Liquid Crystal Layer Research Articles

Electrically Tunable Defect-Mode Wavelengths in a Liquid-Crystal-in-Cavity Hybrid Structure in the Near-Infrared Range.

This work proposes a novel approach to developing a core component for a near-infrared (NIR) spectrometer with wavelength tunability, which is based on a liquid crystal (LC)-in-cavity structure as a hybrid photonic crystal (PC). By electrically altering the tilt angle of the LC molecules under applied voltage, the proposed PC/LC photonic structure consisting of an LC layer sandwiched between two multilayer films generates transmitted photons at specific wavelengths as defect modes within the photonic bandgap (PBG). The relationship between the number of defect-mode peaks and the cell thickness is investigated using a simulated approach based on the 4 × 4 Berreman numerical method. Furthermore, the defect-mode wavelength shifts driven by various applied voltages are studied experimentally. To minimize the power consumption of the optical module for spectrometric application, cells of different thicknesses are explored for the wavelength-tunability performance of the defect modes scanning through the entire free spectral ranges to the wavelengths of their next higher orders at null voltage. A 7.9 μm thick PC/LC cell is verified to attain the low operating voltage of merely 2.5 Vrms required to successfully cover the entire NIR spectral range between 1250 and 1650 nm. The proposed PBG structure is thus an excellent candidate for application in monochromator or spectrometer development.

응답시간이 개선된 액정 기반 능동 반사 배열 안테나 단위 셀 구조

This paper presents a unit cell structure for liquid crystal (LC)-based reconfigurable reflective arrays, aimed at improving the imbalance in response time. Conventional LC-based reflectarray antenna unit cells, which have been widely used as high-gain beam-steerable antennas, have an imbalance in response time because of different alignment of LC molecules during the rise and decay times. By separating the metal layers in contact with the LC layer and applying four bias voltages, we generated both horizontal and vertical electric field. Accordingly, the decay time was improved by unifying the methods in which the LC molecules were aligned during the rise and decay times. Our measurements confirm that the decay time can be reduced to approximately 1/3 compared to the conventional structure, indicating the possibility of resolving the imbalance.

47.1: Green Technology of Photoalignment Layer Coating from H2O solution for Achromatic Polymerizable Liquid Crystal Retarder

Combination of several films from polymerizable liquid crystal (PLC) into single device system with complex properties faces a fabrication issue due to chemical compatibility and mutual alignment effect of the neighbouring layers. Eco-friendly green technology of high anchoring azo-dye photoalignment layer coating from water solvent provides efficient solution to hinder interlayer interaction of bottom PLC layer avoiding its chemical damage and providing unique photoalignment pattern for top PLC retarder. The advanced possibilities of green technology of photoalignment layers coated from H2O solution are demonstrated through fabrication of achromatic quarter-wave retarder system comprising formation of polimerizable liquid crystal layers on top of one another with arbitrary azimuthal photoalignment direction. The merge of photoaligned PLC retarders into single multi-layer anisotropic structure opens new approach to fabrication of thin-film phase devices with complex optical properties.

Helfrich-Hurault elastic instabilities driven by geometrical frustration

The Helfrich-Hurault instability is a well-known mechanism behind the undulations that occur as a result of strain upon liquid crystal systems with periodic ground states. In this review, the Helfrich-Hurault elastic instability is examined with a focus on layered liquid crystals that are geometrically frustrated. The frustration is relieved by undulations in the layered structure to maintain the preferred layer spacing. Examples of cholesteric and smectic liquid crystals confined between two spherical fluid interfaces are described and the effects of topological constraints, anchoring conditions, and curvature on the instability are examined. Lastly, the Helfrich-Hurault instability is surveyed as a pattern formation mechanism across a range of materials, both biological and synthetic.

Nanoporous multilayer graphene oxide membrane for forward osmosis metal ion recovery from spent Li-ion batteries

The recovery of Li and rare metals from the spent electrodes of Li-ion batteries (LIBs) is becoming increasingly important. Herein, nanoporous multilayer graphene oxide (NMG) membranes were fabricated via the confined thermal annealing method to achieve Li-ion selectivity. A graphene oxide (GO) membrane was prepared by coating the membrane with an aqueous layer of GO liquid crystal via the scalable bar coating method, followed by hot-pressing. The influence of the GO interlayer spacing and nanopore presence on the ion separation performance was investigated. The NMG membrane shows different ion permeance phenomena depending on ion concentration. The permeation rate of divalent ions (Co, Ni, Mn) through the NMG membrane was faster than that of Li ions in solution with low ionic strength, whereas the membrane was Li-ion selective in mixed ionic solutions or at high ionic strength. This result indicates that electrostatic interaction by oxygen groups is important at low ionic strength, but size exclusion by interlayer spacing and adsorption by nanopore is critical at high ionic strength. The ion permeation mechanisms were further examined based on molecular calculations, which revealed that the binding energies between the divalent ions and nanopores or basal plane of graphene were high, resulting in slow ion permeation. When the NMG membrane was combined in a forward osmosis system, Li-ion can be separated continuously from the mixture solution simulated from the spent Li-battery electrode. This approach shows the high potential of nanoporous multilayer graphene membrane for Li extraction in particular with dense pore structure and around 7 Å of d-spacing.

Optical efficiency modulation of vertical alignment liquid crystal displays with transparent shielding and storage electrode

A high-transmittance vertical alignment liquid crystal display (VA-LCD) using a transparent shielding and storage electrode (TSS) design is proposed. The aperture ratio of the proposed four domain TSS pixel with size of 52 × 156 μm improves approximately by 40% over the conventional pixel due to the shielding and storage metal electrode can be replaced by TSS electrode. Experimental results shown that the transmittance of TSS designed panel with 3.2 μm cell gap is 35% higher than that with conventional pixel design, whereas it is only enhanced by 21% when the cell gap is 2.6 μm. The liquid crystal dynamics simulation results revealed that both the effective birefringence and the azimuthally controlled director profile of the liquid crystal layer decreases with TSS pixel design, and these adverse impacts are magnified as the cell gap decreases. This is due to that the introduction of TSS common electrode not only weakens the vertical electric field but also affects the horizontal electric field of liquid crystal layer, which leads to a greater loss of optical efficiency under lower cell gap, resulting in the worse transmittance promotion. The proposed method is expected to be advantageously employed in enhancing transmittance of VA-LCDs for power saving.

Manipulation of sub-terahertz waves using digital coding metasurfaces based on liquid crystals.

This paper presents a novel sub-terahertz liquid crystal (LC) phase shifter based on digital coding metasurfaces. The proposed structure consists of metal gratings and resonant structures. They are both immersed in LC. The metal gratings function as reflective surfaces for electromagnetic waves and electrodes for controlling the LC layer. The proposed structure changes the state of the phase shifter by switching the voltage on every grating. It allows the deflection of LC molecules within a subregion of the metasurface structure. Four switchable coding states of the phase shifter are obtained experimentally. The phase of the reflected wave varies by 0°, 102°, 166°, and 233° at 120 GHz. Due to the presence of the transverse control electric field, modulation speed is approximately doubled compared to the free relaxation state. This work provides a novel idea for wavefront modulation of phase.

Electronic Beam Steering Metamaterial Antenna with Dual-Tuned Mode of Liquid Crystal Material

In this study, a dual-tuned mode of liquid crystal (LC) material was proposed and adopted on reconfigurable metamaterial antennas to expand the fixed-frequency beam-steering range. The novel dual-tuned mode of the LC is composed of double LC layers combined with composite right/left-handed (CRLH) transmission line theory. Through a multi-separated metal layer, the double LC layers can be loaded with controllable bias voltage independently. Therefore, the LC material exhibits four extreme states, among which the permittivity of LC can be varied linearly. On the strength of the dual-tuned mode of LC, a CRLH unit cell is elaborately designed on three-layer substrates with balanced dispersion values under arbitrary LC state. Then five CRLH unit cells are cascaded to form an electronically controlled beam-steering CRLH metamaterial antenna on a downlink Ku satellite communication band with dual-tuned characteristics. The simulated results demonstrate that the metamaterial antenna features' continuous electronic beam-steering capacity from broadside to -35° at 14.4 GHz. Furthermore, the beam-steering properties are implemented in a broad frequency band from 13.8 GHz to 17 GHz, with good impedance matching. The proposed dual-tuned mode can make the regulation of LC material more flexible and enlarge the beam-steering range simultaneously.

Fast tunable metamaterial liquid crystal achromatic waveplate

Abstract Photonic metamaterials combined with liquid crystals (LCs) for tunability is a great niche for building miniature devices with high performance such as fast flat tunable lenses, tunable filters, and waveplates. Sub-wavelength or nano-grating surfaces are homogenized to uniaxial waveplates with negative birefringence of unique dispersion when the period is less than the wavelength by at least a few times. This uniaxial metasurface, combined with the LC layer, is shown to act as a tunable retardation achromatic waveplate with 8 μm thick LC layer operating over wide spectral and angular ranges, as compared to using two nematic liquid crystal (NLC) retarders of thicknesses on the order of 30–60 μm, when no metasurface is used. Hence the device becomes miniature and 50× faster due to the thinner liquid crystal layer. The silicon nano-grating of 351 nm pitch and 0.282 fill factor is designed and fabricated to operate in the short-wave infrared range (SWIR). Switching between three achromatic retardation levels: full-, half-, and quarter-waveplates is accomplished by changing the applied voltages on the NLC cell with a switching time of a few milliseconds. This device has applications in fast broadband shutters, low coherence phase shift interferometry, ellipso-polarimetry, dynamic control of light intensity, and smart windows.

Optical Properties of One‐Dimensional Photonic Crystal Composed of Superconductor and Dielectric Layers with Liquid Crystal Layer as Defect

In this article, the optical properties of 1DPC composed of superconductor and dielectric layer with an introduced defect layer of liquid crystal are discussed. To design the 1DPS, the study considers Bi-2223 of Bismuth Strontium Calcium Copper Oxide (BSSCO) and silica (SiO2) materials as superconductor and dielectric layers, and E7 liquid crystal (LC) as a defect layer. For the theoretical study of the considered periodic structure, transfer matrix method (TMM) is employed, which gives the transmittance and reflectance for the structure. The periodic structure shows tunable transmission and reflectance properties under variations of the temperatures of superconductor and LC and incident angle. The variations of temperatures of superconductor and LC show red and blue shifts in the defect mode peak, respectively. Also, the tuning of the photonic bandgap (PBG) with incident angle, in the three-dimensional (3D) reflectance, for both transverse electric (TE) and transverse magnetic (TM) modes, is discussed in the article. The PBG in TM polarization disappears at the incident angle nearly 50°, and reappears with further increase in the incident angle above 60°. Further, the defect mode always exhibits blue shift with increase in the incident angle in TE and TM mode both. This simulation work can be beneficial in analysis of dispersive media and tunable optical devices.

Temperature-switched orientation properties through physicochemically constructed aluminum zirconium oxide films

In general, it has one of the characteristics of homeotropic alignment and homogeneous alignment depending on the material and manufacturing process of the liquid crystal alignment layer. However, in this study, we propose a new type of alignment film that has the characteristics of changing the liquid crystal alignment direction according to the curing temperature. The AlZrO alignment film produced by the solution process and brush coating method showed homeotropic alignment characteristics when cured at low temperatures and homogeneous alignment characteristics when cured at high temperatures. These switching characteristics according to the curing temperature showed stable LC alignment, respectively, and the threshold voltages were 0.81 V and 0.857 V in vertical alignment (VA) mode and twisted nematic (TN) mode, respectively, demonstrating excellent electro-optical properties. The mechanism of these switching characteristics was analyzed through surface modification analysis. This study introduces new insights into liquid crystal alignment films that satisfy all of the high-efficiency fabrication process, various application possibilities due to their switching properties, and excellent electro-optical properties.

Suppression Effect of Randomly-Disturbed LC Alignment Fluctuation on Speckle Noise for Electronic Holography Imaging

In this paper, we proposed the phase disturbing device using randomly-fluctuated liquid crystal (LC) alignment to reduce the speckle noise generated in holographic displays. Some parameters corresponding to the alignment fluctuation of thick LC layer were quantitatively evaluated, and we clarified the effect of the LC alignment fluctuation with the parameters on speckle noise reduction.

Rethinking Liquid Crystal Tunable Phase Shifter Design with Inverted Microstrip Lines at 1–67 GHz by Dissipative Loss Analysis

Growing 5G/6G phased-array beam-steering applications, for which liquid crystal (LC) is one of the enabling technology candidates, have sparked interest in the modulation of the phase (and amplitude) of microwave and millimeter-wave signals. In this communication, fresh insights into the systematic design analysis of a 1–67 GHz passive inverted microstrip line (IMSL) phase shifter filled with highly anisotropic LC as tunable dielectric media are obtained. Based on waveguide disturbance tests to characterize the dielectric properties of the non-tunable PCB and tunable LC used in the IMSL phase shift device filled with a GT3-24002 LC layer (125 µm thick) partially enclosing a 220 µm wide, 17 µm thick, 1.35 cm long copper core line, a 0–π differential phase shift in the 1–67 GHz range with less than 2 dB insertion loss is reported. Dissipative loss analysis shows that the dielectric absorption of the LC is 21.28% of the input signal power at 60 GHz. Further investigation is performed to quantify the impacts of dielectric substrate thicknesses (PCB and LC) on the wave-occupied volume ratio (and hence the phase tuning range), as well as on dissipative losses (including conductor loss and dielectric loss). Specifically, conductor loss is observed to follow a linear relationship with the reciprocal of the LC thickness.

Orientation Behavior of Nematic Liquid Crystals at Flow-Wall Interfaces in Microfluidic Channels

This work characterizes the orientation behavior of nematic liquid crystals in pressure-driven flows of microfluidic channels at interfaces between the flow and microchannel walls. The impact of flow velocity and microchannel geometry on the orientation of liquid crystals in single-phase and two-phase flows is discussed. Polarizing optical microscopy images revealed the homeotropic orientation of liquid crystal molecules at microchannel walls at zero flow velocities, which gradually transitioned into planar alignment along the microchannel axis when the flow velocity increased in the 50 μm/s to 5 mm/s range. Liquid crystal droplets demonstrated homeotropic or planar alignment depending on the sizes of droplets and flow velocities. The polarized light pattern from homeotropically aligned droplets deposited on microchannel walls was found to be logarithmically proportional to the flow velocity in the 2 to 40 mm/s range. The revealed behavior of nematic liquid crystals at microchannel wall surfaces in dynamic flow conditions offers new tools for on-demand control of the optical properties of microfluidic devices and can contribute to the development of analytical lab-on-chip tools with internal continuous or discrete liquid crystal layers for flow characterization in microchannel confinement.

Tuneable optical diffractive structures from liquid crystalline materials incorporated into periodic polymeric scaffolds

ABSTRACTDiffractive optical elements (DOEs) are micro-structured components used in various photonic devices to manipulate propagation direction and often also polarisation state of optical beams. The simplest type of DOEs are one-dimensional diffraction gratings. We perform theoretical investigation of electrical and magnetic tunability of such gratings composed as a periodic assembly of polymer and ferromagnetic nematic liquid crystal (LC) layers. We analyse how various grating parameters and boundary conditions influence the LC configuration in the assembly. For static response to external electric and/or magnetic fields, the distortion profile of the director field is determined numerically and analytically by minimisation of the Landau-de Gennes free energy, while for the dynamic response only numerical solutions are provided. The resulting optical diffraction properties are determined numerically via solving the Maxwell’s equations by using the rigorous coupled-wave analysis. We demonstrate that the described methodology provides an efficient tool for designing various new types of polarisation-sensitive LC-based DOEs, such as three-state polarisation switches for application in spectroscopic, optical communication, and remote sensing systems.

Optical Tamm states in a hybrid structure with a holographic polymer-liquid crystal grating

ABSTRACT The reflection spectrum of a hybrid structure formed by a metal film and a holographic grating consisting of a sequence of polymer and liquid crystal (LC) layers is theoretically studied. It is shown that in such a hybrid structure, a narrow dip in the reflection spectrum appears in the region of the grating band gap, which is associated with the formation of an optical Tamm state (OTS). The spectral position of the reflection dip depends on the parameters of the polymer and LC. The type of metal and its thickness affect the value of the OTS reflection dip, but they do not affect its spectral position. The dependence of the OTS wavelength on the LC director orientation makes it possible to control the spectral position of the reflection dip using an external electric or magnetic field.

A Low-Loss Defected-Ground-Structure Based Phase Shifter and Antenna on a 4-μm Thin Liquid Crystal Layer

In this paper, a liquid crystal (LC) phase shifter is proposed using a defected-ground-structure (DGS) transmission line on a 4-μm-thin LC layer. The DGS transmission line is a modified micro-strip line that improves phase shift and loss in a 4-μm-thin LC layer by partially removing the ground plane. The phase shift is achieved through the variation of the LC dielectric constant caused by the bias voltage of the DGS transmission line. The proposed DGS phase shifter exhibits the highest figure-of-merit (FoM) of 61.5°/dB at 30 GHz. Furthermore, the phase shifter exhibits an rms phase error of less than 20° at 26-30 GHz and a 1-dB compression point of 30 dBm with 2.5° phase error at 35 dBm. To demonstrate the feasibility of the LC-based antenna array systems, the DGS phase shifter is combined with a patch antenna, resulting in a gain of 0 dBi and 360° phase shift at 18 GHz. The thin LC layer and high FoM make the proposed DGS phase shifter a suitable solution for use in large phased array systems and reconfigurable intelligent surfaces.

LCP /TLC based composite multi-dimensional polarization-dependent anti-counterfeiting device

Modern anti-counterfeiting technology can effectively suppress and combat forgery and counterfeiting behaviors, which is of great significance in information security, national defense and economy. However, the realization of multi-dimensional, integrated, difficult-to-copy and easy-to-detect optical anti-counterfeiting devices is still a challenge. In this paper, a multi-dimensional and polarization-dependent anti-counterfeiting device with structure color is designed, which is composed of patterned liquid crystal polymer (LCP) nematic layer and thermotropic cholesteric liquid crystal (TLC) layer. It has the advantages of displaying and hiding polarization states, wide color tuning range, convenient operation, high integration and security. For incident light with a specific polarization state, the patterned nematic phase LCP layer can carry out regionalized phase editing and polarization state modulation, while the TLC layer can selectively reflect the incident light. Therefore, a patterned structural color security label is subtly realized. The anti-counterfeiting device can realize the display, hiding, color adjustment and image/background conversion of patterns by adjusting the polarization direction of incident light. In addition, the TLC layer in the device can meet the application requirements of the anti-counterfeit device at different environmental temperatures through the flexible design of the system weight ratio. Furthermore, the device can be easily heated by body temperature, realize dynamic real-time wide-spectrum color modulation and reversible pattern erasure, and further enhance its security dimension and security. The multi-polarization-type anti-counterfeiting device has three-dimensional anti-counterfeiting efficacy. The first dimensional anti-counterfeiting efficacy is achieved by the thermochromic liquid crystal layer. The thermochromic liquid crystal layer has no reflection color outside the operating temperature range of TLC material, and the entire device displays black background. The second and the third dimensional anti-counterfeiting efficacy are related to the polarization state of the incident light and the linear polarization direction, respectively. Only when the incident light is linearly polarized light and its polarization direction makes an angle of 45° or –45° with respect to the optical axis of the liquid crystal, will the device show the designed pattern. Consequently, our proposed anti-counterfeiting device is expected to provide a new idea for developing the anti-counterfeiting field.

Photo-reconfigurable and electrically switchable spatial terahertz wave modulator [Invited

Spatial terahertz wave modulators that can arbitrarily tailor the electromagnetic wavefront are in high demand in nondestructive inspections and high-capacity wireless communications. Here, we propose a liquid crystal integrated metadevice. It modulates the terahertz wave based on the adjustable electromagnetically induced transparency analog when spatially changing the environmental refractive index. The functions of the device can be arbitrarily programmed via photo-reorienting the directors of liquid crystals with a digital micromirror device-based exposing system. The thin liquid crystal layer can be further driven by an electric field, and thus the function can be rapidly switched. Amplitude modulation and the lens effect are demonstrated with modulation depths over 50% at 0.94 THz.

High phase retardation polarization-independent liquid crystal devices

A polarization-independent single-layer liquid crystal (LC) device is demonstrated for high optical phase retardation. Using a single LC layer with twist angles of an integer multiple of 180°, the LC device shows good polarization independence. As the phase retardation increases with the decrease of the twist angle, the LC device with a single LC layer of 180°twist angle may get the highest polarization-independent phase retardation when the polarization dependence is less than 15%. Compared with OCB and ECB modes, the LC device with a twist angle of 180°has a larger field of view (FoV). The simple structure LC device shows a great application for display, optical communication and imaging systems.