Increased wear in methanol fuelled engines has been observed, especially at low operating temperatures. Combustion intermediates, for instance formic acid, are believed to promote wear in the piston ring/cylinder liner assembly. In this study, tribological effects of methanol and formic acid were investigated in a model system. The study was focused on the running-in process under normal conditions and how the running-in was affected by the presence of methanol and formic acid in oils with different lubricant additives. The study showed that a tribosystem with the anti-wear additive ZDDP (zinc dialkyldithiophosphate) had the ability to redistribute the surface layer. After an initial phase of large wear, this redistribution process resulted in a surface film with excellent wear resistance. Adding methanol and formic acid contaminants to this lubricant disturbed the film formation process and a higher steady state wear was observed. A more fully formulated lubricant, with detergent and dispersant, could better withstand these contaminants even though a rise in the steady state wear rate was found in experiments performed at room temperature.
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