally, laser diffraction is used to measure line averaged droplet sizes. The results indicate notable differences between ethanol and water films. The ethanol film spreads more extensively across the width of airfoil which is attributed due to its lower surface tension. The maximum ligament length for both liquids decrease with higher air velocity and increase with the liquid flow rate. A correlation for maximum ligament length is developed and captures the effect of liquid properties, flow rate, and air velocity. Furthermore, the variation in liquid volume flow rate did not impact droplet size. However, for a given air velocity, the Sauter Mean Diameter is found to depend on surface tension. On the dependency of droplet size on the Weber number, ethanol produced smaller droplet sizes at low values of Weber number. However, at relatively high Weber numbers, the droplet sizes for both water and ethanol were similar. This suggests that droplet size is influenced by factors besides surface tension at low Weber numbers but not at higher Weber numbers. In addition, the Nukiyama-Tanasawa model to fit the volume distribution curves is simplified by fixing p and q terms. Simplification makes the model easier to understand and implement.